公开(公告)号：US3935146A

公开(公告)日：1976-01-27

申请号：US452153

申请日：1974-03-18

申请人： Klaus Noll ,  Walter Schroer ,  Josef Pedain ,  Helmut Reiff

发明人： Klaus Noll ,  Walter Schroer ,  Josef Pedain ,  Helmut Reiff

IPC分类号： D06N3/14 ,  C08G18/00 ,  C08G18/10 ,  C08G18/50 ,  C08G18/60 ,  C08G18/77 ,  C09D175/04 ,  D21H19/24 ,  C08G18/12

CPC分类号： C08G18/771 ,  C08G18/10 ,  C08G18/5042 ,  C08G18/60 ,  Y10S428/904

摘要： A polyurethaneamide containing ethylene oxide units and adapted to be dispersed in water without added emulsifiers and dispersions containing them are provided. The novel dispersions produce coatings on leather and other substrates having an improved glossy appearance.

摘要翻译： 提供含有环氧乙烷单元并适于分散在水中而不添加乳化剂和含有它们的分散体的聚氨酯酰胺。 新型分散体在具有改善的光泽外观的皮革和其它基材上产生涂层。

公开(公告)号：US4876302A

公开(公告)日：1989-10-24

申请号：US284970

申请日：1988-12-15

申请人： Klaus Noll ,  Wilhelm Thoma ,  Klaus Nachtkamp ,  Walter Schroer ,  Josef Pedain

发明人： Klaus Noll ,  Wilhelm Thoma ,  Klaus Nachtkamp ,  Walter Schroer ,  Josef Pedain

IPC分类号： C08L75/04 ,  C08G18/00 ,  C08G18/08 ,  C08G18/12 ,  C08G18/66 ,  C08G18/72 ,  C08G18/73 ,  C08G18/75 ,  C08J7/04 ,  C08L75/00 ,  C09D175/00 ,  C09D175/04 ,  C09D175/06 ,  C09D175/12

CPC分类号： C09D175/06 ,  C08G18/0819 ,  C08G18/12 ,  C08G18/6644 ,  C08G18/6659 ,  C08G18/722 ,  C08J7/047 ,  C08J2475/00

摘要： The present invention is directed to aqueous coating compositions suitable for use as coating and finishing agents for surface coatings, preferably PVC or polyurethane coatings, based on sedimentation-stable polyurethane dispersions having a solids content of about 10-70% by weight wherein the polyurethane-urea solids material is based on polyester diols, low molecular weight diols and optionally triols, chemically incorporated hydrophilic groups, specific mixtures of diisocyanates and polyamine chain extenders having an average functionality of greater than 2 and wherein the aqueous preparations additionally contain alkoxylated dimethyl-polysiloxanes and water-soluble polyethylene oxides. The present invention is also directed to a process for applying top coats and finishes to surface coatings, preferably PVC or polyurethane surface coatings, wherein the above-described aqueous coating and finishing agents are used as the top coat and the coatings are cured at about 70.degree.-170.degree. C.

摘要翻译： 本发明涉及适用于基于沉积稳定的聚氨酯分散体的表面涂层（优选PVC或聚氨酯涂层）的涂层和整理剂的水性涂料组合物，其中固体含量为约10-70％（重量），其中聚氨酯 - 脲固体材料基于聚酯二醇，低分子量二醇和任选的三醇，化学引入的亲水基团，二异氰酸酯的特定混合物和平均官能度大于2的多胺扩链剂，其中所述水性制剂另外含有烷氧基化二甲基 - 聚硅氧烷， 水溶性聚环氧乙烷。 本发明还涉及一种将表面涂层和表面涂层施用于表面涂层，优选PVC或聚氨酯表面涂层的方法，其中上述水性涂料和整理剂用作顶涂层，并且涂层在约70℃下固化 DEG-170℃

公开(公告)号：US4652466A

公开(公告)日：1987-03-24

申请号：US841492

申请日：1986-03-19

申请人： Wilhelm Thoma ,  Klaus Noll ,  Klaus Nachtkamp ,  Josef Pedain ,  Walter Schroer

发明人： Wilhelm Thoma ,  Klaus Noll ,  Klaus Nachtkamp ,  Josef Pedain ,  Walter Schroer

IPC分类号： C08G18/08 ,  C08G18/12 ,  C08G18/42 ,  C08G18/44 ,  C08G18/66 ,  C08G18/72 ,  C08G18/75 ,  C08J7/04 ,  B05D5/00

CPC分类号： C08G18/0804 ,  C08G18/12 ,  C08G18/42 ,  C08G18/4238 ,  C08G18/44 ,  C08G18/6644 ,  C08G18/722 ,  C08G18/75 ,  C08J7/047 ,  C08J2327/06 ,  Y10T428/3158

摘要： This invention relates to coating compositions based on aqueous polyurethane dispersions, as well as the use of the coating compositions for the production of top coats or finishes on flexible substrates, particularly on PVC. The present coating agents contain an aqueous polyurethane dispersion having certain physico-chemical properties and the following composition of the solid substance:(A) from about 30 to 60%, by weight, of a hexane diol-1,6-polyester diol having a molecular weight of from about 500 to 6000;(B) up to about 8%, by weight, of a relatively low molecular weight triol having a molecular weight of from about 91 to 399;(C) from about 3 to 30%, by weight, of one or more mono- or poly-functional compounds bearing cationic and/or anionic groups and/or containing non-ionic polyoxyethylene segments;(D) from about 20 to 50%, by weight, of a diisocyanate corresponding to the following general formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents hydrogen or a straight- or branched-chain aliphatic hydrocarbon radical containing from 1 to 4 carbon atoms;(E) from about 2.5 to 20%, by weight, of other aliphatic and/or cycloaliphatic diisocyanates; and(F) from about 0.5 to 4%, by weight, of hydrazine; and optionally conventional additives, auxiliaries and catalysts.

摘要翻译： 本发明涉及基于水性聚氨酯分散体的涂料组合物，以及用于在柔性基材上，特别是PVC上生产顶涂层或表面处理剂的涂料组合物的用途。 本发明的涂层剂含有具有一定物理化学性质和以下固体物质组成的水性聚氨酯分散体：（A）约30至60重量％的己二醇-1,6-聚酯二醇，其具有 分子量为约500至6000; （B）至多约8重量％的分子量为约91至399的较低分子量三醇; （C）约3至30重量％的一种或多种带有阳离子和/或阴离子基团和/或含有非离子聚氧乙烯链段的单官能或多官能化合物; （D）约20至50重量％的对应于以下通式的二异氰酸酯：其中R 1，R 2和R 3可以相同或不同，各自表示氢或直链或支链 含有1至4个碳原子的链脂族烃基; （E）约2.5至20重量％的其它脂族和/或脂环族二异氰酸酯; 和（F）约0.5至4重量％的肼; 和任选的常规添加剂，助剂和催化剂。

公开(公告)号：US4594385A

公开(公告)日：1986-06-10

申请号：US411137

申请日：1982-08-24

申请人： Wilhelm Thoma ,  Klaus Noll ,  Klaus Nachtkamp ,  Josef Pedain ,  Walter Schroer

发明人： Wilhelm Thoma ,  Klaus Noll ,  Klaus Nachtkamp ,  Josef Pedain ,  Walter Schroer

IPC分类号： C08G18/08 ,  C08G18/12 ,  C08G18/42 ,  C08G18/44 ,  C08G18/66 ,  C08G18/72 ,  C08G18/75 ,  C08J7/04 ,  C08L75/00

CPC分类号： C08G18/0804 ,  C08G18/12 ,  C08G18/42 ,  C08G18/4238 ,  C08G18/44 ,  C08G18/6644 ,  C08G18/722 ,  C08G18/75 ,  C08J7/047 ,  C08J2327/06 ,  Y10T428/3158

摘要： This invention relates to coating compositions based on aqueous polyurethane dispersions, as well as the use of the coating compositions for the production of top coats or finishes on flexible substrates, particularly on PVC. The present coating agents contain an aqueous polyurethane dispersion having certain physico-chemical properties and the following composition of the solid substance:(A) from about 30 to 60%, by weight, of a hexane diol-1,6-polyester diol having a molecular weight of from about 500 to 6000;(B) up to about 8%, by weight, of a relatively low molecular weight triol having a molecular weight of from about 91 to 399;(C) from about 3 to 30%, by weight, of one or more mono- or poly-functional compounds bearing cationic and/or anionic groups and/or containing non-ionic polyoxyethylene segments;(D) from about 20 to 50%, by weight, of a diisocyanate corresponding to the following general formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents hydrogen or a straight- or branched-chain aliphatic hydrocarbon radical containing from 1 to 4 carbon atoms;(E) from about 2.5 to 20%, by weight, of other aliphatic and/or cycloaliphatic diisocyanates; and(F) from about 0.5 to 4%, by weight, of hydrazine; and optionally conventional additives, auxiliaries and catalysts.

公开(公告)号：US4728542A

公开(公告)日：1988-03-01

申请号：US874326

申请日：1986-06-13

申请人： Klaus Nachtkamp ,  Wilhelm Thoma ,  Josef Pedain ,  Walter Schroer ,  Rolf Langel ,  Klaus Noll

发明人： Klaus Nachtkamp ,  Wilhelm Thoma ,  Josef Pedain ,  Walter Schroer ,  Rolf Langel ,  Klaus Noll

IPC分类号： C08G18/08 ,  C08G18/40 ,  C08G18/61 ,  C09D5/00 ,  C09D175/00 ,  C09D175/04 ,  C14C11/00 ,  D06M13/02 ,  D06M13/07 ,  D06M13/224 ,  D06M15/564 ,  D06N3/14 ,  B05D3/02 ,  C08F8/30 ,  C08F283/04

CPC分类号： D06N3/14 ,  C08G18/0804 ,  C08G18/4009 ,  C08G18/61 ,  C09D175/04 ,  C14C11/006

摘要： The present invention is directed to the preparation of optionally pigmented spreading paste based on multiphase mixtures of ionically-modified polyurethanes and/or polyurethane ureas which are prepared from special synthesis components based on silicone resins, aromatic hydroxypolyethers, aromatichydroxy polyesters, and perfluorocarbon resins, the multiphase mixtures additionally containing water and organic solvents for the polyurethanes and/or polyurethane ureas. The present invention is also directed to the preparation of these optionally pigmented spreading pastes and to their use for the production of coatings permeable to water vapor on fabric or leather substrates by the direct or transfer method using the technique of evaporation.

摘要翻译： 本发明涉及基于由基于有机硅树脂，芳族羟基聚醚，芳基三羟基聚酯和全氟化碳树脂的特殊合成成分制备的基于离子改性聚氨酯和/或聚氨酯脲的多相混合物的任意着色的铺展浆料的制备， 多相混合物另外含有聚氨酯和/或聚氨酯脲的水和有机溶剂。 本发明还涉及这些任选着色的铺展糊剂的制备及其用于通过使用蒸发技术的直接或转移方法生产可渗透织物或皮革基底上的水蒸汽的涂层。

公开(公告)号：US4308184A

公开(公告)日：1981-12-29

申请号：US25152

申请日：1979-03-29

申请人： Wilhelm Thoma ,  Gerhard Berndt ,  Josef Pedain ,  Walter Schroer ,  Waldemar Kling

发明人： Wilhelm Thoma ,  Gerhard Berndt ,  Josef Pedain ,  Walter Schroer ,  Waldemar Kling

IPC分类号： C09D175/04 ,  D06N3/14 ,  C08L75/04

CPC分类号： D06N3/142 ,  C09D175/04 ,  Y10S428/904 ,  Y10T428/31591

摘要： The present disclosure is concerned with solvent free or very low solvent coating compositions suitable for use on flexible sheet form substrates particularly textile substrates. The composition comprises a urethane group-containing prepolymer with OH or CONH.sub.2 terminal groups mixed with a urea or melamine formaldehyde resin and a stable aqueous polymer dispersion or solution. The composition may also contain small amounts of an organic solvent. The coating can be applied to the substrate by direct or reverse coating techniques.

摘要翻译： 本公开涉及适用于柔性片状基材，特别是纺织品基材的无溶剂或非常低溶剂涂料组合物。 该组合物包含与尿素或三聚氰胺甲醛树脂混合的OH或CONH 2端基和稳定的含水聚合物分散体或溶液的含氨基甲酸酯基的预聚物。 组合物还可以含有少量的有机溶剂。 可以通过直接或反向涂布技术将涂层施加到基底上。

公开(公告)号：US4743470A

公开(公告)日：1988-05-10

申请号：US829892

申请日：1986-02-18

申请人： Klaus Nachtkamp ,  Wilhelm Thoma ,  Josef Pedain ,  Walter Schroer ,  Rolf Langel

发明人： Klaus Nachtkamp ,  Wilhelm Thoma ,  Josef Pedain ,  Walter Schroer ,  Rolf Langel

IPC分类号： C08J7/04 ,  C08G18/00 ,  C08G18/04 ,  C08G18/08 ,  C08G18/38 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/61 ,  C08L75/00 ,  C09D175/00 ,  C09D175/04 ,  C14C11/00 ,  D06M13/02 ,  D06M13/224 ,  D06M13/325 ,  D06M13/338 ,  D06M15/256 ,  D06M15/263 ,  D06M15/507 ,  D06M15/53 ,  D06M15/564 ,  D06M15/568 ,  D06M15/576 ,  D06M15/61 ,  D06M15/643 ,  D06N3/14 ,  D06M15/572 ,  D06M15/653

CPC分类号： D06N3/142 ,  C08G18/3861 ,  C08G18/4018 ,  C08G18/4202 ,  C08G18/4211 ,  C08G18/4879 ,  C08G18/61 ,  C09D175/04 ,  C14C11/006 ,  D06N3/14 ,  D06N3/141 ,  Y10T428/31558 ,  Y10T442/2861 ,  Y10T442/2893

摘要： This invention relates to spreading pastes containing polyurethanes which are prepared from special synthesis components selected from the group of silicone resins, polyethers or polyesters containing aromatic segments or perfluorocarbon resins. The spreading pastes also contain organic solvents and optionally non-solvents for the polyurethanes so that when the coatings are used to coat textile substrates according to the direct or transfer process, the coatings may be cured based on the principle of evaporation coagulation.

摘要翻译： 本发明涉及由含有聚硅氧烷树脂，聚醚或含有芳族链段或全氟化碳树脂的聚酯组成的特殊合成成分制备的含有聚氨酯的铺展浆料。 铺展的糊料还含有有机溶剂和任选的用于聚氨酯的非溶剂，使得当根据直接或转移过程将涂层用于涂覆织物基材时，可以基于蒸发凝结原理固化涂层。

公开(公告)号：US4935485A

公开(公告)日：1990-06-19

申请号：US292695

申请日：1989-01-03

申请人： Josef Pedain ,  Wilhelm Thoma ,  Walter Schroer ,  Waldemar Kling

发明人： Josef Pedain ,  Wilhelm Thoma ,  Walter Schroer ,  Waldemar Kling

IPC分类号： B32B27/12 ,  C08G18/10 ,  C08G18/12 ,  C08G18/32 ,  C08G18/48 ,  C08G18/65 ,  C08G18/80 ,  C09D175/00 ,  C09D175/04 ,  C09D175/08 ,  D06M15/564 ,  D06N3/14

CPC分类号： D06N3/14 ,  C08G18/10 ,  C08G18/12 ,  C08G18/4833

摘要： The present invention is directed to a heat hardenable coating composition containing(A) a prepolymer containing an average of 2-4 ketoxime-blocked isocyanate groups, having an average molecular weight of about 500 to 15,000 and based on an aromatic polyisocyanate and a polyhydroxyl component which contains about 20-100% by weight of ethylene oxide units and(B) a cross-linking agent corresponding to the following formula ##STR1## in which R and R.sup.1 denote H or C.sub.1 -C.sub.4 -alkyl, the equivalent ratio of blocked isocyanate groups in (A) to NH.sub.2 groups in (B) being about 1.35:1 to 0.95:1.The invention is also directed to the coated substrates obtained from the compositions according to the invention.

摘要翻译： 本发明涉及一种热硬化涂料组合物，其包含（A）含有平均2-4个酮肟嵌段异氰酸酯基团的预聚物，其平均分子量为约500至15,000，基于芳族多异氰酸酯和多羟基组分 其包含约20-100重量％的环氧乙烷单元和（B）对应于下式的IMAAG的交联剂，其中R和R 1表示H或C 1 -C 4烷基，封端异氰酸酯的当量比 （A）中的（A）中的NH 2基团的基团为约1.35：1至0.95：1。 本发明还涉及由根据本发明的组合物获得的涂覆基材。

公开(公告)号：US4675211A

公开(公告)日：1987-06-23

申请号：US599112

申请日：1984-04-11

申请人： Wilhelm Thoma ,  Josef Pedain ,  Walter Schroer

发明人： Wilhelm Thoma ,  Josef Pedain ,  Walter Schroer

IPC分类号： C08G18/32 ,  C08G18/38 ,  D06N3/14 ,  B05D5/10

CPC分类号： C08G18/3206 ,  C08G18/3221 ,  C08G18/3823 ,  D06N3/14

摘要： This invention relates to a process for multiple-coat reverse coating using at least two different polyurethane coating solutions, all the coating solutions containing one and the same polar solvent, preferably substantially anhydrous dimethyl formamide. By choosing(A) surface-coat polyurethane solutions specially made up using high-melting diol chain-extending agents and by using(B) highly concentrated adhesive-coat polyurethane solutions containing at least 40% by weight of polyurethane,it is possible to effectively prevent the so-called "frostwork effect" when applying the adhesive coat to the surface coat (A) by the reverse coating process and the troublesome "overlamination" off the web-form textile during its lamination onto the PU-layers formed by reverse coating. In addition, recovery of the solvent from the coating solutions is simplified.

摘要翻译： 本发明涉及一种使用至少两种不同的聚氨酯涂层溶液进行多层反涂的方法，所有涂层溶液都含有一种相同的极性溶剂，优选基本上无水的二甲基甲酰胺。 通过选择（A）使用高熔点二醇增链剂特别制成的（A）表面涂层聚氨酯溶液，并且使用（B）含有至少40重量％聚氨酯的高浓度粘合剂涂层聚氨酯溶液，可以有效地 当通过反向涂布法将粘合剂涂层施加到表面涂层（A）上时，防止所谓的“霜冻效应”，并且在层压到网状织物上的麻烦的“叠层”到由反涂层形成的PU层上 。 此外，简化了溶剂从涂布溶液的回收。

公开(公告)号：US4401801A

公开(公告)日：1983-08-30

申请号：US408371

申请日：1982-08-16

申请人： Josef Pedain ,  Wilhelm Thoma ,  Jurgen Grammel ,  Walter Schroer

发明人： Josef Pedain ,  Wilhelm Thoma ,  Jurgen Grammel ,  Walter Schroer

IPC分类号： C08G18/12 ,  C08G18/40 ,  C08G18/42 ,  C08G18/75 ,  C14C11/00 ,  D06N3/14 ,  C08G18/65

CPC分类号： D06N3/14 ,  C08G18/12 ,  C08G18/4018 ,  C08G18/4202 ,  C08G18/75 ,  C14C11/006

摘要： This invention relates to coating agents and dressing agents for leather and leather substitutes with improved resistance to plasticizer migration, greater hardness and folding strength, a dry hand and resistance to aqueous alcoholic solutions, based on linear or only slightly branched thermoplastic polyurethane ureas built up from the following components(A) at least two macrodiols in a molar ratio of from about 1:6 to 6:1, one of which macrodiols(1) has an average molecular weight of from about 254 to 650 and contains at least one benzene, cyclohexane or cyclohexene ring, while(2) the second macrodiol has an average molecular weight in the range of from about 1200 to 3000 but has at least three times the molecular weight of A/l, and which contain(B) from about 0.5 to 11 mol of chain lengthening agent per mol of macrodiol mixture, at least about 50 mol % of the chain lengthening agents used being aliphatic and/or cycloaliphatic diamines and/or hydrazine,and in which(C) the diisocyanates used are cycloaliphatic diisocyanates, up to about 50 mol % of which may be replaced by aliphatic and/or aromatic diisocyanates.

摘要翻译： 本发明涉及用于皮革和皮革代用品的涂料和改性剂，其具有改善的耐增塑剂迁移性，更高的硬度和折叠强度，干手和耐醇水溶液，基于线性或仅轻微分支的热塑性聚氨酯脲，其由 以下组分（A）至少两种摩尔比为约1:6至6:1的大分子二醇，其中一个大分子二醇（1）的平均分子量为约254至650，并含有至少一个苯， 环己烷或环己烯环，而（2）第二大二茂醇的平均分子量为约1200-3000，但具有至少三倍于A / l的分子量，并且含有（B）约0.5至 每摩尔大分子二醇混合物使用11摩尔的链延长剂，至少约50摩尔％的使用的链增长剂是脂族和/或脂环族二胺和/或肼，其中（C）二异氰酸酯 使用的氰酸酯是脂环族二异氰酸酯，其中最多约50mol％可以被脂族和/或芳族二异氰酸酯代替。