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公开(公告)号：US09303096B2
公开(公告)日：2016-04-05
申请号：US12799153
申请日：2010-04-20
Applicant: Herve Adam , Arnaud Cadix , Chi-Thanh Vuong
Inventor： Herve Adam , Arnaud Cadix , Chi-Thanh Vuong
Abstract: A process for the preparation of an elastomer capable of swelling in oil and/or in water and brine comprising the steps of: a) making an aqueous inverse emulsion of particles of a polymer comprising a betaine group prepared by inverse emulsion polymerization of monomers Ab comprising a betaine group, optionally other monomers Ba and a small quantity of polyvalent, preferably divalent or trivalent monomers Ca, comprised in an aqueous phase dispersed in the form of droplets in a hydrophobic external phase having hydrophobic surfactants, the molar ratio of the monomers Ab to the optional monomers Ba being between 4/96 and 40/60, preferably 7/93 and 30/70, the molar ratio of the polyvalent, preferably divalent or trivalent monomers Ca per mole of polymer being between 1.5 and 10, preferably between 2 and 4, and b) compounding said elastomer with the aqueous inverse emulsion obtained by step a).
Abstract translation: 一种制备能够在油和/或水和盐水中溶胀的弹性体的方法，包括以下步骤：a）制备含有通过反相乳液聚合制备的甜菜碱基团的聚合物颗粒的水性反相乳液，所述单体包含 甜菜碱基团，任选的其它单体Ba和少量多价，优选二价或三价单体Ca，其包含在疏水性外相中以水滴形式分散在具有疏水性表面活性剂的水相中，单体Ab与 任选的单体Ba在4/96和40/60之间，优选7/93和30/70，每摩尔聚合物的多价，优选二价或三价单体Ca的摩尔比在1.5和10之间，优选在2和 4，和b）将所述弹性体与通过步骤a）获得的水性反相乳液混合。
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公开(公告)号：US08507624B2
公开(公告)日：2013-08-13
申请号：US13373154
申请日：2011-11-07
Applicant: Hui Shirley Yang , Derek Pakenham , Herve Adam , Pierre Hennaux
Inventor： Hui Shirley Yang , Derek Pakenham , Herve Adam , Pierre Hennaux
IPC: C08F236/20
CPC classification number: C08F220/68 , A61K8/8152 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q19/00 , A61Q19/10 , C07C69/54 , C07C2602/42 , C08F220/26 , C08F220/28 , C08F236/20 , C09K3/00
Abstract: A monomer compound that contains at least one polymerizable functional group per molecule, and at least one bicycloheptyl-, bicycloheptenyl-, or branched (C5-C42)alkyl-polyether radical per molecule, wherein the bicycloheptyl- or bicycloheptenyl-polyether radical may optionally be substituted on one or more of the ring carbon atoms by one or two (C1-C6)alkyl groups per ring carbon atom is useful in making polymers, particularly pH responsive polymers.
Abstract translation: 每分子含有至少一个可聚合官能团的单体化合物，和每分子至少一个双环庚基 - 双环庚烯基 - ，二环庚烯基 - 或支链（C5-C42）烷基 - 聚醚基团，其中双环庚基或双环庚烯基 - 聚醚基团可以任选地为 每个环碳原子在一个或多个环碳原子上被一个或两个（C 1 -C 6）烷基取代，可用于制备聚合物，特别是pH响应聚合物。
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公开(公告)号：US08501860B2
公开(公告)日：2013-08-06
申请号：US13317948
申请日：2011-11-01
Applicant: Hui Shirley Yang , Derek Pakenham , Herve Adam , Pierre Hennaux
Inventor： Hui Shirley Yang , Derek Pakenham , Herve Adam , Pierre Hennaux
CPC classification number: C08F220/68 , A61K8/8152 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q19/00 , A61Q19/10 , C07C69/54 , C07C2602/42 , C08F220/26 , C08F220/28 , C08F236/20 , C09K3/00
Abstract: A monomer compound that contains at least one polymerizable functional group per molecule, and at least one bicycloheptyl-, bicycloheptenyl-, or branched (C5-C42)alkyl-polyether radical per molecule, wherein the bicycloheptyl- or bicycloheptenyl-polyether radical may optionally be substituted on one or more of the ring carbon atoms by one or two (C1-C6)alkyl groups per ring carbon atom is useful in making polymers, particularly pH responsive polymers.
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公开(公告)号：US20120121523A1
公开(公告)日：2012-05-17
申请号：US13373170
申请日：2011-11-07
Applicant: Hui Shirley Yang , Derek Pakenham , Herve Adam , Pierre Hennaux , Brian Chung , Subramanian Kesavan , Seren Frantz
Inventor： Hui Shirley Yang , Derek Pakenham , Herve Adam , Pierre Hennaux , Brian Chung , Subramanian Kesavan , Seren Frantz
CPC classification number: C08F220/68 , A61K8/8152 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q19/00 , A61Q19/10 , C07C69/54 , C07C2602/42 , C08F220/26 , C08F220/28 , C08F236/20 , C09K3/00
Abstract: A monomer compound that contains at least one polymerizable functional group per molecule, and at least one bicycloheptyl-, bicycloheptenyl-, or branched (C5-C42)alkyl-polyether radical per molecule, wherein the bicycloheptyl- or bicycloheptenyl-polyether radical may optionally be substituted on one or more of the ring carbon atoms by one or two (C1-C6)alkyl groups per ring carbon atom is useful in making polymers, particularly pH responsive polymers.
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公开(公告)号：US20110257333A1
公开(公告)日：2011-10-20
申请号：US12799153
申请日：2010-04-20
Applicant: Herve Adam , Arnaud Cadix , Chi-Thanh Vuong
Inventor： Herve Adam , Arnaud Cadix , Chi-Thanh Vuong
Abstract: A process for the preparation of an elastomer capable of swelling in oil and/or in water and brine comprising the steps of: a) making an aqueous inverse emulsion of particles of a polymer comprising a betaine group prepared by inverse emulsion polymerization of monomers Ab comprising a betaine group, optionally other monomers Ba and a small quantity of polyvalent, preferably divalent or trivalent monomers Ca, comprised in an aqueous phase dispersed in the form of droplets in a hydrophobic external phase having hydrophobic surfactants, the molar ratio of the monomers Ab to the optional monomers Ba being between 4/96 and 40/60, preferably 7/93 and 30/70, the molar ratio of the polyvalent, preferably divalent or trivalent monomers Ca per mole of polymer being between 1.5 and 10, preferably between 2 and 4, and b) compounding said elastomer with the aqueous inverse emulsion obtained by step a).
Abstract translation: 一种制备能够在油和/或水和盐水中溶胀的弹性体的方法，包括以下步骤：a）制备含有通过反相乳液聚合制备的甜菜碱基团的聚合物颗粒的水性反相乳液， 甜菜碱基团，任选的其它单体Ba和少量多价，优选二价或三价单体Ca，其包含在疏水性外相中以水滴形式分散在具有疏水性表面活性剂的水相中，单体Ab与 任选的单体Ba在4/96和40/60之间，优选7/93和30/70，每摩尔聚合物的多价，优选二价或三价单体Ca的摩尔比在1.5和10之间，优选在2和 4，和b）将所述弹性体与通过步骤a）获得的水性反相乳液混合。
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Patent Agency Ranking
公开(公告)号：US20100273683A1
公开(公告)日：2010-10-28
申请号：US12803386
申请日：2010-06-25
Applicant: Hui Shirley Yang , Derek Pakenham , Herve Adam , Pierre Hennaux , Brian Chung , Subramanian Kesavan , Seren Frantz
Inventor： Hui Shirley Yang , Derek Pakenham , Herve Adam , Pierre Hennaux , Brian Chung , Subramanian Kesavan , Seren Frantz
IPC: A61K8/81 , A61Q5/06 , C07C69/533 , A61Q19/10 , C08F118/02 , C08L33/04 , A61Q5/02 , C11D3/37 , C09D107/02 , C09K8/28 , C09K8/66 , C08L55/00
CPC classification number: C08F220/68 , A61K8/8152 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q19/00 , A61Q19/10 , C07C69/54 , C07C2602/42 , C08F220/26 , C08F220/28 , C08F236/20 , C09K3/00
Abstract: A monomer compound that contains at least one polymerizable functional group per molecule, and at least one bicycloheptyl-, bicycloheptenyl-, or branched (C5-C42)alkyl-polyether radical per molecule, wherein the bicycloheptyl- or bicycloheptenyl-polyether radical may optionally be substituted on one or more of the ring carbon atoms by one or two (C1-C6)alkyl groups per ring carbon atom is useful in making polymers, particularly pH responsive polymers.
Abstract translation: 每分子含有至少一个可聚合官能团的单体化合物，和每分子至少一个双环庚基 - 双环庚烯基 - ，二环庚烯基 - 或支链（C5-C42）烷基 - 聚醚基团，其中双环庚基或双环庚烯基 - 聚醚基团可以任选地为 每个环碳原子在一个或多个环碳原子上被一个或两个（C 1 -C 6）烷基取代，可用于制备聚合物，特别是pH响应聚合物。
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27.发明授权Addition of nonionic surfactants to water soluble block copolymers to increase the stability of the copolymer in aqueous solutions containing salt and/or surfactants 有权向水溶性嵌段共聚物中加入非离子表面活性剂以增加共聚物在含有盐和/或表面活性剂的水溶液中的稳定性公开(公告)号：US07789160B2
公开(公告)日：2010-09-07
申请号：US12253934
申请日：2008-10-17
Applicant: Lawrence Alan Hough , Gilda Maria Lizarraga , Herve Adam , Jean-Christophe Castaing , Subramanian Kesavan
Inventor： Lawrence Alan Hough , Gilda Maria Lizarraga , Herve Adam , Jean-Christophe Castaing , Subramanian Kesavan
CPC classification number: C09K8/584 , C04B2103/0052 , C04B2103/0053 , C04B2103/0061 , C09K8/44 , C09K8/588 , C09K8/68 , C09K2208/30
Abstract: An aqueous fluid useful for the recovery of crude oil from a subterranean formation, which includes a composition including a mixture of water, a water soluble block copolymer, an inorganic salt and at least one member of the group of a nonionic surfactant having an HLB of less than 12, and methods for using same.
Abstract translation: 一种用于从地层中回收原油的水性流体，其包括包含水，水溶性嵌段共聚物，无机盐和HLB的非离子表面活性剂组中的至少一种的混合物的组合物 小于12，使用方法。
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28.发明申请公开(公告)号：US20090149557A1
公开(公告)日：2009-06-11
申请号：US12319440
申请日：2009-01-07
Applicant: Ruela Talingting-Pabalan , Gary Woodward , Manilal S. Dahanayake , Herve Adam
Inventor： Ruela Talingting-Pabalan , Gary Woodward , Manilal S. Dahanayake , Herve Adam
IPC: B01D17/05
CPC classification number: B01D17/047
Abstract: Demulsifiers containing an anionic surfactant selected from alkylsulfosuccinates, alkylphosphonic acids, and their salts; a nonionic surfactant selected from ethylene oxide/propylene oxide copolymers, ethoxylated fatty acids of polyethylene glycol, terpene alkoxylates, and modified alkanolamides; and solvent bases comprising blends of dibasic esters. Methods for breaking emulsions using such demulsifiers and solvent bases are also disclosed.
Abstract translation: 含有选自烷基磺基琥珀酸盐，烷基膦酸及其盐的阴离子表面活性剂的破乳剂; 选自环氧乙烷/环氧丙烷共聚物，聚乙二醇的乙氧基化脂肪酸，萜烯烷氧基化物和改性链烷醇酰胺的非离子表面活性剂; 和包含二元酯共混物的溶剂基料。 还公开了使用这种破乳剂和溶剂基来破乳的方法。
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公开(公告)号：US20060270563A1
公开(公告)日：2006-11-30
申请号：US11443919
申请日：2006-05-31
Applicant: Hui Yang , Derek Pakenham , Herve Adam , Pierre Hennaux , Brian Chung , Subramanian Kesavan , Seren Frantz
Inventor： Hui Yang , Derek Pakenham , Herve Adam , Pierre Hennaux , Brian Chung , Subramanian Kesavan , Seren Frantz
CPC classification number: C08F220/68 , A61K8/8152 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q19/00 , A61Q19/10 , C07C69/54 , C07C2602/42 , C08F220/26 , C08F220/28 , C08F236/20 , C09K3/00
Abstract: A monomer compound that contains at least one polymerizable functional group per molecule, and at least one bicycloheptyl-, bicycloheptenyl-, or branched (C5-C42)alkyl-polyether radical per molecule, wherein the bicycloheptyl- or bicycloheptenyl- polyether radical may optionally be substituted on one or more of the ring carbon atoms by one or two (C1-C6)alkyl groups per ring carbon atom is useful in making polymers, particularly pH responsive polymers.
Abstract translation: 每分子含有至少一个可聚合官能团的单体化合物和至少一种双环庚基 - 双环庚烯基 - 或支链（C 5 -C 42 - ）烷基 - 聚醚 其中双环庚基或双环庚烯基 - 聚醚基团可以任选地在一个或多个环碳原子上被一个或两个（C 1 -C 6） ）烷基可用于制备聚合物，特别是pH响应聚合物。
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公开(公告)号：US6124382A
公开(公告)日：2000-09-26
申请号：US029702
申请日：1998-09-08
Applicant: Pascale Corpart , Herve Adam , Dominique Charmot
Inventor： Pascale Corpart , Herve Adam , Dominique Charmot
IPC: C09D7/00 , C09K8/12 , C09K8/24 , C10M119/24 , C10M119/26 , C10M173/02 , C11D3/37 , C08K5/39
CPC classification number: C09K8/12 , C09D7/002 , C09K8/24 , C10M119/24 , C10M119/26 , C10M173/02 , C11D3/37 , C10M2201/02 , C10M2217/00 , C10M2217/02 , C10M2217/04 , C10M2221/00 , C10M2221/04 , C10M2221/041 , C10M2221/043 , C10N2240/06 , C10N2240/08 , C10N2250/02
Abstract: The invention concerns the use as thermothickeners of multi-block copolymers of general formula (I) or (II): ##STR1## wherein E designates a polyoxyalkylene sequence; A designates a water-soluble polymer sequence; X is a sulphur or oxygen atom; Y is an oxygen atom or an --N--R' group, R' being a linear or branched alkyl; R is a linear or branched alkyl, aralky or alkylaryl group; and n is such that the molecular mass of the multi-block copolymers Mp is greater than 250,000 g/mol.
Abstract translation: PCT No.PCT / FR96 / 01373 Sec。 371日期：1998年9月8日 102（e）1998年9月8日PCT PCT 1996年9月6日PCT公布。 出版物WO97 / 09400 日期1997年03月13日本发明涉及作为通式（I）或（II）的多嵌段共聚物的热固化剂的用途：其中E表示聚氧化烯序列; A表示水溶性聚合物序列; X是硫或氧原子; Y是氧原子或-N-R'基团，R'是直链或支链烷基; R是直链或支链烷基，芳烷基或烷基芳基; 并且n使得多嵌段共聚物Mp的分子量大于250,000g / mol。
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