Abstract:
A start-up method for a hydrocarbon synthesis reaction apparatus, comprising: an initial slurry-loading step in which the slurry is loaded into the reactor at the initial stage of the Fischer-Tropsch synthesis reaction at a lower loading rate than that applied to the reactor in a steady-state operation; and a CO conversion ratio-increasing step in which the liquid level of the slurry in the reactor is raised by adding to the slurry the hydrocarbons synthesized at the early stage of the Fischer-Tropsch synthesis reaction so that the CO conversion ratio is increased in proportion to a rise in the liquid level of the slurry in the reactor.
Abstract:
Provided is a hydrotreating step (A) containing a hydroisomerization step (A1) that obtains a hydroisomerized oil (a1) by bringing a FT synthesis oil into contact with a hydroisomerization catalyst and/or a hydrocracking step (A2) that obtains a hydrocracked oil (a2) by bringing it into contact with a hydrocracking catalyst, and a fractionation step (B) that transfers at least a portion of the hydrotreated oil (a) composed of the hydroisomerized oil (a1) and/or the hydrocracked oil (a2) to a fractionator and, at the very least, obtains a middle distillate (b1) with a 5% distillation point of 130 to 170° C. and a 95% distillation point of 240 to 300° C., and a heavy oil (b2) that is heavier than the middle distillate (b1).
Abstract:
A catalyst filling apparatus is for a bubble column slurry bed reactor for the FT synthesis reaction. The apparatus includes: a slurry preparation tank installed adjacent to the reactor and configured to prepare a slurry S from a FT synthesis reaction catalyst and a slurry preparation oil; an upper part communication line configured to direct the slurry from the reactor to the slurry preparation tank; a lower part communication line configured to direct the slurry in the slurry preparation tank to the reactor; and a pressure equalizing line configured to communicate the reactor with the slurry preparation tank. The upper part communication line is downwardly inclined from the reactor toward the slurry preparation tank, and the lower part communication line is upwardly inclined from the reactor toward the slurry preparation tank. An inert gas introduction device is provided on the slurry preparation tank.
Abstract:
There is provided a method for recovering hydrocarbon compounds from a gaseous by-products generated in the Fisher-Tropsch synthesis reaction, the method comprising a pressurizing step in which the gaseous by-products are pressurized, a cooling step in which the pressurized gaseous by-products are pressurized to liquefy hydrocarbon compounds in the gaseous by-products, and a separating step in which the hydrocarbon compounds liquefied in the cooling step are separated from the remaining gaseous by-products.
Abstract:
A method of underground storage of an injection gas containing CO2 gas and enhanced oil recovery includes: supplying injection water through a water flow path; jetting the injection water as a high-pressure water jet which is increased in velocity by narrowing a fluid flow through a fine bubble-generating device placed at a lower end of the water flow path; suctioning an injection gas through a gas flow path by a negative pressure generated by the Venturi effect downstream of the high-pressure water jet; jetting the injection gas as fine bubbles from the fine bubble-generating device placed at a lower end of the gas flow path; and performing underground storage of the injection gas by allowing a gas-liquid mixed fluid containing fine bubbles generated by mixing the injection water with the fine bubbles in the fine bubble-generating device to penetrate into a permeable formation such as an oil reservoir.
Abstract:
A method of underground storage of an injection gas containing CO2 gas and enhanced oil recovery includes: supplying injection water through a water flow path; jetting the injection water as a high-pressure water jet which is increased in velocity by narrowing a fluid flow through a fine bubble-generating device placed at a lower end of the water flow path; suctioning an injection gas through a gas flow path by a negative pressure generated by the Venturi effect downstream of the high-pressure water jet; jetting the injection gas as fine bubbles from the fine bubble-generating device placed at a lower end of the gas flow path; and performing underground storage of the injection gas by allowing a gas-liquid mixed fluid containing fine bubbles generated by mixing the injection water with the fine bubbles in the fine bubble-generating device to penetrate into a permeable formation such as an oil reservoir.
Abstract:
The method enables enhanced recovery of oil contained in an underground oil reservoir by using an injection well including two passages of a water passage and a gas passage. The enhanced oil recovery method includes steps of injecting an injection water from the water passage, injecting an injection gas from the gas passage and spraying the injection gas as a fine gas bubble flow through a micro-bubble generator which is installed at a lower end of the gas passage, and penetrating into the underground oil reservoir a gas-liquid mixture fluid containing micro-bubbles generated by mixing the injection water and the fine gas bubble flow in the injection well.
Abstract:
There is provided a hydrocarbon distillation separation apparatus for fractionally distilling hydrocarbon compounds discharged from a Fisher-Tropsch synthesis reactor synthesizing hydrocarbon compounds, comprising a heavy hydrocarbon fractionator configured to fractionally distil liquid heavy components of the hydrocarbon compounds discharged from the reactor into a first middle distillate and a wax fraction, a light hydrocarbon fractionator configured to fractionally distil gaseous light components of the hydrocarbon compounds discharged from the reactor into a second middle distillate and a light gas fraction, a light hydrocarbon separator configured to separate hydrocarbon compounds equivalent to naphtha from the light gas fraction; and a mixing section configured to mix the first and second middle distillates, and the hydrocarbon compounds equivalent to naphtha separated from the light gas fraction by the light hydrocarbon separator.
Abstract:
A synthesis gas production apparatus (reformer) to be used for a synthesis gas production step in a GTL (gas-to-liquid) process is prevented from being contaminated by metal components. A method of suppressing metal contamination of a synthesis gas production apparatus operating for a GTL process that includes a synthesis gas production step of producing synthesis gas by causing natural gas and gas containing steam and/or carbon dioxide to react with each other for reforming in a synthesis gas production apparatus in which, at the time of separating and collecting a carbon dioxide contained in the synthesis gas produced in the synthesis gas production step and recycling the separated and collected carbon dioxide as source gas for the reforming reaction in the synthesis gas production step, a nickel concentration in the recycled carbon dioxide is not higher than 0.05 ppmv.
Abstract:
A catalyst filling apparatus is for a bubble column slurry bed reactor for the FT synthesis reaction. The apparatus includes: a slurry preparation tank installed adjacent to the reactor and configured to prepare a slurry S from a FT synthesis reaction catalyst and a slurry preparation oil; an upper part communication line configured to direct the slurry from the reactor to the slurry preparation tank; a lower part communication line configured to direct the slurry in the slurry preparation tank to the reactor; and a pressure equalizing line configured to communicate the reactor with the slurry preparation tank. The upper part communication line is downwardly inclined from the reactor toward the slurry preparation tank, and the lower part communication line is upwardly inclined from the reactor toward the slurry preparation tank. An inert gas introduction device is provided on the slurry preparation tank.