Methods for preparation of macrocyclic polyester oligomer via heterogeneous catalysis
    21.
    发明授权
    Methods for preparation of macrocyclic polyester oligomer via heterogeneous catalysis 有权
    通过多相催化制备大环聚酯低聚物的方法

    公开(公告)号:US08829152B2

    公开(公告)日:2014-09-09

    申请号:US13403608

    申请日:2012-02-23

    Abstract: The invention relates to methods and systems for preparing macrocyclic polyester oligomer (MPO) directly from monomer via heterogeneous catalysis, rather than by depolymerizing a polyester. For example, in an exemplary embodiment, cyclic poly(butylene terephthalate) (cPBT) is produced by reacting butanediol (BDO) and dimethylterephthalate (DMT) in an organic solvent—for example, ortho-dichlorobenzene (oDCB). The mixture flows over (or otherwise contacts) the catalyst-coated fiberglass or silica gel, e.g., which is packed in a column or bed. MPO is produced in the reaction mixture, while residual linears and catalyst residue remain in the column/bed.

    Abstract translation: 本发明涉及通过非均相催化从单体直接制备大环聚酯低聚物(MPO)的方法和系统,而不是通过解聚聚酯。 例如,在一个示例性实施方案中,通过在有机溶剂例如邻二氯苯(oDCB)中使丁二醇(BDO)和对苯二甲酸二甲酯(DMT)反应来制备环状聚对苯二甲酸丁二醇酯(cPBT)。 混合物流过(或以其它方式接触)催化剂涂覆的玻璃纤维或硅胶,例如其被包装在柱或床中。 MPO在反应混合物中产生,而残留的线条和催化剂残留物残留在柱/床中。

    Process for recovering sodium nitrite
    25.
    发明授权
    Process for recovering sodium nitrite 失效
    回收亚硝酸钠的方法

    公开(公告)号:US06251354B1

    公开(公告)日:2001-06-26

    申请号:US09285927

    申请日:1999-04-02

    CPC classification number: C01B21/50

    Abstract: The present invention provides a process for recovering a metal nitrite, e.g., sodium nitrite, from a reaction mixture formed from an aromatic displacement reaction such as the synthesis of an aromatic bis(ether phthalimide) in an organic non-polar solvent. The process comprises forming a reaction mixture from the synthesis of an aromatic bis(ether phthalimide) comprising a recoverable amount of metal nitrite; treating the reaction mixture with an amount of water effective to produce an aqueous solution phase of metal nitrite and an organic non-polar phase; and separating the aqueous solution phase of metal nitrite from the organic non-polar phase.

    Abstract translation: 本发明提供了从由有机非极性溶剂中的芳族双(醚邻苯二甲酰亚胺)的合成等芳香置换反应形成的反应混合物中回收亚硝酸金属亚硝酸盐的方法。 该方法包括从合成包含可回收量的金属亚硝酸盐的芳族双(醚邻苯二甲酰亚胺)形成反应混合物; 用有效量的水处理反应混合物以产生金属亚硝酸盐和有机非极性相的水溶液相; 并从有机非极性相分离金属亚硝酸盐的水溶液相。

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