摘要:
The invention is a method of treating exhaust gases generated by an internal combustion engine using a NOx trap in the exhaust flow system. The method comprises locating a nitrogen oxide trap in the exhaust gas passage and cycling the air/fuel ratio of the exhaust gases entering the trap between lean and rich, such that the trap absorbs nitrogen oxides during the lean cycle and desorbs the nitrogen oxides when the concentration of the oxygen in the exhaust flow is lowered as during a rich cycle. The trap comprises: (a) a porous support material comprising mostly &ggr;-alumina; (b) a sulfur-suppressing metal selected from the group consisting of cesium, zinc and a combination of cesium and zinc; (c) a precious metal; and (d) a NOx sorption metal such as barium, the metals being deposited in the support material, the amount of the metals being individually dependent on the weight of the support material. The desorbed nitrogen oxides may be converted over the precious metal to N2 by reductants like hydrogen, hydrocarbon and carbon monoxide present in the exhaust gas.
摘要:
In a furnace having a primary combustion zone for combustion of a fuel and oxidant, an in-furnace method for reducing nitrogen oxides in combustion products generated in the primary combustion zone in which at least one fluid fuel selected from the group consisting of natural gas, hydrogen, CxHy compounds, CxHyOz compounds and mixtures thereof in an amount in a range of about 2.0% to about 25% of a total heat input to the furnace and at least one nitrogenous compound selected from the group consisting of ammonia, amines, urea, cyanuric acid and mixtures thereof are injected into the furnace downstream of the primary combustion zone, forming an overall fuel-lean NOx-reduction zone.
摘要翻译:在具有用于燃烧和氧化剂燃烧的初级燃烧区的炉子中,用于还原在主燃烧区产生的燃烧产物中的氮氧化物的炉内方法,其中至少一种选自天然气, 氢,C x H y化合物,C x H y O z化合物及其混合物,其量为输入炉内总热量的约2.0%至约25%,以及至少一种选自氨,胺,脲, 将氰尿酸及其混合物注入到主燃烧区下游的炉中,形成总体贫燃氮氧化物还原区。
摘要:
The present invention provides an ecofriendly method for preparing dinitramidic acid and its salts by nitration of ammonium sulfamate with fuming nitric acid as a nitrating agent using solid acid catalysts selected from the group consisting of a montmorillonite clay catalyst and metal ion exchanged K10 montmorillonite clay catalysts and surface supported catalysts and preparation of ammonium dinitramide by neutralization of the dinitramidic acid with ammonia and separation of ammonium dinitramide.
摘要:
The present invention provides a process for recovering a metal nitrite, e.g., sodium nitrite, from a reaction mixture formed from an aromatic displacement reaction such as the synthesis of an aromatic bis(ether phthalimide) in an organic non-polar solvent. The process comprises forming a reaction mixture from the synthesis of an aromatic bis(ether phthalimide) comprising a recoverable amount of metal nitrite; treating the reaction mixture with an amount of water effective to produce an aqueous solution phase of metal nitrite and an organic non-polar phase; and separating the aqueous solution phase of metal nitrite from the organic non-polar phase.
摘要:
Calcium nitrate, which is known to have the effect of inhibiting elution of phosphorus contained as insoluble substance in sludge in rivers, lakes and coasts in a reducing environment, can be applied not by injection of an aqueous solution of calcium nitrate, but by putting it in a solid form. An agent for inhibiting elution of phosphorus is proposed which comprises calcium nitrate as the major component (10-30%), calcium carbonate or calcium sulfate (a total of 50-90%), and stearic acid or its salt (1-20%) as a hydrophobic substance for delaying elution of the calcium salt, and sucrose fatty acid isobutyl or paraoxy isobutyl benzoate (1-20%) as a binder, and the composition is pressed in a mold into tablets or briquette. The application into sludge by use of an air gun is preferable.
摘要:
Process for the separation of a hydroxylammonium salt solution from an aqueous reaction mixture comprising solid catalyst particles by means of filtration, wherein cake filtration through an asymmetric filter is applied, the asymmetric filter comprising at least two layers having different pore diameter, at least one layer being a filter layer, the pore diameter of the filter layer being between 0.1 and 10 &mgr;m and the thickness of the filter layer being 10 to 1000 &mgr;m.
摘要:
This invention provides a highly pure and highly concentrated free hydroxylamine aqueous solution substantially not containing any salt or organic substance. This invention is a process for obtaining a free hydroxylamine aqueous solution, comprising the steps of letting an aqueous solution or slurry containing hydroxylammonium sulfate and an alkali react with each other, to obtain an aqueous solution or slurry containing free hydroxylamine and dissolved or partially precipitated sulfates; mixing the obtained reaction solution and a lower alcohol, to precipitate solid sulfates; separating a solution containing the lower alcohol and some of water by distillation from the aqueous solution remaining after separating and removing the solid sulfates; and obtaining a free hydroxylamine aqueous solution from the remaining solution by distillation.