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    Dental materials based on dimer acid derivatives with ring opening polymerizable groups
    23.
    发明授权
    Dental materials based on dimer acid derivatives with ring opening polymerizable groups 有权
    基于具有开环聚合基团的二聚酸衍生物的牙科材料

    公开(公告)号：US08921450B2

    公开(公告)日：2014-12-30

    申请号：US13175988

    申请日：2011-07-05

    Applicant: Norbert Moszner ,  Jörg Angermann ,  Urs Karl Fischer ,  Volker Rheinberger

    Inventor： Norbert Moszner ,  Jörg Angermann ,  Urs Karl Fischer ,  Volker Rheinberger

    IPC: A61K6/08 ,  A61K6/083 ,  C07D339/00 ,  A61K6/00

    CPC classification number: C07D339/00 ,  A61K6/0023 ,  A61K6/083 ,  C08L33/08 ,  C08L33/10 ,  C08L65/00

    Abstract: The invention relates to a radically polymerizable monomer of formula (I) wherein W1 and W2 in each case independently represent H or X—R—Y—PG, wherein at least one of W1 and W2 represents X—R—Y—PG, X in each case independently is missing or represents an ether, ester, amide, urethane or urea group, Y in each case independently is missing or represents an ether, ester, amide, urethane or urea group, R in each case independently is missing or represents a C1-C16 alkylene radical which can be interrupted by one or more O atoms, wherein R can be missing only if X and/or Y is simultaneously also missing, and PG in each case independently represents a cyclic, ring-opening polymerizable group, a, b, c and d independently of each other can take the values 3 to 10. The invention also relates to polymerizable compositions which comprise the monomers according to the invention, as well as their use as dental materials and for the preparation of dental materials, in particular composites, cements, adhesives or coatings.

    Abstract translation: 本发明涉及式（I）的自由基聚合性单体，其中W1和W2各自独立地表示H或X-R-Y-PG，其中W1和W2中的至少一个表示X-R-Y-PG，X 在每种情况下都独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，Y在每种情况下独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，R各自独立地缺失或表示 可以被一个或多个O原子中断的C1-C16亚烷基，其中只有当X和/或Y同时缺失时，R只能缺失，并且每种情况下PG都独立地表示环状的开环聚合基团， a，b，c和d可以取值为3至10.本发明还涉及包含根据本发明的单体的可聚合组合物，以及它们作为牙科材料和用于制备牙科材料的用途 ，特别是composi 水泥，粘合剂或涂料。

    Dental materials based on dimer acid derivatives with ring opening polymerizable groups
    24.
    发明申请
    Dental materials based on dimer acid derivatives with ring opening polymerizable groups 有权
    基于具有开环聚合基团的二聚酸衍生物的牙科材料

    公开(公告)号：US20120010322A1

    公开(公告)日：2012-01-12

    申请号：US13175988

    申请日：2011-07-05

    Applicant: Norbert MOSZNER ,  Jörg ANGERMANN ,  Urs Karl FISCHER ,  Volker RHEINBERGER

    Inventor： Norbert MOSZNER ,  Jörg ANGERMANN ,  Urs Karl FISCHER ,  Volker RHEINBERGER

    IPC: A61K6/083 ,  C07D409/12 ,  C08F28/06

    CPC classification number: C07D339/00 ,  A61K6/0023 ,  A61K6/083 ,  C08L33/08 ,  C08L33/10 ,  C08L65/00

    Abstract: The invention relates to a radically polymerizable monomer of formula (I) wherein W1 and W2 in each case independently represent H or X—R—Y—PG, wherein at least one of W1 and W2 represents X—R—Y—PG, X in each case independently is missing or represents an ether, ester, amide, urethane or urea group, Y in each case independently is missing or represents an ether, ester, amide, urethane or urea group, R in each case independently is missing or represents a C1-C16 alkylene radical which can be interrupted by one or more O atoms, wherein R can be missing only if X and/or Y is simultaneously also missing, and PG in each case independently represents a cyclic, ring-opening polymerizable group, a, b, c and d independently of each other can take the values 3 to 10. The invention also relates to polymerizable compositions which comprise the monomers according to the invention, as well as their use as dental materials and for the preparation of dental materials, in particular composites, cements, adhesives or coatings.

    Abstract translation: 本发明涉及式（I）的自由基聚合性单体，其中W1和W2各自独立地表示H或X-R-Y-PG，其中W1和W2中的至少一个表示X-R-Y-PG，X 在每种情况下都独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，Y在每种情况下独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，R各自独立地缺失或表示 可以被一个或多个O原子中断的C1-C16亚烷基，其中只有当X和/或Y同时缺失时，R只能缺失，并且每种情况下PG都独立地表示环状的开环聚合基团， a，b，c和d可以取值为3至10.本发明还涉及包含根据本发明的单体的可聚合组合物，以及它们作为牙科材料和用于制备牙科材料的用途 ，特别是composi 水泥，粘合剂或涂料。

    PROCESS FOR PREPARING DENTAL MATERIALS HAVING LOW POLYMERIZATION SHRINKAGE
    25.
    发明申请
    PROCESS FOR PREPARING DENTAL MATERIALS HAVING LOW POLYMERIZATION SHRINKAGE 有权
    用于制备具有低聚合收缩的牙科材料的方法

    公开(公告)号：US20100311863A1

    公开(公告)日：2010-12-09

    申请号：US12859052

    申请日：2010-08-18

    Applicant: Norbert Moszner ,  Helmut Ritter ,  Urs-Karl Fischer ,  Monir Tabatabai ,  Matthias Schaub ,  Andreas Utterodt

    Inventor： Norbert Moszner ,  Helmut Ritter ,  Urs-Karl Fischer ,  Monir Tabatabai ,  Matthias Schaub ,  Andreas Utterodt

    IPC: A61K6/08

    CPC classification number: A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  A61K6/087 ,  C08F222/1006 ,  C08L61/14 ,  C08L33/04

    Abstract: The present invention relates to dental materials composed of calix[n]arenes and also to the use thereof for cements, composites, adhesives and coating materials in the dental field. The materials include (a) 0.5 to 90% by weight of at least one polymerizable calix[n]arene according to formula (I), (b) 0.01 to 5% by weight of initiator, (c) 0 to 90% by weight of at least one additional monomer which can polymerize under cationic and/or radical conditions and/or which can polymerize by ring opening, (d) 0 to 85% by weight of filler, (e) 0.01 to 5% by weight of additive and (f) 0 to 70% by weight of solvent.

    Abstract translation: 本发明涉及由杯形[n]芳烃组成的牙科用材料，以及其在牙科领域中用于粘合剂，复合材料，粘合剂和涂层材料的用途。 这些材料包括：（a）0.5至90重量％的至少一种根据式（I）的可聚合杯[n]芳烃，（b）0.01至5重量％的引发剂，（c）0至90重量％ 的至少一种可在阳离子和/或自由基条件下聚合的另外的单体和/或可以通过开环聚合，（d）0至85重量％的填料，（e）0.01至5重量％的添加剂和 （f）0〜70重量％的溶剂。

    Dental coating materials
    28.
    发明授权
    Dental coating materials 有权
    牙科涂料

    公开(公告)号：US07495037B2

    公开(公告)日：2009-02-24

    申请号：US10928540

    申请日：2004-08-27

    Applicant: Norbert Moszner ,  Simone Klapdohr ,  Ulrich Salz ,  Jörg Zimmermann ,  Volker M. Rheinberger ,  Rolf Mülhaupt

    Inventor： Norbert Moszner ,  Simone Klapdohr ,  Ulrich Salz ,  Jörg Zimmermann ,  Volker M. Rheinberger ,  Rolf Mülhaupt

    IPC: A61K6/083 ,  A61K6/08 ,  A61K6/00 ,  C08F283/12

    CPC classification number: C09D183/04 ,  A61K6/0017 ,  Y10S522/908 ,  C08L83/16

    Abstract: Polymerizable materials which contain (1) 1 to 80 wt.-% of at least one polysiloxane, (2) 0.1 to 5 wt.-% of one or more initiators for radical polymerization, (3) 0 to 60 wt.-% of radically polymerizable monomer and (4) 1 to 50 wt.-% of one or more radically polymerizable monomers which carry at least phosphonic acid group, sulphonic acid group and/or mono- or dihydrogen phosphoric acid ester group, the polysiloxane (1), the monomer (3) or both being substituted by fluorine. The materials are suitable in particular for the coating of natural or artificial teeth.

    Abstract translation: 含有（1）1至80重量％的至少一种聚硅氧烷的可聚合材料，（2）0.1至5重量％的一种或多种用于自由基聚合的引发剂，（3）0至60重量％ 可自由基聚合的单体和（4）1至50重量％的至少携带膦酸基，磺酸基和/或单或二氢磷酸酯基的一种或多种可自由基聚合的单体，聚硅氧烷（1）， 单体（3）或两者均被氟取代。 这些材料特别适用于天然或人造牙齿的涂层。

    Polymerizable compositions with acylgermanes as initiatiors
    29.
    发明申请
    Polymerizable compositions with acylgermanes as initiatiors 审中-公开
    具有酰基作为起始物的可聚合组合物

    公开(公告)号：US20080076847A1

    公开(公告)日：2008-03-27

    申请号：US11730533

    申请日：2007-04-02

    Applicant: Norbert Moszner ,  Ulrich Salz ,  Urs Karl Fischer ,  Robert Liska ,  Heinrich Gruber ,  Beate Ganster

    Inventor： Norbert Moszner ,  Ulrich Salz ,  Urs Karl Fischer ,  Robert Liska ,  Heinrich Gruber ,  Beate Ganster

    IPC: C08F2/50 ,  A61K6/08 ,  C08J3/28 ,  C08F2/46

    CPC classification number: A61K6/0023 ,  A61K6/0017 ,  A61K6/0052 ,  A61K6/083 ,  C08F2/50 ,  C08F4/72 ,  C08F222/1006 ,  C08F230/10 ,  C08L33/00

    Abstract: Composition with at least one polymerizable binder and a polymerization initiator, which contains at least one acylgermane according to general Formula (I), in which R0 is a substituted or unsubstituted C1-18-alkyl radical or an acyl group; R1 and R2 are H, an acyl group or have one of the meanings given for R3; R3 is a branched or linear C1-18-alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH3)2Si—[OSi(CH3)2]r−, (CH3)3Si—[OSi(CH3)2]r—, —COOH, —COO—R10, —CO—NR11R12, —CO-vinyl, —CO-phenyl, phenyl-C1-4-alkyl, phenyl, naphthyl or biphenyl, C5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; and the use of acyl germanes of Formula (I) for example as initiator for radical polymerization.

    Abstract translation: 含有至少一种可聚合粘合剂和聚合引发剂的组合物，其含有至少一种根据通式（I）的酰基锗烷，其中R 0是取代或未取代的C 1-18烷基， /烷基或酰基; R 1和R 2均为H，酰基或具有R 3给出的含义之一; R 3是支链或直链C 1-18 - 烷基，其可以是未取代的或被-O - ， - NH-，-NR- ，-S-或被其它基团中断，三甲基甲硅烷基，卤代（CH 3）2 Si- [OSi（CH 3）3） （CH 3）3 Si- [OSi（CH 3）3） -COOH，-COO-R 10，-CO-NR， - ， - SO 2 - ， - 11- 12，-CO-乙烯基，-CO-苯基，苯基-C 1-4 - 烷基，苯基，萘基或联苯基，C

    Dental materials based on ring-opening polymerizable acid monomers
    30.
    发明申请
    Dental materials based on ring-opening polymerizable acid monomers 审中-公开
    基于开环聚合酸单体的牙科材料

    公开(公告)号：US20070287792A1

    公开(公告)日：2007-12-13

    申请号：US11585280

    申请日：2006-10-24

    Applicant: Norbert Moszner ,  Jorg Angermann ,  Frank Zeuner ,  Armin de Mejere ,  Urs Karl Fischer ,  Volker Rheinberger

    Inventor： Norbert Moszner ,  Jorg Angermann ,  Frank Zeuner ,  Armin de Mejere ,  Urs Karl Fischer ,  Volker Rheinberger

    IPC: C08L31/00

    CPC classification number: A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  C08L33/00

    Abstract: Dental material which contains at least one radically polymerizable monomer according to the general formula (I): in which PG is a cyclic, ring-opening polymerizable group; X1 is absent, O, S, is an ester, amide or urethane group; X2 is absent with, O, S, is an ester, amide or urethane group; Y is absent, O, S, is an ester, amide or urethane group; R is an organic radical with a valency of (n+m), with 1 to 35 carbon atoms and 0 to 8 heteroatoms, the H atoms of which can be wholly or partially substituted by F atoms; R1 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; R2 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; n is 1, 2, 3, 4, 5 or 6; m is 1, 2 or 3; HG is —P═O(OH)2; —P═O(OH)(OR14); —O—P═O(OH)2, —O—P═O(OH)(OR15) or —SO2OH, wherein R14 is a C1-C15 alkyl radical, phenyl or benzyl radical; and R15 is a C1-C15 alkyl radical, phenyl or benzyl radical.

    Abstract translation: 含有至少一种根据通式（I）的可自由基聚合的单体的牙科材料：其中PG是环状可开环聚合基团; X 1不存在，O，S是酯，酰胺或氨基甲酸酯基; O，S不是酯，酰胺或氨基甲酸酯基; Y不存在，O，S是酯，酰胺或氨基甲酸酯基; R为化合价为（n + m），有1至35个碳原子和0至8个杂原子的有机基团，其H原子可以被F原子全部或部分取代; R 1不存在或可被O原子间断的C 1 -C 16亚烷基; R 2不存在或可被O原子间隔的C 1 -C 16亚烷基; n为1,2,3,4,5或6; m为1,2或3; HG是-P-O（OH）2; -P-O（OH）（OR 14）; -OPO（OH）2，-OPO（OH）（OR 15）或-SO 2 OH，其中R 14， CH 2是C 1 -C 15烷基，苯基或苄基; R 15是C 1 -C 15烷基，苯基或苄基。

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