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公开(公告)号：US08067327B2
公开(公告)日：2011-11-29
申请号：US12894562
申请日：2010-09-30
IPC分类号： B01J20/28
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0051 , B01D67/0093 , B01D69/10 , B01D2253/108 , B01D2257/504 , B01D2325/20 , B01J20/28033 , C07C7/144 , C10L3/10 , C10L3/102 , Y02C10/10 , Y02P20/152 , C07C9/04
摘要： The present invention provides modified molecular sieve membranes with improved CO2/CH4 separation selectivity and methods for making such membranes. The molecular sieve membranes are modified by adsorption of a modifying agent, such as ammonia, within and/or on the membrane.
摘要翻译： 本发明提供具有改进的CO 2 / CH 4分离选择性的改性分子筛膜和制备这种膜的方法。 分子筛膜通过在膜内和/或膜上吸附改性剂例如氨来修饰。
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公开(公告)号：US20110015057A1
公开(公告)日：2011-01-20
申请号：US12894562
申请日：2010-09-30
IPC分类号： B01J29/85 , B01J29/04 , B01J29/40 , B01J29/072
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0051 , B01D67/0093 , B01D69/10 , B01D2253/108 , B01D2257/504 , B01D2325/20 , B01J20/28033 , C07C7/144 , C10L3/10 , C10L3/102 , Y02C10/10 , Y02P20/152 , C07C9/04
摘要： The present invention provides modified molecular sieve membranes with improved CO2/CH4 separation selectivity and methods for making such membranes. The molecular sieve membranes are modified by adsorption of a modifying agent, such as ammonia, within and/or on the membrane.
摘要翻译： 本发明提供具有改进的CO 2 / CH 4分离选择性的改性分子筛膜和制备这种膜的方法。 分子筛膜通过在膜内和/或膜上吸附改性剂例如氨来修饰。
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公开(公告)号：US07604129B2
公开(公告)日：2009-10-20
申请号：US10529409
申请日：2003-10-03
申请人： Douglas L. Gin , Meijuan Zhou , Richard D. Noble
发明人： Douglas L. Gin , Meijuan Zhou , Richard D. Noble
CPC分类号： B01D69/125 , B01D67/0006 , B01D69/02 , B01D69/142 , B01D71/28 , B01D71/40 , B01D71/44 , B01D2323/18 , B01D2323/30 , B01D2325/02 , B01D2325/021 , B01D2325/04
摘要： The invention provides composite nanofiltration membranes (FIG. 5) with lyotropic liquid crystal (LLC) polymer porous membranes (30) attached to a porous support (20). The LLC membranes are prepared from LLC monomers which form the inverted hexagonal or bicontinuous cubic phase. The arrangement, size, and chemical properties of the pores can be tailored on the molecular level. The composite membrane of the invention is useful for separation processes involving aqueous and nonaqueous solutions as well as gases. Methods for making and using the composite nanofiltration membranes of the inventions are also provided.
摘要翻译： 本发明提供了复合纳滤膜（图5），其具有连接到多孔载体（20）上的溶致液晶（LLC）聚合物多孔膜（30）。 LLC膜由形成倒六角或双连续立方相的LLC单体制备。 毛孔的布置，尺寸和化学性质可以在分子水平上进行调整。 本发明的复合膜可用于涉及水和非水溶液以及气体的分离方法。 还提供了制备和使用本发明的复合纳滤膜的方法。
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24.发明申请LYOTROPIC LIQUID CRYSTAL MEMBRANES BASED ON CROSS-LINKED TYPE I BICONTINUOUS CUBIC PHASES 审中-公开基于交叉型I型双相立柱的LYOTROPIC液晶膜公开(公告)号：US20090173693A1
公开(公告)日：2009-07-09
申请号：US12121617
申请日：2008-05-15
申请人： Douglas L. Gin , Meijuan Zhou , Richard D. Noble , Jason E. Bara , Robert L. Kerr , Brian R. Wiesenauer
发明人： Douglas L. Gin , Meijuan Zhou , Richard D. Noble , Jason E. Bara , Robert L. Kerr , Brian R. Wiesenauer
CPC分类号： B01D69/02 , B01D61/027 , B01D67/0006 , B01D69/10 , B01D2325/021 , B01D2325/028 , Y02A20/131
摘要： The invention provides composite nanofiltration membranes with a lyotropic liquid crystal (LLC) polymer composition embedded in or forming a layer on a porous support. The LLC membranes are prepared from LLC monomers which form a bicontinuous cubic (QI) phase. The arrangement, size, and chemical properties of the pores can be tailored on the molecular level. The composite membranes of the invention are useful for separation processes involving aqueous and nonaqueous solutions as well as gases. Methods for making and using the composite nanofiltration membranes of the invention are also provided.
摘要翻译： 本发明提供了复合纳米过滤膜，其具有嵌入或形成多孔载体上的层的溶致液晶（LLC）聚合物组合物。 LLC膜由形成双连续立方（QI）相的LLC单体制备。 毛孔的布置，尺寸和化学性质可以在分子水平上进行调整。 本发明的复合膜可用于涉及水和非水溶液以及气体的分离过程。 还提供了制备和使用本发明的复合纳滤膜的方法。
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公开(公告)号：US20090171098A1
公开(公告)日：2009-07-02
申请号：US12333052
申请日：2008-12-11
IPC分类号： C07D233/58
CPC分类号： C07D207/20
摘要： The invention provides heteroaryl salts and methods for producing the same. In particular, the invention provides heteroaryl salts of the formula: and methods for producing the same, where M, a, X1, X2, X3, and X4 are those defined herein.
摘要翻译： 本发明提供了杂芳基盐及其制备方法。 特别地，本发明提供下式的杂芳基盐及其制备方法，其中M，a，X 1，X 2，X 3和X 4是本文定义的那些。
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26.发明申请公开(公告)号：US20080216650A1
公开(公告)日：2008-09-11
申请号：US12044116
申请日：2008-03-07
CPC分类号： B01D67/0051 , B01D53/228 , B01D67/0058 , B01D71/028 , B01D2256/24 , B01D2257/504 , B01D2323/18 , Y02C10/10 , Y10T428/24999
摘要： SAPO-34 membranes and methods for their preparation and use are described. The SAPO-34 membranes are prepared by contacting at least one surface of a porous membrane support with a synthesis gel comprising a first and a second templating agent. SAPO-34 crystals having a narrow size distribution were applied to the surface of the support prior to synthesis. A layer of SAPO-34 crystals is formed on at least one surface of the support. SAPO-34 membranes of the invention can have improved selectivity for certain gas mixtures, including mixtures of carbon dioxide and methane.
摘要翻译： 描述了SAPO-34膜及其制备和使用的方法。 通过使多孔膜载体的至少一个表面与包含第一和第二模板剂的合成凝胶接触来制备SAPO-34膜。 在合成之前将具有窄尺寸分布的SAPO-34晶体施加到载体的表面。 在载体的至少一个表面上形成一层SAPO-34晶体。 本发明的SAPO-34膜可以对某些气体混合物（包括二氧化碳和甲烷的混合物）具有改进的选择性。
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公开(公告)号：US06767384B1
公开(公告)日：2004-07-27
申请号：US09766307
申请日：2001-01-19
申请人： Tuan Anh Vu , Richard D. Noble , John L. Falconer
发明人： Tuan Anh Vu , Richard D. Noble , John L. Falconer
IPC分类号： B01J2906
CPC分类号： B01D71/028 , B01D61/362 , B01D63/06 , B01D63/063 , B01D67/0069 , B01D69/10 , B01D2323/08 , B01D2323/24 , B01D2323/40 , B01J29/06 , B01J29/061 , B01J29/86
摘要： Zeolite membranes that can be used to continuously separate components of mixtures are disclosed. The zeolite membranes are prepared by isomorphous substitution, which allows systematic modification of the zeolite surface and pore structure. Through proper selection of the basic zeolite framework structure and compensating cations, isomorphous substitution permits high separation selectivity without many of the problems associated with zeolite post-synthesis treatments. The inventive method for preparing zeolite membranes is alkali-free and is much simpler than prior methods for making acid hydrogen zeolite membranes, which can be used as catalysts in membrane reactors.
摘要翻译： 公开了可用于连续分离混合物组分的沸石膜。 沸石膜通过同晶取代制备，其允许系统地改性沸石表面和孔结构。 通过适当选择碱性沸石骨架结构和补偿阳离子，同晶取代允许高分离选择性，而不需要与沸石后合成处理相关的许多问题。 用于制备沸石膜的本发明方法是无碱的，并且比制备酸性氢沸石膜的现有方法简单得多，其可以用作膜反应器中的催化剂。
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28.发明授权Method of production of novel molybdenum-sulfide dimers and reactions of the same 失效新型硫化钼二聚体的生产方法及其反应
公开(公告)号：US5414194A
公开(公告)日：1995-05-09
申请号：US96167
申请日：1993-07-22
申请人： Mary R. Dubois , Richard D. Noble , Carl A. Koval
发明人： Mary R. Dubois , Richard D. Noble , Carl A. Koval
摘要： Derivatized molybdenum-sulfide dimers of the general formula [(C.sub.5 R.sub.5 Mo).sub.2 (.mu.-S).sub.4-x (.mu.-SR).sub.x ].sup.n are utilized in the solid state, incorporated in permselective membranes and in aqueous solution as chemical specific complexing agents in various separation processes.
摘要翻译： 衍生的通式为[（C5R5Mo）2（mu-S）4-x（mu -SR）x] n的钼硫化物二聚体以固态使用，掺入渗透选择膜和水溶液中作为化学特异性络合剂 在各种分离过程中。
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29.发明授权Stationary magnetically stabilized fluidized bed for protein separation and purification 失效用于蛋白质分离和纯化的固定磁稳定流化床
公开(公告)号：US5130027A
公开(公告)日：1992-07-14
申请号：US675553
申请日：1991-03-26
申请人： Richard D. Noble , Carl A. Koval , Lori Nixon , Geoffrey F. Slaff
发明人： Richard D. Noble , Carl A. Koval , Lori Nixon , Geoffrey F. Slaff
CPC分类号： B01D15/361 , B01D15/1807 , G01N30/58
摘要： Magnetically stabilized fluidized bed technology is utilized in conjunction with ion-exchange adsorption/desorption processes in a method and system for isolating proteins from cell lysate. The invention also includes a magnetizable, porous, ion-exchange particle, and a method for producing the same, for use with the stationary magnetically stabilized fluidized bed protein isolation process.
摘要翻译： 在用于从细胞裂解物中分离蛋白质的方法和系统中，使用磁稳定流化床技术与离子交换吸附/解吸过程结合使用。 本发明还包括可磁化，多孔的离子交换颗粒及其制备方法，用于静态磁稳定流化床蛋白质分离过程。
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30.发明授权公开(公告)号：US08993806B2
公开(公告)日：2015-03-31
申请号：US13635882
申请日：2011-03-18
申请人： Wei Zhang , Richard D. Noble , Yinghua Jin , Bret A. Voss
发明人： Wei Zhang , Richard D. Noble , Yinghua Jin , Bret A. Voss
CPC分类号： B01D53/02 , B01D2253/20 , B01D2253/202 , B01D2257/504 , B01J20/267 , B01J20/28007 , B01J20/28045 , B01J20/3212 , B01J20/3236 , B82Y30/00 , Y02C10/08
摘要： Porous bulk materials formed of shape-persistent, non-collapsible, three-dimensional molecular cage building blocks are presented that are useful for a variety of applications including gas separation/storage, sensing, and catalysis.
摘要翻译： 提出了由形状持久的，不可塌陷的三维分子笼构建块形成的多孔体材料，其可用于多种应用，包括气体分离/储存，感测和催化。
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