公开(公告)号：US4562118A

公开(公告)日：1985-12-31

申请号：US664308

申请日：1984-10-24

申请人： Yoshitsugu Maruhashi ,  Fumio Kano ,  Muneki Yamada ,  Sadao Hirata

发明人： Yoshitsugu Maruhashi ,  Fumio Kano ,  Muneki Yamada ,  Sadao Hirata

IPC分类号： C08L23/00 ,  C08L23/26 ,  C08L29/04 ,  C08L77/00 ,  C08L101/00 ,  B32B27/36

CPC分类号： C08L29/04 ,  C08L77/00 ,  Y10T428/31507 ,  Y10T428/31797 ,  Y10T428/31906 ,  Y10T428/31909 ,  Y10T428/31935 ,  Y10T428/31938

摘要： Disclosed is a resin composition excellent in its drawability, which comprises (A) a saponified ethylene-vinyl ester copolymer having an ethylene content of 20 to 55 mole % and a saponification degree of at least 95%, (B) a saponified ethylene-vinyl ester copolymer having an ethylene content of 25 to 60 mole % and a saponification degree of at least 90%, the ethylene content of the saponified copolymer (B) being higher by at least 3 mole % than the ethylene content of the saponified copolymer (A), and (C) a polyamide, wherein the weight ratio of the saponified copolymer (A) to the saponified copolymer (B) is in the range of from 90/10 to 10/90 and the weight ratio of the sum of the saponified copolymers (A) and (B) to the polyamide (C) is in the range of from 95/5 to 5/95. The resin compositions have excellent gas barrier properties and can be molded into films or sheets or laminated with other film-forming materials. Molded articles such as cups and other vessels having gas barrier properties can be obtained by molding the laminated films prepared from the resin compositions.

公开(公告)号：US4486378A

公开(公告)日：1984-12-04

申请号：US598543

申请日：1984-04-12

申请人： Sadao Hirata ,  Isao Tanikawa ,  Yoshitsugu Maruhashi

发明人： Sadao Hirata ,  Isao Tanikawa ,  Yoshitsugu Maruhashi

IPC分类号： B05D5/00 ,  B05D7/02 ,  B05D7/22 ,  B29C39/00 ,  B29C39/34 ,  B29C49/22 ,  B32B27/30 ,  B65D23/02 ,  B65D23/08 ,  C08J7/04 ,  B29D9/04

CPC分类号： B05D7/02 ,  B05D7/227 ,  B29C39/006 ,  B29C39/34 ,  B29C49/22 ,  B32B27/30 ,  B65D23/02 ,  B65D23/0814 ,  C08J7/047 ,  B05D2701/10 ,  B29B2911/14593 ,  B29B2911/14646 ,  B29B2911/1466 ,  B29B2911/14713 ,  B29B2911/1498 ,  B29L2031/7158 ,  C08J2427/00

摘要： A plastic bottle has as a wall-forming component a layer of a copolymer consisting essentially of 99 to 70% by weight of vinylidene cloride and 1 to 40% by weight of at least one acrylic or methacrylic monomer and further including up to 100 parts by weight of at least one member selected from other ethylenically unsaturated monomers per 100 parts by weight of the total amount of the first two monomers, the copolymer having an oxygen permeability constant of less than 9.times.10.sup.-14 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg as measured at a temperature of 20.degree. C. and a relative humidity of 100% and a water vapor permeability constant of less than 3.times.10.sup.-3 g.multidot.cm/m.sup.2 .multidot.day as determined according to the method of JIS Z-0208.This plastic bottle is obtained by casting an aqueous latex or the like of the above-mentioned copolymer in a bottle mold and drying the cast latex. This aqueous latex may be formed as a coating layer on a preformed plastic bottle. In this plastic bottle, the humidity dependency of the oxygen barrier property is prominently reduced.

摘要翻译： 塑料瓶具有作为壁形成组分的一层共聚物，其基本上由99至70重量％的亚乙烯基氯化物和1至40重量％的至少一种丙烯酸或甲基丙烯酸单体组成，并且还包括至多100份 选自其它烯属不饱和单体中的至少一种的重量，相对于前两种单体的总量的100重量份，所述共聚物的氧气渗透常数小于9×10-14立方厘米/厘米2·秒·厘米汞柱，其温度为20℃ ℃，相对湿度为100％，水蒸气透过率常数小于3×10-3gxcm / m2×day，根据JIS Z-0208的方法测定。 该塑料瓶通过将上述共聚物的水性胶乳等浇铸在瓶模中并干燥流延胶乳而获得。 该水性胶乳可以形成为预成型塑料瓶上的涂层。 在这种塑料瓶中，阻氧性的湿度依赖性明显降低。

公开(公告)号：US4393106A

公开(公告)日：1983-07-12

申请号：US315952

申请日：1981-10-28

申请人： Yoshitsugu Maruhashi ,  Isao Tanikawa ,  Sadao Hirata ,  Jinichi Yazaki ,  Kozaburo Sakano

发明人： Yoshitsugu Maruhashi ,  Isao Tanikawa ,  Sadao Hirata ,  Jinichi Yazaki ,  Kozaburo Sakano

IPC分类号： B29C49/22 ,  B65D1/02 ,  B65D23/02 ,  B65D23/08 ,  C08J7/04 ,  B65D23/00 ,  B05D1/36 ,  B29D9/04 ,  B32B31/00

CPC分类号： B29C49/22 ,  B65D1/0215 ,  B65D23/02 ,  B65D23/0814 ,  C08J7/042 ,  B29B11/08 ,  B29B11/10 ,  B29B11/14 ,  B29B2911/14053 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14093 ,  B29B2911/1412 ,  B29B2911/14133 ,  B29B2911/1414 ,  B29B2911/1416 ,  B29B2911/14166 ,  B29B2911/1424 ,  B29B2911/14273 ,  B29B2911/1428 ,  B29B2911/14293 ,  B29B2911/14593 ,  B29B2911/14646 ,  B29B2911/14653 ,  B29B2911/14713 ,  B29B2911/1498 ,  B29C2049/026 ,  B29C2049/027 ,  B29C49/12 ,  B29K2023/06 ,  B29K2023/12 ,  B29K2027/06 ,  B29K2067/00 ,  B29K2105/253 ,  B29K2105/258 ,  B29K2623/06 ,  B29K2995/0073 ,  B29L2031/7158 ,  C08J2323/12 ,  C08J2427/08 ,  C08J2433/12 ,  Y10T428/1383

摘要： Disclosed is a laminated plastic container in the form of a bottle, the wall of which comprises a substrate formed of a melt-moldable plastic material, a coating layer formed on at least one surface of the substrate, said coating layer being composed of a copolymer consisting essentially of 99 to 70% by weight of vinylidene chloride and 1 to 30% by weight of at least one acrylic or methacrylic monomer and further including up to 100 parts by weight of at least one member selected from other ethylenically unsaturated monomers per 100 parts by weight of the total amount of said two monomers, said copolymer having an oxygen permeation coefficient of less than 9.times.10.sup.-14 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg as measured at a temperature of 20.degree. C. and a relative humidity of 100% and a water vapor permeability coefficient of less than 3.times.10.sup.-3 g.multidot.cm/m.sup.2 .multidot.day as determined according to the method of JIS Z-0208, and a protecting surface layer of a film-forming synthetic resin other than a vinylidene chloride resin, which is formed contiguously to said coating layer.This laminated plastic container is excellent in the barrier property to various gases such as oxygen, water vapor, nitrogen and carbon dioxide gas and other properties required for plastic containers. The humidity dependency of the oxygen barrier property is highly improved in this laminated plastic container.

摘要翻译： 公开了一种瓶形的层压塑料容器，其壁包括由可熔融模塑的塑料材料形成的基材，形成在基材的至少一个表面上的涂层，所述涂层由共聚物 基本上由99至70重量％的偏二氯乙烯和1至30重量％的至少一种丙烯酸或甲基丙烯酸单体组成，并且还包括至多100重量份的选自其它烯属不饱和单体每100份的至少一种 的所述两种单体的总量，所述共聚物在20℃的温度和相对湿度为100％下测得的氧透过系数小于9×10-14 ccxcm / cm2xsecxcmHg，水蒸气透过系数 根据JIS Z-0208的方法测定的小于3×10 -3 gxcm / m 2·x日，以及除了偏二氯乙烯树脂之外的成膜合成树脂的保护表面层，w 其形成与所述涂层相邻。 这种层压塑料容器对于各种气体如氧气，水蒸汽，氮气和二氧化碳气体以及塑料容器所需的其它性能的阻隔性能优异。 在该层压塑料容器中，氧阻隔性的湿度依赖性大大提高。