Methods of making functionalized nanoparticles
    24.
    发明授权
    Methods of making functionalized nanoparticles 失效
    制备官能化纳米粒子的方法

    公开(公告)号:US06410765B1

    公开(公告)日:2002-06-25

    申请号:US09690527

    申请日:2000-10-17

    IPC分类号: C07F908

    摘要: There are disclosed amphoteric nano-sized metal oxide particles functionalized with silyl esters of a phosphonate and composites thereof with an acrylate-based monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Also disclosed are the method making such functionalized particular by reacting a metal oxide with a silyl ester of a phosphonate in the presence of a non-aqueous solvent and in an inert atmosphere and the method of making the composites wherein the functionalized particles are admixed with an acrylate-based matrix monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Further disclosed is the method of dental repair wherein the composites are applied to a tooth and photopolymerized.

    摘要翻译: 公开了用膦酸酯的甲硅烷基酯和其与丙烯酸酯类单体的复合材料官能化的两性纳米尺寸金属氧化物颗粒,包括在环境温度下可光聚合的液晶单体。 还公开了通过使金属氧化物与膦酸酯的甲硅烷基酯在非水溶剂和惰性气氛的存在下反应而进行官能化的方法,以及制备复合物的方法,其中官能化颗粒与 丙烯酸酯基基体单体,包括在环境温度下可光聚合的液晶单体。 进一步公开了牙科修复方法,其中将复合材料应用于牙齿并进行光聚合。

    Selective electrochemical detector for nitric oxide and method
    28.
    发明授权
    Selective electrochemical detector for nitric oxide and method 失效
    一氧化氮选择性电化学检测器及方法

    公开(公告)号:US5580433A

    公开(公告)日:1996-12-03

    申请号:US540849

    申请日:1995-10-11

    IPC分类号: G01N27/407 G01N27/26

    CPC分类号: G01N27/4074

    摘要: A thin film solid state amperometric detector for nitric oxide is provided based upon a mobile cation electrolyte that selectively transmits nitrosonium cations (NO*) therethrough. The presently most preferred embodiment employs NO-.beta.-alumina as the mobile cation electrolyte. The electrodes of the detector are preferably arranged in a bipotentiostat arrangement. The first and second working electrodes share a common reference electrode and a common counter electrode, which are positioned such that the potentials of the first and second working electrodes can be independently controlled. The first working electrode is exposed to a fluid (liquid or gaseous), whereas the second working electrode is normally isolated from the fluid. The first working electrode is set at a potential capable of oxidizing NO to NO+, the NO+ moves through the mobile cation solid electrolyte to the second electrode, and the second working electrode is set at a potential capable of reducing the NO+ back to NO. The detector has a diffusion barrier for the nitric oxide so that the voltage-current characteristics of the detector under diffusion limiting conditions are proportional to the concentration of nitric oxide in a fluid.

    摘要翻译: 基于通过其选择性地转移亚硝鎓阳离子(NO *)的移动阳离子电解质提供用于一氧化氮的薄膜固态电流计检测器。 目前最优选的实施方案使用NO-β-氧化铝作为可移动阳离子电解质。 检测器的电极优选地布置成双重定位装置。 第一工作电极和第二工作电极共用公共参考电极和公共对电极,其被定位成使得可以独立地控制第一和第二工作电极的电位。 第一工作电极暴露于流体(液体或气体),而第二工作电极通常与流体隔离。 第一工作电极被设定为能够将NO氧化成NO +的电位,NO +通过移动阳离子固体电解质移动到第二电极,并且将第二工作电极设定为能够将NO +还原为NO的电位。 检测器具有用于一氧化氮的扩散阻挡层,使得扩散限制条件下的检测器的电压 - 电流特性与流体中一氧化氮的浓度成比例。

    Surface treatment and exchange of nanostructures from aqueous suspension into organic media and into polymer-matrix composites
    30.
    发明授权
    Surface treatment and exchange of nanostructures from aqueous suspension into organic media and into polymer-matrix composites 有权
    表面处理和纳米结构从水性悬浮液的交换到有机介质和聚合物基质复合材料

    公开(公告)号:US08415491B2

    公开(公告)日:2013-04-09

    申请号:US12960195

    申请日:2010-12-03

    摘要: The present invention is directed to a method of exchanging nanostructures from within aqueous liquid media into organic liquid media. The steps comprise first supplying solid nanostructures in an aqueous liquid media, adjusting the pH, incorporating an ionic surfactant sufficient to reduce nanostructure aggregation, followed by concentrating the nanostructures in the aqueous liquid media. The nanostructures may them be placed in organic liquid media followed by introduction of a coupling agent capable of covalent attachment to the nanostructure surface while providing a functional group capable of polymerization to covalently bond the nanostructures to a selected monomer and/or polymer resin.

    摘要翻译: 本发明涉及一种从含水液体介质中将纳米结构交换成有机液体介质的方法。 这些步骤包括首先在水性液体介质中提供固体纳米结构,调节pH值,加入足以减少纳米结构聚集的离子表面活性剂,然后将纳米结构物浓缩在含水液体介质中。 纳米结构可以将它们置于有机液体介质中,随后引入能够共价连接到纳米结构表面的偶联剂,同时提供能够聚合以将纳米结构共价键合到选定的单体和/或聚合物树脂的官能团。