公开(公告)号：US07014837B2

公开(公告)日：2006-03-21

申请号：US10664774

申请日：2003-09-16

Applicant: David Richard Corbin ,  Albert J. Sacco ,  Steven L. Suib ,  Qiuhua Zhang

Inventor： David Richard Corbin ,  Albert J. Sacco ,  Steven L. Suib ,  Qiuhua Zhang

IPC: C01B39/14

CPC classification number: B82Y30/00 ,  B01J29/7003 ,  C01B39/14 ,  C01B39/145 ,  C11D3/128 ,  Y10S423/24

Abstract: Described is a process to synthesize nano-size Zeolite A from an amorphous gel precursor which can be synthesized via reaction of NaAlO2, NaOH, and tetraethoxysilane (TEOS). Zeolite A with particle sizes of ˜150 nm was made by transformation of the amorphous precursor in (CH3)4NOH solution with Zeolite A seeding. The nano-sized Zeolite A can be part of processes for making non-phosphate detergent where the as-synthesized Zeolite A used as builders, for making thin films for separation and/or catalysis, for making secondary ordered patterns.

Abstract translation: 描述了从无定形凝胶前体合成纳米尺寸沸石A的方法，该无定形凝胶前体可以通过NaAlO 2 H 2，NaOH和四乙氧基硅烷（TEOS）的反应合成。 通过将（CH 3/3）4NH 4 NOH溶液中的无定形前体与沸石A接种进行转化，制备粒径为〜150nm的沸石A. 纳米尺寸的沸石A可以是制备非磷酸盐洗涤剂的方法的一部分，其中合成的沸石A用作助洗剂，用于制备用于分离和/或催化的薄膜，用于制备二次有序图案。

公开(公告)号：US6027617A

公开(公告)日：2000-02-22

申请号：US888834

申请日：1997-07-07

Applicant: Yuji Hayashi ,  Steven L. Suib ,  Hiroshige Matsumoto ,  Masao Hiyane ,  Shuji Tanabe

Inventor： Yuji Hayashi ,  Steven L. Suib ,  Hiroshige Matsumoto ,  Masao Hiyane ,  Shuji Tanabe

IPC: B01D53/86 ,  B01J12/00 ,  B01J19/08 ,  B01J19/24 ,  C07B61/00 ,  C07C1/04 ,  C07C9/04 ,  C07C29/50 ,  C07C31/04 ,  H05F3/00

CPC classification number: B01J12/007 ,  B01J19/088 ,  B01J19/242 ,  B01J2219/0818 ,  B01J2219/083 ,  B01J2219/0847 ,  B01J2219/0869 ,  B01J2219/0871 ,  B01J2219/0875

Abstract: A gas reactor includes a dielectric casing made of a dielectric material and forming a first conduit for directing first gas in one direction, a first electrode positioned inside the dielectric casing along a general center thereof and extending in the direction, at least one catalyst layer formed on a surface of the first electrode, and a second electrode surrounding an outer wall of the dielectric casing. The gas reactor further includes a power-supply unit applying AC power between the first electrode and the second electrode to generate glow discharge inside the dielectric casing.

Abstract translation: 气体反应器包括由电介质材料制成的电介质壳体，并形成用于沿一个方向引导第一气体的第一导管，位于电介质外壳内沿其一般中心并在该方向上延伸的第一电极，形成至少一个催化剂层 在第一电极的表面上，以及围绕电介质外壳的外壁的第二电极。 气体反应器还包括电源单元，其在第一电极和第二电极之间施加AC电力，以在电介质壳体内产生辉光放电。

公开(公告)号：US5635155A

公开(公告)日：1997-06-03

申请号：US712136

申请日：1996-09-11

Applicant: Chi-Lin O'Young ,  Yan-Fei Shen ,  Richard P. Zerger ,  Steven L. Suib

Inventor： Chi-Lin O'Young ,  Yan-Fei Shen ,  Richard P. Zerger ,  Steven L. Suib

IPC: B01J20/02 ,  C01B37/00 ,  C01B39/00 ,  C01G45/00 ,  C01G45/02 ,  C01G45/12

CPC classification number: C01G45/02 ,  C01B37/00 ,  C01G45/00 ,  C01P2002/02 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2002/88

Abstract: A process of synthesizing synthetic manganese oxide hydrates having various structures including hollandite and todorokite structure by hydrothermal synthesis. The products have a high degree of crystallinity, and thermal stability.

Abstract translation: 通过水热合成合成具有各种结构的合成氧化锰水合物的方法，包括胡萝卜素和硬球形结构。 该产品具有高度的结晶度和热稳定性。

公开(公告)号：US5597944A

公开(公告)日：1997-01-28

申请号：US335317

申请日：1994-11-07

Applicant: Chi-Lin O'Young ,  Robert A. Sawicki ,  Yuan-Gen Yin ,  Wen-Qing Xu ,  Steven L. Suib

Inventor： Chi-Lin O'Young ,  Robert A. Sawicki ,  Yuan-Gen Yin ,  Wen-Qing Xu ,  Steven L. Suib

IPC: C07C5/333 ,  C07C5/327

CPC classification number: C07C5/3332 ,  C07C2523/34 ,  C07C2529/03

Abstract: The dehydrogenation of n-parrofins to n-olefins is catalyzed by novel synthetic manganese oxide octahedral molecular sieves such as OMS-1 and OMS-2.

Abstract translation: 新型合成氧化锰八面体分子筛如OMS-1和OMS-2催化正烯烃脱氢为正烯烃。

公开(公告)号：US5578282A

公开(公告)日：1996-11-26

申请号：US335498

申请日：1994-11-07

Applicant: Chi-Lin O'Young ,  Steven L. Suib

Inventor： Chi-Lin O'Young ,  Steven L. Suib

IPC: C01G45/02 ,  C01B37/00 ,  C01B39/00 ,  C01G45/00 ,  C01G45/12

CPC classification number: C01G45/006 ,  C01B39/00 ,  C01G45/02 ,  C01G45/1221 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2006/16

Abstract: A new class of manganese oxide octahedral molecular sieves possess a (4.times.4) tunnel structure. The molecular sieves possess the general compositionA.sub.a M.sub.b Mn.sub.16-b O.sub.32 n.multidot.H.sub.2 Owherein A is +1, +2, +3 or +4 tunnel cation or combination thereof, 0.ltoreq.a.ltoreq.8, M is +1, +2, +3 or +4 framework-substituting metal cation or combination thereof, 0.ltoreq.b.ltoreq.16 and n.gtoreq.0.A method of producing the molecular sieves includes the steps of dissolving a manganese salt in an organic solvent, e.g., ethanol, adding a permanganate salt to the resulting solution to provide a solid intermediate which is recovered and heated to a temperature which results in producing an octahedral molecular sieve having a (4.times.4) tunnel structure.The molecular sieves are useful in such applications as oxidation catalysis, hydrocarbon conversion, adsorption and electrochemical sensors.

Abstract translation: 一类新型的氧化锰八面体分子筛具有（4×4）隧道结构。 分子筛具有一般组成AaMbMn16-bO32nxH2O，其中A为+1，+2，+3或+4隧道阳离子或其组合，0≤a≤8，M为+1，+2，+ 3 或+4构架取代金属阳离子或其组合，0 / = 0。 制造分子筛的方法包括以下步骤：将锰盐溶解在有机溶剂如乙醇中，向所得溶液中加入高锰酸盐，提供固体中间体，将其回收并加热至导致产生 具有（4×4）隧道结构的八面体分子筛。 分子筛可用于氧化催化，烃转化，吸附和电化学传感器等应用。