摘要:
A proton conductive electrolyte (20) is made of AB(1-x)MxO3 structure perovskite, and is characterized in that: the B is Ce; the M is a metal having valence that is smaller than +4; and an average of an ion radius of the M is less than an ion radius of Tm3+ and more than 56.4 pm.
摘要:
A proton conductive electrolyte (20) is made of AB(1−x)MxO3 structure perovskite, and is characterized in that: the B is Ce; the M is a metal having valence that is smaller than +4; and an average of an ion radius of the M is less than an ion radius of Tm3+ and more than 56.4 pm.
摘要:
A gas reactor includes a dielectric casing made of a dielectric material and forming a first conduit for directing first gas in one direction, a first electrode positioned inside the dielectric casing along a general center thereof and extending in the direction, at least one catalyst layer formed on a surface of the first electrode, and a second electrode surrounding an outer wall of the dielectric casing. The gas reactor further includes a power-supply unit applying AC power between the first electrode and the second electrode to generate glow discharge inside the dielectric casing.
摘要:
To provide a pre-heating apparatus capable of improving the installation reliability of a raw material holding gate of a pre-heating apparatus, reducing an installation cost and reducing melting electric power energy without deteriorating an operation environment while improving the pre-heating effect on raw materials by an exhaust gas, a shaft equipped with a raw material charging portion and an exhaust gas outlet at the top thereof and with a raw material holding gate at the bottom thereof is disposed in the proximity of an arc furnace, a gap is defined between the lower end portion of the shaft and the holding gate, and an outer cylinder connecting with an exhaust gas duct of the arc furnace is disposed around the outer periphery of the gap.
摘要:
A proton conductor includes a main constituent element. A part of the main constituent element is substituted by a transition metal. Valence of the transition metal is variable between valence of the main constituent element and valence lower than the valence of the main constituent element.
摘要:
An electrochemical cell including a proton conductor as an electrolyte with superior stability, particularly against gases containing carbon dioxide, is provided.A proton-conductive electrolyte 21 used for an electrochemical cell 20B was a ceramic having the composition SrZr0.5Ce0.4Y0.1O3−δ. As the cathode, a thin film of a proton conductor having the composition SrCe0.95Yb0.05O3−δwas provided on the electrolyte 21 as an intermediate layer 22, and a porous platinum electrode 23c was provided thereon. The anode used was a palladium electrode 23a. A cell 20A including no intermediate layer 22 had a high overvoltage approaching 600 mV at a low current density, namely, 70 mA/cm2. In contrast, the cell 20B, including the intermediate layer 21, had a low overvoltage, namely, about 170 mV, at a current density of 680 mA/cm2.
摘要翻译:提供一种电化学电池,其包括作为具有优异稳定性的电解质的质子导体,特别是对含有二氧化碳的气体。 用于电化学电池20B的质子传导电解质21是具有SrZr0.5Ce0.4Y0.1O3-δ组成的陶瓷。 作为阴极,在其上设置具有作为中间层22的电解质21上提供的组成为SrCu0.95Yb0.05O3-deltawas的质子导体薄膜和多孔铂电极23c。 所使用的阳极是钯电极23a。 不包含中间层22的电池20A在低电流密度即70mA / cm 2下的高过电压接近600mV。 相反,包括中间层21的电池20B在680mA / cm 2的电流密度下具有低过电压,即约170mV。
摘要:
A proton conducting electrolyte having good proton conductivity and an electrochemical cell that includes the proton conducting electrolyte are provided. The proton conducting electrolyte has the ABO3 type perovskite structure, and a Site-B contains a first metal having a valence that is smaller than the average valence of the Site-B, and a second metal element having a valence that is larger than the average valence of the Site-B by at least one. Holes are formed in the proton conducting electrolyte. Thus, good proton conductivity is imparted to the proton conducting electrolyte.
摘要:
In a scrap conveyor for feeding a scrap to a processing furnace such as an arc furnace, etc, while pre-heating the scrap by an exhaust gas from the processing furnace, the periphery of the scrap conveyor is covered with a gas seal cover, a flue is disposed above the scrap conveyed, an exhaust gas passage portion is disposed below the scrap conveyor, and an exhaust gas suction duct opening to the exhaust gas passage portion through an exhaust gas suction space is disposed. In the conveyor, an exhaust gas flow passage for allowing the exhaust gas inside the flue to pass through the scrap from its surface layer to its lower layer is formed inside the layer of the scrap, so that pre-heating of the scrap can be efficiently effected throughout the whole layer of the scrap.
摘要:
To provide low-overpotential electrodes for an electrochemical cell including a proton-conductive electrolyte and an electrochemical cell including the electrodes. The following reaction occurs at the interface between a gas phase and an anode 3: H2→2H++2e− At this time, the resultant protons (H+) and electrons (e−) exist in the anode 3. The subsequent electrode reaction is completed after the protons travel to an electrolyte 2 and the electrons travel to a lead 5. The reverse reaction occurs at a cathode 4 to generate hydrogen gas.
摘要:
A mixed proton-electron conducting ceramic is a metallic oxide having a perovskite type structure, includes at least one member selected from the group consisting of chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni) and ruthenium (Ru) in a range of from 0.01 or more to 0.8 or less when a molar-ratio sum of metals constituting the metallic oxide is taken as 2, and has proton conductivity and electron conductivity.