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    Electrocatalytic method for producing quinone methides
    22.
    发明授权
    Electrocatalytic method for producing quinone methides 失效
    生产喹啉甲基化物的电催化方法

    公开(公告)号：US4624757A

    公开(公告)日：1986-11-25

    申请号：US816501

    申请日：1986-01-06

    Applicant: Zenon Lysenko ,  Eric E. Bancroft

    Inventor： Zenon Lysenko ,  Eric E. Bancroft

    IPC: C25B3/02 ,  C07B29/06 ,  C07C49/64

    CPC classification number: C25B3/02

    Abstract: A method for producing quinone methides by the electrocatalytic oxidation of bis(4-hydroxyphenyl)methanes using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as the oxidant. Spent oxidant, in the form of DDQH.sub.2, may be recycled and electrochemically regenerated to active DDQ oxidant.

    Abstract translation: 通过使用2,3-二氯-5,6-二氰基-1,4-苯醌（DDQ）作为氧化剂，通过双（4-羟基苯基）甲烷的电催化氧化来生产醌甲基化物的方法。 以DDQH2形式的废氧化剂可以循环使用并电化学再生成活性DDQ氧化剂。

    Method for preparing cyclic ethers and thioethers including oxygen isomers and sulfur analogs of prostacyclin
    23.
    发明授权
    Method for preparing cyclic ethers and thioethers including oxygen isomers and sulfur analogs of prostacyclin 失效
    制备环醚和硫醚的方法，包括前列环素的氧异构体和硫类似物

    公开(公告)号：US4258199A

    公开(公告)日：1981-03-24

    申请号：US886143

    申请日：1978-03-13

    Applicant: Kyriacos C. Nicolaou ,  William E. Barnette ,  Ronald L. Magolda ,  Zenon Lysenko

    Inventor： Kyriacos C. Nicolaou ,  William E. Barnette ,  Ronald L. Magolda ,  Zenon Lysenko

    IPC: C07D307/937 ,  C07D333/78 ,  C07D493/06 ,  C07F7/18 ,  C07D307/93

    CPC classification number: C07D307/937 ,  C07D333/78 ,  C07D493/06 ,  C07F7/1856

    Abstract: Unsaturated alcohols, thiols and thioesters are cyclized by a phenyl selenenyl halide; wherein the conformation flexibility of the unsaturated alcohol, thiol or thioester is selected such that the hydroxy group, thiol group or thioester group is capable of internal addition to at least one unsaturated bond in said alcohol, thiol or thioester; and wherein the ratio of the phenyl selenenyl halide to said unsaturated alcohol, thiol or thioester is 0.9-1.5 to 1. In a preferred embodiment, oxygen isomers and sulfur analogs of prostacyclin of the formula ##STR1## wherein X= ##STR2## Y=(E)- and (Z)- >C.dbd.CH--CH.sub.2 CH.sub.2 CH.sub.2 COOR; (E)- >CH--CH.dbd.CH--CH.sub.2 CH.sub.2 COOR; andR=any pharmaceutically acceptable cation or lower alkyl group comprising 1 to 4 carbon atoms are formed by:(1) cyclizing a PGF.sub.2.alpha. prostaglandin derivative or a 9.alpha. thio or 9.alpha. -thioester analog of prostaglandin PGF.sub.2.alpha. by reacting said prostaglandin derivative or analog with a phenyl selenenyl halide, wherein the molar ratio of said phenyl selenenyl halide to said prostaglandin derivative or analog is 0.9-1.5:1; and(2) oxidizing the product obtained therefrom.

    Abstract translation: 不饱和醇，硫醇和硫酯通过苯基硒基卤化物环化; 其中选择不饱和醇，硫醇或硫酯的构象柔性，使得羟基，硫醇基或硫酯基能够在所述醇，硫醇或硫酯中内部加成至少一个不饱和键; 苯基硒基卤化物与所述不饱和醇，硫醇或硫酯的比例为0.9-1.5:1。在优选的实施方案中，下式的前列环素的氧异构体和硫类似物，其中X = Y = （E） - 和（Z） - > C = CH-CH 2 CH 2 CH 2 COOR; （E） - > CH-CH = CH-CH 2 CH 2 COOR; 并且R =任何药学上可接受的阳离子或含有1-4个碳原子的低级烷基是通过以下方法形成的：（1）通过使所述前列腺素衍生物反应来环化前列腺素PGF2α的PGF2α前列腺素衍生物或9α硫代或9α-硫酯类似物 或与苯基硒基卤化物的类似物，其中所述苯基硒基卤化物与所述前列腺素衍生物或类似物的摩尔比为0.9-1.5:1; 和（2）氧化由其获得的产物。

    Hydroxy-functional polyesters
    29.
    发明授权
    Hydroxy-functional polyesters 失效
    羟基官能聚酯

    公开(公告)号：US07279546B2

    公开(公告)日：2007-10-09

    申请号：US10484419

    申请日：2002-07-16

    Applicant: Jerry E. White ,  Zenon Lysenko ,  Jimmy D. Earls ,  Marvin L. Dettloff ,  James A. Rabon, Jr. ,  Leonardo C. Lopez

    Inventor： Jerry E. White ,  Zenon Lysenko ,  Jimmy D. Earls ,  Marvin L. Dettloff ,  James A. Rabon, Jr. ,  Leonardo C. Lopez

    IPC: C08G63/00 ,  C08L67/00

    CPC classification number: C08L67/04 ,  C08G63/06 ,  C08G63/823 ,  C08G63/87 ,  C08L3/04 ,  C08L23/06 ,  C08L23/12 ,  C08L67/02 ,  Y10T428/31786 ,  C08L2666/26 ,  C08L2666/18 ,  C08L23/00 ,  C08L2666/06

    Abstract: The present invention provides thermoplastic hydroxy-functional polyesters. The polyesters have at least 10 sequential units, wherein the sequential units consist of units selected from units represented by the following formula (1) and units represented by the following formula (2); Wherein each of R1 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R2 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; each of R3 independently represents hydrogen or a substituted or unsubstituted homoalkyl or heteroalkyl group; Each of R4 independently represents a substituted or unsubstituted homoalkyl or heteroalkyl group; and said moiety having no fewer than 1 unit represented by formula (1) and no fewer than 1 unit represented by formula (2). The present invention further provides processes for making hydroxyfunctional polyesters, such as polymerizing epoxidized fatty acids in the presence of an onium salt, and compositions and articles that include or are derived from the hydroxyfuntional polyesters

    Abstract translation: 本发明提供热塑性羟基官能聚酯。 聚酯具有至少10个连续单元，其中顺序单元由选自下式（1）表示的单元和由下式（2）表示的单元组成。 其中R 1和R 2各自独立地表示氢或取代或未取代的高级烷基或杂烷基; R 2各自独立地表示氢或取代或未取代的均烷基或杂烷基; R 3各自独立地表示氢或取代或未取代的高级烷基或杂烷基; R 4各自独立地表示取代或未取代的均烷基或杂烷基; 并且所述部分具有不少于1个由式（1）表示的单元和不少于1个由式（2）表示的单元。 本发明还提供制备羟基官能聚酯的方法，例如在鎓盐存在下聚合环氧化脂肪酸，以及包含或衍生自羟基官能聚酯的组合物和制品

    Aldehyde and alcohol compositions derived from seed oils
    30.
    发明申请
    Aldehyde and alcohol compositions derived from seed oils 有权
    衍生自种子油的醛和醇组合物

    公开(公告)号：US20060193802A1

    公开(公告)日：2006-08-31

    申请号：US10551854

    申请日：2004-04-22

    Applicant: Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

    Inventor： Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

    IPC: C07C29/14

    CPC classification number: C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

    Abstract: An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxmethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foams.

    Abstract translation: 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或脂肪酸酯的混合物，所述羟甲基取代的脂肪酸或脂肪酸酯具有以下重量组成：大于约10至小于约95％的一元醇{单（羟甲基，大于 约1至小于约65％的二醇{二（羟甲基，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯;优选大于约3至小于约35％ 饱和物;优选小于约10％的不饱和度。醇组合物可以转化为用于制备聚氨酯板坯柔性泡沫的低聚多元醇。

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