公开(公告)号：US20150266000A1

公开(公告)日：2015-09-24

申请号：US14659753

申请日：2015-03-17

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: B01J19/24

CPC classification number: B01J19/24 ,  B01J8/067 ,  B01J19/0013 ,  B01J19/2425 ,  B01J2208/00176 ,  B01J2208/00256 ,  B01J2219/00081 ,  B01J2219/00094 ,  B01J2219/00103 ,  B01J2219/24

Abstract: The present invention relates to a reactor system (1) comprising a reactor 3, at least one cooler (5) connected to the reactor (3), at least one pump (7) for circulating at least some of a liquid heat-transfer medium (9), wherein the pump (7) is connected to the reactor (3) and/or the at least one cooler (5), and a container (11) for collecting the liquid heat-transfer medium (9), wherein the container (11) is connected to the reactor (3) and/or the at least one cooler (5), wherein the container (11) is disposed substantially below the reactor (3) and/or the at least one cooler (5). Moreover, the use of the reactor system (1) according to the invention for carrying out exothermic reactions is described.

Abstract translation: 本发明涉及一种包括反应器3的反应器系统（1），连接到反应器（3）的至少一个冷却器（5），至少一个泵（7），用于使至少一些液体传热介质 （9），其中泵（7）连接到反应器（3）和/或至少一个冷却器（5）和用于收集液体传热介质（9）的容器（11），其中 容器（11）连接到反应器（3）和/或至少一个冷却器（5），其中容器（11）基本上设置在反应器（3）和/或至少一个冷却器（5）的下方， 。 此外，描述了使用根据本发明的反应器系统（1）进行放热反应。

公开(公告)号：US20150246343A1

公开(公告)日：2015-09-03

申请号：US14633433

申请日：2015-02-27

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Cathrin Alexandra WELKER-NIEUWOUDT ,  Josef MACHT ,  Christian WALSDORFF ,  Cornelia Katharina DOBNER

IPC: B01J23/888 ,  B01J35/10 ,  C07C5/48 ,  B01J37/00 ,  C07C51/235 ,  C07D307/89 ,  B01J35/00 ,  B01J37/02

CPC classification number: B01J23/8885 ,  B01J23/002 ,  B01J23/007 ,  B01J23/70 ,  B01J23/8877 ,  B01J32/00 ,  B01J35/0006 ,  B01J35/1009 ,  B01J37/0009 ,  B01J37/0215 ,  B01J2219/30203 ,  B01J2219/30475 ,  C07C5/48 ,  C07C51/235 ,  C07C51/252 ,  C07C51/313 ,  C07C2523/888 ,  C07D307/89 ,  C07C57/04

Abstract: The invention relates to an oxidation catalyst comprising at least one inorganic, oxidic or ceramic, shaped support body having a BET surface area of less than 0.5 m2/g, based on the support, which is at least partly coated with a catalytically active multielement oxide, the catalyst being precious metal-free and the shaped support body having the form of a saddle whose saddle surface is curved oppositely in the two principal directions, to a process for producing it, to its use in various catalytic gas phase oxidations, and to corresponding processes for catalytic gas phase oxidation.

Abstract translation: 本发明涉及一种氧化催化剂，其包含至少一种基于载体的至少一种BET表面积小于0.5m 2 / g的无机，氧化或陶瓷形状的支撑体，所述载体至少部分地涂覆有催化活性多元素氧化物 ，催化剂是无贵金属的，并且具有鞍座形式的成形支撑体，其鞍形面在两个主要方向上相对弯曲，形成为其制造方法，用于各种催化气相氧化，以及 催化气相氧化的相应过程。

公开(公告)号：US20230174452A1

公开(公告)日：2023-06-08

申请号：US17921997

申请日：2021-04-26

Applicant: BASF SE

Inventor： Tile GIESHOFF ,  Ulrich HAMMON ,  Christian RAITH ,  Volker SCHLIEPHAKE ,  Anna Katharina DUERR ,  Tim VAN LOOVEREN ,  Christian REIN

IPC: C07C51/44

CPC classification number: C07C51/44

Abstract: The present invention relates to a method of redissociating Michael adducts of acrylic acid present in a liquid F in a redissociation apparatus comprising at least one separating column K, an evaporator V and a pump P, wherein, in the event of an unwanted rise in the viscosity of the residue R in the bottom space of the separating column K, the feed of the liquid F into the redissociation apparatus is stopped, the residue R in the bottom space of the separating column K is diluted and cooled with a solvent 1, and the bottom space of the separating column K is emptied.

公开(公告)号：US20210309598A1

公开(公告)日：2021-10-07

申请号：US17263415

申请日：2019-07-16

Applicant: BASF SE

Inventor： Nicole JANSSEN ,  Peter ZUROWSKI ,  Ulrich HAMMON ,  Sylke HAREMZA

IPC: C07C51/50 ,  C07C51/44

Abstract: Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with furfural in an amount that results in a furfural content in the range from 25 to 1000 ppmw based on the weight of the acrylic acid present in P. Liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 25 to 1000 ppmw of furfural in each case based on the weight of the acrylic acid present in P.

公开(公告)号：US20170173492A1

公开(公告)日：2017-06-22

申请号：US15382073

申请日：2016-12-16

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: B01D3/32 ,  C07C67/52 ,  B01D53/18 ,  B01D3/22 ,  B01D3/26

CPC classification number: B01D3/324 ,  B01D3/20 ,  B01D3/205 ,  B01D3/225 ,  B01D3/26 ,  B01D3/32 ,  B01D53/18 ,  C07C51/42 ,  C07C51/44 ,  C07C67/52 ,  C07C57/04

Abstract: The present invention relates to a column (1) for thermal treatment of fluid mixtures, having a cylindrical, vertically aligned column body (2) which forms a column cavity (3), having a sequence of vertically spaced-apart dual-flow mass transfer trays (8) which are mounted in the column cavity (3) and which have orifices for passage of liquid and gas in countercurrent, and having at least one gas entry orifice (5) disposed below the lowermost of the sequence of dual-flow mass transfer trays (8). It is a characteristic feature of the column of the invention that a gas distribution tray (9) which is disposed between the lowermost of the sequence of dual-flow mass transfer trays (8) and the gas entry orifice (5) has orifices (32) for vertical passage of gas which can be introduced into the column cavity (3) via the gas entry orifice (5), the orifices (32) being formed so as to bring about equal gas distribution over the column cross section. The invention further relates to a process for thermal treatment of fluid mixtures in such a column (1).

公开(公告)号：US20160083267A1

公开(公告)日：2016-03-24

申请号：US14857998

申请日：2015-09-18

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER ,  Christian RAITH

IPC: C02F1/04 ,  B01D3/26 ,  B01D1/00 ,  C02F1/16

CPC classification number: C02F1/048 ,  B01D1/0058 ,  B01D3/26 ,  B01D3/346 ,  C02F1/16 ,  C02F2103/36 ,  C02F2303/10 ,  C07C51/44 ,  C07C57/04 ,  Y02W10/30

Abstract: The present invention relates to a process for treating secondary components obtained in acrolein and/or (meth)acrylic acid production, comprising the steps of: a) contacting at least one wastewater stream (201) comprising at least a portion of the water of reaction removed in a first stage of a saturation column (101) with at least one process offgas stream (203), b) introducing energy by means of a first heat transferer (103) provided in a first saturation circuit (301) into the first stage of the saturation column (101), c) partly vaporizing the wastewater stream (201) into the process offgas stream (203) and passing the combined gas stream (205) into a second stage of the saturation column (101), d) drawing off a concentrated wastewater stream (207) from the bottom (1011) of the first stage of the saturation column (101) and feeding it to the top (1023) of the second stage of the saturation column (101), e) introducing energy by means of a second heat transferer (105) provided in a second circuit (303) into the second stage of the saturation column (101), f) partly vaporizing the concentrated wastewater stream (207) into the combined gas stream (205) to obtain an offgas stream (209), g) superheating the offgas stream (209), after it has been saturated, in a third heat transferer (113) to obtain a superheated offgas stream (211) and h) transferring the offgas stream (209) or the superheated offgas stream (211) from the saturation column (101) to a thermal aftertreatment. The present invention further relates to a plant (1) for treating the secondary components obtained in acrolein and/or (meth)acrylic acid production.

Abstract translation: 本发明涉及一种用于处理由丙烯醛和/或（甲基）丙烯酸生产获得的二次成分的方法，包括以下步骤：a）使至少一个包含至少一部分反应水的废水流（201） 在具有至少一个工艺废气流（203）的饱和塔（101）的第一级中去除，b）通过设置在第一饱和电路（301）中的第一热传递器（103）将能量引入第一级 的饱和塔（101），c）将废水流（201）部分蒸发到工艺废气流（203）中，并将组合气流（205）送入饱和塔（101）的第二级，d） 从饱和塔（101）的第一级的底部（1011）离开浓缩废水流（207）并将其供给到饱和塔（101）的第二级的顶部（1023），e）引入能量 通过设置在其中的第二传热器（105） 第二回路（303）进入饱和塔（101）的第二阶段，f）将浓缩废水流（207）部分汽化成合并气流（205）以获得废气流（209），g）使废气过热 （209）或过热废气流（211）从饱和塔（209）中转移出来，在第三热转移器（113）中， （101）进行热后处理。 本发明还涉及用于处理在丙烯醛和/或（甲基）丙烯酸生产中获得的二次成分的设备（1）。

公开(公告)号：US20160040929A1

公开(公告)日：2016-02-11

申请号：US14817351

申请日：2015-08-04

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: F25J3/02

CPC classification number: F25J3/0271 ,  B01D3/20 ,  B01D3/22 ,  B01D3/32 ,  B01D3/4261 ,  C07C45/783 ,  C07C45/80 ,  C07C45/82 ,  C07C51/44 ,  C07C51/48 ,  C07C67/54 ,  C07C47/22 ,  C07C57/04 ,  C07C69/54

Abstract: The present invention relates to a column (1) for thermal treatment of a fluid, having a cylindrical, vertical column body (2) which forms a column cavity (3), and a mass transfer tray (4) which is disposed in the column cavity (3) and forms a collecting area (5). The inventive column (1) is characterized by a circulation device (9) having at least one drain orifice (10) formed in the column body (2) above the collecting area (5), a circulation line (11) in fluid connection with the drain orifice (10) and at least one recycling orifice (14; 14-1 to 14-3) which is in fluid connection with the circulation line (11) and is formed in the column body (2) above the collecting area (5). The invention also relates to a thermal separating process in which such a column (1) is used. In this separating process, a gas ascends within the column and a liquid descends within the column, said gas and/or liquid especially comprising (meth)acrylic monomers.

Abstract translation: 本发明涉及一种用于热处理流体的柱（1），其具有形成柱腔（3）的圆柱形垂直柱体（2）和设置在柱中的传质托盘（4） （3）并形成收集区域（5）。 本发明的塔（1）的特征在于具有在收集区域（5）上方的柱体（2）中形成的至少一个排水孔（10）的循环装置（9），与流体连通 所述排水孔（10）和至少一个与所述循环管线（11）流体连接并且在所述塔体（2）中的所述收集区域上方形成的再循环孔（14; 14-1至14-3） 5）。 本发明还涉及使用这种塔（1）的热分离方法。 在该分离过程中，气体在柱内上升，液体在柱内下降，所述气体和/或液体特别包含（甲基）丙烯酸单体。

公开(公告)号：US20160010850A1

公开(公告)日：2016-01-14

申请号：US14738050

申请日：2015-06-12

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: F22B1/02

CPC classification number: F22B1/021 ,  B01D1/0082 ,  F17C2221/035 ,  F17C2223/0153 ,  F17C2223/033 ,  F17C2225/0123 ,  F17C2225/035 ,  F17C2225/036 ,  F17C2227/0393 ,  F17C2265/05

Abstract: The present invention relates to a system (1) for operating a liquid gas evaporator (3), comprising an evaporator (3) for evaporating a liquid gas into its gaseous aggregation state, a trough (5) carrying the evaporator (3), a housing (7) which surrounds the evaporator (3) on three sides and which terminates flush with the trough (5), at least one detector (9) which is sensitive to the liquid gas and its gaseous aggregation state and which is arranged in the trough (5), a line (11) for the distribution of vapor D, which is provided on the fourth, non-housed side of the evaporator (3) and which is arranged at that margin of the trough (5) which is not closed off by the housing (7), a feed (13), connected to the line (11), for the vapor D, and a regulating valve (15) provided on the feed (13) and connected to the detector (9) and at least one shut-off valve (17). The present invention relates furthermore, to a method for operating a liquid gas evaporator (3).

Abstract translation: 本发明涉及一种用于操作液体气体蒸发器（3）的系统（1），包括用于将液体气体蒸发成气态聚集状态的蒸发器（3），承载蒸发器（3）的槽（5） 在三侧围绕蒸发器（3）并且与槽（5）齐平的壳体（7），至少一个对液体气体和其气体聚集状态敏感的检测器（9） 槽（5），用于分配蒸气D的管线（11），其设置在蒸发器（3）的第四非容纳侧上，并且布置在不是的槽（5）的边缘处 通过壳体（7）封闭，连接到管线（11）的用于蒸气D的进料（13）和设置在进料（13）上并连接到检测器（9）的调节阀（15） 和至少一个截止阀（17）。 本发明还涉及一种操作液体气体蒸发器（3）的方法。

公开(公告)号：US20150360142A1

公开(公告)日：2015-12-17

申请号：US14738033

申请日：2015-06-12

Applicant: BASF SE

Inventor： Joerg HEILEK ,  Rainer ASKANI ,  Ulrich HAMMON ,  Wolfgang SCHNEIDER ,  Thomas WALTER

IPC: B01D9/00

CPC classification number: B01D9/0004 ,  B01D9/0013 ,  B01D9/005 ,  C07C51/43

Abstract: The present invention relates to an apparatus (1) for separation of a target product from a liquid phase P comprising the target product, comprising at least one primary space (3) for a heat transfer medium W, at least one first feed unit (5a) and one first removal unit (5b) for the heat transfer medium W, at least one secondary space (7) for the liquid phase P, at least one second feed unit (9) for the liquid phase P, at least one crystallization surface (13) which divides the primary space (3) and the secondary space (7), at least one second removal unit (15) for the target product and at least one application unit (11) for a liquid phase P0 essentially directly to the crystallization surface (13) or the surfaces of lines that conduct the heat transfer medium W. The present invention further relates to a process for removing a target product from a liquid phase P comprising the target product.

Abstract translation: 本发明涉及一种用于从包括目标产品的液相P分离目标产物的装置（1），其包括用于传热介质W的至少一个主空间（3），至少一个第一进料单元（5a ）和用于传热介质W的一个第一移除单元（5b），用于液相P的至少一个辅助空间（7），用于液相P的至少一个第二进料单元（9），至少一个结晶表面 （3）和二次空间（7）的至少一个第二移除单元（13）和至少一个用于液相P0的至少一个施加单元（11），其基本上直接连接到所述第一空间 结晶表面（13）或传导传热介质W的管线表面。本发明还涉及从包含目标产物的液相P除去目标产物的方法。

公开(公告)号：US20150267391A1

公开(公告)日：2015-09-24

申请号：US14661462

申请日：2015-03-18

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: E03F5/10 ,  E03F5/22

CPC classification number: E03F5/105 ,  B01J2219/00006 ,  B08B9/08 ,  E03F5/22 ,  Y10T137/0318 ,  Y10T137/86035

Abstract: The present invention describes a system (1) for recovering liquid or free-flowing chemicals in a chemical plant (3), comprising at least two plant sections (3a, 3b), for each plant section (3a, 3b) at least one connecting device (5a, 5b) arranged at the lowest point, at least one common collecting line (7) which runs beneath the connecting devices (5a, 5b) and connects them to one another, at least one collecting vessel (9) arranged at the same height as or higher than the at least two plant sections (3a, 3b) and above the collecting line (7), at least one pump (11) provided in the collecting line (7) between the connecting devices (5a, 5b) and the collecting vessel (9) for drawing off the at least one liquid or free-flowing chemical combined in the collecting line (7) and introducing it into the collecting vessel (9).

Abstract translation: 本发明描述了一种用于在化学设备（3）中回收液体或自由流动的化学物质的系统（1），其包括至少两个植物区段（3a，3b），每个植物区段（3a，3b）至少一个连接 布置在最低点处的装置（5a，5b），在连接装置（5a，5b）下方延伸并将它们彼此连接的至少一个公共收集线（7），至少一个集中容器（9） 与所述至少两个植物部分（3a，3b）和收集线（7）上方相同的高度或高于在所述连接装置（5a，5b）之间的收集线（7）中的至少一个泵（11） 以及收集容器（9），用于抽出组合在收集管线（7）中的至少一种液体或自由流动化学品并将其引入收集容器（9）中。