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21.发明授权Silicon rubber composition having excellent durability in repeated mold release 失效硅橡胶组合物在反复脱模时具有优异的耐久性
公开(公告)号：US5342913A
公开(公告)日：1994-08-30
申请号：US92807
申请日：1993-09-29
申请人： Toshio Takago , Hiroshi Inomata , Shinichi Sato , Hitoshi Kinami
发明人： Toshio Takago , Hiroshi Inomata , Shinichi Sato , Hitoshi Kinami
摘要： An addition-curable type rubber composition comprising a vinyl-containing organopolysiloxane as a base polymer and, particularly, further comprising as a crosslinking agent an organohydrogenpolysiloxane which contains, in its molecule, at least one unit having the following formula: ##STR1## wherein J is an alkylene group of from 2 to 4 carbon atoms, Rf is a perfluoropolyether group, and a is an integer of from 0 to 2. The composition has excellent durability in repeated mold release, and a mold prepared from the composition is able to produce moldings of constant quality even when molding is repeated a large number of times.
摘要翻译： 一种可加成固化型橡胶组合物，其包含含乙烯基的有机聚硅氧烷作为基础聚合物，特别是还包含作为交联剂的有机氢聚硅氧烷，所述有机氢聚硅氧烷在其分子中含有至少一个具有下式的单元：其中J 是2至4个碳原子的亚烷基，Rf是全氟聚醚基团，a是0-2的整数。该组合物在反复脱模时具有优异的耐久性，并且由该组合物制备的模具能够产生 即使在成型时重复多次也能保持恒定质量的模制品。
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22.发明授权Mold releasing resin composition and molding of curable resin using the same 失效脱模树脂组合物和使用其的可固化树脂的成型
公开(公告)号：US5316716A
公开(公告)日：1994-05-31
申请号：US897385
申请日：1992-06-12
申请人： Shinichi Sato , Morio Oohasi , Hiroshi Inomata
发明人： Shinichi Sato , Morio Oohasi , Hiroshi Inomata
IPC分类号： B29C33/64 , B29K63/00 , B29K67/00 , B29K75/00 , C10M105/76 , C10M107/50 , C10N40/36 , B29C33/58
CPC分类号： B29C33/64 , B29K2083/00
摘要： A mold releasing resin composition is provided which contains at least one fluorinated compound end-blocked with a dimethylhydrogensiloxane group and optionally having a fluorinated polyether linkage. The composition is applied to the inner surface of a silicone rubber mold and cured thereat before a curable resin is admitted into the mold, cured therein, and then removed from the mold.
摘要翻译： 提供一种脱模树脂组合物，其含有至少一种用二甲基氢硅氧烷基封端的氟化化合物，并且任选具有氟化聚醚键。 将组合物施加到硅橡胶模具的内表面上并固化，然后将可固化树脂进入模具，在其中固化，然后从模具中取出。
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公开(公告)号：US5312885A
公开(公告)日：1994-05-17
申请号：US38600
申请日：1993-03-23
申请人： Toshio Takago , Hiroshi Inomata , Shinichi Sato , Hitoshi Kinami , Hirofumi Kishita , Noriyuki Koike , Takashi Matsuda
发明人： Toshio Takago , Hiroshi Inomata , Shinichi Sato , Hitoshi Kinami , Hirofumi Kishita , Noriyuki Koike , Takashi Matsuda
IPC分类号： C08L83/07 , C08G65/336 , C08K5/09 , C08K5/5313 , C08L71/02 , C08L83/04 , C08L83/08 , C08L83/12 , C08L83/14 , C09D183/04 , C09D183/14 , C08G77/06
CPC分类号： C08L71/02 , C08G65/336 , C08L83/12 , C08L83/14
摘要： Disclosed is an organosiloxane polymer-based composition curable by the mechanism of the hydrosilation reaction between silicon-bonded vinyl groups in a vinylsilyl-terminated perfluoropolyalkylene or perfluoropolyalkylene polyether compound and silicon-bonded hydrogen atoms in a hydrosilyl-terminated perfluoropolyalkylene or perfluoropolyalkylene polyether compound as promoted by a catalyst. Different from conventional platinum compounds as the catalyst for the hydrosilation reaction, the catalyst in the inventive composition is a complex compound of rhodium such as tris(triphenylphosphine) rhodium chloride, rhodium acetate dimer and rhodium acetylacetonate so that the composition is imparted with greatly improved storage stability without viscosity increase over months at room temperature but without affectibg the curability at an elevated temperature.
摘要翻译： 公开了一种基于有机硅氧烷聚合物的组合物，其可通过在乙烯基甲硅烷基封端的全氟聚亚烷基或全氟聚亚烷基聚醚化合物中与硅键合的乙烯基之间的硅氢化硅烷化氢化硅烷基封端的全氟聚亚烷基或全氟聚亚烷基聚醚化合物中与硅键合的氢原子 通过催化剂。 与作为硅氢化反应的催化剂的常规铂化合物不同，本发明组合物中的催化剂是铑的络合物，例如三（三苯基膦）氯化铑，乙酸铑二聚体和乙酰丙酮化铑，使得组合物被赋予极大改善的储存 在室温下几个月没有粘度增加的稳定性，但在高温下不影响固化性。
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公开(公告)号：US5310846A
公开(公告)日：1994-05-10
申请号：US36252
申请日：1993-03-24
CPC分类号： C08K5/14
摘要： A fluorine-containing silicone rubber composition comprising (A) a fluorocarbonsiloxane having the following general formula (1): ##STR1## wherein a to d is a positive integer, R.sup.1 and R.sup.2 are a monovalent hydrocarbon group free of aliphatic unsaturated groups, R.sup.3 is a monovalent hydrocarbon group containing an aliphatic unsaturated bond, Rf.sup.1 is a fluorine-containing alkylene polyether group, and (B) an organic peroxide. The composition is excellent in solvent resistance, chemical resistance and water and oil repellency, and can be molded by press molding and has been improved in respect of insufficient curing.
摘要翻译： 一种含氟硅橡胶组合物，其包含（A）具有以下通式（1）的氟代硅氧烷：其中a至d为正整数，R 1和R 2为不含 脂肪族不饱和基团，R 3为含有脂肪族不饱和键的一价烃基，Rf 1为含氟亚烷基聚醚基，（B）有机过氧化物。 该组合物的耐溶剂性，耐化学性和拒水斥油性优异，可以通过压制成型而成型，在固化不足方面得到改善。
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公开(公告)号：US5292848A
公开(公告)日：1994-03-08
申请号：US964946
申请日：1992-10-22
申请人： Masayuki Ikeno , Miyuki Tanaka , Hiroyasu Hara , Hironao Fujiki , Shinichi Sato , Hiroshi Inomata
发明人： Masayuki Ikeno , Miyuki Tanaka , Hiroyasu Hara , Hironao Fujiki , Shinichi Sato , Hiroshi Inomata
摘要： The present fluorosilicone composition is an addition reaction curable composition that uses, as an alkenyl group-containing organopolysiloxane, a fluorine-containing organopolysiloxane represented by the following general formula (1): ##STR1## wherein R represents a vinyl group, R.sup.1 represents an alkyl group or a phenyl group, R.sup.2 represents a group represented by the following formula (2): ##STR2## in which p is an integer of 2 to 8 and q is an integer of 1 to 10, and n and m are each a positive integer. This composition can form a gellike cured product particularly excellent in acid resistance.
摘要翻译： 本发明的氟硅酮组合物是使用由以下通式（1）表示的含氟有机聚硅氧烷作为含烯基的有机聚硅氧烷的加成反应固化性组合物：（*化学结构*）（1）其中R表示乙烯基 基团，R 1表示烷基或苯基，R 2表示由下式（2）表示的基团：（*化学结构*）（2）其中p为2〜8的整数，q为 1〜10，n和m各自为正整数。 该组合物可以形成特别优异的耐酸性的胶凝固化产物。
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公开(公告)号：US5196558A
公开(公告)日：1993-03-23
申请号：US925147
申请日：1992-08-06
IPC分类号： C07F7/08
CPC分类号： C07F7/0852 , C07F7/0896
摘要： Novel siloxane compounds are provided which have 1-5 hydrogen atoms each attached to a silicon atom (SiH group) and 1-5 epoxy or alkoxy - containing organic groups each attached to a silicon atom in a molecule. These siloxane compounds are useful tackifiers to conventional resins, have good affinity to fluorinated silicone resins and rubbers so that they impart adhesion to fluorinated silicone resins and rubbers, and contribute to solvent resistance and minimal moisture permeability.
摘要翻译： 提供了新的硅氧烷化合物，其具有各自连接到硅原子（SiH基团）上的1-5个氢原子和分别连接到硅原子上的1-5个环氧基或含烷氧基的有机基团。 这些硅氧烷化合物是常规树脂的有用的增粘剂，对氟化硅树脂和橡胶具有良好的亲和性，使得它们赋予氟化硅树脂和橡胶粘合性，并且有助于耐溶剂性和最小的透湿性。
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公开(公告)号：US4364809A
公开(公告)日：1982-12-21
申请号：US127523
申请日：1980-03-05
IPC分类号： C08F2/48 , C08F30/08 , C08F292/00 , C08F299/08 , C08K5/14 , C08L83/04 , G03F7/075 , C08F130/08
CPC分类号： G03F7/0757 , C08F292/00 , C08F299/08 , C08F30/08 , C08K5/14 , C08G77/06 , C08G77/20 , C08G77/70 , Y10S525/925
摘要： There is disclosed a method for preparing a rubbery cured product of an organopolysiloxane. This product is free from the problems caused by the limited crosslinking velocity or by the necessity of admixing a foreign material such as a crosslinking catalyzing curing agent or a photosensitizer. In this method, a substantially linear diorganopolysiloxane terminated at both chain ends with triorganosilyl groups, each of the triorganosilyl groups having, preferably, 2 or 3 vinyl groups bonded to the silicon atom, is irradiated with ultraviolet light having an energy distribution predominantly rich in the wavelength region from 100 to 300 nm or, preferably, from 180 to 250 nm whereby the energy of the ultraviolet light is most effectively utilized for effecting the crosslinking of the organopolysiloxane. When rapid decrease of the surface tackiness and rapid curing in the depth of a relatively thick layer are desired in the photocuring of the organopolysiloxane by the ultraviolet irradiation, the organopolysiloxane is admixed with small amounts of an organic peroxide.
摘要翻译： 公开了一种制备有机聚硅氧烷的橡胶状固化产物的方法。 该产品没有由有限的交联速度引起的问题，或不需要混合外来材料如交联催化固化剂或光敏剂。 在这种方法中，用三有机甲硅烷基终止在两个链端的基本上线性的二有机聚硅氧烷，具有优选2或3个与硅原子键合的乙烯基的三有机甲硅烷基中的每一个被紫外线照射，该紫外光具有主要富含 波长范围为100〜300nm，优选为180〜250nm，由此紫外线的能量最有效地用于有机聚硅氧烷的交联。 当通过紫外线照射在有机聚硅氧烷的光固化中期望在相对厚的层的深度上快速降低表面粘性和快速固化时，有机聚硅氧烷与少量有机过氧化物混合。
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28.发明授权公开(公告)号：US08970749B2
公开(公告)日：2015-03-03
申请号：US13049837
申请日：2011-03-16
申请人： Hiroshi Inomata , Eiji Watanabe
发明人： Hiroshi Inomata , Eiji Watanabe
IPC分类号： H04N5/335 , H01L27/146
CPC分类号： H01L27/14632 , H01L27/14618 , H01L2924/0002 , H01L2924/00
摘要： There are provided a semiconductor substrate; a photoelectric conversion film stacked on a layer that is disposed on the light incidence side of the semiconductor substrate; signal reading unit formed in a surface portion of the semiconductor substrate, for reading out, as shot image signals, signals corresponding to signal charge amounts detected by the photoelectric conversion film according to incident light quantities; a transparent substrate bonded to a layer that is disposed on the light incidence side of the photoelectric conversion film with a transparent resin as an adhesive; and electric connection terminals which are connected to the signal reading unit by interconnections and which penetrate through the semiconductor substrate and are exposed in a surface, located on the opposite side to the side where the photoelectric conversion film is provided, of the semiconductor substrate.
摘要翻译： 提供半导体衬底; 叠层在设置在半导体衬底的光入射侧的层上的光电转换膜; 信号读取单元，形成在所述半导体衬底的表面部分中，用于根据入射光量读出与所述光电转换膜检测到的信号电荷量相对应的信号作为镜像信号; 透明基板，以透明树脂作为粘合剂结合到设置在光电转换膜的光入射侧的层; 以及电连接端子，其通过互连连接到信号读取单元，并且穿过半导体衬底并暴露在位于与设置有光电转换膜的一侧相对的表面上的半导体衬底。
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公开(公告)号：US5639845A
公开(公告)日：1997-06-17
申请号：US551339
申请日：1995-11-01
IPC分类号： C08G77/385 , C08G77/08
CPC分类号： C08G77/385
摘要： A novel and very efficient method is disclosed for the introduction of perfluoroalkyl groups into an organopolysiloxane by utilizing the hydrosilation reaction with an organohydrogenpolysiloxane. Different from the conventional but inefficient hydrosilation reaction using a perfluoroalkyl-substituted ethylene as the olefin compound, the inventive method utilizes a propene-1 3-substituted by a perfluoroalkyl group compound as the olefin compound to react with an organohydrogenpolysiloxane by which a very high efficiency in the hydrosilation reaction can be obtained without side reactions which otherwise greatly decrease the yield of the desired perfluoroalkyl-containing organopolysiloxane product.
摘要翻译： 公开了一种通过利用有机氢聚硅氧烷的氢硅化反应将全氟烷基引入有机聚硅氧烷的新颖而非常有效的方法。 与使用全氟烷基取代的乙烯作为烯烃化合物的常规但低效的硅氢化反应不同，本发明的方法利用由全氟烷基化合物作为烯烃化合物取代的丙烯-1,3-与有机氢聚硅氧烷反应，通过该有机氢聚硅氧烷具有非常高的效率 在氢化硅烷化反应中可以获得无副反应，否则大大降低了所需的含全氟烷基的有机聚硅氧烷产物的产率。
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公开(公告)号：US5331076A
公开(公告)日：1994-07-19
申请号：US993877
申请日：1992-12-23
IPC分类号： C07F7/12 , C07F7/08 , C08G59/00 , C08G59/02 , C08G77/42 , C08G77/46 , C08G77/50 , C08K5/54 , C09J183/00 , C09J183/10 , G03C1/93 , C08L83/08
CPC分类号： C08G77/50 , C07F7/0852 , C07F7/0896 , C08G77/46 , C08K5/5406
摘要： Novel siloxane compounds having a fluorinated group, an SiH group reactive with silicone resins, and an epoxy-bearing organic group attached to a silicon atom, each in a backbone, are effective for providing adhesion and are useful tackifiers for various resins.
摘要翻译： 具有氟化基团的新型硅氧烷化合物，与有机硅树脂反应的SiH基团和与硅原子连接的含环氧基的有机基团各自在骨架中，对于提供粘合性是有效的，并且是各种树脂的有用的增粘剂。
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