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    Gas Separations Using High Performance Mixed Matrix Membranes
    21.
    发明申请
    Gas Separations Using High Performance Mixed Matrix Membranes 有权
    使用高性能混合基质膜进行气体分离

    公开(公告)号：US20080141858A1

    公开(公告)日：2008-06-19

    申请号：US11612388

    申请日：2006-12-18

    申请人： Chunqing Liu ,  Man-Wing Tang ,  Stephen T. Wilson ,  David A. Lesch

    发明人： Chunqing Liu ,  Man-Wing Tang ,  Stephen T. Wilson ,  David A. Lesch

    IPC分类号： B01D53/22

    CPC分类号： B01D69/141 ,  B01D53/228 ,  B01D61/362 ,  B01D67/0079

    摘要： The present invention discloses a novel method of making high performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions of solvents, uniformly dispersed polymer stabilized molecular sieves, and at least two different types of polymers as the continuous blend polymer matrix. MMMs as dense films or asymmetric flat sheet or hollow fiber membranes fabricated by the method described in the current invention exhibit significantly enhanced permeation performance for separations over the polymer membranes made from the continuous blend polymer matrix. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.

    摘要翻译： 本发明公开了使用稳定的溶剂浓缩悬浮液，均匀分散的聚合物稳定化分子筛和至少两种不同类型的聚合物作为连续共混聚合物基质制备高性能混合基质膜（MMM）的新方法。 通过本发明所述方法制造的致密膜或非对称平板或中空纤维膜的MMM显示出从由连续共混聚合物基质制成的聚合物膜上的分离显着提高的渗透性能。 本发明的MMM适用于各种气体，蒸汽和液体分离，例如醇/水，CO 2 / CH 4，H 2 CH 2，N 2，N 2，CO 2，N 2，N 2， 烯烃/石蜡，异/正链烷烃和其它轻质气体分离。

    PLASTICIZATION RESISTANT MEMBRANES
    23.
    发明申请
    PLASTICIZATION RESISTANT MEMBRANES 审中-公开
    耐化学腐蚀膜

    公开(公告)号：US20100270234A1

    公开(公告)日：2010-10-28

    申请号：US12833193

    申请日：2010-07-09

    申请人： Chunqing Liu ,  Stephen T. Wilson ,  Jeffrey J. Chiou ,  David A. Lesch ,  Santi Kulprathipanja

    发明人： Chunqing Liu ,  Stephen T. Wilson ,  Jeffrey J. Chiou ,  David A. Lesch ,  Santi Kulprathipanja

    IPC分类号： B01D71/06 ,  C08J5/22

    CPC分类号： B01D71/16 ,  B01D53/228 ,  B01D67/0006 ,  B01D67/0079 ,  B01D71/54 ,  B01D2323/30 ,  C08J5/2275 ,  C08J2375/04 ,  Y02P20/152

    摘要： This invention discloses a composition of, a method of making, and an application of high plasticization-resistant chemically cross-linked organic-inorganic hybrid membranes such as cross-linked cellulose acetate-cellulose triacetate-polyurethanepropylsilsesquioxane membranes. These cross-linked membranes with covalently interpolymer-chain-connected hybrid networks were prepared via a sol-gel condensation polymerization of cross-linkable organic polymer-organosilicon alkoxide precursor membrane materials. CO2 plasticization tests on these cross-linked membranes demonstrate extremely high CO2 plasticization resistance under CO2 pressure up to 5516 kPa (800 psig). These new cross-linked membranes can be used not only for gas separations such as CO2/CH4 and CO2/N2 separations, O2/N2 separation, olefin/paraffin separations (e.g. propylene/propane separation), iso/normal paraffins separations, but also for liquid separations such as desalination.

    摘要翻译： 本发明公开了一种组合物，制备和应用高增塑性化学交联的有机 - 无机杂化膜的组合物，例如交联的乙酸纤维素 - 三乙酸纤维素 - 聚氨酯丙基倍半硅氧烷膜。 通过可交联的有机聚合物 - 有机硅醇盐前体膜材料的溶胶 - 凝胶缩聚制备了具有共价互聚物链连接的杂化网络的这些交联膜。 这些交联膜上的二氧化碳增塑试验在二氧化碳压力高达5516 kPa（800 psig）下表现出极高的二氧化碳增塑性。 这些新的交联膜不仅可用于气体分离，如CO2 / CH4和CO2 / N2分离，O2 / N2分离，烯烃/石蜡分离（如丙烯/丙烷分离），异/正链烷烃分离， 用于液体分离，如脱盐。

    Molecular Sieve/Polymer Asymmetric Flat Sheet Mixed Matrix Membranes
    24.
    发明申请
    Molecular Sieve/Polymer Asymmetric Flat Sheet Mixed Matrix Membranes 有权
    分子筛/聚合物不对称平板混合基质膜

    公开(公告)号：US20090152763A1

    公开(公告)日：2009-06-18

    申请号：US11954454

    申请日：2007-12-12

    申请人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch

    发明人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch

    IPC分类号： B29D7/01

    CPC分类号： B01D69/148 ,  B01D67/0079 ,  B01D69/06 ,  B01D71/028 ,  B01D2325/022

    摘要： The present invention discloses an approach for making mixed matrix membranes (MMMS) and methods for using these membranes. These MMMs contain a continuous polymer matrix and dispersed microporous molecular sieve particles. This invention also pertains to control of the thickness of the thin dense selective mixed matrix membrane layer that is equal to or greater than the particle size of the largest molecular sieve particles for making large scale asymmetric MMMs. In particular, the invention is directed to making asymmetric flat sheet MMM by a phase inversion technique. The MMMs of the present invention exhibit at least 20% increase in selectivity compared to the polymer membranes prepared from their corresponding continuous polymer matrices. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor separations.

    摘要翻译： 本发明公开了一种制备混合基质膜（MMMS）的方法和使用这些膜的方法。 这些MMM含有连续的聚合物基质和分散的微孔分子筛颗粒。 本发明还涉及等于或大于用于制造大规模不对称MMM的最大分子筛颗粒的粒度的薄致密选择性混合基质膜层的厚度的控制。 特别地，本发明涉及通过相位反转技术制造不对称平板MMM。 与由其相应的连续聚合物基质制备的聚合物膜相比，本发明的MMM显示出至少20％的选择性增加。 本发明的MMM适用于各种液体，气体和蒸气分离。

    Molecular Sieve/Polymer Hollow Fiber Mixed Matrix Membranes
    25.
    发明申请
    Molecular Sieve/Polymer Hollow Fiber Mixed Matrix Membranes 审中-公开
    分子筛/聚合物中空纤维混合基质膜

    公开(公告)号：US20090152755A1

    公开(公告)日：2009-06-18

    申请号：US11954463

    申请日：2007-12-12

    申请人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch

    发明人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch

    IPC分类号： D04H3/16

    CPC分类号： B01D69/148 ,  B01D67/0079 ,  B01D69/08 ,  B01D69/087 ,  B01D71/028

    摘要： The present invention discloses a method for making mixed matrix membranes (MMMs) and methods for using these membranes. These MMMs contain a continuous polymer matrix and dispersed microporous molecular sieve particles. This invention also pertains to control the thickness of the thin dense selective mixed matrix layer equal to or greater than the particle size of the largest molecular sieve particles for making large scale asymmetric MMMs. In particular, the invention is directed to make asymmetric hollow fiber MMM by a phase inversion technique. The MMMs of the present invention exhibit at least 20% increase in selectivity compared to the polymer membranes prepared from their corresponding continuous polymer matrices. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor separations.

    摘要翻译： 本发明公开了一种制备混合基质膜（MMM）的方法和使用这些膜的方法。 这些MMM含有连续的聚合物基质和分散的微孔分子筛颗粒。 本发明还涉及控制等于或大于用于制造大规模非对称MMM的最大分子筛颗粒的粒度的薄致密选择性混合基质层的厚度。 特别地，本发明涉及通过相位反转技术制造不对称中空纤维MMM。 与由其相应的连续聚合物基质制备的聚合物膜相比，本发明的MMM显示出至少20％的选择性增加。 本发明的MMM适用于各种液体，气体和蒸气分离。

    Method of Making Polymer Functionalized Molecular Sieve/Polymer Mixed Matrix Membranes
    26.
    发明申请
    Method of Making Polymer Functionalized Molecular Sieve/Polymer Mixed Matrix Membranes 审中-公开
    制备聚合物官能化分子筛/聚合物混合基质膜的方法

    公开(公告)号：US20090131242A1

    公开(公告)日：2009-05-21

    申请号：US11940539

    申请日：2007-11-15

    申请人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch ,  Douglas B. Galloway

    发明人： Chunqing Liu ,  Stephen T. Wilson ,  David A. Lesch ,  Douglas B. Galloway

    IPC分类号： B01J20/28

    CPC分类号： B01J20/28004 ,  B01D53/228 ,  B01D61/362 ,  B01D67/0088 ,  B01D67/0093 ,  B01D69/148 ,  B01D71/028 ,  B01D71/64 ,  B01D71/68 ,  B01D2256/24 ,  B01D2257/504 ,  B01J20/18 ,  B01J20/26 ,  B01J20/28026 ,  Y02C10/10

    摘要： The present invention discloses a method of making polymer functionalized molecular sieve/polymer mixed matrix membranes (MMMs) with either no macrovoids or voids of less than several Angstroms at the interface of the polymer matrix and the molecular sieves by incorporating polyethersulfone (PES) or cellulose triacetate (CTA) functionalized molecular sieves into a continuous polyimide or cellulose acetate polymer matrix. The MMMs, particularly PES functionalized AlPO-14/polyimide MMMs and CTA functionalized AlPO-14/CA MMMs have good flexibility and high mechanical strength, and exhibit significantly enhanced selectivity and/or permeability over the polymer membranes made from the corresponding continuous polymer matrices for carbon dioxide/methane (CO2/CH4), hydrogen/methane (H2/CH4), and propylene/propane separations. The MMMs are suitable for a variety of liquid, gas, and vapor separations such as deep desulphurization of gasoline and diesel fuels, ethanol/water separations, pervaporation dehydration of aqueous/organic mixtures, CO2/CH4, CO2/N2, H2/CH4, O2/N2, olefin/paraffin, iso/normal paraffins separations, and other light gas mixture separations.

    摘要翻译： 本发明公开了一种通过加入聚醚砜（PES）或纤维素，在聚合物基体和分子筛的界面处制备聚合物官能化分子筛/聚合物混合基质膜（MMM）的方法，该聚合物官能化分子筛/聚合物混合基质膜（MMMs）在聚合物基体和分子筛的界面处没有大于或等于几埃的大孔或空隙 三乙酸酯（CTA）官能化分子筛成为连续聚酰亚胺或乙酸纤维素聚合物基质。 MMMs，特别是PES功能化的AlPO-14 /聚酰亚胺MMM和CTA官能化的AlPO-14 / CA MMM具有良好的柔韧性和高的机械强度，并且显示出从由相应的连续聚合物基体制成的聚合物膜显着增强的选择性和/或渗透性 二氧化碳/甲烷（CO2 / CH4），氢/甲烷（H2 / CH4）和丙烯/丙烷分离。 MMM适用于各种液体，气体和蒸气分离，如汽油和柴油的深度脱硫，乙醇/水分离，水/有机混合物的渗透蒸发脱水，CO2 / CH4，CO2 / N2，H2 / CH4， O2 / N2，烯烃/石蜡，异/正链烷烃分离和其他轻质气体混合物分离。

    Liquid Separations Using High Performance Mixed Matrix Membranes
    27.
    发明申请
    Liquid Separations Using High Performance Mixed Matrix Membranes 审中-公开
    使用高性能混合基质膜的液体分离

    公开(公告)号：US20080142440A1

    公开(公告)日：2008-06-19

    申请号：US11612402

    申请日：2006-12-18

    申请人： Chunqing Liu ,  Man-Wing Tang ,  Stephen T. Wilson ,  David A. Lesch

    发明人： Chunqing Liu ,  Man-Wing Tang ,  Stephen T. Wilson ,  David A. Lesch

    IPC分类号： B01D61/14 ,  B01D61/36

    CPC分类号： B01D61/362 ,  B01D53/228 ,  B01D67/0079 ,  B01D69/141

    摘要： The present invention discloses a novel method of making high performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions of solvents, uniformly dispersed polymer stabilized molecular sieves, and at least two different types of polymers as the continuous blend polymer matrix. MMMs as dense films or asymmetric flat sheet or hollow fiber membranes fabricated by the method described in the current invention exhibit significantly enhanced permeation performance for separations over the polymer membranes made from the continuous blend polymer matrix. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.

    摘要翻译： 本发明公开了使用稳定的溶剂浓缩悬浮液，均匀分散的聚合物稳定化分子筛和至少两种不同类型的聚合物作为连续共混聚合物基质制备高性能混合基质膜（MMM）的新方法。 通过本发明所述方法制造的致密膜或非对称平板或中空纤维膜的MMM显示出从由连续共混聚合物基质制成的聚合物膜上的分离显着增强的渗透性能。 本发明的MMM适用于各种气体，蒸汽和液体分离，例如醇/水，CO 2 / CH 4，H 2 CH 2，N 2，N 2，CO 2，N 2，N 2， 烯烃/石蜡，异/正链烷烃和其它轻质气体分离。

    Gas separations using high performance mixed matrix membranes
    28.
    发明授权
    Gas separations using high performance mixed matrix membranes 有权
    使用高性能混合基质膜进行气体分离

    公开(公告)号：US07998246B2

    公开(公告)日：2011-08-16

    申请号：US11612388

    申请日：2006-12-18

    申请人： Chunoing Liu ,  Man-Wing Tang ,  Stephen T. Wilson ,  David A. Lesch

    发明人： Chunoing Liu ,  Man-Wing Tang ,  Stephen T. Wilson ,  David A. Lesch

    IPC分类号： B01D53/22

    CPC分类号： B01D69/141 ,  B01D53/228 ,  B01D61/362 ,  B01D67/0079

    摘要： The present invention discloses a novel method of making high performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions of solvents, uniformly dispersed polymer stabilized molecular sieves, and at least two different types of polymers as the continuous blend polymer matrix. MMMs as dense films or asymmetric flat sheet or hollow fiber membranes fabricated by the method described in the current invention exhibit significantly enhanced permeation performance for separations over the polymer membranes made from the continuous blend polymer matrix. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.

    摘要翻译： 本发明公开了使用稳定的溶剂浓缩悬浮液，均匀分散的聚合物稳定化分子筛和至少两种不同类型的聚合物作为连续共混聚合物基质制备高性能混合基质膜（MMM）的新方法。 通过本发明所述方法制造的致密膜或非对称平板或中空纤维膜的MMM显示出从由连续共混聚合物基质制成的聚合物膜上的分离显着增强的渗透性能。 本发明的MMM适用于各种气体，蒸汽和液体分离，例如醇/水，CO 2 / CH 4，H 2 / CH 4，O 2 / N 2，CO 2 / N 2，烯烃/石蜡，异/正构链烷烃， 和其他轻质气体分离。