公开(公告)号：US06908968B2

公开(公告)日：2005-06-21

申请号：US10764776

申请日：2004-01-26

申请人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

发明人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

IPC分类号： B65D30/02 ,  B32B27/32 ,  C08F2/00 ,  C08F2/01 ,  C08F4/60 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/70 ,  C08F210/02 ,  C08F210/16 ,  C08J5/18 ,  C08L23/08 ,  C08L23/06 ,  C08F4/44 ,  C08F110/02

CPC分类号： C08L23/0815 ,  C08F210/16 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/26 ,  C08F2/001

摘要： A polymer composition comprises at least two polymer components, the first component having an ATREF peak temperature, Tpeak1, and a viscosity average molecular weight, Mv1, and the second component having an ATREF peak temperature, Tpeak2, and a viscosity average molecular weight, Mv2, wherein the temperature differential between Tpeak2 and Tpeak1 decreases with increased composition density and Mv1/Mv2 is less than or equal to 1.2. the composition is further characterized as having a Mw/Mn of less than or equal to 3.3, an I10/I2>6.6, and a composition density less than 0.945 gram/cubic centimeter.

摘要翻译： 聚合物组合物包含至少两种聚合物组分，第一组分具有ATREF峰温度T max 1和粘度平均分子量M 1 v 1，并且第二组分 具有ATREF峰值温度T 2峰2和粘度平均分子量M 2 V 2，其中T 2峰2和T 2之间的温差， SUB> peak1 随着组成密度的增加而降低，并且M 1/2 / M 2 V 2小于或等于1.2。 该组合物进一步被表征为具有小于或等于3.3的M

公开(公告)号：US06683149B2

公开(公告)日：2004-01-27

申请号：US10247025

申请日：2002-09-19

申请人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

发明人： Pradeep Jain ,  Lonnie G. Hazlitt ,  Jacquelyn A. deGroot ,  Kenneth W. Anderson

IPC分类号： C08F11002

CPC分类号： C08L23/0815 ,  C08F210/16 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/26 ,  C08F2/001

摘要： The present invention pertains to an ethylene interpolymer composition characterized as having a narrow molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having at least two polymer components, the first component having an ATREF peak temperature, Tpeak1 and a viscosity average molecular weight, Mv1, and the second component having an ATREF peak temperature, Tpeak2, and a viscosity average molecular, Mv2, wherein the temperature differential between Tpeak2 and Tpeak1 decreases with iincreased composition density and Mv1/Mv2 is less than or equal to 1.2. The novel composition exhibits high, balanced toughness properties, good processibility and surprisingly improved optical properties and is particularly well-suited for use in applications such as lamination films trash can liners and heavy duty shipping bags, especially as a blown film.

摘要翻译： 本发明涉及具有窄分子量分布（MWD）和优化组合均匀性的乙烯互聚物组合物，制备这种组合物的方法和由这种组合物制成的制造制品。 该新型组合物的特征在于具有至少两种聚合物组分，第一组分具有ATREF峰温度，Tpeak1和粘均分子量Mv1，第二组分具有ATREF峰温度Tpeak2和粘均分子， Mv2，其中Tpeak2和Tpeak1之间的温差随着组合物浓度的增加而降低，Mv1 / Mv2小于或等于1.2。 该新型组合物显示出高的平衡的韧性，良好的加工性和令人惊奇的改进的光学性能，特别适用于诸如层压膜垃圾桶衬里和重型运输袋，特别是作为吹塑薄膜的应用。

公开(公告)号：US06486284B1

公开(公告)日：2002-11-26

申请号：US09485801

申请日：2000-05-08

申请人： Seema V. Karande ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kaelyn Koch ,  Shih-Yaw Lai ,  Li-Min Tau

发明人： Seema V. Karande ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kaelyn Koch ,  Shih-Yaw Lai ,  Li-Min Tau

IPC分类号： C08F21016

CPC分类号： B32B27/32 ,  B32B2323/046 ,  B32B2323/10 ,  B32B2369/00 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L101/00 ,  C08L2314/06 ,  Y10T428/24 ,  Y10T428/269 ,  C08L2666/04

摘要： The subject invention provides a film having at least one layer comprising an interpolymer of ethylene and at least one comonomer selected from the group consisting of C3-C20 &agr;-olefins, dienes, and cycloalkenes, wherein the interpolymer is characteried as having a high degree of processability good optical performance, and good mechanical properties. The subject invention further provides film fabrication processes and polymer compositions which are useful in preparing the subject films.

摘要翻译： 本发明提供了一种膜，其具有包含乙烯和至少一种选自C 3 -C 20α-烯烃，二烯和环烯烃的共聚单体的互聚物的至少一层，其中所述互聚物的特征在于具有高度 加工性好的光学性能，以及良好的机械性能。 本发明还提供了可用于制备本发明膜的膜制造方法和聚合物组合物。

公开(公告)号：US10274465B2

公开(公告)日：2019-04-30

申请号：US14119403

申请日：2012-06-01

申请人： Rongjuan Cong ,  Charles M. Cheatham ,  Al Parrott ,  Wallace W. Yau ,  Lonnie G. Hazlitt ,  Zhe Zhou ,  Alexander W. Degroot ,  Matthew D. Miller

发明人： Rongjuan Cong ,  Charles M. Cheatham ,  Al Parrott ,  Wallace W. Yau ,  Lonnie G. Hazlitt ,  Zhe Zhou ,  Alexander W. Degroot ,  Matthew D. Miller

IPC分类号： G01N30/54 ,  B01J20/281 ,  B01D15/34 ,  B01J20/02 ,  B01J20/286 ,  B01J20/32

摘要： The invention provides an apparatus for polymer chromatography, comprising at least one column that comprises a first stationary phase comprising one of the following: A) a material comprising at least one non-carbon atom, excluding glass or a metal, selected from molybdenum sulfide MoS2, tungsten sulfide WS2, silicon carbide SiC, boron nitride BN, or combinations thereof, or B) glass, or a metal, or combinations thereof, and a material comprising at least one non-carbon atom selected from molybdenum sulfide MoS2, tungsten sulfide WS2, silicon carbide SiC, boron nitride BN, or combinations thereof. The invention also provides a method for polymer chromatography, comprising introducing a solution, comprising a polymer, into a liquid flowing through a first stationary phase, and wherein the first stationary phase comprises one of foregoing materials (A) or (B).

公开(公告)号：US08907030B2

公开(公告)日：2014-12-09

申请号：US13820795

申请日：2010-09-29

申请人： Mehmet Demirors ,  Lawrence J. Effler ,  Lonnie G. Hazlitt ,  Teresa P. Karjala ,  Cristina Serrat

发明人： Mehmet Demirors ,  Lawrence J. Effler ,  Lonnie G. Hazlitt ,  Teresa P. Karjala ,  Cristina Serrat

IPC分类号： C08F210/16 ,  C08F10/00 ,  D01F6/30

CPC分类号： C08F210/16 ,  C08F10/00 ,  D01F6/30 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/06 ,  C08F2500/12 ,  C08F4/6546

摘要： The instant invention provides an ethylene/alpha-olefin interpolymer suitable for use in fiber applications, and fibers made therefrom. The ethylene/alpha-olefin interpolymer according to the present invention has a CDBI of less than 60%, and comprises at least two fractions in crossfractionation of the ethylene/alpha-olefin interpolymer, eluting from 85° C. to 90° C. and from 90° C. to 95° C., comprising a weight fraction ratio of >0.68 and a molecular weight homogeneity index of greater than 0.65; wherein the weight fraction ratio is the ratio of the weight of polymer in each fraction divided by the weight of polymer eluting between 95° C. and 100° C. and the molecular weight homogeneity index is the ratio of the weight average molecular weight of the polymer in the fraction divided by the weight average molecular weight of the polymer eluting between 95° C. and 100° C., and wherein the ethylene/alpha-olefin interpolymer has a density in the range of from 0.920 to 0.965 g/cm3, and a melt index (I2) in the range of from 0.5 to 100 g/10 minutes, and melt flow ratio (I10/I2) in the range of from 5.8 to 8.

摘要翻译： 本发明提供了适用于纤维应用的乙烯/α-烯烃互聚物和由其制成的纤维。 根据本发明的乙烯/α-烯烃互聚物的CDBI小于60％，并且在85℃至90℃下从乙烯/α-烯烃互聚物的交叉分级中至少包含两个馏分， 包括重量分数比> 0.68且分子量均匀度指数大于0.65的90℃至95℃; 其中重量分数比是每个级分中聚合物的重量比除以95℃和100℃之间洗脱的聚合物的重量的比例，分子量均匀度指数是重均分子量 所述级分中的聚合物除以在95℃和100℃之间洗脱的聚合物的重均分子量，并且其中所述乙烯/α-烯烃互聚物的密度在0.920至0.965g / cm 3的范围内， 熔体指数（I 2）为0.5-100g / 10分钟，熔体流动比（I10 / I2）为5.8-8。

公开(公告)号：US20130190465A1

公开(公告)日：2013-07-25

申请号：US13820795

申请日：2010-09-29

申请人： Mehmet Demirors ,  Lawrence J. Effler ,  Lonnie G. Hazlitt ,  Teresa P. Karjala ,  Cristina Serrat

发明人： Mehmet Demirors ,  Lawrence J. Effler ,  Lonnie G. Hazlitt ,  Teresa P. Karjala ,  Cristina Serrat

IPC分类号： C08F210/16

CPC分类号： C08F210/16 ,  C08F10/00 ,  D01F6/30 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/06 ,  C08F2500/12 ,  C08F4/6546

摘要： The instant invention provides an ethylene/alpha-olefin interpolymer suitable for use in fiber applications, and fibers made therefrom. The ethylene/alpha-olefin interpolymer according to the present invention has a CDBI of less than 60%, and comprises at least two fractions in crossfractionation of the ethylene/alpha-olefin interpolymer, eluting from 85° C. to 90° C. and from 90° C. to 95° C., comprising a weight fraction ratio of >0.68 and a molecular weight homogeneity index of greater than 0.65; wherein the weight fraction ratio is the ratio of the weight of polymer in each fraction divided by the weight of polymer eluting between 95° C. and 100° C. and the molecular weight homogeneity index is the ratio of the weight average molecular weight of the polymer in the fraction divided by the weight average molecular weight of the polymer eluting between 95° C. and 100° C., and wherein the ethylene/alpha-olefin interpolymer has a density in the range of from 0.920 to 0.965 g/cm3, and a melt index (I2) in the range of from 0.5 to 100 g/10 minutes, and melt flow ratio (I10/I2) in the range of from 5.8 to 8.

摘要翻译： 本发明提供了适用于纤维应用的乙烯/α-烯烃互聚物和由其制成的纤维。 根据本发明的乙烯/α-烯烃互聚物的CDBI小于60％，并且在85℃至90℃下从乙烯/α-烯烃互聚物的交叉分级中至少包含两个馏分， 包括重量分数比> 0.68且分子量均匀度指数大于0.65的90℃至95℃; 其中重量分数比是每个级分中聚合物的重量比除以95℃和100℃之间洗脱的聚合物的重量的比例，分子量均匀度指数是重均分子量 所述级分中的聚合物除以在95℃和100℃之间洗脱的聚合物的重均分子量，并且其中所述乙烯/α-烯烃互聚物的密度在0.920至0.965g / cm 3的范围内， 熔体指数（I 2）为0.5-100g / 10分钟，熔体流动比（I10 / I2）为5.8-8。

公开(公告)号：US08202958B2

公开(公告)日：2012-06-19

申请号：US12402789

申请日：2009-03-12

申请人： Mehmet Demirors ,  Teresa P. Karjala ,  Christopher R. Eddy ,  Lonnie G. Hazlitt ,  Pak-Meng Cham ,  Sarat Munjal ,  Wallace W. Yau

发明人： Mehmet Demirors ,  Teresa P. Karjala ,  Christopher R. Eddy ,  Lonnie G. Hazlitt ,  Pak-Meng Cham ,  Sarat Munjal ,  Wallace W. Yau

IPC分类号： C08F4/06 ,  B01J31/00

CPC分类号： C08F255/02 ,  C08F110/02 ,  C08F255/00 ,  C08F297/08 ,  C08F297/083 ,  C08L23/0815 ,  C08L51/06 ,  C08L53/00 ,  C08L2666/02 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/07 ,  C08F2500/19

摘要： An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm≧(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.

摘要翻译： 包含通过核磁共振测定的约0.1至约2.0单位/ 1000个碳原子的乙烯基聚合物，峰值熔融温度Tm，℃，熔融热，Hf / J， 通过DSC结晶度测定，其中Tm和Hf的数值对应于Tm≥（0.2143×Hf）+79.643的关系。 包含至少一种使用制备型升温洗脱分级方法在95℃或更高洗脱的制备性TREF级分的乙烯性聚合物，其中至少一种在95℃或更高洗脱的制备性TREF级分的gpcBR值大于 通过3D-GPC通过gpcBR分枝指数测定的0.05和小于5，并且其中至少5％的乙烯类聚合物在基于乙烯类聚合物的总重量的95℃或更高的温度下洗脱。

公开(公告)号：US20110021713A1

公开(公告)日：2011-01-27

申请号：US12918090

申请日：2009-03-12

申请人： Mehmet Demirors ,  Teresa P. Karjala ,  Christopher R. Eddy ,  Lonnie G. Hazlitt ,  Pak-Meng Cham ,  Sarat Munjal ,  Wallace W. Yau

发明人： Mehmet Demirors ,  Teresa P. Karjala ,  Christopher R. Eddy ,  Lonnie G. Hazlitt ,  Pak-Meng Cham ,  Sarat Munjal ,  Wallace W. Yau

IPC分类号： C08F255/02 ,  C08F110/14

CPC分类号： C08F255/02 ,  C08F110/02 ,  C08F255/00 ,  C08F297/08 ,  C08F297/083 ,  C08L23/0815 ,  C08L51/06 ,  C08L53/00 ,  C08L2666/02 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/07 ,  C08F2500/19

摘要： An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm>(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.

摘要翻译： 包含通过核磁共振测定的约0.1至约2.0单位/ 1000个碳原子的乙烯基聚合物，峰值熔融温度Tm，℃，熔融热，Hf / J， 通过DSC结晶度测定，其中Tm和Hf的数值对应于Tm>（0.2143×Hf）+79.643的关系。 包含至少一种使用制备型升温洗脱分级方法在95℃或更高洗脱的制备性TREF级分的乙烯性聚合物，其中至少一种在95℃或更高洗脱的制备性TREF级分的gpcBR值大于 通过3D-GPC通过gpcBR分枝指数测定的0.05和小于5，并且其中至少5％的乙烯类聚合物在基于乙烯类聚合物的总重量的95℃或更高的温度下洗脱。

公开(公告)号：US20080221273A1

公开(公告)日：2008-09-11

申请号：US12067832

申请日：2007-05-02

申请人： William J. Michie Jr. ,  Thomas W. Kay ,  Stephanie M. Whited ,  Dale M. Elley-Bristow ,  David T. Gillespie ,  Lonnie G. Hazlitt

发明人： William J. Michie Jr. ,  Thomas W. Kay ,  Stephanie M. Whited ,  Dale M. Elley-Bristow ,  David T. Gillespie ,  Lonnie G. Hazlitt

IPC分类号： C08L23/04 ,  C08F2/00 ,  B29C43/00 ,  B29C45/00

CPC分类号： C08L23/08 ,  C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2203/10 ,  Y10T428/24992 ,  Y10T428/273 ,  C08L2666/06

摘要： The instant invention is a high-density polyethylene compositions, and method of making the same. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g′ of equal or greater than 1. The method of producing a high-density polyethylene composition include the following steps: (1) introducing ethylene, and an alpha-olefin comonomer into a first reactor; (2) copolymerizing the ethylene with the alpha-olefin comonomer in the first reactor thereby producing a first component, wherein the first component being a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21) in the range of 0.5 to 10 g/10 minutes; (3) introducing the first component and additional ethylene into a second reactor; (4) polymerizing the additional ethylene in the second reactor thereby producing a second component, wherein the second component being a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes; and (5) thereby producing the high-density polyethylene composition, wherein the high-density polyethylene composition having a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g′ of equal or greater than 1.

公开(公告)号：US06451916B1

公开(公告)日：2002-09-17

申请号：US09943853

申请日：2001-08-31

申请人： Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

发明人： Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

IPC分类号： C08F800

CPC分类号： B01J8/0015 ,  B01J19/2435 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/04 ,  C08L2205/02 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08F2/001 ,  C08L2666/04 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F210/14

摘要： The present invention pertains to a continuous process and polymerization system characterized by separate injection of catalyst and make-up feed, an ethylene interpolymer composition characterized as having broad molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having a melt flow ratio, I10/I2, from 8 to 30, a Mw/Mn of greater than 4 as determined by gel permeation chromatography, a melt index, I2, from 0.01 to 1000 grams/10 minutes, preferably greater that 0.1 to 10 grams/10 minutes, and a density less than 0.945 g/cm3. The novel composition exhibits good processibility and improved toughness properties, especially excellent film tear and impact resistance, and is particularly well-suited for use in applications such as high performance trash can liners and heavy duty shipping bags.

摘要翻译： 本发明涉及连续工艺和聚合体系，其特征在于分别注入催化剂和补充进料，特征在于具有宽分子量分布（MWD）和优化的组成均匀性的乙烯互聚物组合物，制备这种组合物的方法和 由这种组合物制成的制成品。 该新型组合物的特征在于具有通过凝胶渗透色谱法测定的熔体流动比I10 / I2，8至30，Mw / Mn大于4，熔体指数I 2为0.01至1000克/ 10分钟 ，优选为0.1〜10克/ 10分钟，密度小于0.945g / cm 3。 该新型组合物显示出良好的加工性和改进的韧性，特别优异的膜撕裂和抗冲击性，并且特别适合用于高性能垃圾桶衬里和重型运输袋等应用中。