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公开(公告)号：US09982001B2
公开(公告)日：2018-05-29
申请号：US14958143
申请日：2015-12-03
IPC分类号： C07F9/6574 , C07C45/50 , C07F15/00 , C07F15/06
CPC分类号： C07F9/65744 , C07C45/50 , C07F9/65746 , C07F15/0033 , C07F15/0046 , C07F15/0073 , C07F15/06 , C07C47/02
摘要： Bisphosphites having an unsymmetric central biaryl unit.
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公开(公告)号：US09950979B2
公开(公告)日：2018-04-24
申请号：US15313606
申请日：2015-05-20
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
IPC分类号： C07C41/30
摘要： A process for preparing unsymmetric biphenols, comprising: a) adding a first substituted phenol to the reaction mixture; b) adding a second substituted phenol having different substitution than the first phenol to the reaction mixture; c) adding selenium dioxide to the reaction mixture; d) adding a solvent; and e) heating the reaction mixture such that the first substituted phenol and the second phenol having different substitution are converted to an unsymmetric biphenol.
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公开(公告)号：US09624153B2
公开(公告)日：2017-04-18
申请号：US15103842
申请日：2014-12-10
申请人： Evonik Degussa GmbH , Marc Becker , Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Hanna Hahn , Marina Lazar , Markus Priske , Guido Stochniol
发明人： Marc Becker , Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Hanna Hahn , Marina Lazar , Markus Priske , Guido Stochniol
IPC分类号： C07C45/50 , B01D5/00 , B01J31/00 , B01D61/38 , B01J31/02 , B01J31/18 , C07C45/78 , B01D61/36 , B01J31/24 , C07C45/79 , C07C45/82
CPC分类号： C07C45/50 , B01D5/006 , B01D5/0072 , B01D61/362 , B01D61/38 , B01D2311/02 , B01D2311/04 , B01D2311/06 , B01D2311/263 , B01D2311/2669 , B01D2311/2673 , B01J31/0292 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J2231/321 , B01J2531/822 , C07C45/786 , C07C45/79 , C07C45/82 , C07C47/02
摘要： The invention relates to processes for preparing aldehydes by hydroformylation of alkenes, in which an alkene-containing feed mixture is subjected to a primary hydroformylation with synthesis gas in the presence of a homogeneous catalyst system, the primary hydroformylation being effected in a primary reaction zone from which a cycle gas containing at least some of the products and unconverted reactants of the primary hydroformylation are drawn off continuously and partly condensed, with recycling of uncondensed components of the cycle gas into the primary reaction zone, and with distillative separation of condensed components of the cycle gas in an aldehyde removal stage to give an aldehyde-rich mixture and a low-aldehyde mixture. The problem that it addresses is that of developing the process such that it achieves high conversions and affords aldehyde in good product quality even in the case of a deteriorating raw material position. More particularly, a solution is to be found for making legacy oxo process plants capable of utilizing lower-value raw material sources. This problem is solved by separating the low-aldehyde mixture into a retentate and a permeate by means of a membrane separation unit in such a way that alkenes present in the low-aldehyde mixture become enriched in the permeate, while alkanes present in the low-aldehyde mixture become enriched in the retentate. The alkene-rich permeate is then transferred into a secondary reaction zone and subjected to a secondary hydroformylation therein with synthesis gas in the presence of an SILP catalyst system. The reaction product obtained from the secondary hydroformylation is recycled into the aldehyde removal stage.
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24.发明申请PROCESS FOR PREPARING 2,2'-SELENOBIARYL ETHERS OR 4,4'-SELENOBIARYL ETHERS USING SELENIUM DIOXIDE 审中-公开使用二氧化二铱制备2,2'-二苯并噻唑或4,4'-己二醇的方法公开(公告)号：US20150336885A1
公开(公告)日：2015-11-26
申请号：US14720063
申请日：2015-05-22
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
IPC分类号： C07C391/02
CPC分类号： C07C391/02
摘要： A process for preparing a 2,2′-selenobiaryl ether or a 4,4′-selenobiaryl ether, proceeds by a) adding a first phenol to the reaction mixture, b) adding a second phenol to the reaction mixture, c) adding selenium dioxide to the reaction mixture, d) adding a base having a pKb in the range from 8 to 11 to the reaction mixture, and e) adjusting the reaction temperature of the reaction mixture such that the first phenol and the second phenol are converted to said 2,2′-selenobiaryl ether or said 4,4′-selenobiaryl ether.
摘要翻译： 一种制备2,2'-硒二芳基醚或4,4'-硒二芳基醚的方法是通过以下步骤：a）向反应混合物中加入第一酚，b）向反应混合物中加入第二酚，c）加入硒 二氧化碳反应混合物，d）向反应混合物中加入具有8至11范围内的pKb的碱，以及e）调节反应混合物的反应温度，使得第一酚和第二酚转化为所述 2,2'-硒二芳基醚或所述4,4'-硒二芳基醚。
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公开(公告)号：US09879353B2
公开(公告)日：2018-01-30
申请号：US14772874
申请日：2013-12-10
摘要： Electrochemical process for coupling two phenols of different oxidation potential, and novel biphenols which can be prepared by this electrochemical coupling.
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公开(公告)号：US09670585B2
公开(公告)日：2017-06-06
申请号：US14773228
申请日：2013-12-10
摘要： The invention relates to an electrochemical method for the selective coupling of a phenol to a naphthol which differ in their oxidation potential. The invention also relates to compounds which can be produced by electrochemical coupling.
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公开(公告)号：US20150336865A1
公开(公告)日：2015-11-26
申请号：US14719900
申请日：2015-05-22
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
IPC分类号： C07C37/11
摘要： A process for preparing a 2,2′-biphenol, proceeds by a) adding a first phenol to a reaction mixture, b) adding a second phenol to the reaction mixture, c) adding selenium dioxide to the reaction mixture, d) adding an acid having a pKa in the range from 0.0 to 5.0 to the reaction mixture, and e) heating the reaction mixture such that the first phenol and the second phenol are converted to said 2,2′-biphenol.
摘要翻译： 制备2,2'-联苯酚的方法是由a）向反应混合物中加入第一酚，b）向反应混合物中加入第二酚，c）向反应混合物中加入二氧化硒，d） 对反应混合物具有0.0-5.0的pKa的酸，以及e）加热反应混合物使得第一酚和第二酚被转化成所述的2,2'-联苯酚。
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公开(公告)号：US10422047B2
公开(公告)日：2019-09-24
申请号：US14773102
申请日：2014-02-19
摘要： An electrochemical method for C—C coupling a phenol and an aniline in a reaction vessel containing a suitable solvent or solvent mixture and a conductive salt to produce biaryls having both hydroxyl and amino functions, wherein the difference in the oxidation potentials ΔE of the substrates ranges from 10 mV to 450 mV and the substrate with the highest oxidation potential is in excess, which method dispenses with multi-step syntheses using metallic reagents.
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公开(公告)号：US09790244B2
公开(公告)日：2017-10-17
申请号：US14954339
申请日：2015-11-30
IPC分类号： C07B41/06 , C07C45/50 , B01J31/18 , C07F9/6574
CPC分类号： C07F9/65746 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07B41/06 , C07C45/50 , C07C47/02
摘要： Bisphosphites having at least one unsymmetric outer biphenol unit are useful for the hydroformylation of an olefin.
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公开(公告)号：US20170204031A1
公开(公告)日：2017-07-20
申请号：US15313606
申请日：2015-05-20
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
IPC分类号： C07C41/30
摘要： The present invention concerns a method for producing asymmetrical biphenols using selenium dioxide.
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