公开(公告)号：US5409878A

公开(公告)日：1995-04-25

申请号：US956498

申请日：1993-01-06

申请人： Luc Blanchard ,  Patrick Briot ,  Michel Primet ,  Edouard Garbowski

发明人： Luc Blanchard ,  Patrick Briot ,  Michel Primet ,  Edouard Garbowski

IPC分类号： B01J21/12 ,  B01J23/40 ,  B01J37/02 ,  B01J37/08 ,  B01J21/04

CPC分类号： B01J21/12 ,  B01J23/40 ,  B01J37/0201 ,  B01J37/086 ,  Y10S502/50

摘要： The present invention concerns a non selective oxidation catalyst resistant to high temperatures and a method of preparation of this catalyst.According to the invention, this catalyst comprises an essentially alumina-based support stabilized with silicon and a precursor of the active phase consisting of a noble metal M in which the active phase is cationic amino-complex of the [M(NH.sub.3).sub.4 ].sup.++ type or a compound selected among the tetrachloropalladic acid.The catalyst of the invention is usable in particular in processes of catalytic combustion of hydrocarbons, of carbone monoxide, of hydrogen or of their mixtures.

摘要翻译： PCT No.PCT / FR92 / 00413 Sec。 371日期1993年3月2日 102（e）日期1993年3月2日PCT提交1992年5月6日PCT公布。 WO92 / 19375 PCT出版物 日期：1992年11月12日。本发明涉及耐高温的非选择性氧化催化剂及其制备方法。 根据本发明，该催化剂包括基本上由硅稳定的氧化铝基载体和由贵金属M组成的活性相前体，其中活性相是[M（NH 3）4] +的阳离子氨基络合物 +型或选自四氯钯酸的化合物。 本发明的催化剂特别可用于烃，碳氧化物，氢气或其混合物的催化燃烧方法。

公开(公告)号：US07504548B2

公开(公告)日：2009-03-17

申请号：US10943896

申请日：2004-09-20

申请人： Patrick Briot ,  Sylvie Lacombe ,  Jean-François Joly ,  Eric Llido

发明人： Patrick Briot ,  Sylvie Lacombe ,  Jean-François Joly ,  Eric Llido

IPC分类号： C07C2/64 ,  C10G35/00

CPC分类号： C10L1/08 ,  C07C2/64 ,  C07C2/66 ,  C07C2/861 ,  C07C5/10 ,  C07C13/18 ,  C07C2521/04 ,  C07C2527/126 ,  C07C2529/18 ,  C07C2601/14 ,  C07C15/107

摘要： The invention relates to a method for formulation of a synthetic gas oil or an additive for gas oil in which an alkyl-aromatic compound or a mixture of alkyl-aromatic compounds is selected based on at least one parameter that is selected from the group that consists of the number of cycles of the aromatic core, the number of alkyl chains that are grafted to the aromatic cycle, the length of the alkyl chain or chains, the position of the aromatic cycle or cycles on the alkyl chain or chains of said alkyl-aromatic compound or compounds such that the cetane number of the synthetic gas oil or the additive for gas oil is greater than 30. The invention also relates to a process for the production of alkyl-aromatic compounds for use as a gas oil or additive.

摘要翻译： 本发明涉及一种用于制备瓦斯油的合成瓦斯油或其添加剂的方法，其中烷基芳族化合物或烷基芳族化合物的混合物基于至少一个参数，该参数选自组成 的芳族核心的循环次数，接枝到芳香环的烷基链的数量，烷基链或链的长度，芳族环或在所述烷基链或烷基链的烷基链上的循环的位置， 芳族化合物或化合物，使得合成瓦斯油的十六烷值或瓦斯油的添加剂大于30.本发明还涉及用作瓦斯油或添加剂的烷基 - 芳族化合物的制备方法。

公开(公告)号：US07344635B2

公开(公告)日：2008-03-18

申请号：US10503807

申请日：2003-01-22

申请人： Patrick Briot ,  Pierre Boucot ,  Alain Forestiere ,  Nathalie Marchal-George ,  Florent Picard

发明人： Patrick Briot ,  Pierre Boucot ,  Alain Forestiere ,  Nathalie Marchal-George ,  Florent Picard

IPC分类号： C10G45/02

CPC分类号： C10G69/123 ,  C10G29/205

摘要： Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.

摘要翻译： 用于裂化或蒸汽裂解烃的流出物的脱硫方法，更具体地，例如用于催化裂解的汽油，其包括通过这些化合物的烷基化除去噻吩化合物，然后蒸馏，所述烷基 - 噻吩化合物的加氢裂化， 然后从加氢裂化区获得的流出物的加氢脱硫。 在优选的实施方案中，该方法包括用于将裂化或蒸汽裂解流出物分离成三个馏分的初步阶段，并且建议仅向最初存在于重质碱性含氮化合物中的低碱性含氮化合物的中间馏分 待烷基化的废水。

公开(公告)号：US07161052B2

公开(公告)日：2007-01-09

申请号：US10653426

申请日：2003-09-03

申请人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

发明人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

IPC分类号： C07C2/68 ,  C07C2/04 ,  C07C2/00

CPC分类号： C10G29/205 ,  C10G50/00

摘要： A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (α) the upper distillation point of which is less than 100° C. and a kerosene cut (β) having a distillation range between 100° C. and 300° C.

摘要翻译： 描述了一种用于增加烃类和降低所述电荷的蒸气压的方法，包括三个步骤：步骤a）由将所述烃分离成基本上含有5个碳原子的化合物的馏分（O1）组成的步骤 ，包括至少2重量％的戊烯，步骤b）将所述馏分（O1）与至少部分包含6至10个碳原子的烃的馏分（O 2）接触，包括 至少2重量％的烯烃，以及步骤c），其通过将来自步骤b）的流出物分离成上馏分小于100℃的汽油馏分（α）和煤油切割（β ），其蒸馏范围为100℃至300℃。

公开(公告)号：US20050283037A1

公开(公告)日：2005-12-22

申请号：US11144739

申请日：2005-06-06

申请人： Patrick Briot ,  Arnaud Baudot ,  Vincent Coupard ,  Alain Methivier

发明人： Patrick Briot ,  Arnaud Baudot ,  Vincent Coupard ,  Alain Methivier

IPC分类号： C10G57/02 ,  C10G31/09 ,  C10G31/10 ,  C10G31/11 ,  C10G35/04 ,  C10G50/00 ,  C07C2/00

CPC分类号： C10G50/00 ,  C10G31/10

摘要： The invention relates to a process for converting a hydrocarbons charge comprising linear and branched olefins comprising the following stages: a) a stage of membrane separation of the hydrocarbon charge under conditions making it possible to produce a cut β containing the majority of the linear olefins present in said charge, and a cut γ containing the majority of the branched olefins, b) a stage of treatment of the linear olefins contained in the effluents originating from the membrane separation stage (cut β) under moderate oligomerization conditions, c) a stage of distillation separation of the effluents originating from the oligomerization stage into at least two cuts, d) a stage of hydrogenation of the cut η under conditions for obtaining a gas oil with a high cetane number.

摘要翻译： 本发明涉及一种用于转化含有直链和支链烯烃的烃装料的方法，包括以下阶段：a）在使得有可能产生含有大部分直链烯烃存在的馏分β的条件下进行烃装料的膜分离阶段 所述电荷中含有大部分支链烯烃的切割γ，b）在中等低聚条件下处理来自膜分离阶段（切断β）的流出物中所含的直链烯烃的阶段，c） 从源于低聚阶段的流出物蒸馏分离成至少两个切割，d）在获得具有高十六烷值的瓦斯油的条件下，切割的η的氢化阶段。

公开(公告)号：US20050065388A1

公开(公告)日：2005-03-24

申请号：US10943896

申请日：2004-09-20

申请人： Patrick Briot ,  Sylvie Lacombe ,  Jean-Francois Joly ,  Eric Llido

发明人： Patrick Briot ,  Sylvie Lacombe ,  Jean-Francois Joly ,  Eric Llido

IPC分类号： C07C2/64 ,  C07C2/66 ,  C07C2/86 ,  C07C5/10 ,  C07C13/18 ,  C10L1/08

CPC分类号： C10L1/08 ,  C07C2/64 ,  C07C2/66 ,  C07C2/861 ,  C07C5/10 ,  C07C13/18 ,  C07C2521/04 ,  C07C2527/126 ,  C07C2529/18 ,  C07C2601/14 ,  C07C15/107

摘要： The invention relates to a method for formulation of a synthetic gas oil or an additive for gas oil in which an alkyl-aromatic compound or a mixture of alkyl-aromatic compounds is selected based on at least one parameter that is selected from the group that consists of the number of cycles of the aromatic core, the number of alkyl chains that are grafted to the aromatic cycle, the length of the alkyl chain or chains, the position of the aromatic cycle or cycles on the alkyl chain or chains of said alkyl-aromatic compound or compounds such that the cetane number of the synthetic gas oil or the additive for gas oil is greater than 30. The invention also relates to a process for the production of alkyl-aromatic compounds for use as a gas oil or additive.

摘要翻译： 本发明涉及一种用于制备瓦斯油的合成瓦斯油或其添加剂的方法，其中烷基芳族化合物或烷基芳族化合物的混合物基于至少一个参数，该参数选自组成 的芳族核心的循环次数，接枝到芳香环的烷基链的数量，烷基链或链的长度，芳族环或在所述烷基链或烷基链的烷基链上的循环的位置， 芳族化合物或化合物，使得合成瓦斯油的十六烷值或瓦斯油的添加剂大于30.本发明还涉及用作瓦斯油或添加剂的烷基 - 芳族化合物的制备方法。

公开(公告)号：US20050010072A1

公开(公告)日：2005-01-13

申请号：US10495773

申请日：2002-11-05

申请人： Jean-Francois Joly ,  Patrick Briot

发明人： Jean-Francois Joly ,  Patrick Briot

IPC分类号： B01J29/08 ,  B01J29/18 ,  C07C2/64 ,  C07C2/66 ,  C07C15/067 ,  C07C15/107 ,  C11D1/22

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/50 ,  C07C2529/70 ,  C11D1/22 ,  C07C15/107

摘要： A process is described for producing phenylalkanes by alkylating at least one aromatic compound using at least one linear olefin containing 9 to 16 carbon atoms per molecule. The alkylation reaction is carried out in the presence of at least two different catalysts used in at least two distinct reaction zones. The selectivity for a monoalkylated products of the catalyst contained in the first reaction zone is lower than that for the catalyst contained in the second reaction zone located downstream of the first in the direction movement of the fluids.

摘要翻译： 描述了通过使用至少一种每分子含有9至16个碳原子的直链烯烃烷基化至少一种芳族化合物来制备苯基烷烃的方法。 烷基化反应在至少两个不同的反应区中使用的至少两种不同的催化剂存在下进行。 包含在第一反应区中的催化剂的单烷基化产物的选择性低于位于流体方向移动中第一个下游的第二反应区中的催化剂的选择性。

公开(公告)号：US07847141B2

公开(公告)日：2010-12-07

申请号：US11144739

申请日：2005-06-06

申请人： Patrick Briot ,  Arnaud Baudot ,  Vincent Coupard ,  Alain Methivier

发明人： Patrick Briot ,  Arnaud Baudot ,  Vincent Coupard ,  Alain Methivier

IPC分类号： C07C2/00

CPC分类号： C10G50/00 ,  C10G31/10

摘要： The invention relates to a process for converting a hydrocarbon charge of linear and branched olefins, comprises the following stages: a) a stage of membrane separation of the hydrocarbon charge under conditions making it possible to produce a cut β containing the majority of the linear olefins present in said charge, and a cut γ containing the majority of the branched olefins, b) a stage of treatment of the linear olefins contained in the effluents originating from the membrane separation stage (cut β) under moderate oligomerization conditions, c) a stage of distillation separation of the effluents originating from the oligomerization stage into at least two cuts, d) a stage of hydrogenation of the cut η under conditions for obtaining a gas oil with a high cetane number.

摘要翻译： 本发明涉及一种用于转化直链和支链烯烃的烃装料的方法，包括以下阶段：a）在使得能够产生切割的条件下进行烃装料的膜分离阶段; 含有大部分存在于所述电荷中的直链烯烃，和含有大部分支链烯烃的切割γ，b）处理源自膜分离阶段（切割）的流出物中的直链烯烃的处理阶段 中等低聚条件，c）将源自低聚阶段的流出物蒸馏分离成至少两个馏分的阶段，d）切割的氢化阶段; 在获得具有高十六烷值的瓦斯油的条件下。

公开(公告)号：US07572946B2

公开(公告)日：2009-08-11

申请号：US11182021

申请日：2005-07-15

申请人： Sylvie Lacombe ,  Renaud Revel ,  Patrick Briot ,  Eric Llido ,  Patrick Euzen ,  Carole Bobin

发明人： Sylvie Lacombe ,  Renaud Revel ,  Patrick Briot ,  Eric Llido ,  Patrick Euzen ,  Carole Bobin

IPC分类号： C07C2/08

CPC分类号： C10G69/126 ,  C07C2/10 ,  C07C2521/12 ,  C10G50/00 ,  C10G2300/1092 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/802 ,  C10G2400/02 ,  C07C11/02

摘要： An olefin oligomerization process employs a particular silica-alumina catalyst which comprises a non zeolitic support based on silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2) and has the following characteristics: a mean pore diameter, measured by mercury porosimetry, in the range 20 to 140 Å; a total pore volume, measured by mercury porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a total pore volume, measured by nitrogen porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a BET specific surface area in the range 100 to 550 m2/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 140 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 160 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 200 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 500 Å, of less than 0.1 ml/g; and an X ray diffraction diagram containing at least the principal characteristic peaks of at least one of the transition aluminas included in the group composed of alpha, rho, khi, eta, gamma, kappa, theta and delta aluminas.

摘要翻译： 烯烃低聚方法使用特定的二氧化硅 - 氧化铝催化剂，其包含基于二氧化硅 - 氧化铝的非沸石载体，其含有大于5重量％且95重量％以下的二氧化硅（SiO 2），并具有以下特征： 通过水银孔率法测量的平均孔径在20至140埃的范围内; 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 100-550m2 / g范围内的BET比表面积; 通过水银孔率法测定的孔体积，其直径大于140埃，小于0.1ml / g; 通过水银孔率法测量的孔体积，其直径大于160埃的孔隙小于0.1ml / g; 包含在直径大于200埃的孔中，通过水银孔率法测量的孔体积小于0.1ml / g; 通过水银孔率法测量的孔体积包含在直径大于500埃的小于0.1ml / g的孔中; 以及X射线衍射图，其至少包含由α，rho，khi，eta，γ，κ，θ和δ氧化铝组成的组中的至少一种过渡氧化铝的主要特征峰。

公开(公告)号：US07297826B2

公开(公告)日：2007-11-20

申请号：US10495773

申请日：2002-11-05

申请人： Jean-François Joly ,  Patrick Briot

发明人： Jean-François Joly ,  Patrick Briot

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/50 ,  C07C2529/70 ,  C11D1/22 ,  C07C15/107

摘要： A process is described for producing phenylalkanes by alkylating at least one aromatic compound using at least one linear olefin containing 9 to 16 carbon atoms per molecule. The alkylation reaction is carried out in the presence of at least two different catalysts used in at least two distinct reaction zones. The selectivity for a monoalkylated products of the catalyst contained in the first reaction zone is lower than that for the catalyst contained in the second reaction zone located downstream of the first in the direction movement of the fluids.

摘要翻译： 描述了通过使用至少一种每分子含有9至16个碳原子的直链烯烃烷基化至少一种芳族化合物来制备苯基烷烃的方法。 烷基化反应在至少两个不同的反应区中使用的至少两种不同的催化剂存在下进行。 包含在第一反应区中的催化剂的单烷基化产物的选择性低于位于流体方向移动中第一个下游的第二反应区中的催化剂的选择性。