公开(公告)号：US07504548B2

公开(公告)日：2009-03-17

申请号：US10943896

申请日：2004-09-20

申请人： Patrick Briot ,  Sylvie Lacombe ,  Jean-François Joly ,  Eric Llido

发明人： Patrick Briot ,  Sylvie Lacombe ,  Jean-François Joly ,  Eric Llido

IPC分类号： C07C2/64 ,  C10G35/00

CPC分类号： C10L1/08 ,  C07C2/64 ,  C07C2/66 ,  C07C2/861 ,  C07C5/10 ,  C07C13/18 ,  C07C2521/04 ,  C07C2527/126 ,  C07C2529/18 ,  C07C2601/14 ,  C07C15/107

摘要： The invention relates to a method for formulation of a synthetic gas oil or an additive for gas oil in which an alkyl-aromatic compound or a mixture of alkyl-aromatic compounds is selected based on at least one parameter that is selected from the group that consists of the number of cycles of the aromatic core, the number of alkyl chains that are grafted to the aromatic cycle, the length of the alkyl chain or chains, the position of the aromatic cycle or cycles on the alkyl chain or chains of said alkyl-aromatic compound or compounds such that the cetane number of the synthetic gas oil or the additive for gas oil is greater than 30. The invention also relates to a process for the production of alkyl-aromatic compounds for use as a gas oil or additive.

摘要翻译： 本发明涉及一种用于制备瓦斯油的合成瓦斯油或其添加剂的方法，其中烷基芳族化合物或烷基芳族化合物的混合物基于至少一个参数，该参数选自组成 的芳族核心的循环次数，接枝到芳香环的烷基链的数量，烷基链或链的长度，芳族环或在所述烷基链或烷基链的烷基链上的循环的位置， 芳族化合物或化合物，使得合成瓦斯油的十六烷值或瓦斯油的添加剂大于30.本发明还涉及用作瓦斯油或添加剂的烷基 - 芳族化合物的制备方法。

公开(公告)号：US20050065388A1

公开(公告)日：2005-03-24

申请号：US10943896

申请日：2004-09-20

申请人： Patrick Briot ,  Sylvie Lacombe ,  Jean-Francois Joly ,  Eric Llido

发明人： Patrick Briot ,  Sylvie Lacombe ,  Jean-Francois Joly ,  Eric Llido

IPC分类号： C07C2/64 ,  C07C2/66 ,  C07C2/86 ,  C07C5/10 ,  C07C13/18 ,  C10L1/08

CPC分类号： C10L1/08 ,  C07C2/64 ,  C07C2/66 ,  C07C2/861 ,  C07C5/10 ,  C07C13/18 ,  C07C2521/04 ,  C07C2527/126 ,  C07C2529/18 ,  C07C2601/14 ,  C07C15/107

摘要： The invention relates to a method for formulation of a synthetic gas oil or an additive for gas oil in which an alkyl-aromatic compound or a mixture of alkyl-aromatic compounds is selected based on at least one parameter that is selected from the group that consists of the number of cycles of the aromatic core, the number of alkyl chains that are grafted to the aromatic cycle, the length of the alkyl chain or chains, the position of the aromatic cycle or cycles on the alkyl chain or chains of said alkyl-aromatic compound or compounds such that the cetane number of the synthetic gas oil or the additive for gas oil is greater than 30. The invention also relates to a process for the production of alkyl-aromatic compounds for use as a gas oil or additive.

摘要翻译： 本发明涉及一种用于制备瓦斯油的合成瓦斯油或其添加剂的方法，其中烷基芳族化合物或烷基芳族化合物的混合物基于至少一个参数，该参数选自组成 的芳族核心的循环次数，接枝到芳香环的烷基链的数量，烷基链或链的长度，芳族环或在所述烷基链或烷基链的烷基链上的循环的位置， 芳族化合物或化合物，使得合成瓦斯油的十六烷值或瓦斯油的添加剂大于30.本发明还涉及用作瓦斯油或添加剂的烷基 - 芳族化合物的制备方法。

公开(公告)号：US07572946B2

公开(公告)日：2009-08-11

申请号：US11182021

申请日：2005-07-15

申请人： Sylvie Lacombe ,  Renaud Revel ,  Patrick Briot ,  Eric Llido ,  Patrick Euzen ,  Carole Bobin

发明人： Sylvie Lacombe ,  Renaud Revel ,  Patrick Briot ,  Eric Llido ,  Patrick Euzen ,  Carole Bobin

IPC分类号： C07C2/08

CPC分类号： C10G69/126 ,  C07C2/10 ,  C07C2521/12 ,  C10G50/00 ,  C10G2300/1092 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/802 ,  C10G2400/02 ,  C07C11/02

摘要： An olefin oligomerization process employs a particular silica-alumina catalyst which comprises a non zeolitic support based on silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2) and has the following characteristics: a mean pore diameter, measured by mercury porosimetry, in the range 20 to 140 Å; a total pore volume, measured by mercury porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a total pore volume, measured by nitrogen porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a BET specific surface area in the range 100 to 550 m2/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 140 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 160 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 200 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 500 Å, of less than 0.1 ml/g; and an X ray diffraction diagram containing at least the principal characteristic peaks of at least one of the transition aluminas included in the group composed of alpha, rho, khi, eta, gamma, kappa, theta and delta aluminas.

摘要翻译： 烯烃低聚方法使用特定的二氧化硅 - 氧化铝催化剂，其包含基于二氧化硅 - 氧化铝的非沸石载体，其含有大于5重量％且95重量％以下的二氧化硅（SiO 2），并具有以下特征： 通过水银孔率法测量的平均孔径在20至140埃的范围内; 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 100-550m2 / g范围内的BET比表面积; 通过水银孔率法测定的孔体积，其直径大于140埃，小于0.1ml / g; 通过水银孔率法测量的孔体积，其直径大于160埃的孔隙小于0.1ml / g; 包含在直径大于200埃的孔中，通过水银孔率法测量的孔体积小于0.1ml / g; 通过水银孔率法测量的孔体积包含在直径大于500埃的小于0.1ml / g的孔中; 以及X射线衍射图，其至少包含由α，rho，khi，eta，γ，κ，θ和δ氧化铝组成的组中的至少一种过渡氧化铝的主要特征峰。

公开(公告)号：US20060079704A1

公开(公告)日：2006-04-13

申请号：US11286351

申请日：2005-11-25

申请人： Sylvie Lacombe ,  Renaud Revel ,  Patrick Briot ,  Eric Llido ,  Patrick Euzen ,  Carole Bobin

发明人： Sylvie Lacombe ,  Renaud Revel ,  Patrick Briot ,  Eric Llido ,  Patrick Euzen ,  Carole Bobin

IPC分类号： C07C67/00 ,  C07C5/00

CPC分类号： C07C6/04 ,  C07C2/10 ,  C07C67/333 ,  C07C2521/12 ,  C10G50/00 ,  C10G69/126 ,  C10G2300/1014 ,  C10G2400/22 ,  C11C3/00 ,  C07C11/02 ,  C07C69/533

摘要： A process is described in which an unsaturated fat is reacted with ethylene in a metathesis reaction in the presence of at least one non-aqueous ionic liquid to produce both an olefinic fraction and a composition of monoalcohol or polyol esters. Particular application to an oleic sunflower seed oil, an oleic rapeseed oil or to a mixture of monoalcohol esters of said oils, the process producing both an olefinic fraction and a monoalcohol or glycerol esters composition generally having more than half of its chains constituted by unsaturated C10 chains.

摘要翻译： 描述了一种方法，其中不饱和脂肪在复分解反应中在至少一种非水离子液体存在下与乙烯反应，以产生烯属馏分和一元醇或多元醇酯的组合物。 特别应用于油酸向日葵籽油，油菜菜籽油或所述油的一元醇酯的混合物，该方法生产烯烃级分和一元醇或甘油酯组合物，其通常具有由不饱和C构成的链的一半以上 10个链。

公开(公告)号：US20060063955A1

公开(公告)日：2006-03-23

申请号：US11182021

申请日：2005-07-15

申请人： Sylvie Lacombe ,  Renaud Revel ,  Patrick Briot ,  Eric Llido ,  Patrick Euzen ,  Carole Bobin

发明人： Sylvie Lacombe ,  Renaud Revel ,  Patrick Briot ,  Eric Llido ,  Patrick Euzen ,  Carole Bobin

IPC分类号： C07C2/00

CPC分类号： C10G69/126 ,  C07C2/10 ,  C07C2521/12 ,  C10G50/00 ,  C10G2300/1092 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/802 ,  C10G2400/02 ,  C07C11/02

摘要： An olefin oligomerization process employs a particular silica-alumina catalyst which comprises a non zeolitic support based on silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2) and has the following characteristics: a mean pore diameter, measured by mercury porosimetry, in the range 20 to 140 Å; a total pore volume, measured by mercury porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a total pore volume, measured by nitrogen porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a BET specific surface area in the range 100 to 550 m2/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 140 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 160 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 200 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 500 Å, of less than 0.1 ml/g; and an X ray diffraction diagram containing at least the principal characteristic peaks of at least one of the transition aluminas included in the group composed of alpha, rho, khi, eta, gamma, kappa, theta and delta aluminas.

摘要翻译： 烯烃低聚方法使用特定的二氧化硅 - 氧化铝催化剂，其包含基于二氧化硅 - 氧化铝的非沸石载体，其含有大于5重量％和95重量％以下的二氧化硅（SiO 2/2） >），具有以下特征：通过水银孔率法测定的平均孔径在20〜140范围内; 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 在100〜550m 2 / g范围内的BET比表面积; 通过水银孔率法测定的孔体积，其直径大于140埃，小于0.1ml / g; 包含在直径大于160埃的孔中，通过水银孔率法测量的孔体积小于0.1ml / g; 包含在直径大于200埃的孔中，通过水银孔率法测量的孔体积小于0.1ml / g; 通过水银孔率法测量的孔体积包含在直径大于500埃的小于0.1ml / g的孔中; 以及X射线衍射图，其至少包含由α，rho，khi，eta，γ，κ，θ和δ氧化铝组成的组中的至少一种过渡氧化铝的主要特征峰。

公开(公告)号：US07297826B2

公开(公告)日：2007-11-20

申请号：US10495773

申请日：2002-11-05

申请人： Jean-François Joly ,  Patrick Briot

发明人： Jean-François Joly ,  Patrick Briot

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/50 ,  C07C2529/70 ,  C11D1/22 ,  C07C15/107

摘要： A process is described for producing phenylalkanes by alkylating at least one aromatic compound using at least one linear olefin containing 9 to 16 carbon atoms per molecule. The alkylation reaction is carried out in the presence of at least two different catalysts used in at least two distinct reaction zones. The selectivity for a monoalkylated products of the catalyst contained in the first reaction zone is lower than that for the catalyst contained in the second reaction zone located downstream of the first in the direction movement of the fluids.

摘要翻译： 描述了通过使用至少一种每分子含有9至16个碳原子的直链烯烃烷基化至少一种芳族化合物来制备苯基烷烃的方法。 烷基化反应在至少两个不同的反应区中使用的至少两种不同的催化剂存在下进行。 包含在第一反应区中的催化剂的单烷基化产物的选择性低于位于流体方向移动中第一个下游的第二反应区中的催化剂的选择性。

公开(公告)号：US07329787B2

公开(公告)日：2008-02-12

申请号：US10740685

申请日：2003-12-22

申请人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido

发明人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido

IPC分类号： C07C2/04 ,  C07C5/03 ,  C07C5/00

CPC分类号： C10L1/06 ,  C10G57/02 ,  C10G69/14 ,  C10L1/08

摘要： A process is described for transforming an initial hydrocarbon feed containing 4 to 15 carbon atoms, limits included, into a hydrocarbon fraction having an improved octane number and a hydrocarbon fraction with a high cetane number.

摘要翻译： 描述了一种将含有4至15个碳原子的初始烃进料（包括限制）转化为具有改进的辛烷值的烃馏分和具有高十六烷值的烃馏分的方法。

公开(公告)号：US07161052B2

公开(公告)日：2007-01-09

申请号：US10653426

申请日：2003-09-03

申请人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

发明人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

IPC分类号： C07C2/68 ,  C07C2/04 ,  C07C2/00

CPC分类号： C10G29/205 ,  C10G50/00

摘要： A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (α) the upper distillation point of which is less than 100° C. and a kerosene cut (β) having a distillation range between 100° C. and 300° C.

摘要翻译： 描述了一种用于增加烃类和降低所述电荷的蒸气压的方法，包括三个步骤：步骤a）由将所述烃分离成基本上含有5个碳原子的化合物的馏分（O1）组成的步骤 ，包括至少2重量％的戊烯，步骤b）将所述馏分（O1）与至少部分包含6至10个碳原子的烃的馏分（O 2）接触，包括 至少2重量％的烯烃，以及步骤c），其通过将来自步骤b）的流出物分离成上馏分小于100℃的汽油馏分（α）和煤油切割（β ），其蒸馏范围为100℃至300℃。

公开(公告)号：US20050189261A1

公开(公告)日：2005-09-01

申请号：US10662817

申请日：2003-09-16

申请人： Patrick Briot ,  Alain Forestiere ,  Thierry Chapus ,  Frederic Morel ,  Eric Llido

发明人： Patrick Briot ,  Alain Forestiere ,  Thierry Chapus ,  Frederic Morel ,  Eric Llido

IPC分类号： C10G27/12 ,  C10G53/14 ,  C10G27/04 ,  C10G29/16

CPC分类号： C10G53/14 ,  C10G27/12

摘要： The desulfurization of a hydrocarbon-containing fraction, e.g. kerosene or gas oil that comprises at least one stage of treatment of said fraction with an oxidizing agent in the presence of a catalyst of said oxidation, in which said catalyst comprises at least one oxide of chemical formula MxOy, whereby M is an element that is selected from the group that consists of the elements of groups IV-B, V-B or VI-B of the periodic table.

摘要翻译： 含烃馏分的脱硫，例如 煤油或瓦斯油，其包括在所述氧化催化剂存在下用氧化剂处理所述馏分的至少一个阶段，其中所述催化剂包含至少一种化学式M x O y的氧化物，其中M是 选自由周期表第IV-B，VB或VI-B族的元素组成的组。

公开(公告)号：US20050101821A1

公开(公告)日：2005-05-12

申请号：US10653426

申请日：2003-09-03

申请人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

发明人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

IPC分类号： C10L1/04 ,  C10G17/02 ,  C10G17/095 ,  C10G29/20 ,  C10G45/10 ,  C10G45/44 ,  C10G50/00 ,  C10G55/04 ,  C10G55/06 ,  C10G67/08 ,  C10G67/16 ,  C07C7/20

CPC分类号： C10G29/205 ,  C10G50/00

摘要： A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (α) the upper distillation point of which is less than 100° C. and a kerosene cut (β) having a distillation range between 100° C. and 300° C.

摘要翻译： 描述了一种用于增加烃类和降低所述电荷的蒸气压的方法，包括三个步骤：步骤a）由将所述烃分离成基本上含有5个碳原子的化合物的馏分（O1）组成的步骤 ，包括至少2重量％的戊烯，步骤b）将所述馏分（O1）与至少部分包含6至10个碳原子的烃的馏分（O 2）接触，包括 至少2重量％的烯烃，以及步骤c），其通过将来自步骤b）的流出物分离成上馏分小于100℃的汽油馏分（α）和煤油切割（β ），其蒸馏范围为100℃至300℃。