公开(公告)号：US20160257634A1

公开(公告)日：2016-09-08

申请号：US15058426

申请日：2016-03-02

申请人： Evonik Degussa GmbH

发明人： Katrin Marie Dyballa ,  Robert Franke ,  Dirk Fridag ,  Michael Mirion ,  Thomas Quell ,  Siegfried R. Waldvogel

IPC分类号： C07C41/30 ,  C07C37/14 ,  C07C391/02

CPC分类号： C07C41/30 ,  C07C37/11 ,  C07C37/14 ,  C07C391/02 ,  C07C39/15 ,  C07C43/2055

摘要： The invention is concerned with a process for preparing 2,2′-biaryls, especially of 2,2′-biphenols in which a reaction mixture comprising a first aryl, a second aryl and selenium dioxide is heated, the first aryl being reacted with the second aryl to give the corresponding 2,2′-biaryl, wherein the reaction mixture additionally comprises molybdenum(V) chloride.

摘要翻译： 本发明涉及制备2,2'-联芳基，特别是2,2'-联苯酚的方法，其中加热包含第一芳基，第二芳基和二氧化硒的反应混合物，第一芳基与 第二芳基得到相应的2,2'-联芳基，其中反应混合物另外含有氯化钼（V）。

公开(公告)号：US10167244B2

公开(公告)日：2019-01-01

申请号：US15939373

申请日：2018-03-29

申请人： EVONIK DEGUSSA GMBH

发明人： Katrin Marie Dyballa ,  Robert Franke ,  Dirk Fridag ,  Dieter Hess ,  Detlef Selent ,  Armin Börner

IPC分类号： C07C45/50 ,  B01J31/00 ,  B01J31/18

摘要： A catalytic method for hydroformylating a cyclooctadiene substrate involving forming a reaction mixture that includes the cyclooctadiene and a precursor of or a transitional metal ligand complex where the ligand has structure (1): H2 and CO are fed into the reaction mixture and the mixture is heated to convert the cyclooctadiene into an aldehyde. A preferred ligand is 2-(anthracen-9-yloxy)-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane.

公开(公告)号：US10087134B2

公开(公告)日：2018-10-02

申请号：US15651062

申请日：2017-07-17

申请人： EVONIK DEGUSSA GMBH

发明人： Kaiwu Dong ,  Ralf Jackstell ,  Helfried Neumann ,  Matthias Beller ,  Dirk Fridag ,  Dieter Hess ,  Katrin Marie Dyballa ,  Frank Geilen ,  Robert Franke

IPC分类号： C07C67/37 ,  B01J27/13 ,  C07F9/58

摘要： The invention relates to a process comprising the process steps of: a) initially charging an ether having from 3 to 30 carbon atoms; b) adding a phosphine ligand and a compound comprising Pd, or adding a comprising Pd and a phosphine ligand; c) feeding in CO; d) heating the reaction mixture, with conversion of the ether; wherein the phosphine ligand is a compound of formula (I) where m and n are each independently 0 or 1; R1, R2, R3, R4 are each independently selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl, —(C3-C20)-heteroaryl; at least one of the R1, R2, R3, R4 radicals is a —(C3-C20)-heteroaryl radical; and R1, R2, R3, R4, if they are —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl or —(C3-C20)-heteroaryl, may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-cycloalkyl, —S—(C1-C12)-alkyl, —S—(C3-C12)-cycloalkyl, —COO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —CONH—(C1-C12)-alkyl, —CONH—(C3-C12)-cycloalkyl, —CO—(C1-C12)-alkyl, —CO—(C3-C12)-cycloalkyl, —N—[(C1-C12)-alkyl]2, —(C6-C20)-aryl, —(C6-C20)-aryl-(C1-C12)-alkyl, —(C6-C20)-aryl-O—(C1-C12)-alkyl, —(C3-C20)-heteroaryl, —(C3-C20)heteroaryl-(C1-C12)-alkyl, —(C3-C20)-heteroaryl-O—(C1-C12)-alkyl, —COOH, —SO3H, —NH2, halogen; and wherein no alcohol is added to the reaction mixture.

公开(公告)号：US20180208538A1

公开(公告)日：2018-07-26

申请号：US15925401

申请日：2018-03-19

申请人： Evonik Degussa GmbH

发明人： Helene Reeker ,  Guido Stochniol ,  Dietrich Maschmeyer ,  Horst-Werner Zanthoff ,  Jörg Schallenberg ,  Frank Geilen ,  Katrin Marie Dyballa ,  Dirk Fridag ,  Stephan Peitz ,  Lena Altmann ,  Robert Franke

IPC分类号： C07C67/08 ,  C07C45/50 ,  C07C2/24 ,  C07C29/141

CPC分类号： C07C67/08 ,  C07C2/24 ,  C07C29/141 ,  C07C45/50 ,  C07C45/505 ,  C07C2521/12 ,  C07C2523/755 ,  Y02P20/52 ,  C07C47/02 ,  C07C31/125 ,  C07C69/80 ,  C07C11/02

摘要： The invention relates to a process for preparing an ester mixture, in which an n-butene-containing feed mixture having a composition which changes over time is first oligomerized and then converted by hydroformylation, hydrogenation and esterification to an ester mixture. In this process, an approximation of the actual viscosity of the ester mixture is determined. The problem that it addresses is that of specifying a comparatively simple process which enables conversion of an n-butene with a variable composition over time to an ester mixture having a viscosity which can be kept very substantially constant over a long period even when an inconstant C4 source which delivers fluctuating qualities over this period is utilized. This is achieved through controlled use of a second raw material, namely ethene. It has been found that the viscosity of n-butene-based ester mixtures can be influenced by controlled use of ethene in the preparation of the ester precursors. Specifically, the invention proposes two measures by which the ethene can be used: either directly as C2 olefin or as C8 olefin after prior separate oligomerization.

公开(公告)号：US10011619B2

公开(公告)日：2018-07-03

申请号：US15363746

申请日：2016-11-29

申请人： EVONIK DEGUSSA GMBH

发明人： Katrin Marie Dyballa ,  Robert Franke

IPC分类号： C07F9/02 ,  C07F9/06 ,  C07F9/655 ,  C07F9/576 ,  C07F9/6574 ,  C07F9/6584 ,  C07F9/145 ,  C07F9/24

摘要： Universally usable process for reducing the chlorine content of organotetraphosphites.

公开(公告)号：US09938310B2

公开(公告)日：2018-04-10

申请号：US15649759

申请日：2017-07-14

申请人： EVONIK DEGUSSA GMBH

发明人： Kaiwu Dong ,  Helfried Neumann ,  Ralf Jackstell ,  Matthias Beller ,  Dirk Fridag ,  Dieter Hess ,  Katrin Marie Dyballa ,  Frank Geilen ,  Robert Franke

IPC分类号： C07F15/02 ,  C07F9/58 ,  B01J31/12 ,  C07F17/02 ,  C07C67/38 ,  C07C213/02

CPC分类号： C07F17/02 ,  C07C67/38 ,  C07C213/02 ,  C07C2527/185 ,  C07F15/0066 ,  C07C69/24

摘要： Diastereomer mixture comprising diastereomers of the formulae (I.1) and (I.2) where R2, R4 are each independently selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl; the R1, R3 radicals are each a —(C3-C20)-heteroaryl radical. The invention further relates to Pd complex mixtures comprising the diastereomers according to the invention, and to the use thereof in an alkoxycarbonylation process.

公开(公告)号：US20170144959A1

公开(公告)日：2017-05-25

申请号：US15356507

申请日：2016-11-18

申请人： Evonik Degussa GmbH

发明人： Helene Reeker ,  Guido Stochniol ,  Dietrich Maschmeyer ,  Horst-Werner Zanthoff ,  Jörg Schallenberg ,  Frank Geilen ,  Katrin Marie Dyballa ,  Dirk Fridag ,  Stephan Peitz ,  Lena Altmann ,  Robert Franke

IPC分类号： C07C67/08 ,  C07C45/50 ,  C07C29/141 ,  C07C2/24

CPC分类号： C07C67/08 ,  C07C2/24 ,  C07C29/141 ,  C07C45/50 ,  C07C45/505 ,  C07C2521/12 ,  C07C2523/755 ,  Y02P20/52 ,  C07C47/02 ,  C07C31/125 ,  C07C69/80 ,  C07C11/02

摘要： The invention relates to a process for preparing an ester mixture, in which an n-butene-containing feed mixture having a composition which changes over time is first oligomerized and then converted by hydroformylation, hydrogenation and esterification to an ester mixture. In this process, an approximation of the actual viscosity of the ester mixture is determined. The problem that it addresses is that of specifying a comparatively simple process which enables conversion of an n-butene with a variable composition over time to an ester mixture having a viscosity which can be kept very substantially constant over a long period even when an inconstant C4 source which delivers fluctuating qualities over this period is utilized. This is achieved through controlled use of a second raw material, namely ethene. It has been found that the viscosity of n-butene-based ester mixtures can be influenced by controlled use of ethene in the preparation of the ester precursors. Specifically, the invention proposes two measures by which the ethene can be used: either directly as C2 olefin or as C8 olefin after prior separate oligomerization.

公开(公告)号：US09624153B2

公开(公告)日：2017-04-18

申请号：US15103842

申请日：2014-12-10

申请人： Evonik Degussa GmbH ,  Marc Becker ,  Katrin Marie Dyballa ,  Robert Franke ,  Dirk Fridag ,  Hanna Hahn ,  Marina Lazar ,  Markus Priske ,  Guido Stochniol

发明人： Marc Becker ,  Katrin Marie Dyballa ,  Robert Franke ,  Dirk Fridag ,  Hanna Hahn ,  Marina Lazar ,  Markus Priske ,  Guido Stochniol

IPC分类号： C07C45/50 ,  B01D5/00 ,  B01J31/00 ,  B01D61/38 ,  B01J31/02 ,  B01J31/18 ,  C07C45/78 ,  B01D61/36 ,  B01J31/24 ,  C07C45/79 ,  C07C45/82

CPC分类号： C07C45/50 ,  B01D5/006 ,  B01D5/0072 ,  B01D61/362 ,  B01D61/38 ,  B01D2311/02 ,  B01D2311/04 ,  B01D2311/06 ,  B01D2311/263 ,  B01D2311/2669 ,  B01D2311/2673 ,  B01J31/0292 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/786 ,  C07C45/79 ,  C07C45/82 ,  C07C47/02

摘要： The invention relates to processes for preparing aldehydes by hydroformylation of alkenes, in which an alkene-containing feed mixture is subjected to a primary hydroformylation with synthesis gas in the presence of a homogeneous catalyst system, the primary hydroformylation being effected in a primary reaction zone from which a cycle gas containing at least some of the products and unconverted reactants of the primary hydroformylation are drawn off continuously and partly condensed, with recycling of uncondensed components of the cycle gas into the primary reaction zone, and with distillative separation of condensed components of the cycle gas in an aldehyde removal stage to give an aldehyde-rich mixture and a low-aldehyde mixture. The problem that it addresses is that of developing the process such that it achieves high conversions and affords aldehyde in good product quality even in the case of a deteriorating raw material position. More particularly, a solution is to be found for making legacy oxo process plants capable of utilizing lower-value raw material sources. This problem is solved by separating the low-aldehyde mixture into a retentate and a permeate by means of a membrane separation unit in such a way that alkenes present in the low-aldehyde mixture become enriched in the permeate, while alkanes present in the low-aldehyde mixture become enriched in the retentate. The alkene-rich permeate is then transferred into a secondary reaction zone and subjected to a secondary hydroformylation therein with synthesis gas in the presence of an SILP catalyst system. The reaction product obtained from the secondary hydroformylation is recycled into the aldehyde removal stage.

公开(公告)号：US09605010B2

公开(公告)日：2017-03-28

申请号：US15141069

申请日：2016-04-28

申请人： EVONIK DEGUSSA GMBH

发明人： Katrin Marie Dyballa ,  Robert Franke

IPC分类号： C07F15/00 ,  C07C45/50 ,  B01J31/18 ,  C07F9/6574 ,  B01J31/22 ,  C07F9/145

CPC分类号： C07F9/65744 ,  B01J31/185 ,  B01J31/22 ,  B01J2231/321 ,  B01J2531/821 ,  C07C45/50 ,  C07F9/145 ,  C07F15/008

摘要： Novel monophosphite compounds having a methyl group, and a process for preparing these compounds, which are especially suitable for use as ligands in hydroformylation reactions.

公开(公告)号：US11028110B2

公开(公告)日：2021-06-08

申请号：US15649770

申请日：2017-07-14

申请人： EVONIK DEGUSSA GMBH

发明人： Kaiwu Dong ,  Ralf Jackstell ,  Helfried Neumann ,  Matthias Beller ,  Dirk Fridag ,  Dieter Hess ,  Katrin Marie Dyballa ,  Frank Geilen ,  Robert Franke

IPC分类号： C07F9/50 ,  C07C67/36 ,  C07C67/38 ,  C07D471/00 ,  C07F15/00

摘要： The invention relates to a process comprising the following process steps: a) introducing a first alcohol, the first alcohol having 2 to 30 carbon atoms; b) adding a phosphine ligand and a compound which comprises Pd, or adding a complex comprising Pd and a phosphine ligand; c) adding a second alcohol; d) supplying CO; e) heating the reaction mixture, the first alcohol reacting with CO and the second alcohol to form an ester; where the phosphine ligand is a compound of formula (I) where m and n are each independently 0 or 1; R1, R2, R3, R4 are each independently selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl, —(C3-C20)-heteroaryl; at least one of the R1, R2, R3, R4 radicals is a —(C3-C20)-heteroaryl radical; and R1, R2, R3, R4, if they are —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl or —(C3-C20)-heteroaryl, may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-cycloalkyl, —S—(C1-C12)-alkyl, —S—(C3-C12)-cycloalkyl, —COO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —CONH—(C1-C12)-alkyl, —CONH—(C3-C12)-cycloalkyl, —CO—(C1-C12)-alkyl, —CO—(C3-C12)-cycloalkyl, —N—[(C1-C12)-alkyl]2, —(C6-C20)-aryl, —(C6-C20)-aryl-(C1-C12)-alkyl, —(C6-C20)-aryl-O—(C1-C12)-alkyl, —(C3-C20)-heteroaryl, —(C3-C20)-heteroaryl-(C1-C12)-alkyl, —(C3-C20)-heteroaryl-O—(C1-C12)-alkyl, —COOH, —OH, —SO3H, —NH2, halogen.