摘要:
Method for the water removal from a surface, which comprises covering the surface with a composition having specific weight higher than that of the water, and subsequently removing water from the composition by skimming, such composition comprising a (per)fluoropolyether having molecular weight comprised between 300 and 1500 and a non ionic additive having a (perfluoropolyethereal structure similar to that of the solvent, linked to an hydrogenated part of hydrophilic type, the molecular weight of the (per)fluorinated part is comprised between 400 and 1200 and the ratio by weight between (per)fluorinated part and hydrogenated part is comprised between 1.5 and 3.5.
摘要:
A process for preparing hydrogen-terminated polyoxyperfluoroalkanes having molecular weight lower than 1800, by decarboxylation of the corresponding polyoxyperfluoroalkanes having one or two end groups selected form --OCF.sub.2 COOZ, --OCF.sub.2 CF.sub.2 COOZ and --OCF(CF.sub.3)COOZ, wherein Z is an alkaline metal or ammonium, carried out in the presence of water at temperatures from 140.degree.-170.degree. C. and under a pressure of at least 4 atmospheres.
摘要:
Polytetrafluoroethylene (PTFE) dispersions in an organic solvent, comprising:(A) from 2 to 40% by weight of PTFE in powder form;(B) from 50 to 95% by weight of an organic solvent;(C) from 0.5 to 10% by weight of a dispersing agent of formula:(R.sub.H -L).sub.y -(R.sub.F -L).sub.x R.sub.H (I)whereinx is an integer from 1 to 3;y is 0 or 1, with the proviso that x=1 when y=1;R.sub.H is a x-functional radical having an alkylic or polyoxyalkylenic structure;R.sub.F is (per)fluoropolyoxyalkylenic radical;L is a divalent organic group.Such dispersions are utilized for the surface treatment of metals, glass fibers, and the like, and in particular as mould release agents.
摘要:
Coatings based on perfluoropolyethers terminated with acrylic groups and containing ethoxylic groups as a connecting bridge between the fluorinated part and the (meth)acrylic group.
摘要:
Polishes for metal surfaces, based on dispersions of waxes, fluorinated polymers and perfluoropolyoxyalkylene oils acquire high gloss characteristics combined with improved water-repellency and resistance to soiling of 0.1-5% by weight of at least a cationic emulsifier comprised in the general formulaR--L--Q.sup.+ X.sup.-.sub.t (I)where:R=a chain of perfluoropolyoxyalkylene units;L=a divalent organic group;Q=a polar group;X=a halogen, or a group of formulaCH.sub.3 -Phenylene-SO.sub.3.sup.-R"SO.sub.3 --R"=F-(CF.sub.2).sub.m -;t=1 or 2;m=1-4.The polished containing the emulsifiers of formula (I) as well as the compounds comprised in said formula are claimed as new products.
摘要翻译:基于蜡,氟化聚合物和全氟聚氧化烯油的分散体,用于金属表面的抛光获得高光泽特性,结合改善的防水性和耐污染性至少为通式RL-中包含的至少一种阳离子乳化剂0.1-5重量% Q + Xt(I)其中:R =全氟聚氧化烯单元链; L =二价有机基团; Q =极性基团; X =卤素或式为CH 3 - 亚苯基-SO 3 -R“SO 3 -R”= F-(CF 2)m - 的基团; t = 1或2; m = 1-4。 含有式(I)的乳化剂的抛光剂以及所述式中包含的化合物被称为新产品。
摘要:
Compounds suitable for being used as lubricants, having general formula:(I) RO--(C.sub.3 F.sub.6 O).sub.m --(CFXO).sub.n --CFX--L, or(II) R"CFXO--(C.sub.3 F.sub.6 O).sub.x (CFXO).sub.y --(C.sub.2 F.sub.4 O).sub.z --(CFX--L, whereR=--CF.sub.3, --C.sub.2 F.sub.5, --C.sub.3 F.sub.7X=F, --CF.sub.3R"=F, --CF.sub.3, --C.sub.2 F.sub.5m=an integer from 3 to 100n=a finite integer, or=zero, wherefore m+n ranges from 3 to 100, provided that, if n is finite, m/n ranges from 5 ro 20 and R is preferably=CF.sub.3, if n=zero, R is preferably --C.sub.2 F.sub.5 or --C.sub.3 F.sub.7x=a finite integer, or=zeroy, z=finite integers, such that x+y+z ranges from 5 to 200, while x+z/y ranges from 5 to 0.5, provided that when x=zero, z/y ranges from 1 to 0.5 and y+z ranges from 5 to 200 n while X is preferably F, and R"=LL=group A--Y, whereA=--CH.sub.2 O--, --CH.sub.2 --O--CH.sub.2, --CF.sub.2, CF.sub.2 O--,Y=an organic radical covered by one of the following formulas: ##STR1## where R.sub.1, R.sub.2 =alkyls C.sub.1 -C.sub.3,E=CHR.sub.3 or --CH.sub.2 --CHR.sub.3B=H or a radical OR.sub.3 --R.sub.3 =H or an alkyl C.sub.1 -C.sub.3.
摘要翻译:适用于润滑剂的化合物,具有以下通式:(I)RO-(C 3 F 6 O)m - (CFXO)n -CFX-L或(II)R''CFXO-(C 3 F 6 O)x(CFXO)y - ( C 2 F 4 O)z - (CFX-L,其中R = -CF 3,-C 2 F 5,-C 3 F 7 X = F,-CF 3 R“= F,-CF 3,-C 2 F 5 m = 3至100的整数n =有限整数 或= = 0,因为m + n的范围为3至100,条件是如果n是有限的,则m / n的范围为5罗20,R优选为= CF 3,如果n = 0,则R优选为-C 2 F 5或 - C3F7 x =有限整数,或= 0,z =有限整数,使得x + y + z的范围为5至200,而x + z / y的范围为5至0.5,条件是当x =零时,z / y为1〜0.5,y + z为5〜200n,X优选为F,R“= LL = AY,A = -CH 2 O - , - CH 2 -O-CH 2,-CF 2, CF 2 O-,Y =由下式之一覆盖的有机基团:其中R 1,R 2 =烷基C 1 -C 3,E = CHR 3或-CH 2 -CHR 3 B = H或基团OR 3 -R 3 = H或 烷基C1-C3。
摘要:
A process for fully removing from the perfluoropolyethers having a minimum vapor tension, the organic polluting matters containing group --OH and/or bonds ##STR1## consisting in treating the perfluoropolyether with oxygen, or chlorine or fluorine, at a high temperature and in the presence of ultraviolet radiations, in order to convert the impurities to volatile degradation products easily removable by degassing.
摘要:
A process for preparing perfluoropolyoxyalkylenes with hydroxyl end groups having structure: T1—CFW1—O—Rf—CFW2—T2 (I) wherein: T1, T2, are selected from —CH2OH, —F, —CF3, —CF2CF3 with the proviso that at least one of T1 and T2 is —CH2OH; W1 and W2 are selected from F, CF3; Rf is a perfluoropolyoxyalkylene chain having a number average molecular weight 500-10,000 comprising one or more units of the type —CF2CF2O—, —CF2O—, —C3F6O—, —CF2(CF2)zCF2O— (z=1,2); —CR4R5CF2CF2O— with R4 and R5 selected from H, Cl, perfluoroalkyl group; said process comprising the following steps: a) adding an ester precursor having structure (I) and T1, T2 end groups selected from —F, —CF3, —CF2CF3, —COOR (R=linear or branched alkyl group having a number of C atoms from 1 to 5), with the proviso that at least one of T1 and T2 is —COOR, in a reaction mixture formed by: an inert or protic reaction solvent; a reducing agent selected from metal hydrides; an unreactive organic base with respect to the ester; b) hydrolysis of the product obtained in step a) for obtaining the compounds of structure (I) with at least a —CH2OH end group.
摘要:
Use in curable fluoroelastomer compositions of additives having polyacetal structure of general formula: HOCH2—[Rf—CH2O(CH2O)cCH2]t—Rf—CH2OH (I) wherein: c=1-10, preferably 1-3; t=0.5-20. Rf=poly-fluorooxyalkylenic chain, having number average molecular weight ({overscore (M)}n) in the range 500-2,500, preferably 1,000-2,000; the number average molecular weight of the formula (I) additive is in the range 3,000-15,000, preferably 3,000-10,000.
摘要翻译:在具有以下通式的聚缩醛结构的添加剂的可固化含氟弹性体组合物中使用:其中:c = 1-10,优选1-3; t = 0.5-20.Rf =数均分子量({overscore(M)} n)在500-2,500,优选1,000-2,000范围内的聚氟氧烷基链;式(I)的数均分子量 添加剂在3,000-15,000,优选3,000-10,000的范围内。
摘要:
Use of additives of the classes of mono- and/or di-hydroxypolyfluoroethers comprising the fluoropolyoxyalkylenic repeating units chosen from the following ones: (C.sub.3 F.sub.6 O); (CFXO) wherein X=F, CF.sub.3 ; (CH.sub.2 CF.sub.2 CF.sub.2 O); (CF.sub.2 (CF.sub.2).sub.z CF.sub.2 O) wherein z is an integer equal to 1 or 2; (C.sub.2 F.sub.4 O), in curable compositions of fluoroelastomers to improve the coefficient of friction without lowering the adhesion with bonding agents to metal reinforcements.