摘要:
A process for the production of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) a thermoplastic resin, andb) a rubber-rich graft polymerin which aqueous emulsions of a) and b) having polymer contents of 15 to 50% by weight are mixed continuously or semicontinuously in separate product streams, but at the same time, with a coagulation solution at a temperature of 50.degree. to 100.degree. C. with coagulation of polymers a) and b), the product streams are combined and the polymer mixture is separated off.
摘要:
The invention relates to thermoplastic interpolymers having a certain chemical composition and to their use in thermoplastic molding compounds of polyamides and styrene copolymers and/or graft polymers for the production of improved blends of polyamides and styrene copolymers and/or graft polymers, particularly ABS polymers, having homogeneous surfaces and improved mechanical properties. The interpolymers themselves are produced by compounding of polyamides and copolymers based on styrenes and/or acrylonitrile and/or (meth)acrylates with primary or secondary alcohols and at least one ester of (meth)acrylic acid with a tertiary C.sub.4-10 alcohol in the melt. The interpolymers act as compatibility promoters in the blends and lead to a surprising improvement in a number of properties of thermoplastic molding compounds.
摘要:
A polymer mixture of(a) 45 to 50 parts by weight of a graft product of a mixture of 25 to 40 parts by weight acrylonitrile and 75 to 60 parts by weight styrene, .alpha.-methylstyrene, alkylmethacrylate or mixtures thereof on a particulate, highly crosslinked diene rubber having a rubber content of 20 to 40% by weight,(b) 45 to 10 parts by weight of a graft product of a mixture of 20 to 35 parts by weight acrylonitrile and 80 to 65 parts by weight styrene or .alpha.-methylstyrene on a particulate, highly crosslinked diene rubber having a rubber content of 50 to 75% by weight, the graft yield being greater than 60% by weight,(c) 10 to 50 parts by weight of a particulate, partially crosslinked, rubber-like copolymer of a C.sub.2 -C.sub.8 alkylacrylate and/or butadiene containing up to 40% by weight (based on copolymer) acrylonitrile which has an average particle diameter (d.sub.50) of from 0.1 to 0.3 .mu.m and a gel content of 40 to 99% by weight and(d) optionally up to 5 parts by weight of a high molecular weight, uncrosslinked copolymer of styrene or methylmethacrylate and up to 40% by weight acrylonitrile having an intrinsic viscosity [.eta.] (in dimethylformamide at 20.degree. C. of >4 dl/g,a process for its production and its use as an additive in polyvinyl chloride molding compositions.
摘要:
Process for the preparation of aliphatic polycarbonates by polymerizing cyclic aliphatic carbonates in the presence of initiators and/or catalysts, in which the initiators used are alkoxy silanes of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 independently of one another represent a C.sub.1 -C.sub.4 -alkyl radical, n is an interger from 1 to 6 andR.sub.4 denotes an n-valent, optionally substituted, aliphatic hydrocarbon radical,and the catalysts used are the nucleophilic catalysts which are known from group transfer polymerization.
摘要:
Compositions of the ABS type containing A) one or more graft rubbers of A.1) from 10 to 60 parts by weight of one or more monomers on A.2) from 40 to 90 parts by weight of one or more rubber backbones having glass transition temperatures
摘要:
Thermoplastic molding compounds containingA. 10 to 99 parts by weight polycarbonate or polyester carbonateB. 0 to 90 parts by weight of a rubber-free resin compatible or partly compatible with component A.,C. 0 to 90 parts by weight of a rubber-modified resin compatible or partly compatible with component A.,D. 0.5 to 10 parts by weight, based on 100 parts by weight of A+B+C, of a rubber component having a glass transition temperature below 0.degree. C. which is incompatible with component A,characterized in that component D is used in the form of a powder mixture D* produced froma. 1 to 50 parts by weight of an ungrafted particulate rubber component having a glass transition temperature below 0.degree. C. and an average particle diameter d.sub.50 of 0.05 to 5 .mu.m in latex form andb. 50 to 99 parts by weight of component B, component C or a mixture of components B and C in latex form,the components mentioned under a. and b. initially being mixed with one another as latices and then being worked up together to form a powder mixture D*.
摘要:
Process for pretreating abietic acid derivatives comprising dissolving an abietic derivative in water to form a 2 to 25% by weight solution, adding a base so that the pH of the solution is from 10 to 14 and removing from 0.5 to 25% by weight of the abietic acid derivative originally present in the solution by extraction or steam distillation while maintaining the pH from 10 to 14.
摘要:
Powdery mixture of from 1 to 99 weight % of a graft polymer of resin-forming monomers on a rubber and from 99 to 1 weight % of a bisphenol and the use thereof for improving chemical materials.
摘要:
Thermoplastic molding compositions containingA) ABS-type resin,B) aromatic polycarbonate resins,C) a compound bearing several carboxyl groups or mixtures thereof and optionallyD) further polymer resins,characterized in that an ABS resin with at least one basically acting additive is used as component A, component C is selected from compounds having a molecular weight of from 150 to 260 having at least two carboxyl groups (--COOH) in the molecule, and the weight ratio of basically acting additive in A: carboxyl groups in C is from 5:1 to 1:1.