Thermoplastic interpolymers and their use in mixtures of polyamide and
styrene copolymers and/or graft polymers
    22.
    发明授权
    Thermoplastic interpolymers and their use in mixtures of polyamide and styrene copolymers and/or graft polymers 失效
    热塑性互聚物及其在聚酰胺和苯乙烯共聚物和/或接枝聚合物的混合物中的用途

    公开(公告)号:US5010138A

    公开(公告)日:1991-04-23

    申请号:US389967

    申请日:1989-08-07

    CPC分类号: C08L77/00 C08G81/028

    摘要: The invention relates to thermoplastic interpolymers having a certain chemical composition and to their use in thermoplastic molding compounds of polyamides and styrene copolymers and/or graft polymers for the production of improved blends of polyamides and styrene copolymers and/or graft polymers, particularly ABS polymers, having homogeneous surfaces and improved mechanical properties. The interpolymers themselves are produced by compounding of polyamides and copolymers based on styrenes and/or acrylonitrile and/or (meth)acrylates with primary or secondary alcohols and at least one ester of (meth)acrylic acid with a tertiary C.sub.4-10 alcohol in the melt. The interpolymers act as compatibility promoters in the blends and lead to a surprising improvement in a number of properties of thermoplastic molding compounds.

    摘要翻译: 本发明涉及具有一定化学组成的热塑性互聚物及其在聚酰胺和苯乙烯共聚物和/或接枝聚合物的热塑性模塑化合物中的用途,用于生产聚酰胺和苯乙烯共聚物和/或接枝聚合物,特别是ABS聚合物的改进的共混物, 具有均匀的表面和改善的机械性能。 互聚物本身是通过将聚酰胺和/或丙烯腈和/或(甲基)丙烯酸酯与伯醇或仲醇和至少一种(甲基)丙烯酸酯与叔C4-10醇的酯混合在一起的共聚物和/ 熔化。 互聚物作为共混物中的相容促进剂,并导致热塑性模塑料的许多性能的令人惊奇的改进。

    Polymer mixture and its use as a modifier for polyvinyl chloride
    23.
    发明授权
    Polymer mixture and its use as a modifier for polyvinyl chloride 失效
    聚合物混合物及其用作聚氯乙烯的改性剂

    公开(公告)号:US4902744A

    公开(公告)日:1990-02-20

    申请号:US275925

    申请日:1988-11-25

    摘要: A polymer mixture of(a) 45 to 50 parts by weight of a graft product of a mixture of 25 to 40 parts by weight acrylonitrile and 75 to 60 parts by weight styrene, .alpha.-methylstyrene, alkylmethacrylate or mixtures thereof on a particulate, highly crosslinked diene rubber having a rubber content of 20 to 40% by weight,(b) 45 to 10 parts by weight of a graft product of a mixture of 20 to 35 parts by weight acrylonitrile and 80 to 65 parts by weight styrene or .alpha.-methylstyrene on a particulate, highly crosslinked diene rubber having a rubber content of 50 to 75% by weight, the graft yield being greater than 60% by weight,(c) 10 to 50 parts by weight of a particulate, partially crosslinked, rubber-like copolymer of a C.sub.2 -C.sub.8 alkylacrylate and/or butadiene containing up to 40% by weight (based on copolymer) acrylonitrile which has an average particle diameter (d.sub.50) of from 0.1 to 0.3 .mu.m and a gel content of 40 to 99% by weight and(d) optionally up to 5 parts by weight of a high molecular weight, uncrosslinked copolymer of styrene or methylmethacrylate and up to 40% by weight acrylonitrile having an intrinsic viscosity [.eta.] (in dimethylformamide at 20.degree. C. of >4 dl/g,a process for its production and its use as an additive in polyvinyl chloride molding compositions.

    摘要翻译: (a)45至50重量份的25至40重量份丙烯腈和75至60重量份苯乙烯,α-甲基苯乙烯,甲基丙烯酸烷基酯或其混合物的混合物的接枝产物在颗粒状高度 橡胶含量为20〜40重量%的交联二烯橡胶,(b)45〜10重量份的20〜35重量份丙烯腈和80〜65重量份苯乙烯或α-烯烃的混合物的接枝产物, 甲基苯乙烯在橡胶含量为50〜75重量%,接枝收率大于60重量%的颗粒状,高度交联的二烯橡胶上,(c)10〜50重量份的颗粒状,部分交联的橡胶 - 平均粒径(d50)为0.1-0.3μm,凝胶含量为40-99%的含有至多40重量%(基于共聚物)丙烯腈的C2-C8烷基丙烯酸酯和/或丁二烯的共聚物, (d)任选地至多5重量份的高分子量 苯乙烯或甲基丙烯酸甲酯的未交联共聚物和高达40重量%特性粘度η的丙烯腈(在20℃的二甲基甲酰胺中为> 4dl / g,其制备方法及其用作添加剂的方法) 在聚氯乙烯模塑组合物中。

    Process for the preparation of aliphatic polycarbonates with alkoxy
silane initiator
    24.
    发明授权
    Process for the preparation of aliphatic polycarbonates with alkoxy silane initiator 失效
    用烷氧基硅烷引发剂制备脂族聚碳酸酯的方法

    公开(公告)号:US4879367A

    公开(公告)日:1989-11-07

    申请号:US212817

    申请日:1988-06-29

    CPC分类号: C08G64/30 C08G64/0208

    摘要: Process for the preparation of aliphatic polycarbonates by polymerizing cyclic aliphatic carbonates in the presence of initiators and/or catalysts, in which the initiators used are alkoxy silanes of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 independently of one another represent a C.sub.1 -C.sub.4 -alkyl radical, n is an interger from 1 to 6 andR.sub.4 denotes an n-valent, optionally substituted, aliphatic hydrocarbon radical,and the catalysts used are the nucleophilic catalysts which are known from group transfer polymerization.

    摘要翻译: 用于通过在引发剂和/或催化剂存在下聚合环状脂肪族碳酸酯来制备脂族聚碳酸酯的方法,其中使用的引发剂是式I的烷氧基硅烷,其中R 1,R 2和R 3彼此独立地表示 C 1 -C 4 - 烷基,n是1至6的整数,R 4表示n价任选取代的脂族烃基,所用的催化剂是从组转移聚合中已知的亲核催化剂。

    Powder mixtures for matt polycarbonate molding compounds
    26.
    发明授权
    Powder mixtures for matt polycarbonate molding compounds 失效
    用于哑光聚碳酸酯模塑料的粉末混合物

    公开(公告)号:US5484846A

    公开(公告)日:1996-01-16

    申请号:US349451

    申请日:1994-11-30

    摘要: Thermoplastic molding compounds containingA. 10 to 99 parts by weight polycarbonate or polyester carbonateB. 0 to 90 parts by weight of a rubber-free resin compatible or partly compatible with component A.,C. 0 to 90 parts by weight of a rubber-modified resin compatible or partly compatible with component A.,D. 0.5 to 10 parts by weight, based on 100 parts by weight of A+B+C, of a rubber component having a glass transition temperature below 0.degree. C. which is incompatible with component A,characterized in that component D is used in the form of a powder mixture D* produced froma. 1 to 50 parts by weight of an ungrafted particulate rubber component having a glass transition temperature below 0.degree. C. and an average particle diameter d.sub.50 of 0.05 to 5 .mu.m in latex form andb. 50 to 99 parts by weight of component B, component C or a mixture of components B and C in latex form,the components mentioned under a. and b. initially being mixed with one another as latices and then being worked up together to form a powder mixture D*.

    摘要翻译: 含有A.10-99重量份聚碳酸酯或聚碳酸酯B的热塑性成型化合物B.0-90重量份与组分A,C相容或部分相容的无橡胶树脂。0至90重量份橡胶 与A组分相容或部分相容的树脂D.以0.5至10重量份,基于100重量份的A + B + C,玻璃化转变温度低于0℃的橡胶组分为 与组分A不相容,其特征在于组分D以由a制备的粉末混合物D *的形式使用。 1至50重量份的玻璃化转变温度低于0℃的未接枝的颗粒状橡胶组分和胶乳形式的平均粒径d50为0.05-5μm,b。 50至99重量份的组分B,组分C或胶乳形式的组分B和C的混合物,a。下提及的组分。 和b。 最初彼此混合作为胶乳,然后一起处理以形成粉末混合物D *。