ON-PRESS DEVELOPABLE NEGATIVE-WORKING IMAGEABLE ELEMENTS AND METHODS OF USE
    22.
    发明申请
    ON-PRESS DEVELOPABLE NEGATIVE-WORKING IMAGEABLE ELEMENTS AND METHODS OF USE 审中-公开
    可压缩可开发的负责任的成像元件和使用方法

    公开(公告)号:US20080311520A1

    公开(公告)日:2008-12-18

    申请号:US11762288

    申请日:2007-06-13

    Abstract: A negative-working imageable element has an imageable layer that includes an initiator composition including an iodonium cation and a borate anion, an infrared radiation absorbing compound, a particulate primary polymeric binder, and a phosphate (meth)acrylate adhesion promoter. The element also includes a polymeric overcoat disposed over the imageable layer and can be developed on-press to provide a lithographic printing plate with high run length. The element also has improved shelf-life.

    Abstract translation: 负性可成像元件具有可成像层,其包含包含碘鎓阳离子和硼酸根阴离子的引发剂组合物,红外线辐射吸收化合物,颗粒状初级聚合物粘合剂和磷酸酯(甲基)丙烯酸酯粘合促进剂。 元件还包括设置在可成像层上的聚合物外涂层,并且可以在印刷机上显影以提供具有高游程长度的平版印刷版。 该元素还具有改善的保存期限。

    Nanopastes for use as patterning compositions
    23.
    发明授权
    Nanopastes for use as patterning compositions 失效
    用作图案化组合物的纳米磷

    公开(公告)号:US07217502B2

    公开(公告)日:2007-05-15

    申请号:US11444740

    申请日:2006-06-01

    Abstract: The present invention provides methods of imagewise exposing a thermally sensitive composition formed from a nanopaste comprising inorganic nanoparticles, a carrier, and preferably certain polymeric binders. The composition has been applied to a substrate and treated to improve adhesion. Exposure affects the solubility of exposed portions of the applied and treated layer relative to unexposed portions of the applied layer. The imaged layer is then developed on-press with a fountain solution, lithographic ink, or both, to remove the exposed portions or unexposed portions of the layer to form an image in a printing plate.

    Abstract translation: 本发明提供了成像曝光由包含无机纳米颗粒,载体和优选某些聚合物粘合剂的纳米糊料形成的热敏组合物的方法。 将该组合物施用于基材并进行处理以提高粘合性。 暴露影响施加和处理的层相对于施加层的未曝光部分的暴露部分的溶解度。 然后,利用润版液,平版印刷油墨或两者在印刷机上显影成像层,以去除该层的曝光部分或未曝光部分,以在印版中形成图像。

    Positive-working, thermally sensitive imageable element

    公开(公告)号:US07060416B2

    公开(公告)日:2006-06-13

    申请号:US11072486

    申请日:2005-03-04

    Abstract: Alkali soluble copolymers, imageable elements useful as lithographic printing plate precursors that contain the alkali soluble copolymers, and methods for forming images using the imageable elements are disclosed. The alkali soluble copolymers comprise, in polymerized form: (a) N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, or a mixture thereof; (b) acrylamide, methacrylamide, or a mixture thereof; (c) acrylonitrile, methacrylonitrile, or a mixture thereof; and (d) one or more monomers selected from the group consisting of monomers of the structure: CH2═C(R)-Z-X—NHC(O)NH—Y—R′, in which: X is —[C(CH3)2]— or —[(CH2)n]—, in which n is 0 to 12; Y is o-, m-, or p- —[C6H4]—; Z is —[C(O)O]—, —[C(O)NH]—, or o-, m-, or p- [—C6H4]—; R is hydrogen or C1 to C4 alkyl; R′ is —OC(O)—OR″, —OC(O)—Ar, or —OSO2 —Ar; R″ is C1 to C12 alkyl, C1 to C12 arylalkyl, C1 to C12 aryl, C1 to C12 alkenyl, or trimethylsilyl; Ar is C6H5-n′Tn′, in which Ar has a total of six to ten carbon atoms; each T is independently selected from the group consisting of C1 to C4 alkyl, fluoro, chloro, bromo, iodo, trifluoromethyl, methoxy, and cyano; and n′ is an integer from 0 to 5; and in which the copolymer is soluble in alkaline solutions having a pH greater than at least about 11.

    Methods for imaging and processing negative-working imageable elements
    28.
    发明授权
    Methods for imaging and processing negative-working imageable elements 失效
    用于成像和处理负性可成像元件的方法

    公开(公告)号:US07763413B2

    公开(公告)日:2010-07-27

    申请号:US11872772

    申请日:2007-10-16

    Abstract: An imaged and developed element, such as a lithographic printing plate, is provided by infrared radiation imaging of a negative-working imagable element having an outermost imagable layer that includes a free radically polymerizable component, a free radical initiator composition comprising a diaryliodonium borate, and an infrared radiation absorbing compound. The imagable layer also includes a polymeric binder that is represented by the following Structure (I): -(A)w-(A′)w′-  (I) wherein A represents recurring units comprising a pendant reactive vinyl group, A′ represents recurring units other than those represented by A, w is from about 1 to about 70 mol %, and w′ is from about 30 to about 99 mol %. The imagewise exposed element is developed with a gum to remove only the non-exposed regions. The gum has a pH greater than 7 and up to about 11 and at least 1 weight % of an anionic surfactant.

    Abstract translation: 成像和显影元件,例如平版印刷版,通过具有最外层成像层的负作用可成像元件的红外辐射成像提供,该最外可成像层包括可自由基聚合的组分,包含二芳基碘鎓硼酸盐的自由基引发剂组合物和 红外辐射吸收化合物。 可成像层还包括由以下结构(I)表示的聚合物粘合剂: - (A)w-(A')w'-(I)其中A表示包含侧链的反应性乙烯基的重复单元,A'表示 除了由A代表的重复单元,w为约1至约70mol%,w'为约30至约99mol%。 成像曝光元件用树胶显影,仅去除非曝光区域。 口香糖具有大于7且高至约11和至少1重量%阴离子表面活性剂的pH。

    METHODS FOR IMAGING AND PROCESSING NEGATIVE-WORKING IMAGEABLE ELEMENTS
    30.
    发明申请
    METHODS FOR IMAGING AND PROCESSING NEGATIVE-WORKING IMAGEABLE ELEMENTS 审中-公开
    用于成像和处理负压工作图像元素的方法

    公开(公告)号:US20090246698A1

    公开(公告)日:2009-10-01

    申请号:US12057673

    申请日:2008-03-28

    Abstract: An imaged and developed element, such as a lithographic printing plate, is provided by infrared radiation imaging of a negative-working imageable element having an outermost imageable layer that includes an acid generating compound that generates acid upon exposure to imaging infrared radiation, an infrared radiation absorbing compound, an acid activatable crosslinking agent that has acid activatable reactive groups, and a polymeric binder that is capable of undergoing an acid-catalyzed condensation reaction with the crosslinking agent. The imaged element is heated at from about 120 to about 150° C. for up to two minutes, and then developed with a single processing solution to remove only the non-exposed regions and to provide a protective layer prior to lithographic printing.

    Abstract translation: 通过对具有最外可成像层的负性可成像元件的红外辐射成像提供成像和显影元件,例如平版印刷版,其包括在暴露于成像红外辐射时产生酸的产酸化合物,红外辐射 具有酸可活化反应性基团的酸可活化交联剂和能够与交联剂进行酸催化缩合反应的聚合物粘合剂。 将成像的元件在约120至约150℃加热长达两分钟,然后用单一处理溶液显影以仅去除非曝光区域,并在平版印刷之前提供保护层。

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