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21.发明授权Method for the controlled storage and release of gases using an electrochemically produced crystalline, porous, organometallic skeleton material 有权使用电化学生产的结晶多孔的有机金属骨架材料控制储存和释放气体的方法公开(公告)号：US07553352B2
公开(公告)日：2009-06-30
申请号：US10580192
申请日：2004-11-24
申请人： Ulrich Mueller , Hermann Puetter , Michael Hesse , Markus Schubert , Helge Wessel , Juergen Huff , Marcus Guzmann
发明人： Ulrich Mueller , Hermann Puetter , Michael Hesse , Markus Schubert , Helge Wessel , Juergen Huff , Marcus Guzmann
CPC分类号： C25B3/12 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28042 , B01J31/1691 , B01J31/1805 , B01J31/1815 , B01J31/2239 , B01J31/226 , B01J2531/16 , B01J2531/26 , B01J2531/842 , C01B3/0015 , C01B21/0455 , C01B23/0057 , F17C11/005 , H01M8/04216 , Y02C10/08 , Y02E60/327 , Y02E60/328 , Y02P20/133 , Y02P70/56 , Y10S95/90 , Y10S502/526
摘要： The present invention relates to a method of absorbing and/or storing gases, in which the gas to be stored is brought into contact with an electrochemically prepared metal-organic framework under conditions suitable for absorption of the gas, with absorption of the gas into the metal-organic framework occurring, and, if appropriate, the conditions are subsequently changed so that release of the stored gas occurs.
摘要翻译： 本发明涉及一种吸收和/或储存气体的方法，其中待储存的气体在适于吸收气体的条件下与电化学制备的金属 - 有机骨架接触，吸收气体进入 发生金属 - 有机骨架，并且如果合适的话，随后改变条件以便释放储存的气体。
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公开(公告)号：US20130165687A1
公开(公告)日：2013-06-27
申请号：US13734490
申请日：2013-01-04
申请人： Markus SCHUBERT , Ulrich Mueller , Stefan Marx
发明人： Markus SCHUBERT , Ulrich Mueller , Stefan Marx
CPC分类号： B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28042 , B01J20/28054 , B01J31/1691 , B01J31/2239 , B01J35/1028 , B01J2531/31 , B01J2531/62 , B01J2531/842 , C07C51/418 , C07C63/28 , C07C63/38
摘要： The present invention relates to a porous metal organic framework comprising a bidentate organic compound coordinated to a metal ion selected from the group of metals consisting of Al, Fe and Cr, with the bidentate organic compound being derived from a dicarboxylic acid, wherein the framework has a structure whose projection along [001] has a pattern in which each side of a hexagon is bounded by a triangle. The present invention further relates to shaped bodies and a process for preparing the porous metal organic framework and its use.
摘要翻译： 本发明涉及多孔金属有机骨架，其包含与选自Al，Fe和Cr的金属组合的金属离子配位的二齿有机化合物，二齿有机化合物衍生自二羧酸，其中骨架具有 沿[001]的投影具有六边形的每一边由三角形界定的图案的结构。 本发明还涉及成型体及其制备多孔金属有机骨架及其用途的方法。
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23.发明授权Method for electrochemical production of a crystalline porous metal organic skeleton material 有权电化学生产结晶多孔金属有机骨架材料的方法公开(公告)号：US08163949B2
公开(公告)日：2012-04-24
申请号：US12987548
申请日：2011-01-10
申请人： Ulrich Mueller , Hermann Puetter , Michael Hesse , Markus Schubert , Helge Wessel , Juergen Huff , Marcus Guzmann
发明人： Ulrich Mueller , Hermann Puetter , Michael Hesse , Markus Schubert , Helge Wessel , Juergen Huff , Marcus Guzmann
CPC分类号： C25B3/12 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28042 , B01J31/1691 , B01J31/1805 , B01J31/1815 , B01J31/2239 , B01J31/226 , B01J2531/16 , B01J2531/26 , B01J2531/842 , C01B3/0015 , C01B21/0455 , C01B23/0057 , F17C11/005 , H01M8/04216 , Y02C10/08 , Y02E60/327 , Y02E60/328 , Y02P20/133 , Y02P70/56 , Y10S95/90 , Y10S502/526
摘要： A method of electrochemically preparing a crystalline, porous, metal-organic framework material comprising at least one at least bidentate organic compound coordinately bound to at least one metal ion, in a reaction medium comprising the at least one bidentate organic compound, wherein at least one metal ion is provided in the reaction medium by the oxidation of one anode comprising the corresponding metal.
摘要翻译： 一种在包含至少一种二齿有机化合物的反应介质中电化学制备结晶多孔的金属 - 有机骨架材料的方法，其包含与至少一种金属离子配位结合的至少二齿有机化合物，其中至少一种 金属离子通过包含相应金属的一个阳极的氧化在反应介质中提供。
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公开(公告)号：US08372779B2
公开(公告)日：2013-02-12
申请号：US12597616
申请日：2008-04-23
申请人： Markus Schubert , Ulrich Mueller , Stefan Marx
发明人： Markus Schubert , Ulrich Mueller , Stefan Marx
IPC分类号： B01J23/00
CPC分类号： B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28042 , B01J20/28054 , B01J31/1691 , B01J31/2239 , B01J35/1028 , B01J2531/31 , B01J2531/62 , B01J2531/842 , C07C51/418 , C07C63/28 , C07C63/38
摘要： The present invention relates to a porous metal organic framework comprising a bidentate organic compound coordinated to a metal ion selected from the group of metals consisting of Al, Fe and Cr, with the bidentate organic compound being derived from a dicarboxylic acid, wherein the framework has a structure whose projection along [001] has a pattern in which each side of a hexagon is bounded by a triangle. The present invention further relates to shaped bodies and a process for preparing the porous metal organic framework and its use.
摘要翻译： 本发明涉及多孔金属有机骨架，其包含与选自Al，Fe和Cr的金属组合的金属离子配位的二齿有机化合物，二齿有机化合物衍生自二羧酸，其中骨架具有 沿[001]的投影具有六边形的每一边由三角形界定的图案的结构。 本发明还涉及成型体及其制备多孔金属有机骨架及其用途的方法。
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公开(公告)号：US07777061B2
公开(公告)日：2010-08-17
申请号：US12096619
申请日：2006-12-12
CPC分类号： B01J31/1691 , B01J20/226 , B01J39/26 , B01J45/00 , B01J2231/49 , C07C51/418 , C07F5/069 , C07C63/28
摘要： The present invention relates to porous metal organic frameworks comprising at least one at least bidentate organic compound L coordinated to at least one metal ion M, wherein L has at least one functional group G which bonds noncoordinatively to M and is selected from the group consisting of —SO3H and —PO3H2 and their analogues. The invention further provides processes for their preparation and also their use.
摘要翻译： 本发明涉及包含至少一种与至少一种金属离子M配位的至少二齿有机化合物L的多孔金属有机骨架，其中L具有至少一个官能团G，其与M非键合键合并选自 -SO 3 H和-PO 3 H 2及其类似物。 本发明进一步提供了它们的制备方法及其应用。
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公开(公告)号：US07901619B2
公开(公告)日：2011-03-08
申请号：US11915487
申请日：2006-05-17
申请人： Ulrich Mueller , Michael Hesse , Hermann Puetter , Markus Schubert , Marcus Guzmann , Juergen Huff
发明人： Ulrich Mueller , Michael Hesse , Hermann Puetter , Markus Schubert , Marcus Guzmann , Juergen Huff
IPC分类号： A61L9/00
CPC分类号： A61K8/27 , A61K8/368 , A61L9/012 , A61L9/014 , A61L9/145 , A61L2209/22 , A61Q15/00 , B01D53/1493 , B01D2253/10 , B01D2257/90 , B01J20/226
摘要： The present invention relates to suspensions for odor reduction comprising a porous metal-organic framework material in a liquid, and also atomizer and methods for odor reduction using the suspensions. The invention likewise relates to the use of the suspensions for odor reduction.
摘要翻译： 本发明涉及包含液体中的多孔金属 - 有机骨架材料的气味减少悬浮液，还涉及使用该悬浮液的雾化器和降低气味的方法。 本发明同样涉及悬浮液用于降低气味的用途。
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27.发明授权公开(公告)号：US07815716B2
公开(公告)日：2010-10-19
申请号：US12093656
申请日：2006-11-14
申请人： Ulrich Mueller , Michael Hesse , Markus Schubert , Melanie Urtel , Jens Assmann , Philippe Desbois
发明人： Ulrich Mueller , Michael Hesse , Markus Schubert , Melanie Urtel , Jens Assmann , Philippe Desbois
CPC分类号： B01J31/1691 , B01D53/02 , B01D2257/108 , B01J20/226 , B01J20/28097 , B01J20/3206 , B01J20/327 , B01J20/3272 , B01J20/3276 , B01J20/3278 , B01J31/06 , B01J31/2239 , B01J2531/16 , B01J2531/22 , B01J2531/23 , B01J2531/26 , B01J2531/31 , B01J2531/842 , B01J2531/847 , C01B3/0015 , C25B3/12 , F17C11/00 , Y02E60/328
摘要： The invention relates to a porous metal-organic framework material for taking up at least one substance, the framework material comprising at least one at least bidentate organic compound bound by coordination to at least one metal ion, and the framework material having at least in part pores which comprise a polymer which is suitable to adsorb the at least one substance. In addition, the invention relates to a method for producing the framework material, a method for taking up at least one substance by the framework material and also to the use of the framework material, in particular for the storage, separation, controlled release or chemical reaction of a substance taken up.
摘要翻译： 本发明涉及用于吸收至少一种物质的多孔金属 - 有机骨架材料，所述骨架材料包含至少一种至少二齿的有机化合物，所述至少二齿有机化合物通过配位至少一种金属离子结合，所述骨架材料至少部分地具有 包含适于吸附至少一种物质的聚合物的孔。 此外，本发明涉及一种生产骨架材料的方法，一种通过骨架材料吸收至少一种物质的方法，还涉及骨架材料的使用，特别是用于储存，分离，控释或化学品 物质的反应。
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公开(公告)号：US20100076220A1
公开(公告)日：2010-03-25
申请号：US12597616
申请日：2008-04-23
申请人： Markus Schubert , Ulrich Mueller , Stefan Marx
发明人： Markus Schubert , Ulrich Mueller , Stefan Marx
IPC分类号： C07C63/26
CPC分类号： B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28042 , B01J20/28054 , B01J31/1691 , B01J31/2239 , B01J35/1028 , B01J2531/31 , B01J2531/62 , B01J2531/842 , C07C51/418 , C07C63/28 , C07C63/38
摘要： The present invention relates to a porous metal organic framework comprising a bidentate organic compound coordinated to a metal ion selected from the group of metals consisting of Al, Fe and Cr, with the bidentate organic compound being derived from a dicarboxylic acid, wherein the framework has a structure whose projection along has a pattern in which each side of a hexagon is bounded by a triangle. The present invention further relates to shaped bodies and a process for preparing the porous metal organic framework and its use.
摘要翻译： 本发明涉及多孔金属有机骨架，其包含与选自Al，Fe和Cr的金属组合的金属离子配位的二齿有机化合物，二齿有机化合物衍生自二羧酸，其中骨架具有 其沿着投影的结构具有六边形的每一边由三角形限定的图案。 本发明还涉及成型体及其制备多孔金属有机骨架及其用途的方法。
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29.发明申请Method for the Controlled Storage and Release of Gases Using an Electrochemically Produced Crystalline, Porous, Organometallic Skeleton Material 有权使用电化学生产的结晶多孔有机金属骨架材料控制储存和释放气体的方法公开(公告)号：US20070248852A1
公开(公告)日：2007-10-25
申请号：US10580192
申请日：2004-11-24
申请人： Ulrich Mueller , Hermann Puetter , Michael Hesse , Markus Schubert , Helge Wessel , Juergen Huff , Marcus Guzmann
发明人： Ulrich Mueller , Hermann Puetter , Michael Hesse , Markus Schubert , Helge Wessel , Juergen Huff , Marcus Guzmann
IPC分类号： B03C3/00 , C01B19/00 , C01B21/04 , C01B3/00 , C01B31/18 , C01B31/20 , H01M2/08 , H01M4/02 , H01M8/04 , H05F3/00
CPC分类号： C25B3/12 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28042 , B01J31/1691 , B01J31/1805 , B01J31/1815 , B01J31/2239 , B01J31/226 , B01J2531/16 , B01J2531/26 , B01J2531/842 , C01B3/0015 , C01B21/0455 , C01B23/0057 , F17C11/005 , H01M8/04216 , Y02C10/08 , Y02E60/327 , Y02E60/328 , Y02P20/133 , Y02P70/56 , Y10S95/90 , Y10S502/526
摘要： The present invention relates to a method of absorbing and/or storing gases, in which the gas to be stored is brought into contact with an electrochemically prepared metal-organic framework under conditions suitable for absorption of the gas, with absorption of the gas into the metal-organic framework occurring, and, if appropriate, the conditions are subsequently changed so that release of the stored gas occurs.
摘要翻译： 本发明涉及一种吸收和/或储存气体的方法，其中待储存的气体在适于吸收气体的条件下与电化学制备的金属 - 有机骨架接触，吸收气体进入 发生金属 - 有机骨架，并且如果合适的话，随后改变条件以便释放储存的气体。
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公开(公告)号：US08372998B2
公开(公告)日：2013-02-12
申请号：US13336396
申请日：2011-12-23
申请人： Markus Schubert , Ulrich Mueller , Michael Hesse , Uwe Diehlmann
发明人： Markus Schubert , Ulrich Mueller , Michael Hesse , Uwe Diehlmann
CPC分类号： C07C51/418 , C07C63/307
摘要： The present invention relates to a method for producing a porous metal-organic framework material comprising the stepreacting a reaction mixture in the liquid phase of at least one copper compound having at least one at least bidentate, organic compound which can bind by coordination to the copper in the presence of a nonaqueous solvent, the at least one at least bidentate, organic compound being derived from a polycarboxylic acid having at least three carboxyl groups, and the reaction proceeding at atmospheric pressure above 80° C.
摘要翻译： 本发明涉及多孔金属 - 有机骨架材料的制造方法，该方法包括使具有至少一种至少二齿的有机化合物的至少一种铜化合物的液相中的反应混合物反应，该有机化合物可通过配位与 铜在非水溶剂的存在下，所述至少一种至少二齿的有机化合物衍生自具有至少三个羧基的多元羧酸，并且所述反应在大气压下高于80℃进行。
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