Integral method for desulphurization of a hydrocarbon cracking or stream cracking effluent
    21.
    发明授权
    Integral method for desulphurization of a hydrocarbon cracking or stream cracking effluent 失效
    烃裂化或流裂解流出物脱硫的整体方法

    公开(公告)号:US07344635B2

    公开(公告)日:2008-03-18

    申请号:US10503807

    申请日:2003-01-22

    IPC分类号: C10G45/02

    CPC分类号: C10G69/123 C10G29/205

    摘要: Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.

    摘要翻译: 用于裂化或蒸汽裂解烃的流出物的脱硫方法,更具体地,例如用于催化裂解的汽油,其包括通过这些化合物的烷基化除去噻吩化合物,然后蒸馏,所述烷基 - 噻吩化合物的加氢裂化, 然后从加氢裂化区获得的流出物的加氢脱硫。 在优选的实施方案中,该方法包括用于将裂化或蒸汽裂解流出物分离成三个馏分的初步阶段,并且建议仅向最初存在于重质碱性含氮化合物中的低碱性含氮化合物的中间馏分 待烷基化的废水。

    Alternated process for olefin metathesis
    22.
    发明授权
    Alternated process for olefin metathesis 有权
    烯烃复分解的交替过程

    公开(公告)号:US06281402B1

    公开(公告)日:2001-08-28

    申请号:US09208585

    申请日:1998-12-10

    IPC分类号: C07C604

    摘要: The present invention relates to a process for continuous metathesis or disproportionation of olefins, comprising at least 2 phases, a reaction phase a) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst and a regeneration phase b) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst, characterized in that at least one reactor passes from one phase to the other in alternation. In FIG. 1, the feed containing olefins traverses reactor R1 in riser mode. The feed to be treated containing olefins is introduced into reactor R1 via line 1a. In this reactor, the olefins contained in the feed undergo metathesis or disproportionation, then the effluent leaves the circuit via line 11. Simultaneously, reactor R2 is placed in catalyst regeneration phase, the different regeneration gases are introduced into reactor R2 via line 2b and leave this reactor via line 2c. Passage from the operating phase of a reactor to the catalyst regeneration phase thereof is carried out as follows: the reactor for which the catalyst is to be regenerated is isolated from the remainder of the apparatus, the hydrocarbons contained in the reactor are evacuated, then the reactor is purged. Said reactor is then connected to a regeneration loop and undergoes regeneration of its catalyst, and at the end of the regeneration phase, the reactor and the regeneration loop are purged.

    摘要翻译: 本发明涉及一种烯烃的连续复分解或歧化方法,包括至少两相,在包含至少一个含有至少一个催化剂固定床和再生阶段的反应器的区域中进行的反应相a) 在包含至少一个包含至少一个催化剂固定床的反应器的区域中进行,其特征在于至少一个反应器交替地从一个相转移到另一个相。 在图 如图1所示,含有烯烃的进料以提升管方式穿过反应器R1。 待处理含烯烃的进料通过管线1a引入反应器R1。 在该反应器中,进料中所含的烯烃经过复分解或歧化,然后流出物通过管线11离开回路。同时,将反应器R2置于催化剂再生阶段,不同的再生气体通过管线2b引入反应器R2,并留下 该反应器经由管线2c。 从反应器的操作阶段到催化剂再生阶段的通过如下进行:将待再生催化剂的反应器与装置的其余部分分离,将反应器中包含的烃抽真空,然后 反应器被清除。 然后将所述反应器连接到再生回路并经历其催化剂的再生,并且在再生阶段结束时,将反应器和再生回路清除。

    Process for the separation of alpha-olefins by distillation of an
effluent comprising ethylene and 1-butene
    23.
    发明授权
    Process for the separation of alpha-olefins by distillation of an effluent comprising ethylene and 1-butene 失效
    通过蒸馏出包含乙烯和1-丁烯的流出物来分离α-烯烃的方法

    公开(公告)号:US5853551A

    公开(公告)日:1998-12-29

    申请号:US720384

    申请日:1996-07-23

    IPC分类号: C07C7/05 B01D3/34 B01D3/14

    CPC分类号: C07C7/05

    摘要: The invention concerns a process for the separation of a mixture comprising ethylene, 1-butene, alpha-olefins containing at least 6 carbon atoms per molecule and possibly heavier hydrocarbon products, the ethylene content of the mixture being in the range 30% to 70% by weight, in which separation is effected in a distillation zone to obtain an overhead fraction comprising the major portion of the ethylene present in the mixture and between 0% and 100% by weight of the 1-butene present in the mixture, the process being characterized in that the zone is also supplied with supplemental 1-butene in an amount in the range 1 to 40 times the quantity (by weight) of 1-butene present in the mixture. In a preferred implementation of the process of the invention, the mixture originates form a homogenous liquid phase ethylene oligomerisation zone.

    摘要翻译: 本发明涉及一种分离包含乙烯,1-丁烯,每分子含有至少6个碳原子的α-烯烃和可能较重烃产物的混合物的混合物的方法,该混合物的乙烯含量在30%至70%的范围内, ,其中在蒸馏区中进行分离以获得包含混合物中存在的乙烯的主要部分和0重量%至100重量%的混合物中存在的1-丁烯的塔顶馏分,该方法为 其特征在于,该区域还提供了在混合物中存在的1-丁烯的量(重量)的1至40倍的量的补充的1-丁烯。 在本发明方法的优选实施方案中,混合物起始形成均相液相乙烯齐聚区。

    Process and device for manufacturing synthesis gas and application
    24.
    发明授权
    Process and device for manufacturing synthesis gas and application 失效
    制造合成气和应用的工艺和装置

    公开(公告)号:US5755841A

    公开(公告)日:1998-05-26

    申请号:US631909

    申请日:1996-04-12

    摘要: The present invention relates to a process and to a device for manufacturing synthetic gas. The reactor in accordance with the invention comprises within a single housing: a non catalytic combustion chamber (1) comprising at least one fuel injection element (2) and at least one oxidizer injection element (3) so as to achieve a partial combustion in said chamber referred to as "sufficient residence time chamber", and at least one catalytic bed (4) into which the gases coming from combustion chamber (1) run, and further comprising at least one additional oxidizer injection element (6) and at least one fuel injection element (7). The reactor and the process in accordance with the invention may be applied to any chemical manufacturing utilizing synthetic gas.

    摘要翻译: 本发明涉及一种制造合成气体的方法和装置。 根据本发明的反应器包括在单个壳体内:非催化燃烧室(1),其包括至少一个燃料喷射元件(2)和至少一个氧化剂注入元件(3),以便在所述 称为“足够的停留时间室”的室,以及至少一个催化床(4),来自燃烧室(1)的气体流入其中,并且还包括至少一个附加的氧化剂注入元件(6)和至少一个 燃料喷射元件(7)。 根据本发明的反应器和方法可以应用于利用合成气体的任何化学制造。

    Process for synthesizing and purifying olefins comprising
dehydrogenating a paraffin
    26.
    发明授权
    Process for synthesizing and purifying olefins comprising dehydrogenating a paraffin 失效
    合成和纯化烯烃的方法,包括使石蜡脱氢

    公开(公告)号:US6121505A

    公开(公告)日:2000-09-19

    申请号:US103524

    申请日:1998-06-24

    CPC分类号: C07C11/02 C07C5/333

    摘要: The present invention relates to a process for the production of olefins from a hydrocarbon cut, comprising a step for separating at least one paraffin contained in the hydrocarbon cut, a step for dehydrogenating the paraffin and a step for purifying the hydrogen produced during dehydrogenation, at least a part of that hydrogen being recycled to the dehydrogenation step. The invention is of particular application to the preparation of olefins containing 3 to 5 carbon atoms per molecule from a C.sub.3 to C.sub.5 hydrocarbon cut containing at least one paraffin.

    摘要翻译: 本发明涉及一种从烃切割生产烯烃的方法,包括分离烃馏分中所含的至少一种石蜡的步骤,用于使石蜡脱氢的步骤和用于纯化在脱氢过程中产生的氢气的步骤 将该氢的至少一部分再循环至脱氢步骤。 本发明特别适用于从含有至少一种链烷烃的C 3 -C 5烃馏分制备每分子含3至5个碳原子的烯烃。

    Paraffin isomerization process comprising fractionation having at least
two draw-off levels associated with at least two isomerization zones
    27.
    发明授权
    Paraffin isomerization process comprising fractionation having at least two draw-off levels associated with at least two isomerization zones 有权
    链烷烃异构化方法包括具有至少两个与至少两个异构化区相关联的排出水平的分馏

    公开(公告)号:US5994607A

    公开(公告)日:1999-11-30

    申请号:US129127

    申请日:1998-08-04

    CPC分类号: C10G65/16 C10G59/06

    摘要: The invention concerns a process for isomerising a feed containing essentially hydrocarbons, preferably paraffins containing principally 4 to 8, preferably princiapply to 6 and more principally 5 and/or 6 carbon atoms per molecule, comprising a fractionation zone and at least two isomersation reaction zones, said process comprising carrying out the following steps:(1) sending the feed to a fractionation zone;(2) drawing off at least a portion of the liquid circulating in said zone, via at least two draw-off levels; and(3) sending the major portion of the liquid drawn off in step (2) to at least two isomerisation zones, each isomerisation zone being associated with a draw-off level.

    摘要翻译: 本发明涉及一种异构化基本上烃的方法,所述进料基本上包含烃,优选主要含有4至8,优选原则上至6,更主要为每个分子5和/或6个碳原子的链烷烃,其包含分馏区和至少两个异构化反应区, 所述方法包括进行以下步骤:(1)将进料送至分馏区; (2)经由至少两个抽出水平抽出在所述区域中循环的液体的至少一部分; 和(3)将在步骤(2)中抽出的液体的主要部分送至至少两个异构化区,每个异构化区与排出水平相关联。

    Isomerization process comprising fractionation having at least two
draw-off levels associated with at least two isomerization zones
    28.
    发明授权
    Isomerization process comprising fractionation having at least two draw-off levels associated with at least two isomerization zones 失效
    异构化方法包括具有至少两个与至少两个异构化区相关联的排出水平的分馏

    公开(公告)号:US5831140A

    公开(公告)日:1998-11-03

    申请号:US795703

    申请日:1997-02-04

    摘要: The invention concerns a process for isomerizing a feed containing essentially hydrocarbons, preferably paraffins containing principally 4 to 8, preferably principally 4 to 6 and more preferably principally 5 and/or 6 carbon atoms per molecule, comprising a fractionation zone and at least two isomerization reaction zones, said process comprising carrying out the following steps: (1) sending the feed to a fractionation zone; (2) drawing off at least a portion of the liquid circulating in said zone, via at least two draw-off levels; (3) sending the major portion of the liquid drawn off in step (2) to at least two isomerization zones, each isomerization zone being associated with a draw-off level; (4) sending the major portion of the effluents from step (3) to the fractionation zone, substantially adjacent to the draw-off levels; (5) recovering an effluent from the fractionation zone.

    摘要翻译: 本发明涉及使基本上含有烃的原料异构化的方法,优选主要含有分子量为4至8,优选主要为4至6,更优选主要为5和/或6个碳原子的链烷烃,其包含分馏区和至少两个异构化反应 所述方法包括进行以下步骤:(1)将进料送至分馏区; (2)经由至少两个抽出水平抽出在所述区域中循环的液体的至少一部分; (3)将在步骤(2)中抽出的液体的主要部分送至至少两个异构化区,每个异构化区域与排出水平相关联; (4)将大部分流出物从步骤(3)送至分馏区,基本上与排出水平相邻; (5)从分馏区回收流出物。