Rubber containing hydrophilic sorbitan monostearate and tackifying resin and tire with sidewall thereof
    21.
    发明申请
    Rubber containing hydrophilic sorbitan monostearate and tackifying resin and tire with sidewall thereof 有权
    含有亲水性脱水山梨糖醇单硬脂酸酯和增粘树脂和具有侧壁的轮胎的橡胶

    公开(公告)号:US20090043039A1

    公开(公告)日:2009-02-12

    申请号:US11890390

    申请日:2007-08-06

    IPC分类号: C08C4/00 C08K3/04 C08K3/36

    摘要: A carbon black reinforced rubber composition which contains hydrophilic sorbitan monostearate and specialized tackifying resin and a pneumatic rubber tire having a visually observable rubber component, such as for example a rubber sidewall, of said rubber composition. The surface of said rubber composition, namely the tire sidewall rubber component, in its uncured state contains said hydrophilic sorbitan monostearate on its surface together with said specialized tackifying resin to promote enhanced building tack and thereby counteract building tack loss by the sorbitan monostearate having been exposed to moisture (moisture exposed surface) during the processing of the rubber composition, particularly after its high shear processing such as, for example, extrusion.

    摘要翻译: 一种炭黑增强橡胶组合物,其包含亲水性脱水山梨醇单硬脂酸酯和专用增粘树脂,以及具有目视观察到的橡胶组分的橡胶组分(例如橡胶侧壁)的充气橡胶轮胎。 所述橡胶组合物的表面,即轮胎侧壁橡胶组分在其未固化状态下,与所述专用增粘树脂一起在其表面上含有所述亲水性脱水山梨糖醇单硬脂酸酯,以促进增强的建筑粘性,从而抵抗已暴露于脱水山梨糖醇单硬脂酸酯 在橡胶组合物的加工过程中,特别是在其高剪切加工例如挤出之后的湿度(湿气暴露表面)。

    Tire with sidewall comprised of emulsion styrene/butadiene rubber, cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber
    22.
    发明申请
    Tire with sidewall comprised of emulsion styrene/butadiene rubber, cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber 失效
    具有由乳液苯乙烯/丁二烯橡胶,顺式1,4-聚异戊二烯橡胶和顺式1,4-聚丁二烯橡胶组成的侧壁的轮胎

    公开(公告)号:US20080216935A1

    公开(公告)日:2008-09-11

    申请号:US11715694

    申请日:2007-03-08

    IPC分类号: B60C1/00

    摘要: This invention relates to a tire with a sidewall composition comprised of cis 1,4-polyisoprene rubber, particularly natural cis 1,4-polyisoprene rubber, and high cis 1,4-polybutadiene rubber combined with a partial replacement of the cis 1,4-polyisoprene rubber, particularly natural rubber, with a specialized emulsion polymerization styrene/butadiene rubber (E-SBR) having a glass transition temperature (Tg), similar to the Tg of natural cis 1,4-polyisoprene rubber, from about −70 to about −60° C. and a limited bound styrene content in a range of from about 12 to about 16 percent.

    摘要翻译: 本发明涉及具有侧链组合物的轮胎,该组合物由顺式1,4-聚异戊二烯橡胶,特别是天然顺式1,4-聚异戊二烯橡胶组成,高顺式1,4-聚丁二烯橡胶与部分置换顺式1,4 聚异戊二烯橡胶,特别是天然橡胶,具有与天然顺式1,4-聚异戊二烯橡胶的Tg相似的玻璃化转变温度(Tg)的专门的乳液聚合苯乙烯/丁二烯橡胶(E-SBR),从约-70至 约-60℃,有限的结合苯乙烯含量在约12至约16%的范围内。

    Tire with component comprised of amine functionalized styrene/diene copolymer elastomer, silanol functionalized carbon black and coupling agent
    25.
    发明授权
    Tire with component comprised of amine functionalized styrene/diene copolymer elastomer, silanol functionalized carbon black and coupling agent 失效
    具有胺官能化苯乙烯/二烯共聚物弹性体,硅烷醇官能化炭黑和偶联剂的组分的轮胎

    公开(公告)号:US07137423B2

    公开(公告)日:2006-11-21

    申请号:US10457084

    申请日:2003-06-06

    IPC分类号: B60C11/00

    摘要: The invention relates to a tire having at least one component (e.g. tread) of a rubber composition comprised of an amine functionalized styrene/conjugated diene copolymer elastomer (e.g. styrene/butadiene and/or styrene/isoprene/butadiene copolymer elastomer) which contains reinforcement comprised of silanol functionalized particulate carbon black having silica domains covering a fraction of the carbon black surface together with an alkoxysilane polysulfide coupling agent. The silica domains on the carbon black surface contain hydroxyl groups (e.g. silanol groups) on their surfaces which are reactive with the alkoxysilane moiety of the coupling agent. The amine functionalized styrene/butadiene elastomer is an organic solution polymerization prepared elastomer which contains pendant and/or terminal amine groups as one or more of primary amine, secondary amine, tertiary amine, and/or heterocyclic amine groups. The amine functionalized elastomer may be tin coupled.

    摘要翻译: 本发明涉及一种轮胎,该轮胎具有由胺官能化苯乙烯/共轭二烯共聚物弹性体(例如苯乙烯/丁二烯和/或苯乙烯/异戊二烯/丁二烯共聚物弹性体)组成的橡胶组合物的至少一种组分(例如胎面) 的硅烷醇官能化颗粒炭黑,其具有覆盖碳黑表面的一部分的二氧化硅域和烷氧基硅烷多硫偶联剂。 碳黑表面上的二氧化硅结构域在其表面上含有与偶联剂的烷氧基硅烷部分反应的羟基(例如硅烷醇基)。 胺官能化苯乙烯/丁二烯弹性体是含有作为伯胺,仲胺,叔胺和/或杂环胺基团中的一个或多个的侧基和/或末端胺基团的有机溶液聚合制备的弹性体。 胺官能化的弹性体可以是锡偶合的。

    Tire sidewall compounds having improved flex fatigue and tread compound having improved tear strength
    26.
    发明授权
    Tire sidewall compounds having improved flex fatigue and tread compound having improved tear strength 有权
    轮胎侧壁化合物具有改善的挠曲疲劳和具有改善的撕裂强度的胎面胶料

    公开(公告)号:US06939920B2

    公开(公告)日:2005-09-06

    申请号:US09756334

    申请日:2001-01-08

    摘要: Sidewalls of a pneumatic tire have greater resistance to failure due to dynamic flexing and abrasion, and the tire's tread has better resistance to tearing than with conventionally used rubber compositions, when sidewalls and tread are formed from a compound having a major proportion by weight of synthetic rubber (SR) and a minor proportion by weight of natural rubber (NR), and a major proportion by weight of the SR itself consists essentially of a high cis-1,4-polybutadiene having defined molecular architecture. The high cis-1,4-PBD has more than 90 percent cis-structure, a poly-dispersity in the range from about 3 to 5, a number average molecular weight Mn in the range from 100,000 to 150,000 and a degree of branching in the range from 2 to 3.5. The sidewall compound has characteristics quite different from one made with a typical commercially available high cis-1,4-PBD; and the tread has excellent tear strength. The dendritic structure of the high HI cis-1,4-PBD molecules has an unexpectedly beneficial effect on the performance characteristics of the sidewall and tread, particularly important in a high-performance automobile tire.

    摘要翻译: 充气轮胎的侧壁由于动态弯曲和磨损而具有更大的抗故障能力,并且当胎面和胎面由具有主要重量比的合成物的化合物形成时,轮胎的胎面具有比常规使用的橡胶组合物更好的耐撕裂性 橡胶(SR)和较小比重的天然橡胶(NR),并且主要重量的SR本身基本上由具有确定的分子结构的高顺式-1,4-聚丁二烯组成。 高顺式-1,4- PBD具有90%以上的顺式结构,多分散度在约3至5范围内,数均分子量Mn在100,000至150,000范围内,分支度 范围从2到3.5。 侧壁化合物具有与用典型的市售高顺式-1,4- PBD制成的特征完全不同的特征; 并且胎面具有优异的撕裂强度。 高HI顺式-1,4- PBD分子的树枝状结构对侧壁和胎面的性能特征具有意想不到的有益效果,在高性能汽车轮胎中尤其重要。

    Tread rubber for high traction tires
    27.
    发明授权
    Tread rubber for high traction tires 有权
    轮胎橡胶用于高牵引轮胎

    公开(公告)号:US06670416B1

    公开(公告)日:2003-12-30

    申请号:US09616271

    申请日:2000-07-14

    IPC分类号: C08J510

    摘要: In tire tread formulations, blends of rubbers having low and high glass transition temperatures have significant advantages over blends made with rubbers having intermediate glass transition temperatures. However, blends of rubbers having low and high glass transition temperatures exhibit poor processability. This invention deals with improving the processability of tire tread formulations which are made by blending rubbers having both low and high glass transition temperatures that offer ultra low rolling resistance without sacrificing rolling resistance or tread wear characteristics. This invention more specifically discloses a tire tread rubber composition which is comprised of (a) about 60 phr to about 90 phr of a high cis-1,4-polybutadiene rubber, wherein the high cis-1,4-polybutadiene rubber has a glass transition temperature which is within the range of about −104° C. to about −80° C., (b) about 10 phr to about 40 phr of at least one additional rubbery polymer selected from the group consisting of polyisoprene rubber, polybutadiene rubber and styrene-isoprene-butadiene rubber, wherein the additional rubbery polymer has a glass transition temperature which is within the range of about −30° C. to about −10° C. isoprene-butadiene rubber, (c) about 20 phr to about 60 phr of carbon black, wherein the carbon black has a DBP absorption value of at least 140 cm3/100 grams and wherein the carbon black has a CTAB adsorption area which is within the range of about 60 to about 90.

    摘要翻译: 在轮胎胎面配方中,具有低和高玻璃化转变温度的橡胶的共混物比具有中间玻璃化转变温度的橡胶制成的混合物具有显着的优点。 然而,具有低玻璃化转变温度和高玻璃化转变温度的橡胶的混合物表现出差的加工性能。 本发明涉及改善轮胎胎面配方的加工性能,其通过混合具有低和高玻璃化转变温度的橡胶制成,其提供超低滚动阻力而不牺牲滚动阻力或胎面磨损特性。 本发明更具体地公开了一种轮胎胎面橡胶组合物,其由(a)约60phr至约90phr的高顺式-1,4-聚丁二烯橡胶组成,其中高顺式-1,4-聚丁二烯橡胶具有玻璃 转变温度在约-104℃至约-80℃的范围内,(b)约10phr至约40phr的至少一种另外的橡胶状聚合物,其选自聚异戊二烯橡胶,聚丁二烯橡胶 和苯乙烯 - 异戊二烯 - 丁二烯橡胶,其中所述另外的橡胶状聚合物的玻璃化转变温度在约-30℃至约-10℃的范围内。异戊二烯 - 丁二烯橡胶,(c)约20phr至约 60phr的炭黑,其中炭黑具有至少140cm 3/100克的DBP吸收值,并且其中炭黑的CTAB吸附面积在约60至约90的范围内。