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1.发明授权Tire sidewall compounds having improved flex fatigue and tread compound having improved tear strength 有权轮胎侧壁化合物具有改善的挠曲疲劳和具有改善的撕裂强度的胎面胶料公开(公告)号：US06939920B2
公开(公告)日：2005-09-06
申请号：US09756334
申请日：2001-01-08
CPC分类号： B60C1/0025 , B60C1/0016 , C08L7/00 , C08L9/00 , Y10S152/905 , C08L2666/08
摘要： Sidewalls of a pneumatic tire have greater resistance to failure due to dynamic flexing and abrasion, and the tire's tread has better resistance to tearing than with conventionally used rubber compositions, when sidewalls and tread are formed from a compound having a major proportion by weight of synthetic rubber (SR) and a minor proportion by weight of natural rubber (NR), and a major proportion by weight of the SR itself consists essentially of a high cis-1,4-polybutadiene having defined molecular architecture. The high cis-1,4-PBD has more than 90 percent cis-structure, a poly-dispersity in the range from about 3 to 5, a number average molecular weight Mn in the range from 100,000 to 150,000 and a degree of branching in the range from 2 to 3.5. The sidewall compound has characteristics quite different from one made with a typical commercially available high cis-1,4-PBD; and the tread has excellent tear strength. The dendritic structure of the high HI cis-1,4-PBD molecules has an unexpectedly beneficial effect on the performance characteristics of the sidewall and tread, particularly important in a high-performance automobile tire.
摘要翻译： 充气轮胎的侧壁由于动态弯曲和磨损而具有更大的抗故障能力，并且当胎面和胎面由具有主要重量比的合成物的化合物形成时，轮胎的胎面具有比常规使用的橡胶组合物更好的耐撕裂性 橡胶（SR）和较小比重的天然橡胶（NR），并且主要重量的SR本身基本上由具有确定的分子结构的高顺式-1,4-聚丁二烯组成。 高顺式-1,4- PBD具有90％以上的顺式结构，多分散度在约3至5范围内，数均分子量Mn在100,000至150,000范围内，分支度 范围从2到3.5。 侧壁化合物具有与用典型的市售高顺式-1,4- PBD制成的特征完全不同的特征; 并且胎面具有优异的撕裂强度。 高HI顺式-1,4- PBD分子的树枝状结构对侧壁和胎面的性能特征具有意想不到的有益效果，在高性能汽车轮胎中尤其重要。
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2.发明授权SILICA REINFORCED RUBBER COMPOSITION WHICH CONTAINS THIOGLYCEROL COUPLING AGENT AND BENZOTHIAZYL DISULFIDE AND ARTICLE OF MANUFACTURE, INCLUDING A TIRE, HAVING AT LEAST ONE COMPONENT COMPRISED OF SUCH RUBBER COMPOSITION 失效含有THIOGLYCEROL耦合剂和BENZOTHIAZYL DISOLFIDE的二氧化硅增强橡胶组合物和包含这种橡胶组合物的至少一个组分的制造方法（包括轮胎）公开(公告)号：US06555609B1
公开(公告)日：2003-04-29
申请号：US09662280
申请日：2000-09-14
IPC分类号： C08K330
CPC分类号： C08K5/37 , B60C1/0016 , C08K5/378 , C08L21/00
摘要： This invention relates to a conjugated diene-based rubber composition reinforced with silica-based reinforcement together with a non-silane coupling agent as a combination of 1-thioglycerol(3-mercapto-1,2-propanediol) and 2,2′-benzothiazyl disulfide. Said coupling agent materials may be provided for mixing with said diene-based rubber(s), for example, as individual materials, as at least one of said materials being supported on a carbon black carrier or as being pre-reacted, or otherwise pre-treated, with synthetic silica aggregates. The invention includes an article of manufacture, including a tire, having at least one component comprised of such rubber composition.
摘要翻译： 本发明涉及一种用二氧化硅系增强剂与非硫硅烷偶联剂一起加成的共轭二烯系橡胶组合物，作为1-硫代甘油（3-巯基-1,2-丙二醇）与2,2'-苯并噻唑基 二硫化物 所述偶联剂材料可以提供用于与所述二烯基橡胶（例如，作为单独的材料）混合，因为至少一种所述材料负载在炭黑载体上或作为预反应，或以其他方式预先 用合成二氧化硅聚集体。 本发明包括具有至少一种由这种橡胶组合物组成的组分的包括轮胎的制品。
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3.发明授权Silica reinforced rubber composition which contains non-silane coupling agent and article of manufacture, including a tire, having at least one component comprised of such rubber composition 失效包含非硅烷偶联剂和制品的二氧化硅增强橡胶组合物，包括具有至少一种由这种橡胶组合物组成的组分的轮胎公开(公告)号：US06458882B1
公开(公告)日：2002-10-01
申请号：US09661706
申请日：2000-09-14
IPC分类号： C08K334
CPC分类号： C08K5/36 , B60C1/0016 , C08K5/372 , C08L21/00
摘要： This invention relates to a conjugated diene-based rubber composition reinforced with particulate silica-based reinforcement together with tetrathiodipropionic acid as a non-silane containing coupling agent to aid in the reinforcement of the rubber composition with a particulate silica-based material and an article of manufacture, including a tire, having at least one component comprised of such rubber composition.
摘要翻译： 本发明涉及用颗粒二氧化硅基增强剂和四硫代二丙酸作为非硅烷偶联剂增强的共轭二烯基橡胶组合物，以有助于使用颗粒状二氧化硅基材料和橡胶组合物的增强物 制造，包括具有至少一种由这种橡胶组合物组成的组分的轮胎。
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4.发明授权SILICA REINFORCED RUBBER COMPOSITION WHICH CONTAINS CARBON BLACK SUPPORTED THIOGLYCEROL COUPLING AGENT AND ARTICLE OF MANUFACTURE, INCLUDING A TIRE, HAVING AT LEAST ONE COMPONENT COMPRISED OF SUCH RUBBER COMPOSITION 失效含有炭黑的硫化橡胶组合物，其中含有黑色支持的硫醇类偶联剂和制品，包括轮胎，至少包含这种橡胶组合物的组分公开(公告)号：US06534584B2
公开(公告)日：2003-03-18
申请号：US09756538
申请日：2001-01-08
IPC分类号： C08K334
CPC分类号： C08K5/37 , B60C1/0016 , C08K9/04 , C08L21/00
摘要： This invention relates to a conjugated diene-based rubber composition reinforced with silica-based reinforcement together with a composite of carbon black supported non-silane coupling agent as 1-thioglycerol(3-mercapto-1,2-propanediol) and exclusive of 2,2′-benzothiazyl disulfide. The invention includes an article of manufacture, including a tire, having at least one component comprised of such rubber composition.
摘要翻译： 本发明涉及一种用二氧化硅系增强剂与由碳黑负载的非硅烷偶联剂作为1-硫代甘油（3-巯基-1,2-丙二醇）的复合物而增强的共轭二烯系橡胶组合物， 2'-苯并噻唑基二硫化物。 本发明包括具有至少一种由这种橡胶组合物组成的组分的包括轮胎的制品。
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5.发明授权Silica reinforced rubber composition which contains non-silane coupling agent and article of manufacture, including a tire, having at least one component comprised of such rubber composition 有权包含非硅烷偶联剂和制品的二氧化硅增强橡胶组合物，包括具有至少一种由这种橡胶组合物组成的组分的轮胎公开(公告)号：US06528592B1
公开(公告)日：2003-03-04
申请号：US09661707
申请日：2000-09-14
IPC分类号： C08F23602
摘要： This invention relates to a conjugated diene-based rubber composition reinforced with particulate silica-based reinforcement together with 2-hydroxyethyl methacrylate (a non-silane coupling agent) or a combination of 2-hydroxyethyl methacrylate and bis(3-trialkoxysilylalkyl) polysulfide having an average of from 2 to 2.6, or from 3.5 to 4, sulfur atoms in its polysulfidic bridge to aid in the reinforcement of the rubber composition with a particulate silica-based material and an article of manufacture, including a tire, having at least one component comprised of such rubber composition.
摘要翻译： 本发明涉及一种用颗粒状二氧化硅基增强剂与甲基丙烯酸2-羟乙酯（非硅烷偶联剂）或甲基丙烯酸2-羟乙酯与双（3-三烷氧基甲硅烷基烷基）多硫化物的组合加成的共轭二烯系橡胶组合物，其具有 在其多硫桥中平均为2至2.6，或3.5至4个硫原子，以帮助用颗粒二氧化硅基材料和包括轮胎在内的具有至少一种组分 由这种橡胶组合物组成。
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公开(公告)号：US06092554A
公开(公告)日：2000-07-25
申请号：US4237
申请日：1998-01-09
IPC分类号： C08J3/20 , B29C47/00 , B29C47/20 , B29D23/00 , C08J3/24 , C08K3/04 , C08K3/06 , C08K3/22 , C08K5/01 , C08K5/09 , C08L23/04 , C08L23/06 , C08L23/10 , C08L23/12 , C08L23/16 , F16L11/04 , F16L11/127
CPC分类号： F16L11/127 , B29C47/0004 , B29C47/0023 , B29C47/0026 , B29C47/20 , C08L23/16 , F16L11/04 , C08L23/04 , C08L23/06 , C08L23/10 , C08L23/12
摘要： Hoses are often reinforced with fabric to improve their performance characteristics, such as burst strength. For instance, radiator hose used in automotive applications is generally reinforced with continuous yarn. However, it is a labor-intensive process to manufacture such hoses which include fiber reinforcements. A substantial amount of material waste also generally occurs in the manufacture of such fiber-reinforced hose. By utilizing the technique of this invention, hose which has a high level of burst strength can be manufactured without including continuous yarn reinforcement. This invention specifically reveals a process for manufacturing a hose which comprises (1) extruding a rubber composition into the form of a tube, wherein the rubber composition is comprised of (a) a polypropylene/polyethylene alloy comprised of (i) a low melt index polyethylene and (ii) polypropylene, wherein the polypropylene is homogeneously dispersed throughout the polyethylene in the polypropylene/polyethylene alloy, (b) an EPDM rubber, (c) carbon black, (d) at least one curative, (e) zinc oxide, (f) a processing oil and (g) stearic acid; (2) shaping the tube into the geometric form desired for the hose; and (3) curing the rubber composition at a temperature within the range of 130.degree. C. to 210.degree. C. to produce the hose.
摘要翻译： 软管通常用织物加强以改善其性能特征，例如破裂强度。 例如，用于汽车应用的散热器软管通常用连续纱线加强。 然而，制造这种包括纤维增强材料的软管是劳力密集的过程。 在这种纤维增强软管的制造中，通常也会发生大量的材料浪费。 通过利用本发明的技术，可以在不包括连续纱线增强的情况下制造具有高水平的破裂强度的软管。 本发明具体揭示了一种制造软管的方法，该方法包括（1）将橡胶组合物挤压成管的形式，其中橡胶组合物由（a）聚丙烯/聚乙烯合金组成，该聚丙烯/聚乙烯合金包括：（i）低熔点指数 聚乙烯和（ii）聚丙烯，其中聚丙烯均匀地分散在聚丙烯/聚乙烯合金中的整个聚乙烯中，（b）EPDM橡胶，（c）炭黑，（d）至少一种固化剂，（e）氧化锌， （f）加工油和（g）硬脂酸; （2）将管成形为软管所需的几何形状; 和（3）在130℃至210℃的温度下固化橡胶组合物以产生软管。
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公开(公告)号：US6046266A
公开(公告)日：2000-04-04
申请号：US159663
申请日：1998-09-24
CPC分类号： C08L7/00 , B60C1/0016 , B60C1/0025 , C08J3/20 , C08J3/203 , C08K3/04 , C08K3/36 , C08L9/00 , C08J2307/00 , C08J2309/00
摘要： The present invention relates to the preparation of rubber compositions for tire tread and tire sidewall component applications. A tire is provided having tread of such composition designed for relatively heavy loads such as, for example, truck tires. A tire having a sidewall of such composition is also provided. Such tire component rubber compositions are of rubber compositions reinforced with precipitated silica and selected carbon black in specified amounts and prepared with a prescribed order of addition to the rubber composition and composed of elastomers as a specific combination of natural or synthetic cis 1,4-polyisoprene rubber together with cis 1,4-polybutadiene rubber or with a combination of cis 1,4-polybutadiene rubber and trans 1,4-polybutadiene rubber.
摘要翻译： 本发明涉及用于轮胎胎面和轮胎侧壁部件应用的橡胶组合物的制备。 提供了一种轮胎，其具有为相对较重的载荷设计的这种组合物的胎面，例如卡车轮胎。 还提供了具有这种组成的侧壁的轮胎。 这种轮胎组分橡胶组合物是用沉淀二氧化硅增强的橡胶组合物和选定的规定量的炭黑，并以规定的添加量加入到橡胶组合物中并由弹性体组成，其由天然或合成的顺式1,4-聚异戊二烯的特定组合 橡胶与顺式1,4-聚丁二烯橡胶或顺式1,4-聚丁二烯橡胶和反式1,4-聚丁二烯橡胶的组合。
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公开(公告)号：US05997673A
公开(公告)日：1999-12-07
申请号：US923545
申请日：1997-09-04
申请人： Paul Harry Sandstrom , Samson Samuel Apticar , William Paul Francik , David Allan Kindry , Jerry Lawrence Brenner , Kevin James Pyle
发明人： Paul Harry Sandstrom , Samson Samuel Apticar , William Paul Francik , David Allan Kindry , Jerry Lawrence Brenner , Kevin James Pyle
CPC分类号： B60C1/0016 , B60C1/00 , B60C1/0041 , B60C11/005 , C08L21/00 , B60C2001/0066 , Y10T152/1081 , Y10T152/10846
摘要： In a tire having a tread with cap/base construction, a regulated amount of partially crosslinked natural rubber in a tire tread compound increases the uncured ("green") stiffness, tensile strength and tear resistance of a green compound used for the base without adversely affecting physical properties of the tread after it is cured. Such green stiffness is particularly useful in the construction of a tread for a pneumatic tire, which tread is of cap/base construction because stiffness provides requisite dimensional stability of both cap and base (in the tread) during the curing of the tire. The amount of partially crosslinked natural rubber used in a tread compound depends upon the extent of crosslinking in the natural rubber, the non-crosslinked remainder being virgin latex.
摘要翻译： 在具有盖/基础结构的胎面的轮胎中，轮胎胎面胶中的调节量的部分交联的天然橡胶增加了用于底料的绿色化合物的未固化（“绿”）刚度，抗拉强度和抗撕裂性， 影响胎面的物理性能。 这种绿色刚度在用于充气轮胎的胎面的构造中是特别有用的，该胎面具有帽/底座结构，因为刚度在轮胎固化期间提供了帽和底座（在胎面中）的必要的尺寸稳定性。 用于胎面胶料中的部分交联天然橡胶的量取决于天然橡胶中的交联程度，非交联的剩余物是未处理的胶乳。
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9.发明授权Silica-filled rubber composition containing two different carbon blacks and tire with tread made therefrom 失效含有两种不同炭黑的硅橡胶组合物和由其制成的胎面的轮胎
公开(公告)号：US5780537A
公开(公告)日：1998-07-14
申请号：US915838
申请日：1997-08-21
IPC分类号： B29D30/00 , B29K21/00 , B29K105/04 , B29K507/04 , B29K509/00 , B60C1/00 , C08J3/20 , C08K3/04 , C08K3/36 , C08K5/54 , C08L21/00 , C08K3/00 , C08L7/00
CPC分类号： C08K3/04 , B60C1/0016 , C08K5/548 , C08L9/00 , C08K3/36 , C08L7/00 , C08L9/06 , Y10S152/905
摘要： The present invention relates to a silica-filled rubber composition reinforced with a combination of silica and a mixture of two defined carbon blacks and to pneumatic tires having treads comprised of such rubber composition.
摘要翻译： 本发明涉及用二氧化硅和两种规定的炭黑的混合物组合增强的二氧化硅填充的橡胶组合物，以及具有由这种橡胶组合物构成的胎面的充气轮胎。
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公开(公告)号：US5773504A
公开(公告)日：1998-06-30
申请号：US827767
申请日：1997-04-11
CPC分类号： C08J3/226 , B29B7/007 , B29B7/7495 , B29B7/90 , C08J3/20 , C08J3/203 , C08K3/04 , C08K3/36 , B29C47/00 , B29C47/0019 , B29K2021/00 , B29K2105/16 , B29K2707/04 , C08J2321/00 , C08J2421/00
摘要： The present invention relates to a heterogeneous silica/carbon black-filled rubber compound and a process for making the same. The process comprises (a) intimately dispersing substantially all of the silica filler in a first rubber to form a silica-filled compound; (b) separately intimately dispersing the majority of carbon black in a second rubber, which is different from said first rubber, to form a carbon black-filled compound; and (c) mixing said silica-filled compound with said carbon black-filled compound to form a heterogeneous silica/carbon black-filled rubber compound.
摘要翻译： 本发明涉及非均相二氧化硅/炭黑填充橡胶化合物及其制造方法。 该方法包括（a）将基本上所有的二氧化硅填料充分分散在第一橡胶中以形成二氧化硅填充的化合物; （b）将大部分炭黑分开密封地分散在与所述第一橡胶不同的第二橡胶中以形成填充炭黑的化合物; 和（c）将所述二氧化硅填充的化合物与所述填充炭黑的化合物混合以形成不均匀的二氧化硅/炭黑填充的橡胶化合物。
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