公开(公告)号：US08404036B2

公开(公告)日：2013-03-26

申请号：US13055696

申请日：2009-07-24

申请人： Koji Hirota ,  Takafumi Fujii ,  Tatsuto Yui

发明人： Koji Hirota ,  Takafumi Fujii ,  Tatsuto Yui

IPC分类号： C09D11/02 ,  C09B47/00

CPC分类号： C09B47/26 ,  B41M5/0023 ,  C09B47/24 ,  C09D11/328 ,  Y10T428/24802

摘要： Coloring matters represented by general formula (1) or salts thereof are simply provided at a low cost as water-soluble coloring matters which exhibit absorption in the near-infrared region. Further, aqueous ink compositions which contain the coloring matters and have excellent storage stability are also provided. In general formula (1), Nc is optionally substituted naphthalocyanine; M is a metal oxide or the like; R1 and R2 are each independently hydrogen or the like; A is a crosslinking group; X and Y are each independently substituted arylamino or the like; k is more than 0 but up to 12 (on average); p is 0 to less than 12; the sum of k and p is more than 0 but up to 12; and any two or the three of R1, R2 and A may be united to form a ring.

摘要翻译： 作为在近红外区域具有吸收性的水溶性着色剂，简单地以低成本提供由通式（1）表示的着色剂或其盐。 此外，还提供含有着色剂并且具有优异的储存稳定性的水性油墨组合物。 通式（1）中，Nc为任选取代的萘酞菁; M是金属氧化物等; R1和R2各自独立地为氢等; A是交联基团; X和Y各自独立地为取代的芳基氨基等; k大于0，但最多可达12（平均）; p为0〜小于12; k和p的和大于0，但最多为12; 并且R 1，R 2和A中的任何两个或三个可以结合形成环。

公开(公告)号：US08167991B2

公开(公告)日：2012-05-01

申请号：US12087426

申请日：2006-12-28

申请人： Takahiko Matsui ,  Yoshiyuki Dejima ,  Takashi Yoshimoto ,  Ryoutarou Morita ,  Koji Hirota

发明人： Takahiko Matsui ,  Yoshiyuki Dejima ,  Takashi Yoshimoto ,  Ryoutarou Morita ,  Koji Hirota

IPC分类号： C09D11/02 ,  C09B31/16

CPC分类号： C07D471/04 ,  C09B31/28 ,  C09D11/17 ,  C09D11/328

摘要： The present invention relates to a trisazo compound represented by the following formula (1) or a salt thereof, The formula (1) wherein, the group A is a substituted phenyl group, the group B and the group C are substituted para-phenylene groups, R1 represents a C1 to C4 alkyl group which may be substituted by a carboxy group, a phenyl group which may be substituted by a sulfo group, or a carboxy group, R2 represents a cyano group, a carbamoyl group or a carboxy group, each of R3 and R4 independently represents a hydrogen atom, a methyl group, a chlorine atom or a sulfo group, respectively and a water-based black ink composition containing said compound; said compound has high solubility in a medium where the main component is water, its aqueous solution having a high concentration and ink are stable when stored for a long period of time, black-recorded images with it can be provided where both light fastness and ozone gas fastness of the printed images are excellent.

摘要翻译： 本发明涉及由下式（1）表示的三偶氮化合物或其盐。式（1）其中A组为取代苯基，B组和C组为取代的对亚苯基 R1表示可被羧基取代的C1〜C4烷基，可被磺基取代的苯基或羧基，R2表示氰基，氨基甲酰基或羧基，各自独立地表示 R 3和R 4分别独立地表示氢原子，甲基，氯原子或磺基，以及含有所述化合物的水性黑色油墨组合物。 所述化合物在主要成分为水的介质中具有高溶解度，其浓度高的水溶液和长时间储存​​时的油墨稳定，可以提供具有耐光性和臭氧性的黑色记录图像 印刷图像的耐气牢度优异。

公开(公告)号：US20110132094A1

公开(公告)日：2011-06-09

申请号：US13055376

申请日：2009-07-17

申请人： Kozo Nakamura ,  Isao Onishi ,  Satoru Ohashi ,  Eiichi Minagawa ,  Koji Hirota ,  Ryoichi Sakai ,  Koji Ogawa ,  Koichi Miyasaka ,  Masaru Murashita

发明人： Kozo Nakamura ,  Isao Onishi ,  Satoru Ohashi ,  Eiichi Minagawa ,  Koji Hirota ,  Ryoichi Sakai ,  Koji Ogawa ,  Koichi Miyasaka ,  Masaru Murashita

IPC分类号： G01D21/00

CPC分类号： A61B8/0858 ,  A61B5/4514 ,  A61B5/4528 ,  A61B8/4209 ,  A61B8/4281 ,  A61B8/4405 ,  A61B90/50 ,  A61B2090/378

摘要： A mounting unit (16) is aligned by using a mounting unit frame (58) touching the thigh and a knee-contacting portion (62) touching the knee, with the knee being bent. The mounting unit is also equipped with a probe support frame (60) used for moving an ultrasonic probe along the knee cap. The probe support frame moves rotationally about the mechanical center of the knee joint, thereby allowing the ultrasonic probe (78) to move along the knee cap while facing toward the mechanical center of the knee joint and to perform scanning of an ultrasonic beam.

摘要翻译： 安装单元（16）通过使用接触大腿的安装单元框架（58）和接触膝盖的膝盖接触部分（62）而弯曲而对准。 安装单元还配备有用于沿着膝盖帽移动超声波探头的探针支撑框架（60）。 探针支撑框架围绕膝关节的机械中心旋转移动，从而允许超声波探头（78）沿着膝盖帽移动，同时面向膝关节的机械中心并执行超声波束的扫描。

公开(公告)号：US20100309246A1

公开(公告)日：2010-12-09

申请号：US12734655

申请日：2008-11-25

申请人： Koji Hirota ,  Takahiko Matsui ,  Takashi Yoshimoto ,  Shinsuke Shimizu

发明人： Koji Hirota ,  Takahiko Matsui ,  Takashi Yoshimoto ,  Shinsuke Shimizu

IPC分类号： B41J2/015 ,  C09B31/16

CPC分类号： C07D471/04 ,  B41M5/0023 ,  C09B31/28 ,  C09D11/328

摘要： The present invention relates to a trisazo compound represented by the following formula (1): (wherein, n represents 0 or 1, the group A represents a substituted heterocyclic group, R1 represents a C1-C4 alkyl group which may be substituted or the like, R2 represents a cyano group or the like, R3 and R4 each independently represent a hydrogen atom, a sulfo group or the like, R5 to R7 each independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, a C1-C4 alkoxy group which may be substituted or the like, respectively) or a salt thereof. Said trisazo compound or a salt thereof provides a coloring matter compound for black ink and an ink composition thereof where they have high solubility in medium where water is a principal component, their aqueous solution and ink having high concentration is stable even when stored for a long period of time, printed images therewith have very high density, no bronzing is caused on the images printed even with their high concentration solution, and they give black recorded images excellent in fastnesses, particularly in both light fastness and ozone gas fastness.

摘要翻译： 本发明涉及由下式（1）表示的三偶氮化合物：其中，n表示0或1，A组代表取代的杂环基，R 1表示可被取代的C 1 -C 4烷基等 ，R 2表示氰基等，R 3和R 4各自独立地表示氢原子，磺基等，R 5〜R 7各自独立地表示氢原子，可以被取代的C 1〜C 4烷基，C 1 可以被取代的C 1-4烷氧基或类似物）或其盐。 所述三偶氮化合物或其盐提供了黑色墨水的着色剂化合物及其油墨组合物，其中以水为主要成分的介质中它们具有高溶解度，即使长时间储存​​，其浓度高的水溶液和油墨也是稳定的 时间段，印刷图像具有非常高的密度，即使在高浓度溶液下印刷图像也不会导致烫伤，并且它们具有耐光性优异的黑色记录图像，特别是耐光牢度和耐臭氧气体牢度。

公开(公告)号：US5803285A

公开(公告)日：1998-09-08

申请号：US798470

申请日：1997-02-10

申请人： Koji Hirota

发明人： Koji Hirota

IPC分类号： B67B7/02 ,  B65D39/04 ,  B65D39/12 ,  B65D39/16 ,  B65D39/00

CPC分类号： B65D39/16

摘要： A cork cap having a head and a leg and adapted to be inserted in a bottle mouth. A cork is press-fitted in the cap so that its bottom end protrudes from the bottom of the leg and is pressed against the inner surface of the bottle mouth to seal the bottle mouth. The cork can be pulled out by pulling the cork cap while twisting it. Protrusions are formed on the inner periphery of the tapered inner surface of the head between adjacent ones of a plurality of vertical ribs. The protrusions bite into the cork, thus keeping the cork strongly coupled to the cork cap even when the latter is pulled and twisted. Thus, the cork can be reliably pulled out together with the cork cap by twisting and pulling only the cork cap.

摘要翻译： 具有头部和腿部并适于插入瓶口中的软木塞。 将软木塞压在盖中，使其底端从腿部的底部伸出并压靠瓶口的内表面以密封瓶口。 软木塞可以通过拉扯软木塞而扭转。 突起形成在头部的锥形内表面的内周上，在相邻的多个垂直肋之间。 突起咬入软木塞，因此即使在后者被拉扯和扭曲的同时，软木塞也牢固地连接到软木塞。 因此，软木塞可以通过扭曲和拉动软木塞与软木塞一起被可靠地拉出。

公开(公告)号：US5118947A

公开(公告)日：1992-06-02

申请号：US556451

申请日：1990-07-24

申请人： Shigeki Hamashima ,  Masaru Koseto ,  Koji Hirota

发明人： Shigeki Hamashima ,  Masaru Koseto ,  Koji Hirota

IPC分类号： G01J1/44 ,  G01J5/06 ,  G01J5/10 ,  G01J5/28 ,  H01L31/0216 ,  H01L31/024 ,  H01L31/09

CPC分类号： H01L31/09 ,  G01J5/28 ,  H01L31/02164 ,  H01L31/024 ,  G01J2005/066 ,  G01J2005/068

摘要： A cooling type infrared rays detecting apparatus is disclosed which prevents a fluctuation of an infrared rays image arising from a variation of the cooling temperature. The infrared rays detecting apparatus includes a dummy element mounted adjacent an infrared rays detecting device on a device mounting portion of an inner tube. The dummy element has a similar structure to that of each of infrared rays detecting elements of the infrared rays detecting device and is formed from the same material as the latter. A temperature variation of the dummy element is detected from a variation in resistance of the dummy element, and an output of the infrared rays detecting device is compensated for in response to the thus detected temperature variation to prevent a possible fluctuation of an infrared rays image arising from a temperature variation. Consequently, an infrared rays image of a high quality can be obtained.

摘要翻译： 公开了一种冷却型红外线检测装置，其防止由于冷却温度的变化引起的红外线图像的波动。 红外线检测装置包括在内管的装置安装部分上安装在红外线检测装置附近的虚拟元件。 伪元件具有与红外线检测装置的红外线检测元件的结构相同的结构，并且由与之相同的材料形成。 根据虚拟元件的电阻的变化来检测虚拟元件的温度变化，并且响应于这样检测的温度变化来补偿红外线检测装置的输出，以防止产生的红外线图像的可能的波动 从温度变化。 因此，可以获得高品质的红外线图像。

公开(公告)号：US5049751A

公开(公告)日：1991-09-17

申请号：US622584

申请日：1990-12-05

申请人： Yukihiro Yoshida ,  Hirokazu Fukuda ,  Hiroyuki Tsuchida ,  Shigeki Hamashima ,  Koji Hirota

发明人： Yukihiro Yoshida ,  Hirokazu Fukuda ,  Hiroyuki Tsuchida ,  Shigeki Hamashima ,  Koji Hirota

IPC分类号： G01J1/02 ,  G01J5/02 ,  G01J5/06 ,  G01J5/28 ,  G01J5/30

CPC分类号： G01J5/061 ,  G01J2005/286 ,  H01L2224/45144 ,  H01L2224/48091

摘要： An infrared rays detecting apparatus is disclosed wherein the area of a loop provided by an element line and a grounding line formed on an inner tube is minimized to reduce an induced electromotive force to minimize production of noises so that correct detection can be accomplished. A grounding line is interposed for each arbitrary number of element lines on a surface of the inner tube, and the element lines are individually connected to output electrodes of an infrared rays sensor of the multi-element type while the individual grounding lines are connected to a common grounding electrode of the infrared rays sensor.

摘要翻译： 公开了一种红外线检测装置，其中由元件线提供的环路和形成在内管上的接地线的面积被最小化以减小感应电动势，以最小化噪声的产生，从而可以实现正确的检测。 在内管表面上的每个任意数量的元件线插入接地线，并且元件线分别连接到多元件类型的红外线传感器的输出电极，而各个接地线连接到 红外线传感器的公共接地电极。

公开(公告)号：US20120202019A1

公开(公告)日：2012-08-09

申请号：US13498431

申请日：2010-09-21

申请人： Takahiko Matsui ,  Takashi Yoshimoto ,  Hiroaki Ohno ,  Koji Hirota ,  Takashi Yoneda ,  Akira Kawaguchi

发明人： Takahiko Matsui ,  Takashi Yoshimoto ,  Hiroaki Ohno ,  Koji Hirota ,  Takashi Yoneda ,  Akira Kawaguchi

IPC分类号： C09B26/06 ,  B32B3/10 ,  B41J2/04

CPC分类号： C09B43/16 ,  C09D11/328 ,  Y10T428/24802

摘要： Azo compounds represented by general formula (1) or salts thereof are provided as highly water-soluble colorants which have hues of yellow, orange, brown or red, and excellent color development properties and which, when used in various recording processes, particularly in an inkjet recording process, ensure various excellent fastnesses such as light fastness, ozone fastness, and fading balance. Ink compositions containing the colorants are also provided. In general formula (1), R1 to R8 are each independently a hydrogen atom, C1-4 alkyl, C1-4 alkoxy, or the like; and X is C1-8 alkylenediamino, xylylenediamino, or the like.

摘要翻译： 提供由通式（1）表示的偶氮化合物或其盐作为具有黄色，橙色，棕色或红色色调的高度水溶性着色剂，并具有优异的显色性，并且当用于各种记录方法时，特别是在 喷墨记录工艺，确保耐光性，耐臭氧性和褪色平衡等各种优异的牢度。 还提供含有着色剂的油墨组合物。 在通式（1）中，R 1至R 8各自独立地为氢原子，C 1-4烷基，C 1-4烷氧基等; X是C 1-8亚烷基二氨基，亚二甲苯基二氨基等。

公开(公告)号：US20120056931A1

公开(公告)日：2012-03-08

申请号：US13320651

申请日：2010-04-09

申请人： Daisuke Ono ,  Yutaka Ishii ,  Koji Hirota ,  Noriko Kajiura

发明人： Daisuke Ono ,  Yutaka Ishii ,  Koji Hirota ,  Noriko Kajiura

IPC分类号： B41J2/015 ,  C09D11/02

CPC分类号： C09B5/14 ,  C09D11/328

摘要： As an ink composition which is highly soluble in water and has a hue and clarity suitable for inkjet recording, an ink composition containing at least one pigment represented by formula (1) or a salt thereof as a pigment is provided. In formula (1), Xa to Xc each independently represent a substituted or unsubstituted sulfoanilino group, a substituted or unsubstituted sulfonaphthylamino group, a hydroxy group, or the like, and at least one of Xa to Xc is a group other than a hydroxy group; R represents a hydrogen atom or the like; R1 represents an alkyl group or the like; and R3 and R4 each independently represent a hydrogen atom or the like.

摘要翻译： 作为高度可溶于水并且具有适于喷墨记录的色调和透明度的油墨组合物，提供了含有至少一种由式（1）表示的颜料或其盐作为颜料的油墨组合物。 在式（1）中，Xa至Xc各自独立地表示取代或未取代的磺基苯胺基，取代或未取代的磺基氨基，羟基等，Xa至Xc中的至少一个为羟基以外的基团 ; R表示氢原子等; R1表示烷基等; 并且R 3和R 4各自独立地表示氢原子等。

公开(公告)号：US20110126629A1

公开(公告)日：2011-06-02

申请号：US13055415

申请日：2009-07-17

申请人： Kozo Nakamura ,  Isao Onishi ,  Satoru Ohashi ,  Eiichi Minagawa ,  Koji Hirota ,  Ryoichi Sakai ,  Koji Ogawa ,  Koichi Miyasaka ,  Masaru Murashita

发明人： Kozo Nakamura ,  Isao Onishi ,  Satoru Ohashi ,  Eiichi Minagawa ,  Koji Hirota ,  Ryoichi Sakai ,  Koji Ogawa ,  Koichi Miyasaka ,  Masaru Murashita

IPC分类号： G01N29/00

CPC分类号： A61B8/4209 ,  A61B8/0858 ,  A61B8/4281

摘要： An acoustic matching device has a water bag (64) that contains water and a water bag support frame (66) that sandwiches and supports the water bag on the left and right sides of the knee and curves along the knee cap. The water bag becomes a plate shape curved along the shape of the water bag support frame, which touches the knee cap and fits the unevenness of the knee. When an ultrasonic probe is moved along the knee cap, the acoustic matching between the knee cap and the ultrasonic probe is obtained.

摘要翻译： 声学匹配装置具有含水的水袋（64）和水袋支撑框架（66），所述水袋支撑框架（66）夹持并支撑在膝盖的左侧和右侧并且沿着膝盖弯曲的水袋。 水袋成为沿着水袋支撑框架的形状弯曲的板形，其接触膝盖并适配膝盖的不平坦部分。 当超声波探头沿膝盖移动时，获得膝盖与超声波探头之间的声学​​匹配。