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公开(公告)号：US20120050380A1
公开(公告)日：2012-03-01
申请号：US12871982
申请日：2010-08-31
CPC分类号： C09D11/322 , C09D11/102 , C09D11/326
摘要： An inkjet printing fluid composition including water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; X1—Y1—X1 represents one or more soft segments wherein Y1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X2—Y2—X2 represents one or more hard segments wherein Y2 represents the central portion of a unit that is the polymerization product of a C2-C8 diol or diamine having a molecular weight of less than 250 Daltons; and X1, V and X2 can be the same or different and are an —O— or —N— atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X2—Y2—X2 hard segments are present at from 1 wt % to less than 13 wt % of the polyurethane additive. Also disclosed is a method for printing an inkjet image including I) providing an inkjet printing fluid according to the invention; and II) jetting the inkjet printing fluid in the form of ink drops onto a recording element to form a printed image.
摘要翻译： 一种喷墨印刷液组合物，其包含水和通式（I）的水分散性聚氨酯添加剂，其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; X1-Y1-X1表示一个或多个软链段，其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段，其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1，V和X2可以相同或不同，为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值，并且所述一个或多个X2-Y2-X2硬链段存在于1 wt％至小于13wt％的聚氨酯添加剂。 还公开了一种用于印刷喷墨图像的方法，包括：I）提供根据本发明的喷墨印刷液; 和II）将墨滴形式的喷墨打印流体喷射到记录元件上以形成打印图像。
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公开(公告)号：US07715050B2
公开(公告)日：2010-05-11
申请号：US12062873
申请日：2008-04-04
申请人： Karin Topfer , Thomas B. Brust , Brent Keller , Elaine W. Jin
发明人： Karin Topfer , Thomas B. Brust , Brent Keller , Elaine W. Jin
CPC分类号： H04N1/6027
摘要： In a method and system for processing a photographic image having lightness values, L*, representing one of the colorimetric values of an original scene, the photographic image is transformed. The transformed image has a gamma as a function of CIE 1976 L*, which includes a dark region having a rising slope, a light region having a falling slope, and a plateau region having a slope constantly within 5 percent of a maximum value in said plateau region. The rising slope is at least twice as large as the absolute value of the falling slope. The plateau region is between 10 L* and 30 L* wide. Gamma is a derivative of visually perceived reproduced CIE 1976 L* versus scene CIE 1976 L*. Gamma has a maximum slope between 1.5 and 2.0.
摘要翻译： 在用于处理具有亮度值的摄影图像的方法和系统中，表示原始场景的色度值之一的L *，变换摄影图像。 经变换的图像具有作为CIE 1976 L *的函数的伽马，其包括具有上升斜率的暗区域，具有下降斜率的光区域，以及具有在所述多个区域中的最大值的5％以内的斜率的平稳区域 高原地区。 上升斜率至少是下降斜率绝对值的两倍。 平台区域在10 L *和30 L *之间。 伽玛是视觉感知再现CIE 1976 L *与场景CIE 1976 L *的衍生物。 伽玛的最大斜率在1.5到2.0之间。
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公开(公告)号：US6114105A
公开(公告)日：2000-09-05
申请号：US290940
申请日：1999-04-13
申请人： Thomas B. Brust , Bernard D. Stich
发明人： Thomas B. Brust , Bernard D. Stich
CPC分类号： G03C1/0051 , G03C1/09 , G03C2001/03517 , G03C2001/03552 , G03C2001/03558 , G03C2001/095 , G03C2001/097 , G03C2001/098 , G03C2200/03
摘要： A high bromide {111} tabular grain emulsion is disclosed in which most of the tabular grains exhibit silver salt epitaxy at a single site. Most of the silver halide epitaxy sites contact an edge region of the tabular grains. These emulsions exhibit chemical sensitization by the epitaxy and surprising lower levels of desensitization by spectral sensitizing dyes.
摘要翻译： 公开了一种高溴酸盐{111}片状颗粒乳剂，其中大多数片状颗粒在单个位点显示银盐外延。 大多数卤化银外延位点接触片状颗粒的边缘区域。 这些乳液通过外延显示化学敏化，并且通过光谱增感染料令人惊讶的较低的脱敏水平。
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公开(公告)号：US5998115A
公开(公告)日：1999-12-07
申请号：US292500
申请日：1999-04-15
CPC分类号： G03C7/3029 , G03C7/3022
摘要： A photographic element is disclosed that relies upon high bromide silver halide grains that are sulfur and/or gold sensitized for latent image formation. Coated to receive exposing radiation directly from a layer containing the latent image forming grains is a non-imaging layer containing (a) tabular silver halide grains (i) comprised of greater than 50 mole percent bromide, based on silver, (ii) having a thickness in the range of from 0.03 to 0.20 .mu.m, and (iii) having an average aspect ratio of greater than 20, and (b) silver halide epitaxy selectively positioned adjacent edges of said tabular grains in said non-imaging layer, said silver halide epitaxy (i) containing greater than 50 mole percent chloride, based on silver, and (ii) accounting for from 0.1 to 50 percent of the total silver in the composite grains.
摘要翻译： 公开了一种照相材料，其依赖于用于潜像形成的硫和/或金敏化的高溴化银卤化物颗粒。 涂覆以从包含潜像形成颗粒的层直接接收曝光辐射是非成像层，其包含（a）由大于50摩尔百分比的溴化银（基于银）构成的片状卤化银颗粒（i），（ii）具有 厚度在0.03至0.20μm的范围内，和（iii）具有大于20的平均纵横比，以及（b）选择性地定位在所述非成像层中所述片状颗粒的边缘附近的卤化银外延，所述银 卤化物外延（i）含有大于50摩尔百分比的氯化物，以银为基准，和（ii）占复合颗粒中总银的0.1％至50％。
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25.发明授权Method of processing originating photographic elements containing tabular silver chloride grains bounded by (100) faces 失效处理由（100）面界定的含片状氯化银颗粒的起始照相元件的处理方法
公开(公告)号：US5491050A
公开(公告)日：1996-02-13
申请号：US193831
申请日：1994-02-09
IPC分类号： G03C1/035 , G03C1/005 , G03C1/43 , G03C5/26 , G03C5/30 , G03C7/392 , G03C7/413 , G03C7/42 , G03C7/46 , G03C1/494 , G03C1/46
CPC分类号： G03C7/39252 , G03C1/0053 , G03C7/413 , G03C2001/0055 , G03C2001/03535 , G03C2001/03558 , G03C2001/03594 , G03C2200/01 , G03C5/3035 , Y10S430/156 , Y10S430/158 , Y10S430/164
摘要： A method of processing an exposed originating silver halide color photographic element comprising developing the photographic element in a color devoloper containing a p-phenylenediamine color developing agent in the presence of a 1-phenyl pyrazolidin-3-one compoundwherein the originating silver halide photographic element comprises a radiation sensitive emulsion in reactive association with a development inhibitor releasing compound and containing a silver halide grain population comprised of grains comprising at least 50 mole percent silver chloride, based on total silver forming the grain population projected area, wherein at least 50 percent of total grain projected area is accounted for by intrinsically stable silver halide tabular grains(1) bounded by {100} major faces having adjacent edge ratios of less than 10 and(2) each having an average aspect ratio of at least 2, and wherein the silver halide content of the photographic element comprises at least 50 mole % silver chloride and no more than 2 mole % silver iodide.
摘要翻译： 一种处理暴露的起始卤化银彩色照相元件的方法，包括在1-苯基吡唑烷-3-酮化合物存在下，将含有对苯二胺彩色显影剂的彩色脱色器中的照相元件显影，其中起始卤化银照相元件 包括与显影抑制剂释放化合物反应性相关的辐射敏感乳剂，并且包含由包含至少50摩尔％氯化银的颗粒组成的卤化银颗粒群，基于形成颗粒群投影面积的总银，其中至少50％ 总颗粒投影面积由本征稳定的卤化银片状颗粒（1）占据了具有相邻边缘比率小于10的{100}主面和（2）各自具有至少2的平均纵横比，并且其中 照相元件的卤化银含量至少为50％（摩尔）氯化银 e且不超过2摩尔％的碘化银。
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公开(公告)号：US09709889B2
公开(公告)日：2017-07-18
申请号：US15012959
申请日：2016-02-02
CPC分类号： G03F7/038 , G03F7/0384 , G03F7/11 , G03F7/16 , G03F7/2002 , G03F7/40 , G03F7/405
摘要： A precursor article has a substrate and a polymeric layer having a reactive composition that contains a non-crosslinked thiosulfate copolymer comprising: (a) recurring units comprising pendant thiosulfate groups, and (b) recurring units comprising pendant carboxy, carboxylate, phospho, phosphonate, phosphate, sulfo, sulfonate, or sulfite groups. The (a) recurring units are present in an amount of 1 to 30 mol %, and the (b) recurring units are present in an amount of 70 to 99 mol %. This precursor article can be used to provide a product article comprising a substrate in which the polymeric layer has both exposed regions and non-exposed regions. The exposed regions contain a pattern of electrolessly plated metal within or deposited on the surface of an at least partially crosslinked polymer that has been derived from the non-crosslinked thiosulfate copolymer. The non-exposed regions have none of the electrolessly plated metal or the non-crosslinked thiosulfate polymer.
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27.发明授权公开(公告)号：US09366965B2
公开(公告)日：2016-06-14
申请号：US14457396
申请日：2014-08-12
CPC分类号： G03F7/16 , G03F7/0045 , G03F7/0046 , G03F7/038 , G03F7/0382 , G03F7/0388 , G03F7/26
摘要： An electrically-conductive pattern is prepared using a reactive composition having: (1) a reactive polymer; (2) a compound that provides a cleaving acid upon exposure to radiation; and (3) a crosslinking agent that reacts in the presence of the cleaving acid, to provide crosslinking in the reactive polymer. A polymeric layer of the reactive composition is patternwise exposed to provide a polymeric layer comprising non-exposed regions and exposed regions comprising a polymer comprising sulfonic acid or sulfonate groups. The exposed regions are contacted with electroless seed metal ions to form a pattern of electroless seed metal ions, which pattern is reduced to provide a pattern of corresponding electroless seed metal particles. Electrolessly plating is then carried out in the exposed regions. The unique reactive comprises (a) recurring units represented Structure (A) as described in the disclosure, and can also include other recurring units that are crosslinkable or provide other properties.
摘要翻译： 使用具有以下物质的反应性组合物制备导电图案：（1）反应性聚合物; （2）暴露于辐射时提供裂解酸的化合物; 和（3）在裂解酸存在下反应以在反应性聚合物中提供交联的交联剂。 将反应性组合物的聚合物层图案地暴露以提供包含非暴露区域的聚合物层和包含包含磺酸或磺酸盐基团的聚合物的暴露区域。 暴露的区域与无电子种子金属离子接触以形成无电晶种金属离子的图案，该图案被还原以提供相应的无电子种子金属颗粒的图案。 然后在暴露的区域进行无电镀。 独特的反应性包括（a）如本公开所述的结构（A）所示的重复单元，并且还可以包括可交联或提供其它性质的其它重复单元。
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公开(公告)号：US20160147148A1
公开(公告)日：2016-05-26
申请号：US15012959
申请日：2016-02-02
CPC分类号： G03F7/038 , G03F7/0384 , G03F7/11 , G03F7/16 , G03F7/2002 , G03F7/40 , G03F7/405
摘要： A precursor article has a substrate and a polymeric layer having a reactive composition that contains a non-crosslinked thiosulfate copolymer comprising: (a) recurring units comprising pendant thiosulfate groups, and (b) recurring units comprising pendant carboxy, carboxylate, phospho, phosphonate, phosphate, sulfo, sulfonate, or sulfite groups. The (a) recurring units are present in an amount of 1 to 30 mol %, and the (b) recurring units are present in an amount of 70 to 99 mol %. This precursor article can be used to provide a product article comprising a substrate in which the polymeric layer has both exposed regions and non-exposed regions. The exposed regions contain a pattern of electrolessly plated metal within or deposited on the surface of an at least partially crosslinked polymer that has been derived from the non-crosslinked thiosulfate copolymer. The non-exposed regions have none of the electrolessly plated metal or the non-crosslinked thiosulfate polymer.
摘要翻译： 前体制品具有底物和具有反应性组合物的聚合物层，其含有非交联硫代硫酸盐共聚物，其包含：（a）包含硫代硫酸盐基团的重复单元，和（b）包含侧羧基，羧酸根，磷酸根，膦酸根， 磷酸盐，磺基，磺酸盐或亚硫酸盐基团。 （a）重复单元的存在量为1〜30摩尔％，（b）重复单元的存在量为70〜99摩尔％。 该前体制品可用于提供包含基材的产品制品，其中聚合物层具有两个暴露区域和非曝光区域。 曝光区域包含在非交联硫代硫酸盐共聚物衍生的至少部分交联的聚合物的表面内或沉积在其表面上的无电镀金属的图案。 未曝光区域不具有无电镀金属或非交联硫代硫酸盐聚合物。
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公开(公告)号：US09329482B2
公开(公告)日：2016-05-03
申请号：US14249390
申请日：2014-04-10
CPC分类号： G03F7/038 , G03F7/0384 , G03F7/11 , G03F7/16 , G03F7/2002 , G03F7/40 , G03F7/405
摘要： A conductive pattern can be formed using a polymeric layer that contains a reactive composition that comprises a reactive polymer that is metal ion-complexing, water-soluble, and crosslinkable. This reactive polymer comprises pendant thiosulfate groups as well as metal ion-complexing and water solubilizing groups. The reactive composition can be patternwise exposed to suitable radiation to induce crosslinking within the reactive polymer. The reactive composition and reactive polymer in the non-exposed regions can be removed due to their aqueous solubility, but the exposed regions of the polymeric layer are contacted with electroless seed metal ions, which are then reduced. The resulting electroless seed metal nuclei are electrolessly plated with a suitable metal to form the desired conductive pattern. Various articles can be prepared during this process, and the product article can be incorporated into various electronic devices.
摘要翻译： 可以使用包含反应性组合物的聚合物层形成导电图案，所述反应性组合物包含金属离子络合，水溶性和可交联的反应性聚合物。 该反应性聚合物包括硫代硫酸根基团以及金属离子络合和水溶性基团。 反应性组合物可以图案化地暴露于合适的辐射以诱导反应性聚合物内的交联。 非暴露区域中的反应性组合物和反应性聚合物可以由于其水溶性而被去除，但是聚合物层的暴露区域与无电晶种金属离子接触，然后将其还原。 所得无电子种子金属核用无电镀的合适金属镀以形成所需的导电图案。 在该过程中可以制备各种物品，并且产品可以并入各种电子设备中。
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公开(公告)号：US20160077438A1
公开(公告)日：2016-03-17
申请号：US14484608
申请日：2014-09-12
CPC分类号： G03F7/40 , G03F7/038 , G03F7/0388
摘要： A conductive pattern can be formed using a polymeric layer that contains a reactive composition having a reactive polymer. This reactive polymer comprises (i) a backbone, and (ii) pendant photosensitive non-aromatic unsaturated heterocyclic groups comprising an amide group that is conjugated with a carbon-carbon double bond. The non-aromatic unsaturated heterocyclic groups are linked to the backbone at an amide nitrogen atom. The reactive composition can be patternwise exposed to suitable radiation to induce crosslinking within the reactive polymer. The reactive composition and reactive polymer in the non-exposed regions can be removed due to their aqueous solubility, but the exposed regions of the polymeric layer are contacted with electroless seed metal ions, which are then reduced, followed by electrolessly plating with a suitable metal to form the desired conductive pattern. Various articles can be prepared during this process, and the product article can be incorporated into various electronic devices.
摘要翻译： 可以使用含有具有反应性聚合物的反应性组合物的聚合物层形成导电图案。 该反应性聚合物包含（i）主链，和（ii）包含与碳 - 碳双键结合的酰胺基的侧光敏非芳族不饱和杂环基。 非芳族不饱和杂环基团在酰胺氮原子上与主链连接。 反应性组合物可以图案化地暴露于合适的辐射以诱导反应性聚合物内的交联。 非暴露区域中的反应性组合物和反应性聚合物可以由于其水溶性而被除去，但聚合物层的暴露区域与无电子种子金属离子接触，然后将其还原，然后用合适的金属进行无电镀 以形成所需的导电图案。 在该过程中可以制备各种物品，并且产品可以并入各种电子设备中。
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