摘要:
Liquid epoxy resin hardeners are mixtures of 2-ethyl-4-methylimidazole, ethyldimethylimidazole and/or diethylmethylimidazole isomers which can also contain other alkylimidazoles, and can be produced by distillation of the products obtained in the dehydrogenation of 2-ethyl-4-methylimidazoline.
摘要:
In a process for isolating alkylene glycol having a low aldehyde content, in which a mixture comprising alkylene glycol is subjected to a final distillation, formic acid or a formate or a mixture of two or more formates or a mixture of formic acid and one or more formates is present in the mixture comprising alkylene glycol.
摘要:
In a process and an apparatus for the continuous preparation of alkyl esters of (meth)acrylic acid by reacting (meth)acrylic acid and monohydric alkanols of 1 to 8 carbon atoms in the homogeneous, liquid, solvent-free phase at elevated temperatures and in the presence of an acidic esterification catalyst, by feeding the (meth)acrylic acid, the alkanol and the acid catalyst continuously to a reaction zone, the reaction zone consists of a cascade of at least two reaction regions connected in series, and the discharge stream of one reaction region forms a feed stream of a downstream reaction region. The cascade may have from two to four reaction regions spatially separated from one another.
摘要:
A diester of (meth)acrylic acid with a C.sub.4 -C.sub.6 -alkanediol is separated from a mixture which essentially consists of the C.sub.4 -C.sub.6 -alkanediol, the monoester of (meth)acrylic acid with the C.sub.4 -C.sub.6 -alkanediol and the diester of (meth)acrylic acid with the C.sub.4 -C.sub.6 -alkanediol by extraction with an organic solvent in the presence of water, by a process in which the diester-containing mixture is added continuously in the middle section of an extraction column and in addition water and the organic extracting agent are passed continuously countercurrent in the extraction column.
摘要:
4-Alkylimidazole derivatives of the formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.4 -alkyl, R.sup.2 is chlorine or bromine and R.sup.3 is an --OR.sup.4 or --NR.sup.5 R.sup.6 group in which R.sup.4 is C.sub.1 -C.sub.4 -alkyl, R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sub.6 is C.sub.1 -C.sub.4 -alkyl or is phenyl which is unsubstituted or substituted by 1 or 2 halogen atoms, and its salts, their preparation and their use as nitrification inhibitors.
摘要:
Adipodinitrile is prepared by reacting adipic acid with excess ammonia at from 250.degree. to 350.degree. C. in the liquid phase in the presence of a diluent by a process in which a liquid hydrocarbon which is inert under the reaction conditions is used as the diluent.
摘要:
Nitroimidazolylvinylthiadiazoles, their production, and formulations containing same for use as chemotherapeutics in the treatment of microbial infections in humans and animals, especially of trichomoniasis, trypanosomiasis and amoebic dysentery.
摘要:
An improved process for the continuous production of N-alkylarylamines by reaction of arylamines with alkanols and/or dialkyl ethers in the gas phase at a temperature of from 180.degree. to 450.degree.C in the presence of carrier substances which contain an oxyacid of phosphorus. The improvement consists in using silicic acid having an internal surface area of from 50 to 500 square meters per gram and a content of from 0.1 to 20% by weight of phosphoric acid and in the continuous supply of phosphoric acid and/or an alkyl phosphate to the catalyst during the reaction. N-alkylarylamines are starting materials for the production of dyes, pesticides, plant protection agents and growth regulators. They are also suitable as additives to mineral oils or to coating compositions and other polymerized systems.
摘要:
In a process and an apparatus for the continuous preparation of alkyl esters of (meth)acrylic acid by reacting (meth)acrylic acid and monohydric alkanols of 1 to 8 carbon atoms in the homogeneous, liquid, solvent-free phase at elevated temperatures and in the presence of an acidic esterification catalyst, by feeding the (meth)acrylic acid, the alkanol and the acid catalyst continuously to a reaction zone, the reaction zone consists of a cascade of at least two reaction regions connected in series, and the discharge stream of one reaction region forms a feed stream of a downstream reaction region. The cascade may have from two to four reaction regions is spatially separated from one another.
摘要:
1,4-butanediol mono(meth)acrylate is prepared by esterification of (meth)acrylic acid with 1,4-butanediol, by a process in which an aqueous solution of unconverted 1,4-butanediol is obtained, wherein the 1,4-butanediol present in the aqueous solution is converted into readily volatile tetrahydrofuran in the presence of a catalytic amount of a strong acid and the tetrahydrofuran is separated off from the aqueous solution.