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    Minimization of ligand degradation products, of reversion of same to useful phosphine ligands
    22.
    发明授权
    Minimization of ligand degradation products, of reversion of same to useful phosphine ligands 有权
    最小化配体降解产物，将其转化为有用的膦配体

    公开(公告)号：US07351868B2

    公开(公告)日：2008-04-01

    申请号：US10562602

    申请日：2004-06-28

    Applicant: John R. Briggs ,  Wei-Jun Peng ,  Brian M. Roesch ,  Anthony G. Abatjoglou ,  Donald L. Morrison

    Inventor： John R. Briggs ,  Wei-Jun Peng ,  Brian M. Roesch ,  Anthony G. Abatjoglou ,  Donald L. Morrison

    IPC: C07C45/49 ,  C07F9/02

    CPC classification number: C07F9/5022 ,  C07C29/16 ,  C07C45/50 ,  C07C45/62 ,  C07C67/38 ,  C07C33/03 ,  C07C69/738 ,  C07C47/21 ,  C07C47/02

    Abstract: A process for the minimization of phosphonium ion ligand degradation products formed during reaction of a polyunsaturated olefin or an unconjugated functionalized olefin in the presence of a transition metal-triorganophosphine ligand complex catalyst to form as a product, by-product, or intermediate product a conjugated functionalized olefin having a carbon-carbon double bond conjugated to an a-electronwithdrawing group, such as, an a,β-unsaturated aldehyde, ketone, ester, acid, or nitrile. The minimization process involves conducting the reaction under selected conditions of conversion, temperature, pressure, or a combination thereof; and/or by selecting a triorganophosphine ligand with a specified steric and/or electronic property. Further, a process for reversion of phosphonium ion ligand degradation product(s) back to useful triorganophosphine ligand(s), the reversion involving treating a reaction product fluid containing the degradation product(s) with an inert gas, hydrogen, synthesis gas, or a mixture thereof under conditions sufficient to regenerate the triorganophosphine ligand(s).

    Abstract translation: 一种在过渡金属 - 三有机膦配体催化剂存在下，在多不饱和烯烃或非共轭官能化烯烃反应期间形成的鏻离子配体降解产物最小化的方法，以形成产物，副产物或中间产物，共轭 具有与α-电子取向基团例如a不饱和醛，酮，酯，酸或腈共轭的碳 - 碳双键的官能化烯烃。 最小化方法包括在选择的转化条件，温度，压力或其组合下进行反应; 和/或通过选择具有特定空间和/或电子性质的三有机膦配体。 此外，将鏻离子配位体降解产物还原回有用的三有机膦配体的方法，涉及用惰性气体，氢气，合成气体或其混合物处理含有降解产物的反应产物流体的逆转 其混合物在足以再生三有机膦配体的条件下进行。

    Process for making amino acids
    23.
    发明申请
    Process for making amino acids 失效
    制备氨基酸的方法

    公开(公告)号：US20070166806A1

    公开(公告)日：2007-07-19

    申请号：US11333937

    申请日：2006-01-18

    Applicant: Michael Lloyd ,  Edward Daugs ,  Cynthia Rand ,  Wei-Jun Peng

    Inventor： Michael Lloyd ,  Edward Daugs ,  Cynthia Rand ,  Wei-Jun Peng

    IPC: C12P13/04 ,  C12P13/22 ,  C07C229/02

    CPC classification number: C07C227/32 ,  C07D317/30 ,  C12P13/04 ,  C12P41/006

    Abstract: A process for making an amino acid by the steps of: (a) contacting a compound of formula I with a hydroformylation catalyst and synthesis gas to produce a mixture of aldehyde compounds comprising the formulas IIa, IIb and IIc; (b) reacting the mixture of aldehyde compounds from step (a) to produce a mixture of derivative compounds; (c) contacting the mixture of derivative compounds from step (b) with an enantioselective hydrolase enzyme in the presence of water to produce an L-amino acid having the formula IV; (d) isolating the amino acid having the formula IV in substantially pure form, wherein in formulas I, IIa, IIb, IIc, IIIa, IIIb, IIIc and IV, R is H, alkyl or aryl and R1 and R2 are the same or different alkyl groups and wherein R1 and R2 may be fused

    Abstract translation: 通过以下步骤制备氨基酸的方法：（a）使式I化合物与加氢甲酰化催化剂和合成气接触以产生包含式IIa，IIb和IIc的醛化合物的混合物; （b）使来自步骤（a）的醛化合物的混合物反应以产生衍生化合物的混合物; （c）在水存在下将来自步骤（b）的衍生化合物的混合物与对映选择性水解酶接触以产生具有式IV的L-氨基酸; （d）以基本上纯的形式分离具有式IV的氨基酸，其中在式I，IIa，IIb，IIc，IIIa，IIIb，IIIc和IV中，R是H，烷基或芳基和R 1， SO 2和R 2是相同或不同的烷基，其中R 1和R 2可以是稠合的

    Minimization of ligand degradation products, of reversion of same to useful phosphine ligands
    25.
    发明申请
    Minimization of ligand degradation products, of reversion of same to useful phosphine ligands 有权
    最小化配体降解产物，将其转化为有用的膦配体

    公开(公告)号：US20070100169A1

    公开(公告)日：2007-05-03

    申请号：US10562602

    申请日：2004-06-28

    Applicant: John Briggs ,  Wei-Jun Peng ,  Brian Roesch ,  Anthony Abatjoglou ,  Donald Morrison

    Inventor： John Briggs ,  Wei-Jun Peng ,  Brian Roesch ,  Anthony Abatjoglou ,  Donald Morrison

    IPC: C07F9/02 ,  C07C45/49

    CPC classification number: C07F9/5022 ,  C07C29/16 ,  C07C45/50 ,  C07C45/62 ,  C07C67/38 ,  C07C33/03 ,  C07C69/738 ,  C07C47/21 ,  C07C47/02

    Abstract: A process for the minimization of phosphonium ion ligand degradation products formed during reaction of a polyunsaturated olefin or an unconjugated functionalized olefin in the presence of a transition metal-triorganophosphine ligand complex catalyst to form as a product, by-product, or intermediate product a conjugated functionalized olefin having a carbon-carbon double bond conjugated to an αelectronwithdrawing group, such as, an α,β-unsaturated aldehyde, ketone, ester, acid, or nitrile. The minimization process involves conducting the reaction under selected conditions of conversion, temperature, pressure, or a combination thereof; and/or by selecting a triorganophosphine ligand with a specified steric and/or electronic property. Further, a process for reversion of phosphonium ion ligand degradation product(s) back to useful triorganophosphine ligand(s), the reversion involving treating a reaction product fluid containing the degradation product(s) with an inert gas, hydrogen, synthesis gas, or a mixture thereof under conditions sufficient to regenerate the triorganophosphine ligand(s).

    Abstract translation: 一种在过渡金属 - 三有机膦配体催化剂存在下，在多不饱和烯烃或非共轭官能化烯烃反应期间形成的鏻离子配体降解产物最小化的方法，以形成产物，副产物或中间产物，共轭 具有与α-电子牵伸基团例如α，β-不饱和醛，酮，酯，酸或腈共轭的碳 - 碳双键的官能化烯烃。 最小化方法包括在选择的转化条件，温度，压力或其组合下进行反应; 和/或通过选择具有特定空间和/或电子性质的三有机膦配体。 此外，将鏻离子配位体降解产物还原回有用的三有机膦配体的方法，涉及用惰性气体，氢气，合成气体或其混合物处理含有降解产物的反应产物流体的逆转 其混合物在足以再生三有机膦配体的条件下进行。

    Phosoxophite ligands and use thereof in carbonylation processes
    26.
    发明授权
    Phosoxophite ligands and use thereof in carbonylation processes 有权
    Phosoxophite配体及其在羰基化过程中的应用

    公开(公告)号：US07196230B2

    公开(公告)日：2007-03-27

    申请号：US10504247

    申请日：2003-03-04

    Applicant: Wei-Jun Peng ,  David Robert Bryant

    Inventor： Wei-Jun Peng ,  David Robert Bryant

    IPC: C07F9/02

    CPC classification number: C07F15/008 ,  C07C45/49 ,  C07C45/50 ,  C07C67/293 ,  C07C67/347 ,  C07F9/65742 ,  C07F9/65744 ,  C07F9/65746 ,  C07C47/19 ,  C07C47/228 ,  C07C69/003 ,  C07C69/716 ,  C07C69/14

    Abstract: A novel organophosphorus composition and synthesis thereof, the composition being characterized by one phosphite moiety, one phosoxophite moiety, and a plurality of sterically bulky substituents. The novel composition finds utility as a ligand in Group VIII transition metal phosoxophite complex catalysts and complex catalyst precursors that are used in carbonylation processes, preferably, hydroformylation processes. Additionally, there is disclosed a novel method of preparing a phosphoromonochloridite composition that finds utility as a precursor to the novel phosoxophite composition.

    Abstract translation: 一种新颖的有机磷组合物及其合成，该组合物的特征在于一个亚磷酸酯部分，一个亚磷酸酯部分和多个空间庞大的取代基。 该新型组合物可用作第VIII族过渡金属磷酸盐络合物催化剂和复合催化剂前体中的配体，其用于羰基化方法，优选加氢甲酰化方法。 此外，公开了一种制备可用作新型磷酸盐组合物的前体的一氯代氯酸盐组合物的新方法。

    Aldehyde and alcohol compositions derived from seed oils
    27.
    发明申请
    Aldehyde and alcohol compositions derived from seed oils 有权
    衍生自种子油的醛和醇组合物

    公开(公告)号：US20060193802A1

    公开(公告)日：2006-08-31

    申请号：US10551854

    申请日：2004-04-22

    Applicant: Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

    Inventor： Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

    IPC: C07C29/14

    CPC classification number: C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

    Abstract: An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxmethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foams.

    Abstract translation: 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或脂肪酸酯的混合物，所述羟甲基取代的脂肪酸或脂肪酸酯具有以下重量组成：大于约10至小于约95％的一元醇{单（羟甲基，大于 约1至小于约65％的二醇{二（羟甲基，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯;优选大于约3至小于约35％ 饱和物;优选小于约10％的不饱和度。醇组合物可以转化为用于制备聚氨酯板坯柔性泡沫的低聚多元醇。

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