Process for producing thick-film tape-shaped re-type (123) superconductor
    21.
    发明授权
    Process for producing thick-film tape-shaped re-type (123) superconductor 失效
    生产厚膜带状再型(123)超导体的方法

    公开(公告)号:US08409657B2

    公开(公告)日:2013-04-02

    申请号:US12086294

    申请日:2006-12-07

    IPC分类号: B05D5/12 H01L39/24

    CPC分类号: H01L39/2451

    摘要: A production process of a thick-film tape-shaped RE-type (123) superconductor having a high critical current value. The production process has the steps of providing a composite substrate having Gd2Zr2O7 and CeO2 stacked in that order onto a Hastelloy substrate, coating a raw material solution prepared by dissolving a trifluoroacetate of Y and Ba and a naphthenate of Cu onto the composite substrate, heat treating the coated composite substrate by calcination, then subjecting the calcined assembly to intermediate heat-treatment at a temperature below the temperature of heat-treatment for superconductor production, and then heat treating the assembly in an argon gas atmosphere under conditions of highest heating temperature 760° C., water vapor partial pressure 13.5%, and oxygen partial pressure 0.09% for superconductor production to produce a tape-shaped RE-type (123) superconductor having a YBCO superconducting film having a thickness of more than about 2 μm.

    摘要翻译: 具有高临界电流值的厚膜带状RE型(123)超导体的制造方法。 该制造方法具有以下步骤:将具有Gd 2 Zr 2 O 7和CeO 2的复合基板依次层叠在Hastelloy基板上,涂布通过将Y和Ba的三氟乙酸盐和Cu的环烷酸盐溶解在复合基板上而制备的原料溶液, 通过煅烧对涂覆的复合基材进行煅烧,然后在低于制备超导体的热处理温度的温度下对煅烧组件进行中间热处理,然后在氩气气氛中在最高加热温度760℃的条件下热处理该组件 C,水蒸气分压为13.5%,氧分压为0.09%,制造出具有厚度大于约2μm的YBCO超导膜的带状RE型(123)超导体。

    Method of and apparatus for manufacturing tape-formed oxide superconductor
    22.
    发明授权
    Method of and apparatus for manufacturing tape-formed oxide superconductor 失效
    制造带状氧化物超导体的方法和装置

    公开(公告)号:US08124171B2

    公开(公告)日:2012-02-28

    申请号:US11385742

    申请日:2006-03-22

    IPC分类号: B05D5/12 H01L39/24

    摘要: A method of manufacturing a tape-formed oxide superconductor, in which a tape-formed wire material (6 in FIG. 1) is extended between a pair of reels (5a and 5b). Besides, a reactive gas is supplied form the gas supply ports of a reactive gas supply pipe (3a) vertically to the upper side film surface of the tape-formed wire material (6), so as to react the film body of this tape-formed wire material into a superconducting layer, while at the same time, a gas after the reaction is discharged from the gas discharge ports of discharge pipes (4a and 4b) for discharging the gas after the reaction. Likewise, the reactive gas is supplied vertically to the lower side film surface of the tape-formed wire material (6), so as to react the film body of this tape-formed wire material into a superconducting layer, while at the same time, the gas after the reaction is discharged from the gas discharge ports of discharge pipes (4c and 4d) for discharging the gas after the reaction. Even when the tape-formed wire material (6) is large in area, the tape-formed oxide superconductor has superconducting characteristics being uniform in it widthwise direction, and it can be manufactured at high speed.

    摘要翻译: 制造带状氧化物超导体的方法,其中带状线材(图1中的6)在一对卷轴(5a和5b)之间延伸。 此外,从反应性气体供给管(3a)的气体供给口向带状线材(6)的上侧膜表面垂直地供给反应性气体, 将导线材料形成为超导层,同时从反应后排出气体的排出管(4a,4b)的排气口排出反应后的气体。 同样地,将反应性气体垂直地供给到带状线材(6)的下侧膜表面,以使该带状线材的膜体与超导层反应,同时, 反应后的气体从排出管(4c,4d)的排气口排出,排出反应后的气体。 即使当带状线材(6)的面积大时,带状氧化物超导体也具有在宽度方向上均匀的超导特性,并且可以高速制造。

    RE-TYPE OXIDE SUPERCONDUCTING WIRE AND PROCESS FOR PRODUCING THE SAME
    23.
    发明申请
    RE-TYPE OXIDE SUPERCONDUCTING WIRE AND PROCESS FOR PRODUCING THE SAME 有权
    RE型氧化物超导线及其制造方法

    公开(公告)号:US20110124508A1

    公开(公告)日:2011-05-26

    申请号:US12811141

    申请日:2008-12-17

    IPC分类号: H01B12/00 H01L39/24

    摘要: A RE-type oxide superconducting wire having excellent angular dependence for magnetic field of Jc is obtained by finely dispersing magnetic flux pinning centers into a superconductor. A mixed solution which comprises a metal-organic complex solution including a metal element which composes a RE-type oxide superconductor whose Ba content is reduced and a metal-organic complex solution including at least one or more kinds of metals which are selected from Zr, Ce, Sn, or Ti which has a larger affinity for Ba is coated onto an intermediate layer of a composite substrate, and the assembly is then calcined to disperse artificially and finely oxide particles (magnetic flux pinning centers) including Zr. Thus, the angular dependence for magnetic field (Jc,min/Jc,max) of Jc can be remarkably improved.

    摘要翻译: 通过将磁通钉扎中心精细地分散到超导体中,获得对Jc的磁场具有优异的角度依赖性的RE型氧化物超导线。 一种混合溶液,其包含含有金属元素的金属有机络合物溶液,所述金属有机络合物溶液中含有Ba含量减少的RE型氧化物超导体和含有选自Zr, 对Ba具有较大亲合力的Ce,Sn或Ti涂覆在复合衬底的中间层上,然后将该组件煅烧以分散包括Zr的人造和细小氧化物颗粒(磁通钉扎中心)。 因此,Jc的磁场的角度依赖性(Jc,min / Jc,max)可以显着提高。

    Continuous observation apparatus and method of magnetic flux distribution
    25.
    发明申请
    Continuous observation apparatus and method of magnetic flux distribution 失效
    连续观察装置及磁通分布方法

    公开(公告)号:US20070108974A1

    公开(公告)日:2007-05-17

    申请号:US11514883

    申请日:2006-09-05

    IPC分类号: G01R33/02

    CPC分类号: G01R33/1253 G01R33/1238

    摘要: A continuous observation apparatus of magnetic flux distribution in which a long sample containing a superconducting material or magnetic material is transferred to an observation position and magnetic flux is observed sequentially at each of certain areas along a longitudinal direction of the sample is provided. A method of continuously observing magnetic flux by which a long sample containing a superconducting material or magnetic material is transferred to an observation position and magnetic flux is observed sequentially at each of certain areas along a longitudinal direction of the sample is also provided.

    摘要翻译: 提供了一种磁通量分布的连续观察装置,其中将包含超导材料或磁性材料的长样品转移到观察位置,并且沿着样品的纵向方向上的每个特定区域依次观察磁通量。 还提供了连续观察磁通量的方法,其中将含有超导材料或磁性材料的长样品转移到观察位置,并且沿着样品的纵向方向上的每个特定区域依次观察磁通量。

    Method of and apparatus for manufacturing tape-formed oxide superconductor
    26.
    发明申请
    Method of and apparatus for manufacturing tape-formed oxide superconductor 失效
    制造带状氧化物超导体的方法和装置

    公开(公告)号:US20060216407A1

    公开(公告)日:2006-09-28

    申请号:US11385742

    申请日:2006-03-22

    IPC分类号: B05D5/12 C23C16/00

    摘要: A method of manufacturing a tape-formed oxide superconductor, in which a tape-formed wire material (6 in FIG. 1) is extended between a pair of reels (5a and 5b). Besides, a reactive gas is supplied form the gas supply ports of a reactive gas supply pipe (3a) vertically to the upper side film surface of the tape-formed wire material (6), so as to react the film body of this tape-formed wire material into a superconducting layer, while at the same time, a gas after the reaction is discharged from the gas discharge ports of discharge pipes (4a and 4b) for discharging the gas after the reaction. Likewise, the reactive gas is supplied vertically to the lower side film surface of the tape-formed wire material (6), so as to react the film body of this tape-formed wire material into a superconducting layer, while at the same time, the gas after the reaction is discharged from the gas discharge ports of discharge pipes (4c and 4d) for discharging the gas after the reaction. Even when the tape-formed wire material (6) is large in area, the tape-formed oxide superconductor has superconducting characteristics being uniform in it widthwise direction, and it can be manufactured at high speed.

    摘要翻译: 一种制造带状氧化物超导体的方法,其中带状线材(图1中的6)在一对卷轴(5a和5b)之间延伸。 此外,从反应性气体供给管(3a)的气体供给口向带状线材(6)的上侧膜表面垂直地供给反应气体,以使该带的膜体反应 形成的导线材料进入超导层,同时反应之后的气体从排出管(4a和4b)的气体排出口排出,用于在反应之后排出气体。 同样地,将反应性气体垂直地供给到带状线材(6)的下侧膜表面,以使该带状线材的膜体与超导层反应,同时, 反应后的气体从排气管(4c和4d)的排气口排出,用于排出反应后的气体。 即使当带状线材(6)的面积大时,带状氧化物超导体也具有在宽度方向上均匀的超导特性,并且可以高速制造。

    PROCESS FOR PRODUCING TAPE-SHAPED Re-TYPE (123) SUPERCONDUCTOR
    27.
    发明申请
    PROCESS FOR PRODUCING TAPE-SHAPED Re-TYPE (123) SUPERCONDUCTOR 审中-公开
    用于生产带状再型(123)超导体的方法

    公开(公告)号:US20090270263A1

    公开(公告)日:2009-10-29

    申请号:US12376099

    申请日:2007-06-12

    IPC分类号: H01L39/24

    摘要: This invention provides a production process of a tape-shaped superconductor which can realize high Jc and Ic values by virtue of the elimination of the cause of generation of cracks and deterioration of an electrical connectivity in crystal grain boundaries. In producing an Re-base (123) superconductor on a substrate by an MAD process, the use of a raw material solution having a Re:Ba:Cu molar ratio of 1:X:3, wherein X is a Ba molar ratio satisfying X

    摘要翻译: 本发明提供了一种带状超导体的制造方法,其通过消除裂纹的产生和晶粒边界的电连接性的劣化,可以实现高的Jc和Ic值。 在通过MAD工艺在基板上制造Re(123)超导体时,使用Re:Ba:Cu摩尔比为1:X:3的原料溶液,其中X为满足X的Ba摩尔比 <2(优选1.0 <= X <= 1.8,特别是1.3 <= x <= 1.7)可以实现具有Jc = 3.20MA / cm 2的超导性和Ic = 525A的厚膜带状超导体的生产 / cm(X = 1.5)。

    Superconducting wire and superconducting coil employing it
    29.
    发明申请
    Superconducting wire and superconducting coil employing it 有权
    超导线和超导线圈采用它

    公开(公告)号:US20060077025A1

    公开(公告)日:2006-04-13

    申请号:US10514194

    申请日:2004-07-13

    IPC分类号: H01F6/00

    摘要: Tape-shaped superconducting wires are made by forming a superconducting film on the substrate. At least the superconducting film is slit, electrically separated into a plurality of superconducting film parts each having a rectangular cross section and arranged in parallel to form parallel conductors. This provides superconducting wires capable of containing AC loss. A superconducting coil is made by winding the superconducting wires described above, wherein the provision of a coil structure containing at least partially a part wherein the perpendicular interlinkage magnetic flux acting among various conductor elements of the parallel conductors by the distribution of the magnetic field generated by the superconducting coils cancel mutually enables a simple structure without transposition to cancel mutually the interlinkage magnetic flux by the perpendicular magnetic field against wires, to contain circulating current within the wires by the perpendicular magnetic field and to make shunt current uniform. This provides a low-loss superconducting coil.

    摘要翻译: 带状超导线通过在基板上形成超导膜而制成。 至少超导膜被切割,电分离成多个超导膜部件,每个超导膜部件具有矩形横截面并且平行布置以形成平行的导体。 这提供了能够包含AC损耗的超导线。 通过缠绕上述超导线来制造超导线圈,其中提供线圈结构,其至少部分地包含部分,其中通过由所述平行导体的各个导体元件中的磁场分布产生的磁场的分布而作用的垂直互连磁通量 超导线圈相互抵消,能够实现简单的结构,而不会发生转移,以相互抵消通过垂直磁场对线的互连磁通,以通过垂直磁场包含线内的循环电流并使分流电流均匀。 这提供了一个低损耗超导线圈。

    Single crystalline base thin film
    30.
    发明申请
    Single crystalline base thin film 审中-公开
    单晶基底薄膜

    公开(公告)号:US20060009362A1

    公开(公告)日:2006-01-12

    申请号:US10526896

    申请日:2003-10-29

    IPC分类号: H01L39/24

    摘要: The invention relates to a technique for forming a single crystalline thin film of good quality on an underlayer. Such a technique is suitably applicable to provision of an oxide high-temperature superconductor thin film usable for a superconducting wire material, a superconducting device or the like. The single crystalline thin film formed on a substratum is made of a substance different from that of the substratum. A specific atomic layer contained in common in the substratum and the thin film is shared at an interface between the substratum and the thin film. In a region as adjacent to the interface as 100 or fewer unit cells of the thin film apart from the interface, a ratio of crystalline region having grown with an orientation of ±2 degrees or less deviation angle on the basis of a crystal orientation of the substratum is 50% or more.

    摘要翻译: 本发明涉及一种在底层上形成质量好的单晶薄膜的技术。 这种技术适用于提供可用于超导线材,超导装置等的氧化物高温超导体薄膜。 在基底上形成的单晶薄膜由与底层不同的物质制成。 在基底和薄膜中共同包含的特定原子层在基底和薄膜之间的界面处共享。 在与接口相邻的区域中,与界面相比,薄膜的单元电池为100个或更少,根据晶体取向为±2度以下的取向生长的结晶区域的比例 基质为50%以上。