公开(公告)号：US20180311611A1

公开(公告)日：2018-11-01

申请号：US15763604

申请日：2016-09-28

Applicant: BASF SE

Inventor： Gerald VORBERG ,  Ralf NOTZ ,  Thomas INGRAM ,  Georg SIEDER ,  Torsten KATZ ,  Christian GRUENANGER ,  Peter DEGLMANN

IPC: B01D53/14 ,  C10L3/10

CPC classification number: B01D53/1493 ,  B01D53/1468 ,  B01D2252/20405 ,  B01D2252/2041 ,  B01D2252/20415 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20484 ,  B01D2252/504 ,  B01D2252/602

Abstract: An absorbent for selective removal of hydrogen sulfide from a fluid stream comprises an aqueous solution comprising a) a tertiary amine; b) an aminic pH promoter selected from the compounds mentioned in the description; where the molar ratio of b) to a) is in the range from 0.05 to 1.0; and c) an acid having a pKA of less than 6 in such an amount that the pH of the aqueous solution measured at 120° C. is 7.9 to less than 8.8. Also described is a process for removing acidic gases from a fluid stream, in which the fluid stream is contacted with the absorbent. The absorbent is notable for a low regeneration energy.

公开(公告)号：US10005022B2

公开(公告)日：2018-06-26

申请号：US15655692

申请日：2017-07-20

Applicant: New Jersey Institute of Technology

Inventor： Kamalesh K. Sirkar

IPC: B01D53/14 ,  B01D53/22

CPC classification number: B01D53/1475 ,  B01D53/1425 ,  B01D53/1493 ,  B01D53/229 ,  B01D2053/224 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20489 ,  B01D2252/30 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2325/38 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06 ,  Y02C10/10

Abstract: The present disclosure provides improved systems, assemblies and methods to remove and recover CO2 from emissions. More particularly, the present disclosure provides improved membrane contactors configured to remove CO2 from flue gas by temperature swing absorption. In exemplary embodiments, the present disclosure provides a novel hollow fiber membrane contactor that integrates absorption and stripping using a nonvolatile reactive absorbent (e.g., 80% polyamidoamine (PAMAM) dendrimer generation 0, and 20% of an ionic liquid (IL)). Equilibrium CO2 absorption in the nonvolatile viscous mixed absorbent is as high as 6.37 mmolCO2/g absorbent in the presence of moisture at 50° C. A novel membrane contactor is provided for CO2 absorption and stripping via a process identified as temperature swing membrane absorption (TSMAB). The contactor integrates non-dispersive gas absorption and hot water-based CO2 stripping in one device/assembly containing two sets of commingled hollow fibers.

公开(公告)号：US09713788B2

公开(公告)日：2017-07-25

申请号：US14885214

申请日：2015-10-16

Applicant: David Charles Calabro ,  Lisa Saunders Baugh ,  Pavel Kortunov ,  Benjamin A. McCool ,  Michael Siskin ,  Dennis George Peiffer ,  Quanchang Li

Inventor： David Charles Calabro ,  Lisa Saunders Baugh ,  Pavel Kortunov ,  Benjamin A. McCool ,  Michael Siskin ,  Dennis George Peiffer ,  Quanchang Li

IPC: C07C215/18 ,  C07C215/12 ,  C07C215/14 ,  C07C211/14 ,  B01D53/14 ,  B01D53/62

CPC classification number: B01D53/1493 ,  B01D53/1475 ,  B01D53/62 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20478 ,  B01D2252/2056 ,  B01D2252/30 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

Abstract: A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.

公开(公告)号：US09555364B2

公开(公告)日：2017-01-31

申请号：US13966404

申请日：2013-08-14

Applicant: NALCO COMPANY

Inventor： Alan M. Blair ,  Keith N. Garside ,  William J. Andrews ,  Kailas B. Sawant

IPC: C07D241/04 ,  C07D295/02 ,  C07D295/12 ,  C07D295/13 ,  C07D233/02 ,  B01D53/14 ,  C12M1/00

CPC classification number: B01D53/1456 ,  B01D53/1462 ,  B01D53/1493 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20447 ,  B01D2252/20473 ,  B01D2252/502 ,  B01D2256/24 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2258/05 ,  B01D2258/06 ,  C12M47/18 ,  Y02P20/59

Abstract: This invention provides novel compositions comprising substituted polyamines as acid gas scrubbing solutions and methods of using the compositions in an industrial system. The invention relates to the use of such polyamine compounds in industrial processes to remove acidic contaminants from natural and industrial fluid streams, such as natural gas, combustion gas, natural gas, synthesis gas, biogas, and other industrial fluid streams. The compositions and methods of the invention are useful for removal, absorption, or sequestration of acidic contaminants and sulfide contaminants including CO2, H2S, RSH, CS2, COS, and SO2.

Abstract translation: 本发明提供包含取代的多胺作为酸性气体洗涤溶液的新型组合物和在工业系统中使用该组合物的方法。 本发明涉及这种多胺化合物在工业过程中从天然气和工业流体流中除去酸性污染物的用途，例如天然气，燃烧气体，天然气，合成气，沼气和其它工业流体物流。 本发明的组合物和方法可用于除去，吸收或螯合酸性污染物和硫化物污染物，包括CO 2，H 2 S，RSH，CS 2，COS和SO 2。

公开(公告)号：US20160325225A1

公开(公告)日：2016-11-10

申请号：US14705937

申请日：2015-05-06

Applicant: Aaron Esser-Kahn

Inventor： Aaron Esser-Kahn ,  Du Nguyen

IPC: B01D53/62 ,  B01D53/14 ,  F01K11/02 ,  B01D53/78

CPC classification number: B01D53/1425 ,  B01D53/1475 ,  B01D53/1493 ,  B01D2252/202 ,  B01D2252/204 ,  B01D2252/20415 ,  B01D2252/20442 ,  B01D2252/20447 ,  B01D2252/20473 ,  B01D2252/20484 ,  B01D2252/20489 ,  B01D2253/102 ,  B01D2253/106 ,  B01D2253/304 ,  B01D2255/104 ,  B01D2255/106 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2256/24 ,  B01D2257/504 ,  B01D2258/0233 ,  B01D2258/0283 ,  B01D2258/06 ,  F01K5/00 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

Abstract: The present disclosure provides methods and apparatuses of recovering CO2 from a gas stream. The methods regenerate CO2 with high regeneration efficiencies, thereby lowering the overall energy cost for CO2 capture.

Abstract translation: 本公开提供了从气流中回收CO 2的方法和装置。 该方法以高再生效率再生二氧化碳，从而降低二氧化碳捕获的总能量成本。

公开(公告)号：US09427698B2

公开(公告)日：2016-08-30

申请号：US14051594

申请日：2013-10-11

Applicant: General Electric Company

Inventor： Michael Joseph O'Brien ,  Rachel Lizabeth Farnum ,  Robert James Perry

IPC: B01D53/14 ,  C10K1/00 ,  C10K1/12 ,  C10K1/14 ,  C10K1/16

CPC classification number: B01D53/1493 ,  B01D53/1475 ,  B01D2252/2041 ,  B01D2252/20415 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20452 ,  B01D2252/2053 ,  B01D2258/0283 ,  C07F7/0838 ,  C10K1/005 ,  C10K1/128 ,  Y02C10/06 ,  Y02P20/152

Abstract: An amino-siloxane composition is presented. The amino-siloxane composition includes structure (I): wherein R1 is independently at each occurrence a C1-C5 aliphatic radical; R2 is a C3-C4 aliphatic radical; R3 is a C1-C5 aliphatic radical or R4, wherein R4 comprises structure (II): and X is an electron donating group. Methods of reducing an amount of carbon dioxide in a process stream using the amino-siloxane composition are also presented.

Abstract translation: 提出氨基硅氧烷组合物。 氨基硅氧烷组合物包括结构（I）：其中R 1在每次出现时独立地为C 1 -C 5脂族基; R2是C3-C4脂族基团; R3是C1-C5脂族基团或R4，其中R4包含结构（II）：X是给电子基团。 还提出了使用氨基 - 硅氧烷组合物减少工艺流中二氧化碳的量的方法。

公开(公告)号：US20160228811A1

公开(公告)日：2016-08-11

申请号：US15022554

申请日：2014-09-16

Applicant: ENVERID SYSTEMS, INC.

Inventor： Udi MEIRAV ,  Israel BIRAN ,  Karthik RAMASWAMI ,  Shira ROSENCWAIG

IPC: B01D53/14

CPC classification number: B01D53/1487 ,  B01D39/02 ,  B01D53/1493 ,  B01D53/72 ,  B01D53/80 ,  B01D2239/0407 ,  B01D2252/204 ,  B01D2252/20405 ,  B01D2252/2041 ,  B01D2252/20415 ,  B01D2252/20484 ,  B01D2252/20489 ,  B01D2253/102 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2253/11 ,  B01D2253/25 ,  B01D2253/302 ,  B01D2257/708 ,  B01D2259/4508

Abstract: Embodiments of the present disclosure are directed to systems and methods for removing formaldehyde from indoor air. Some embodiments include flowing an indoor airflow over and/or through a solid supported amine filtering medium, such that, at least a portion of formaldehyde entrained in the indoor airflow is removed therefrom. Some other embodiments include systems having one or more fans for providing velocity to one and/or another airflows (e.g., airflows to/from a formaldehyde filter).

Abstract translation: 本公开的实施方案涉及从室内空气中除去甲醛的系统和方法。 一些实施方案包括使室内气流流过固体支持的胺过滤介质和/或通过固体支持的胺过滤介质，使得夹带在室内气流中的甲醛的至少一部分从其中移除。 一些其他实施例包括具有一个或多个风扇以提供速度到一个和/或另一个气流（例如，到达/来自甲醛过滤器的气流）的系统。

公开(公告)号：US20160016111A1

公开(公告)日：2016-01-21

申请号：US14801380

申请日：2015-07-16

Applicant: New Jersey Institute of Technology

Inventor： Kamalesh K. Sirkar

IPC: B01D53/62 ,  B01D53/14 ,  B01D53/78 ,  B01D53/22

CPC classification number: B01D53/1475 ,  B01D53/1425 ,  B01D53/1493 ,  B01D53/229 ,  B01D2053/224 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20489 ,  B01D2252/30 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2325/38 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06 ,  Y02C10/10

Abstract: The present disclosure provides improved systems, assemblies and methods to remove and recover CO2 from emissions. More particularly, the present disclosure provides improved membrane contactors configured to remove CO2 from flue gas by temperature swing absorption. In exemplary embodiments, the present disclosure provides a novel hollow fiber membrane contactor that integrates absorption and stripping using a nonvolatile reactive absorbent (e.g., 80% polyamidoamine (PAMAM) dendrimer generation 0, and 20% of an ionic liquid (IL)). Equilibrium CO2 absorption in the nonvolatile viscous mixed absorbent is as high as 6.37 mmolCO2/g absorbent in the presence of moisture at 50° C. A novel membrane contactor is provided for CO2 absorption and stripping via a process identified as temperature swing membrane absorption (TSMAB). The contactor integrates non-dispersive gas absorption and hot water-based CO2 stripping in one device/assembly containing two sets of commingled hollow fibers.

Abstract translation: 本公开提供了改进的系统，组件和方法来从排放物中去除和回收二氧化碳。 更具体地，本公开提供了改进的膜接触器，其被配置为通过温度摆动吸收从烟道气中去除CO 2。 在示例性实施例中，本公开提供了一种新颖的中空纤维膜接触器，其使用非挥发性反应性吸收剂（例如，80％聚酰胺胺（PAMAM）树枝状大分子代0和20％的离子液体（IL））进行吸收和汽提。 在50℃的水分存在下，非挥发性粘性混合吸收剂中的平衡CO 2吸收高达6.37mmolCO 2 / g吸收剂。提供了一种新的膜接触器，用于通过鉴定为温度摆动膜吸收的过程（TSMAB）进行CO 2吸收和汽提 ）。 接触器将非分散气体吸收和热水基二氧化碳汽提在一个包含两组混合中空纤维的装置/组件中集成。

公开(公告)号：US20150314235A1

公开(公告)日：2015-11-05

申请号：US14268174

申请日：2014-05-02

Applicant: Pavel Kortunov ,  Michael Siskin ,  Eugene R. Thomas ,  Hans Thomann

Inventor： Pavel Kortunov ,  Michael Siskin ,  Eugene R. Thomas ,  Hans Thomann

IPC: B01D53/62 ,  B01D53/14

CPC classification number: B01D53/1475 ,  B01D53/1425 ,  B01D53/1493 ,  B01D53/62 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20478 ,  B01D2252/2056 ,  B01D2252/30 ,  B01D2258/0283 ,  Y02C10/04 ,  Y02C10/06

Abstract: A cyclic process for separating CO2 from a gas stream by contacting the gas stream at a first temperature and typically at a pressure of at least 30 barg with a CO2 sorbent comprising an ionic liquid containing a potentially nucleophilic carbon atom bearing a relatively acidic hydrogen atom bonded to a potentially nucleophilic carbon atom to sorb CO2 into the solution and regenerating the ionic liquid absorbent by treating the sorbent under conditions including a second, typically higher, temperature, to cause desorption of at least a portion of the CO2 and to regenerate the ionic liquid.

Abstract translation: 通过在第一温度和通常在至少30barg的压力下将气流与包含含有相对酸性氢原子键合的潜在亲核性碳原子的离子液体的CO 2吸附剂接触，从气流中分离CO 2的循环方法 到潜在的亲核碳原子以将CO 2吸收到溶液中并通过在包括第二，通常较高的温度的条件下处理吸附剂来再生离子液体吸收剂，以引起至少一部分CO 2的解吸并再生离子液体 。

公开(公告)号：US09079134B2

公开(公告)日：2015-07-14

申请号：US14123856

申请日：2012-06-05

Applicant: Tomoyuki Ogino

Inventor： Tomoyuki Ogino

IPC: B01D53/02 ,  B01D53/14 ,  C01B31/20 ,  B01D53/62

CPC classification number: B01D53/1425 ,  B01D53/025 ,  B01D53/62 ,  B01D2252/204 ,  B01D2252/2041 ,  B01D2252/20415 ,  B01D2252/20452 ,  B01D2252/20484 ,  B01D2252/20489 ,  B01D2253/102 ,  B01D2253/25 ,  B01D2253/306 ,  B01D2253/308 ,  B01D2253/311 ,  B01D2257/504 ,  B01D2259/4009 ,  C01B32/50 ,  Y02C10/04 ,  Y02C10/06 ,  Y02C10/08 ,  Y02P20/152

Abstract: A carbon dioxide separating and capturing apparatus includes: a casing including inner space through which a to-be-treated gas containing carbon dioxide flows; a carbon dioxide adsorbing material disposed in the inner space, the carbon dioxide adsorbing material adsorbing and separating carbon dioxide from the to-be-treated gas flowing through the inner space; and a steam generator configured to generate steam in the inner space and release the steam in the inner space, the steam desorbing and capturing the carbon dioxide adsorbed to the carbon dioxide adsorbing material.

Abstract translation: 二氧化碳分离捕获装置包括：壳体，包括内部空间，待处理的含有二氧化碳的气体通过该内部空间流动; 二氧化碳吸附材料设置在内部空间中，二氧化碳吸附材料从流经内部空间的待处理气体中吸收和分离二氧化碳; 以及蒸汽发生器，其构造成在内部空间中产生蒸汽并释放内部空间中的蒸汽，蒸汽解吸和捕获吸附到二氧化碳吸附材料上的二氧化碳。