Method of producing carbon nanostructures, and carbon nanotubes

    公开(公告)号:US10294108B2

    公开(公告)日:2019-05-21

    申请号:US15992586

    申请日:2018-05-30

    申请人: ZEON CORPORATION

    发明人: Akiyoshi Shibuya

    摘要: A method of producing a carbon nanostructure is provided that enables production of a high-quality carbon nanostructure with a high yield. The method of producing a carbon nanostructure includes supplying a feedstock gas to a catalyst and growing a carbon nanostructure by chemical vapor deposition. A gas X that is derived from the feedstock gas and that comes into contact with the catalyst contains a hydrocarbon A having at least one cyclopentadiene skeleton and a hydrocarbon B having at least one acetylene skeleton. A total volume concentration [A] of the hydrocarbon A is at least 0.06%.

    COATING FILM, METHOD FOR MANUFACTURING SAME, AND PVD APPARATUS

    公开(公告)号:US20190100434A1

    公开(公告)日:2019-04-04

    申请号:US16087088

    申请日:2017-03-02

    申请人: NIPPON ITF, INC.

    摘要: Provided is a physical vapor deposition (PVD) method in which a thick, hard carbon film having excellent durability can be formed, and chipping resistance and wear resistance can bot be achieved while improving the low friction properties and peeling resistance of the formed hard carbon film. Provided is a coating film having a total film thickness of greater than 1 μm and less than or equal to 50 μm, wherein, when observed using a bright field TEM image, the cross section of the coating film is revealed to consist of relatively white hard carbon layers and relatively black hard carbon layers alternately stacked in the thickness direction, and the white hard carbon layers have a region having a columns-shape, which has grown in the thickness direction.

    Method for preparation of carbon quantum dots and application

    公开(公告)号:US10174204B2

    公开(公告)日:2019-01-08

    申请号:US15362144

    申请日:2016-11-28

    摘要: The present invention provides carbon quantum dots, preparation method and uses thereof. The preparation method of the carbon quantum dots comprises the following steps: (1) preparing a dispersion of carbon based material; (2) mixing a solution of halogenated quinone with the dispersion of carbon based material and preparing a dispersion of carbon based-halogenated quinone composite material by halogenated quinone grafting method; (3) adding a solution of H2O2 to the dispersion of carbon based-halogenated quinone composite material and carrying out reaction thereof, obtaining reaction products; (4) carrying out solid-liquid separation to the reaction products, with the resulting filtrate continuing to react, thus obtaining a dispersion of carbon quantum dots. This method adopts metal-free catalytic oxidation, the process of which is safe, convenient and low-cost, and is performed under a mild reaction condition without adding additional substances which are difficult to be separated. The obtained quantum dots have a good dispersibility and can be easily separated, also can achieve pollution treatment using pollutants. In addition, the prepared carbon quantum dots have a broad application prospect in the fields of organic pollutant degradation, electrochemical sensors, super capacitors, luminescent materials and photoelectric devices, etc.