Novel polymers for photoresist and photoresist compositions using the same
    21.
    发明申请
    Novel polymers for photoresist and photoresist compositions using the same 失效
    用于光致抗蚀剂和光致抗蚀剂组合物的新型聚合物

    公开(公告)号:US20030191259A1

    公开(公告)日:2003-10-09

    申请号:US10394606

    申请日:2003-03-21

    CPC classification number: C08F232/08 G03F7/0395

    Abstract: The present invention relates to photoresist monomers, polymers formed therefrom and photoresist compositions suitable for photolithography processes employing a DUV light source, such as KrF (249 nm) and ArF(193 nm); EUV; VUV; E-beam; ion-beam; and X-ray. Photoresist monomers of the present invention are represented by the following Chemical Formula 1: 1 wherein, m is 1 or 2. Polymers of the present invention comprise repeating units derived from the comonomer of Chemical Formula 1, preferably together with monomers of the following Chemical Formula 2: 2 wherein, R* is an acid-labile group, and l is 1 or 2.

    Abstract translation: 本发明涉及光致抗蚀剂单体,由其形成的聚合物和适用于使用DUV光源如KrF(249nm)和ArF(193nm))的光刻工艺的光致抗蚀剂组合物; EUV; VUV; 电子束 离子束 和X光片。 本发明的光致抗蚀剂单体由以下化学式1表示:其中m为1或2.本发明的聚合物包含衍生自化学式1的共聚单体的重复单元,优选与以下化学式2的单体一起 其中,R *为酸不稳定基团,l为1或2。

    Process for continuously producing polybutylene terephthalate
    26.
    发明申请
    Process for continuously producing polybutylene terephthalate 有权
    连续生产聚对苯二甲酸丁二醇酯的方法

    公开(公告)号:US20020128399A1

    公开(公告)日:2002-09-12

    申请号:US10092565

    申请日:2002-03-08

    CPC classification number: C08G63/78 C08G63/183 C08G63/785

    Abstract: Polybutylene terephthalate having good heat stability and excellent hydrolysis resistance is continuously produced in a series of a first reactor for reacting an aromatic dicarboxylic acid comprising terephthalic acid as a main ingredient or a derivative thereof with a glycol comprising 1,4-butanediol as a main ingredient, thereby producing an oligomer with an average degree of polymerization of 2.2 to 5, a second reactor for polycondensating the oligomer from the first reactor, thereby preparing a low polymerization product with an average degree of polymerization of 25 to 40, and a third reactor for further polycondensating the low polymerization product from the second reactor, thereby producing a high molecular weight polyester with an average degree of polymerization of 70 to 130, or followed by a fourth reactor for further polycondensing the polyester from the third reactor to an average degree of polymerization of 150 to 200, thereby producing a high molecular weight polyester. Another third reactor or a plurality of third reactors can be provided in parallel to the third reactor, thereby producing different kinds of polybutylene phthalate with different degrees of polymerization from that produced in the main line of the third and fourth reactors or adjusting operating conditions of each of a plurality of the third reactors to increase kinds, precise quality.

    Abstract translation: 将包含对苯二甲酸或其衍生物的芳族二羧酸与以1,4-丁二醇为主要成分的二醇反应的第一反应器中连续生产具有良好热稳定性和优异耐水解性的聚对苯二甲酸丁二醇酯 ,由此制备平均聚合度为2.2〜5的低聚物,第二反应器,其使来自第一反应器的低聚物缩聚,由此制备平均聚合度低的聚合产物为25〜40,第三反应器为 使来自第二反应器的低聚合产物进一步缩聚,从而制备平均聚合度为70至130的高分子量聚酯,或随后是用于将聚酯从第三反应器进一步缩聚至平均聚合度的第四反应器 为150〜200,由此制造高分子量聚酯。 可以与第三反应器平行地提供另外的第三反应器或多个第三反应器,从而产生与在第三和第四反应器的主管线中产生的不同聚合度的不同种类的聚对苯二甲酸丁二酯,或者调节每个反应器的操作条件 的多个第三反应堆,以增加种类,精确的质量。

    Use of NIR (Near-Infrared Spectroscopy) in composite production
    27.
    发明申请
    Use of NIR (Near-Infrared Spectroscopy) in composite production 失效
    NIR(近红外光谱)在复合生产中的应用

    公开(公告)号:US20020128398A1

    公开(公告)日:2002-09-12

    申请号:US09886947

    申请日:2001-06-21

    Applicant: ENIGMA NV

    CPC classification number: C08G12/12 C08G8/10 C08G12/32 G01N21/3577 G01N21/359

    Abstract: A method for controlling the production of formaldehyde resin compositions in which formaldehyde takes part in a reaction with one or a combination of co resin forming material (of the type phenol, urea, melamine) the method includes monitoring at least one of the formation of the reaction mixture and the course of the reaction by near-infrared (NIR) spectroscopy and adjusting the course of the reaction (when necessary) in accordance with the results of the spectroscopy to obtain optimum conditions for the reaction.

    Abstract translation: 一种用于控制甲醛与其中一种或多种树脂形成材料(酚类,尿素,三聚氰胺类型)的组合反应的甲醛树脂组合物的生产方法,包括监测至少一种形成 反应混合物和通过近红外(NIR)光谱的反应过程,并根据光谱结果调整反应过程(必要时)以获得反应的最佳条件。

    Continuous miniemulsion polymerization process
    28.
    发明申请
    Continuous miniemulsion polymerization process 失效
    连续细乳液聚合工艺

    公开(公告)号:US20040260026A1

    公开(公告)日:2004-12-23

    申请号:US10600110

    申请日:2003-06-20

    CPC classification number: C08F2/22 G03G9/0806

    Abstract: A process including: heating to a first polymerization temperature a first mixture including a free radical polymerizable monomer, a free radical initiator, and a stable free radical compound to polymerize only a portion of the monomer, resulting in a prepolymer composition; shearing a second mixture including the prepolymer composition, a continuous phase liquid, and a stabilizing compound to create a miniemulsion; and flowing the miniemulsion within a polymerization reactor and heating the miniemulsion at a second polymerization temperature to form polymeric particles wherein the formation of the polymeric particles occurs while the miniemulsion flows within the reactor.

    Abstract translation: 一种方法,包括:将第一种混合物加热至第一种聚合温度,该混合物包括可自由基聚合的单体,自由基引发剂和稳定的自由基化合物,仅聚合一部分单体,得到预聚物组合物; 剪切包含预聚物组合物,连续相液体和稳定化合物的第二混合物以产生细乳液; 并使细乳液在聚合反应器内流动并在第二聚合温度下加热细乳液以形成聚合物颗粒,其中在细乳液在反应器内流动时发生聚合物颗粒的形成。

    Polymer film comprising a propylene random copolymer
    29.
    发明申请
    Polymer film comprising a propylene random copolymer 有权
    包含丙烯无规共聚物的聚合物膜

    公开(公告)号:US20040175591A1

    公开(公告)日:2004-09-09

    申请号:US10481785

    申请日:2004-04-07

    Abstract: The present invention relates in a first embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the sealing initiation temperature SIT of the film is Tmnull30null C. or less, preferably Tmnull33null C. or less, in a second embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the film is having a relative reduction of the static friction value (inside-inside) from one to four days of 35% or more, preferably 40% or more, in a third embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the distribution of the comonomer in the random copolymer determined according to TREF method is multimodal, preferably bimodal, in a fourth embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol %, wherein the copolymer is having an elution interval of 50null C. or more, and in a fifth embodiment to a polymer film comprising a copolymer with a total comonomer content of 4.5 to 12 mol % wherein the random copolymer is a unimodal polymer and the elution interval is determined by the equationYnull4.5nullmnull16wherein Y is the elution interval in null C. and m is the percentage of ethylene in the copolymer in wt. %.

    Abstract translation: 本发明在第一实施方式中涉及包含总共聚单体含量为4.5〜12摩尔%的丙烯无规共聚物的聚合物膜,其中,所述膜的密封起始温度SIT为Tm-30℃以下,优选为Tm- 33℃以下,在第二实施方式中,为包含总共聚单体含量为4.5〜12摩尔%的丙烯无规共聚物的聚合物膜,其中,膜的静摩擦值(内部)与 在第三个实施方案中,一至四天为35%以上,优选为40%以上,其中共聚单体含量为4.5〜12摩尔%,其中共聚单体在无规共聚物中的分布 根据TREF方法确定的是多峰,优选双峰,在第四个实施方案中,包括总共聚单体含量为4.5-12mol%的丙烯无规共聚物的聚合物膜,其中共聚物具有洗脱 间隔为50℃以上,在第五实施方式中为包含总共聚单体含量为4.5〜12摩尔%的共聚物的聚合物膜,其中无规共聚物为单峰聚合物,洗脱间隔由式Y <= 4.5.m + 16其中Y是以℃计的洗脱间隔,m是共聚物中乙烯的百分比。 %。

    Method of preparing a polymer under predetermined temperature conditions, and apparatus therefor
    30.
    发明申请
    Method of preparing a polymer under predetermined temperature conditions, and apparatus therefor 有权
    在预定温度条件下制备聚合物的方法及其装置

    公开(公告)号:US20040167297A1

    公开(公告)日:2004-08-26

    申请号:US10373361

    申请日:2003-02-24

    Abstract: A method of preparing a polymer under predetermined temperature conditions comprises conducting the polymerization within a closed reaction chamber configured such that most or all of an inner surface has heat exchange capability. The chamber's dimensions are such that the polymerization mixture contacts the effective heat exchange surface sufficiently to ensure that the temperature throughout the polymerization mixture does not vary more than a few degrees from a desired temperature. In one embodiment the chamber is formed of two adjacent, parallel heat exchange plates, wherein at least one plate has a peripheral lip which, in contact with the opposing plate, forms the closed chamber. Multiple plates can be arrayed to form multiple chambers, and each chamber's polymerization temperature, as well as resident polymerization mixture, can be individually predetermined. This method and apparatus are particularly useful for preparing polymers used in drag reducing agents for hydrocarbon transportation pipeline applications, as well as other polymers benefiting from narrow and/or customized temperature profiles during production.

    Abstract translation: 在预定温度条件下制备聚合物的方法包括在封闭的反应室内进行聚合,所述封闭的反应室配置为使得内表面的大部分或全部具有热交换能力。 室的尺寸使得聚合混合物充分接触有效的热交换表面,以确保整个聚合混合物中的温度与期望的温度不相差几度。 在一个实施例中,室由两个相邻的平行热交换板形成,其中至少一个板具有与相对板接触形成封闭室的周缘。 可以排列多个板以形成多个室,并且每个室的聚合温度以及驻留聚合混合物可以单独地预定。 该方法和装置特别适用于制备用于烃输送管线应用的减阻剂中使用的聚合物,以及在生产期间受益于窄和/或定制温度曲线的其它聚合物。

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