公开(公告)号：US6132595A

公开(公告)日：2000-10-17

申请号：US274560

申请日：1999-03-23

申请人： Paula L. Bogdan ,  Qianjun Chen

发明人： Paula L. Bogdan ,  Qianjun Chen

IPC分类号： B01J29/068 ,  B01J35/00 ,  C10G35/095 ,  C10G35/09

CPC分类号： B01J29/62 ,  B01J29/068 ,  B01J35/0006 ,  C10G35/095 ,  B01J21/12 ,  B01J35/0073

摘要： A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is effected using a catalyst containing a uniformly distributed platinum-group metal component, a surface-layer metal component comprising one or more of the Group IVA metals, indium, Group VIIB (IUPAC 7) metals, iron, zinc, gold and bismuth and a nonacidic large-pore molecular sieve. The use of this bed of catalyst results in greater selectivity of conversion of paraffins to aromatics and in improved catalyst stability.

摘要翻译： 使用含有均匀分布的铂族金属组分的催化剂，包含一种或多种IVA族金属的表面金属组分，即铟，ⅦB族（IUPAC）的催化剂来实现选择性地将烷烃脱氢环化到芳族化合物的重整过程 7）金属，铁，锌，金，铋和非酸性大孔分子筛。 使用这种催化剂床导致链烷烃转化为芳族化合物和提高催化剂稳定性的更大选择性。

公开(公告)号：US6048449A

公开(公告)日：2000-04-11

申请号：US177345

申请日：1998-10-23

申请人： Paula L. Bogdan ,  Tamotsu Imai

发明人： Paula L. Bogdan ,  Tamotsu Imai

IPC分类号： B01J23/62 ,  B01J37/02 ,  C10G35/09 ,  C10G35/06

CPC分类号： B01J23/622 ,  B01J37/0201 ,  C10G35/09

摘要： A novel catalyst and the use thereof in a reforming process is disclosed. The dual-function catalyst comprises a refractory inorganic oxide, indium, Group IVA(IUPAC 14) metal, and a platinum-group metal concentrated in the surface layer of each catalyst particle. Utilization of this catalyst in the conversion of hydrocarbons, especially in reforming, results in significantly improved selectivity to the desired gasoline or aromatics product.

摘要翻译： 公开了一种新型催化剂及其在重整过程中的应用。 双功能催化剂包括耐火无机氧化物，铟，IVA族（IUPAC 14）金属和浓缩在每个催化剂颗粒的表面层中的铂族金属。 这种催化剂在烃的转化中的应用，特别是在重整过程中，导致对所需汽油或芳烃产物的显着提高的选择性。

公开(公告)号：US6045689A

公开(公告)日：2000-04-04

申请号：US973402

申请日：1997-12-15

申请人： Fabio Alario ,  Jean-Marie Deves ,  Patrick Euzen

发明人： Fabio Alario ,  Jean-Marie Deves ,  Patrick Euzen

IPC分类号： B01J23/56 ,  B01J23/63 ,  B01J23/64 ,  B01J27/13 ,  B01J27/135 ,  C10G35/09 ,  C10G35/06 ,  C10G35/085

CPC分类号： C10G35/09 ,  B01J23/56 ,  B01J23/63 ,  B01J27/13

摘要： A process for converting hydrocarbons into aromatic compounds, which entails contacting a composition containing hydrocarbons with a catalyst under temperature and pressure conditions to produce the aromatic compounds, the catalyst containing a matrix of .eta. transition alumina and/or .gamma. transition alumina. The catalyst contains 0.001 to 2 wt % of silicon, 0.1 to 15 wt % of at least one platinum group metal, and 0.005 to 10 wt % of at least one promoter metal. The promoter metals may be tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese, chromium, molybdenium or tungsten. The catalyst may also contain a doping metal.

摘要翻译： PCT No.PCT / FR96 / 00919 Sec。 371 1997年12月15日第 102（e）日期1997年12月15日PCT Filted 1996年6月14日PCT公布。 出版物WO97 / 00306 日期1997年1月3日一种将烃转化为芳族化合物的方法，其需要在温度和压力条件下使含烃的组合物与催化剂接触以产生芳族化合物，所述催化剂含有等离子体氧化铝和/或γ过渡氧化铝 。 催化剂含有0.001〜2重量％的硅，0.1〜15重量％的至少一种铂族金属和0.005〜10重量％的至少一种助催化剂金属。 助催化剂金属可以是锡，锗，铟，镓，铊，锑，铅，铼，锰，铬，钼或钨。 催化剂也可以含有掺杂金属。

公开(公告)号：US5858908A

公开(公告)日：1999-01-12

申请号：US840562

申请日：1997-04-17

申请人： Paula L. Bogdan ,  Tamotsu Imai

发明人： Paula L. Bogdan ,  Tamotsu Imai

IPC分类号： B01J23/62 ,  B01J35/00 ,  B01J37/02 ,  C10G35/09 ,  B01J27/06 ,  B01J27/125 ,  B01J27/13 ,  B01J27/135

CPC分类号： B01J37/0201 ,  B01J23/62 ,  B01J35/0006 ,  C10G35/09

摘要： A novel catalyst and the use thereof in a reforming process is disclosed. The dual-function catalyst comprises a refractory inorganic oxide, indium, Group IVA(IUPAC 14) metal, and a platinum-group metal concentrated in the surface layer of each catalyst particle. Utilization of this catalyst in the conversion of hydrocarbons, especially in reforming, results in significantly improved selectivity to the desired gasoline or aromatics product.

摘要翻译： 公开了一种新型催化剂及其在重整过程中的应用。 双功能催化剂包括耐火无机氧化物，铟，IVA族（IUPAC 14）金属和浓缩在每个催化剂颗粒的表面层中的铂族金属。 这种催化剂在烃的转化中的应用，特别是在重整过程中，导致对所需汽油或芳烃产物的显着提高的选择性。

公开(公告)号：US5461016A

公开(公告)日：1995-10-24

申请号：US291641

申请日：1994-08-17

申请人： Steven A. Bradley ,  Leonid B. Galperin

发明人： Steven A. Bradley ,  Leonid B. Galperin

IPC分类号： B01J29/63 ,  C10G35/09 ,  C10G35/095 ,  B01J29/068

CPC分类号： B01J29/63 ,  B01J29/61 ,  C10G35/095

摘要： Reforming selective for the dehydrocyclization of paraffins to aromatics, is effected using a catalyst containing a platinum-group metal, a nonacidic large-pore molecular sieve, and a metal modifier which is positioned on the catalyst to be extrinsic to the pores of the molecular sieve. The use of this catalyst results in greater selectivity converting paraffins to aromatics and improved catalyst stability particularly when processing feedstocks containing small amounts of sulfur compounds.

摘要翻译： 使用含有铂族金属，非酸性大孔分子筛和金属改性剂的催化剂对烷烃的脱氢环化进行芳族化合物的选择性改性，该催化剂位于催化剂上，对于分子筛的孔隙是外在的 。 使用该催化剂导致更有选择性的将烷烃转化为芳族化合物和改进的催化剂稳定性，特别是当加工含少量硫化合物的原料时。

公开(公告)号：US5453558A

公开(公告)日：1995-09-26

申请号：US270443

申请日：1994-07-05

申请人： Bruce D. Alexander ,  George A. Huff, Jr.

发明人： Bruce D. Alexander ,  George A. Huff, Jr.

IPC分类号： B01J29/62 ,  C07C5/333 ,  C10G35/09 ,  C10G35/095

CPC分类号： C10G35/095 ,  B01J29/62 ,  C07C5/3337 ,  B01J2229/26 ,  B01J2229/42

摘要： A process and catalyst are provided for dehydrogenating a hydrocarbon feedstock and producing an olefinic product. The process comprises contacting the feedstock at dehydrogenation conditions with a dehydrogenation catalyst comprising from about 0.01 weight percent to about 5.0 weight percent of a platinum group metal, from about 0.02 weight percent to about 10.0 weight percent of zinc, and a support component comprising L zeolite and an alkali metal.

摘要翻译： 提供了一种用于使烃原料脱氢和生产烯烃产物的方法和催化剂。 该方法包括在脱氢条件下使原料与脱氢催化剂接触，所述脱氢催化剂包含约0.01重量％至约5.0重量％的铂族金属，约0.02重量％至约10.0重量％的锌，以及包含L沸石 和碱金属。

公开(公告)号：US5395513A

公开(公告)日：1995-03-07

申请号：US106690

申请日：1993-08-16

申请人： Arthur A. Chin ,  Mohsen N. Harandi ,  Karen M. Millane ,  Robert A. Ware ,  James S. Warwick

发明人： Arthur A. Chin ,  Mohsen N. Harandi ,  Karen M. Millane ,  Robert A. Ware ,  James S. Warwick

IPC分类号： C10G35/09 ,  C10G35/095

CPC分类号： C10G35/09

摘要： A continuous process for upgrading reformate feedstock or the like to reduce benzene content and increase octane fuel rating. The improved process comprises maintaining a fluidized bed of regenerable acid solid medium pore zeolite catalyst particles in a turbulent regime reaction zone, preferably maintained with a superficial gas velocity of 0.1 to 1 meter/sec. with reformate feedstock being introduced at a bottom portion of the reaction zone at a weight hourly space velocity (WHSV) of 0.1 to 5, based on active catalyst solids; reaction zone total pressure being less than 2000 kPa. The preferred catalyst particles have an average particle size of 20 to 100 microns (.mu.), with about 10 to 25% of the catalyst particles comprising fine particles having a particle size less than 30 microns; and the preferred zeolite catalyst comprises shape selective medium pore aluminosilicate zeolite having a constraint index of 1 to 12. The benzene is reacted by contacting reformate feedstock, such as C.sub.6 distillation heart cut containing at least 70 wt % compounds having six carbon atoms, including benzene, n-hexane and isohexane, with said catalyst particles at reaction temperature of 370.degree. to 540.degree. C. and at benzene partial pressure of at least 200 kPa under reformate conversion conditions sufficient to convert at least 40% of feedstock benzene per pass, thereby producing a high octane fuel product containing less than 10 wt % C.sub.10.sup.+ components.

摘要翻译： 用于升级重整原料等以降低苯含量和提高辛烷值的连续方法。 改进的方法包括将可再生酸固体中孔沸石催化剂颗粒的流化床保持在湍流状态反应区，优选以0.1至1米/秒的表观气体速度保持。 其中重整原料以基于活性催化剂固体的0.1至5的重时空速（WHSV）引入反应区的底部; 反应区总压力小于2000 kPa。 优选的催化剂颗粒具有20至100微米（μm）的平均粒度，约10至25％的催化剂颗粒包含粒径小于30微米的细颗粒; 并且优选的沸石催化剂包括具有1至12约束指数的形状选择性中孔硅铝酸盐沸石。苯通过使重整油原料接触而反应，例如含有至少70重量％的具有6个碳原子的化合物的C6蒸馏心切，包括苯 正己烷和异己烷，所述催化剂颗粒在370〜540℃的反应温度和至少200kPa的苯分压下，在重整转化条件下，足以每道次转化至少40％的原料苯，由此 产生含有少于10重量％的C10 +组分的高辛烷值燃料产物。

公开(公告)号：US5254518A

公开(公告)日：1993-10-19

申请号：US916759

申请日：1992-07-22

申请人： Stuart L. Soled ,  Gary B. McVicker ,  William E. Gates ,  Sabato Miseo

发明人： Stuart L. Soled ,  Gary B. McVicker ,  William E. Gates ,  Sabato Miseo

IPC分类号： B01J21/12 ,  B01J23/10 ,  B01J23/62 ,  B01J23/63 ,  B01J23/656 ,  C10G35/09 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G45/64 ,  B01J23/12 ,  B01J23/16

CPC分类号： B01J23/10 ,  B01J23/626 ,  B01J23/63 ,  B01J23/6567 ,  C10G35/09

摘要： By this invention there is provided a catalyst composition comprising a Group IVB oxide, an amorphous silica-alumina support having dispersed thereon a rare earth oxide, which as herein used also includes yttrium oxide, and a metal(s) selected from the group consisting of Group VIII noble metal(s), mixtures of Group VIII noble metal(s) and tin, mixtures of Group VIII noble metal(s) and rhenium, and mixtures of Group VIII noble metal(s), tin and rhenium. The amorphous silica-alumina support contains at least about 50% silica by weight. The catalyst can function as a hydrocarbon conversion catalyst in reactions where platinum on halided (Cl,F)-alumina is typically used.

公开(公告)号：US5106809A

公开(公告)日：1992-04-21

申请号：US627528

申请日：1990-12-14

申请人： William C. Baird, Jr. ,  George A. Swan, III ,  Joseph P. Boyle

发明人： William C. Baird, Jr. ,  George A. Swan, III ,  Joseph P. Boyle

IPC分类号： B01J23/62 ,  C10G35/09

CPC分类号： C10G35/09 ,  B01J23/626

摘要： Tin modified platinum-iridium catalysts provide high yields of C.sub.5 + liquid reformate in catalytic reforming, concurrent with high activity. In particular, the tin modified platinum-iridium catalysts are of unusually high selectivity, as contrasted with known iridium promoted platinum catalysts. The high selectivity is manifested in reforming a naphtha feed in a reactor charged to capacity with the catalyst, but particularly when used in the dehydrocyclization zone, or tail reactor of a series of reactors, while the lead reactors of the series contain a non tin-containing platinum catalyst, especially a platinum-iridium, or a platinum-rhenium catalyst. The tin modified platinum-iridium catalysts are also highly active, with only moderate loss in the high activity for which iridium stabilized platinum catalysts are known.

公开(公告)号：US4966880A

公开(公告)日：1990-10-30

申请号：US375656

申请日：1989-07-03

申请人： William C. Baird, Jr. ,  Kenneth L. Riley ,  George A. Swan, III

发明人： William C. Baird, Jr. ,  Kenneth L. Riley ,  George A. Swan, III

IPC分类号： B01J23/62 ,  C10G35/09

CPC分类号： B01J23/626 ,  C10G35/09

摘要： A catalyst for reforming gasoline boiling range naphthas which catalysts are comprised of Pt and Sn on alumina and a modifier comprised of about 100 to 500 wppm Si and at least 10 wppm of one or more alkaline earth metals selected from Ca, Mg, Ba, and Sr wherein the total amount of modifier does not exceed about 5000 wppm.

摘要翻译： 一种用于重整汽油沸点石脑油的催化剂，其催化剂由氧化铝上的Pt和Sn组成，改性剂由约100至500wppm的Si和至少10wppm的一种或多种选自Ca，Mg，Ba和 Sr，其中改性剂的总量不超过约5000wppm。