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公开(公告)号：US07456130B2
公开(公告)日：2008-11-25
申请号：US11697471
申请日：2007-04-06
CPC分类号： C10G35/09 , B01J23/6567 , B01J35/0093 , B01J37/0009 , B01J37/0207 , B01J37/24 , C10G35/085
摘要： A process for preparing a naphtha reforming catalyst has been developed. The process involves the use of a chelating ligand such as ethylenediaminetetraacetic acid (EDTA). The aqueous solution of the chelating ligand and a tin compound is used to impregnate a support, e.g., alumina extrudates. A platinum-group metal is also an essential component of the catalyst. Rhenium may also be a component. A reforming process using the catalyst has enhanced yield, activity, and stability for conversion of naphtha into valuable gasoline and aromatic products.
摘要翻译： 已经开发了制备石脑油重整催化剂的方法。 该方法包括使用螯合配体如乙二胺四乙酸（EDTA）。 螯合配体和锡化合物的水溶液用于浸渍载体，例如氧化铝挤出物。 铂族金属也是催化剂的重要组成部分。 铼也可以是组分。 使用该催化剂的重整方法具有提高的石脑油转化成贵重汽油和芳香族产物的产率，活性和稳定性。
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2.发明授权High-stability catalyst containing a platinum group metal and nickel on zeolite L and a binder 失效在沸石L和粘合剂上含有铂族金属和镍的高稳定性催化剂
公开(公告)号：US5461016A
公开(公告)日：1995-10-24
申请号：US291641
申请日：1994-08-17
IPC分类号： B01J29/63 , C10G35/09 , C10G35/095 , B01J29/068
CPC分类号： B01J29/63 , B01J29/61 , C10G35/095
摘要： Reforming selective for the dehydrocyclization of paraffins to aromatics, is effected using a catalyst containing a platinum-group metal, a nonacidic large-pore molecular sieve, and a metal modifier which is positioned on the catalyst to be extrinsic to the pores of the molecular sieve. The use of this catalyst results in greater selectivity converting paraffins to aromatics and improved catalyst stability particularly when processing feedstocks containing small amounts of sulfur compounds.
摘要翻译： 使用含有铂族金属，非酸性大孔分子筛和金属改性剂的催化剂对烷烃的脱氢环化进行芳族化合物的选择性改性，该催化剂位于催化剂上，对于分子筛的孔隙是外在的 。 使用该催化剂导致更有选择性的将烷烃转化为芳族化合物和改进的催化剂稳定性，特别是当加工含少量硫化合物的原料时。
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公开(公告)号：US07037871B1
公开(公告)日：2006-05-02
申请号：US09990252
申请日：2001-11-21
CPC分类号： C10G35/095 , B01J29/62 , B01J29/90 , B01J38/12
摘要： A process is disclosed for regenerating a hydrocarbon conversion catalyst comprising zeolite L with ozone. The catalyst is contacted with ozone at a temperature of from about 20 to about 250° C. and a concentration of ozone of from about 0.1 to about 5 mol-%. The catalyst may contain coke. The process at least partially restores the activity of the catalyst. The process is particularly useful for reforming and dehydrocyclodimerization catalysts.
摘要翻译： 公开了一种用于再生包含沸石L与臭氧的烃转化催化剂的方法。 催化剂在约20至约250℃的温度和约0.1至约5mol％的臭氧浓度下与臭氧接触。 催化剂可能含有焦炭。 该方法至少部分还原催化剂的活性。 该方法对于重整和脱氢环化二聚催化剂特别有用。
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4.发明授权Process for producing phenyl-alkanes using olefin isomerization and paraffin recycle 有权使用烯烃异构化和石蜡回收生产苯基烷烃的方法公开(公告)号：US06670516B1
公开(公告)日：2003-12-30
申请号：US10327281
申请日：2002-12-20
IPC分类号： C07C266
CPC分类号： C07C5/2775 , C07C2/66 , C07C5/3335 , C07C2529/85 , C07C11/02
摘要： A process for producing phenyl-alkanes by paraffin dehydrogenation followed by olefin isomerization and then by alkylation of a phenyl compound by a lightly branched olefin is disclosed. An effluent of the alkylation section comprises paraffins that are recycled to the dehydrogenation step. A process that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups to produce modified alkylbenzene sulfonates is also disclosed. In addition, the compositions produced by these processes, which can comprise detergents, lubricants, and lubricant additives, are disclosed.
摘要翻译： 公开了通过链烷烃脱氢然后烯烃异构化然后通过轻支化烯烃烷基化苯基化合物生产苯基烷烃的方法。 烷基化部分的流出物包含再循环到脱氢步骤的链烷烃。 还公开了具有轻支化脂族烷基的苯基烷烃磺化以生产改性烷基苯磺酸盐的方法。 此外，公开了通过这些方法制备的组合物，其可以包含洗涤剂，润滑剂和润滑剂添加剂。
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5.发明授权Arylalkane compositions produced by isomerization, dehydrogenation, and alkylation 有权通过异构化，脱氢和烷基化生产的芳基烯烃组合物公开(公告)号：US06448458B1
公开(公告)日：2002-09-10
申请号：US09705859
申请日：2000-11-03
IPC分类号： C07C1500
CPC分类号： C07C15/107 , C07C2529/18 , C07C2529/70 , C10M105/06 , C10M2203/06
摘要： The present invention is a process for producing aryl-alkanes by paraffin isomerization followed by paraffin dehydrogenation and then by alkylation of an aryl compound by a lightly branched olefin. The effluent of the alkylation zone comprises paraffins that are recycled to the isomerization step or to the dehydrogenation step. This invention is also a process that that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过石蜡异构化，然后进行链烷烃脱氢，然后通过轻支化烯烃烷基化芳基化合物来制备芳基烷烃的方法。 烷基化区的流出物包括再循环到异构化步骤或脱氢步骤的链烷烃。 本发明也是一种方法，即磺酸化具有轻支化脂族烷基的苯基烷烃，以生产改性烷基苯磺酸盐。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
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6.发明授权Process for producing arylalkanes and arylalkane sulfonates, compositions produced therefrom, and uses thereof 有权制备芳基烷烃和芳基链烷烃磺酸盐的方法，由其制备的组合物及其用途公开(公告)号：US06187981B1
公开(公告)日：2001-02-13
申请号：US09356574
申请日：1999-07-19
IPC分类号： C07C266
CPC分类号： C07C15/107 , C07C2529/18 , C07C2529/70 , C10M105/06 , C10M2203/06
摘要： The present invention is a process for producing aryl-alkanes by paraffin isomerization followed by paraffin dehydrogenation and then by alkylation of an aryl compound by a lightly branched olefin. The effluent of the alkylation zone comprises paraffins that are recycled to the isomerization step or to the dehydrogenation step. This invention is also a process that that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过石蜡异构化，然后进行链烷烃脱氢，然后通过轻支化烯烃烷基化芳基化合物来制备芳基烷烃的方法。 烷基化区的流出物包括再循环到异构化步骤或脱氢步骤的链烷烃。 本发明也是一种方法，即磺酸化具有轻支化脂族烷基的苯基烷烃，以生产改性烷基苯磺酸盐。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
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公开(公告)号：US5954948A
公开(公告)日：1999-09-21
申请号：US203869
申请日：1998-12-02
申请人： Leonid B. Galperin
发明人： Leonid B. Galperin
CPC分类号： B01J31/1616 , B01J31/183 , B01J2231/52 , B01J2531/025 , B01J2531/824 , B01J2531/845 , B01J2531/847
摘要： Hydrocarbon conversion processes are described which use a sulfur tolerant catalyst system. The catalyst is tolerant to large amounts (about 30,000 ppm sulfur) in the feedstream and comprises a first component which comprises at least one Group VIII metal dispersed on an inorganic oxide support and a second component comprising a metal phthalocyanine dispersed on an inorganic oxide support. Preferred Group VIII metals are platinum and palladium, while preferred metal phthalocyanines are cobalt or nickel phthalocyanine. Preferred inorganic oxide supports are molecular sieves, aluminas and mixtures thereof. Processes which can be carried out using this catalyst system include reforming, hydrocracking, dehydrogenation and isomerization.
摘要翻译： 描述了使用耐硫催化剂体系的烃转化方法。 催化剂在进料流中耐受大量（约30,000ppm硫），并且包含第一组分，其包含分散在无机氧化物载体上的至少一种Ⅷ族金属和包含分散在无机氧化物载体上的金属酞菁的第二组分。 优选的VIII族金属是铂和钯，而优选的金属酞菁是钴或镍酞菁。 优选的无机氧化物载体是分子筛，氧化铝及其混合物。 可以使用该催化剂体系进行的方法包括重整，加氢裂化，脱氢和异构化。
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公开(公告)号：US5440034A
公开(公告)日：1995-08-08
申请号：US174093
申请日：1993-12-28
IPC分类号： C07D295/023 , C07D223/04
CPC分类号： C07D295/023
摘要： Propylamines are dehydrocyclized by non-acidic molecular sieves containing a Group VIII zerovalent metal to afford azacycloheptanes with good selectivity. The molecular sieves show less than 5% activity in a standard heptene-1 isomerization test. Performing the reaction in the presence of hydrogen and/or ammonia often is beneficial.
摘要翻译： 丙胺通过含有VIII族零价金属的非酸性分子筛脱氢环化，得到具有良好选择性的氮杂环庚烷。 分子筛在标准庚烯-1异构化试验中显示出小于5％的活性。 在氢气和/或氨存在下进行反应往往是有益的。
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9.发明申请CATALYST FOR SELECTIVE OPENING OF CYCLIC NAPHTHA AND PROCESS FOR USING THE CATALYST 审中-公开催化剂用于选择性地打开循环硫酸盐和使用催化剂的方法公开(公告)号：US20080249346A1
公开(公告)日：2008-10-09
申请号：US12141967
申请日：2008-06-19
IPC分类号： C07C4/08
CPC分类号： B01J23/40 , B01J29/06 , B01J29/70 , B01J29/74 , B01J29/78 , B01J29/85 , B01J35/0006 , B01J35/002 , B01J37/0009 , B01J37/0201 , B01J2229/20 , B01J2229/42 , C07C5/31 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/12 , C07C2523/02 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2529/70 , C07C2529/84 , C07C2529/85 , C10G45/64 , Y10S423/30 , C07C9/15
摘要： A catalyst and process for opening aliphatic cyclic hydrocarbons have been developed. The catalyst comprises a catalytic metal component, a molecular sieve and refractory inorganic oxide component. The molecular sieve is selected from the group consisting of MAPSOs, SAPOs, UZM-8, UZM-8HS, UZM-15, UZM-15HS, UZM-16, UZM-16HS and mixtures thereof. Preferred catalytic metals include platinum, palladium and rhodium. The catalyst may also contain a modifier such as niobium, titanium, or rare earth metals.
摘要翻译： 已经开发了用于开启脂肪族环烃的催化剂和方法。 催化剂包括催化金属组分，分子筛和耐火无机氧化物组分。 分子筛选自MAPSO，SAPO，UZM-8，UZM-8HS，UZM-15，UZM-15HS，UZM-16，UZM-16HS及其混合物。 优选的催化金属包括铂，钯和铑。 催化剂还可以含有诸如铌，钛或稀土金属的改性剂。
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10.发明授权Dual functional catalyst for selective opening of cyclic paraffins and process for using the catalyst 有权用于选择性打开环状链烷烃的双官能催化剂和使用催化剂的方法公开(公告)号：US07407907B2
公开(公告)日：2008-08-05
申请号：US11467189
申请日：2006-08-25
申请人： Leonid B. Galperin , Irina Galperin, legal representative , Michael J. McCall , Joseph A. Kocal
发明人： Leonid B. Galperin , Irina Galperin, legal representative , Michael J. McCall , Joseph A. Kocal
CPC分类号： B01J23/42 , B01J21/00 , B01J23/40 , B01J23/60 , B01J23/62 , B01J23/63 , B01J23/648 , B01J23/6484 , B01J23/656 , B01J23/6567 , B01J27/00 , B01J27/182 , B01J29/04 , B01J29/06 , B01J29/70 , B01J29/84 , B01J35/00 , B01J35/0006 , B01J37/00 , B01J37/0072 , C07C5/31 , C07C2529/85 , C07C9/00
摘要： A catalyst for selectively opening cyclic paraffins has been developed. The catalyst comprises a Group VIII metal, such as platinum, a modifier component, such as niobium or ytterbium, a molecular sieve, such as UZM-16 and a refractory inorganic oxide such as alumina. The Group VIII metal and modifier component are preferably deposited on the refractory inorganic oxide. A process for using the catalyst is also disclosed.
摘要翻译： 已经开发了用于选择性打开环状链烷烃的催化剂。 该催化剂包括Ⅷ族金属如铂，改性剂组分如铌或镱，分子筛如UZM-16和耐火无机氧化物如氧化铝。 优选将VIII族金属和改性剂组分沉积在耐火无机氧化物上。 还公开了使用催化剂的方法。
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