公开(公告)号：US4071546A

公开(公告)日：1978-01-31

申请号：US719015

申请日：1976-08-30

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: B01J45/00 ,  C07F7/18 ,  C07F7/10

CPC classification number: B01J45/00 ,  B01J20/3259 ,  C07F7/1836

Abstract: New organosiloxane chelating compositions comprising a siliceous support and an organosiloxane chelating agent bonded to its surface are disclosed. A new method for preparing the composition comprises contacting the siliceous support with a solution of an organosiloxane comprising units of the formula ##STR1## AND OPTIONALLY, UNITS OF THE FORMULA ##STR2## R is --CH.sub.2 COOH or --CH.sub.2 COO.sup.- M.sup.+ ; M.sup.+ is an alkali metal ion, m = 0 or 1, a = 0 or 1, b = 1 or 2, (m.multidot.a) + b is at least 2 and Z is a monovalent hydrocarbon radical having 1 to 6 inclusive carbon atoms.

Abstract translation: 公开了包含硅质载体和与其表面结合的有机硅氧烷螯合剂的新的有机硅氧烷螯合组合物。 用于制备组合物的新方法包括使硅质载体与包含下式的单元的有机硅氧烷的溶液接触，并且可选地，本发明单元R是-CH 2 COOH或-CH 2 COO-M +; M +是碱金属离子，m = 0或1，a = 0或1，b = 1或2，（mxa）+ b为至少2，Z为含有1至6个碳原子的一价烃基。

公开(公告)号：US3955036A

公开(公告)日：1976-05-04

申请号：US417017

申请日：1973-11-19

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C08K5/544 ,  C09J123/00 ,  B32B15/08 ,  B32B17/10 ,  B32B25/08

CPC classification number: B32B17/10 ,  B32B25/16 ,  B32B7/12 ,  C08K5/544 ,  C09J123/00 ,  Y10T428/31511 ,  Y10T428/3154 ,  Y10T428/31612 ,  Y10T428/31627 ,  Y10T428/31641 ,  Y10T428/31645 ,  Y10T428/31649 ,  Y10T428/31688 ,  Y10T428/31692 ,  Y10T428/31696 ,  Y10T428/31699 ,  Y10T428/31844 ,  Y10T428/31877 ,  Y10T428/31917 ,  Y10T428/3192 ,  Y10T428/31924 ,  Y10T428/31928 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

Abstract: Adhesion of thermoplastic elastomers, such as unvulcanized styrene-butadiene rubber, to a solid substrate is obtained by using a primer containing a tackifier component, such as hydrogenated rosin or a coumarone-indene resin, and an amino-functional trihydrolyzable silane, partial condensates and hydrochloride salts thereof in which the amino-functionality is in the form of a primary or secondary amine.

公开(公告)号：US5051129A

公开(公告)日：1991-09-24

申请号：US543981

申请日：1990-06-25

Applicant: Robert L. Cuthbert ,  Edwin P. Plueddemann

Inventor： Robert L. Cuthbert ,  Edwin P. Plueddemann

IPC: C04B41/49 ,  C04B41/64 ,  C09D4/00 ,  C09D183/04 ,  C09K3/18

CPC classification number: C04B41/009 ,  C04B41/4944 ,  C04B41/64 ,  C09D4/00 ,  C04B2111/27 ,  Y10T428/31663 ,  Y10T428/4935

Abstract: A masonry water repellent composition for treating surfaces which is an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane. The alkyltrialkoxysilane is either an alkyltrialkoxysilanes with C.sub.1 to C.sub.6 alkyl groups on silicon or a blend of alkyltrialkoxysilanes each with C.sub.1 to C.sub.6 alkyl groups on silicon. A treatment method is also disclosed.

Abstract translation: 一种用于处理作为水溶性硅烷偶联剂和烷基三烷氧基硅烷的水溶液的表面的砖石防水组合物。 烷基三烷氧基硅烷是在硅上具有C1至C6烷基的烷基三烷氧基硅烷或在硅上各自具有C1至C6烷基的烷基三烷氧基硅烷的共混物。 还公开了一种治疗方法。

公开(公告)号：US5002831A

公开(公告)日：1991-03-26

申请号：US356153

申请日：1989-05-24

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C07F7/18 ,  C08K5/5455

CPC classification number: C07F7/1836 ,  C08K5/5455 ,  Y10T428/31612 ,  Y10T428/31663

Abstract: Novel ionomeric silane coupling agents are disclosed and their use in bonding a matrix polymer to a mineral substrate is described. The coupling agents comprise amic acid-functional silanes which are partially neutralized with metal cations and are prepared by reacting a mixture of (I) an amine-functional silane, (II) a stoichiometric excess of a dicarboxylic organic acid and (III) an ionic compound containing a metal cation, wherein 10% to 80% of the excess carboxylic acid functionality is neutralized by the metal cations. The coupling agents greatly improve bonding to the matrix polymer in moist environments and are particularly suitable for use in formulating filled injection molding compositions.

Abstract translation: 公开了新的离聚物硅烷偶联剂，并描述了它们将基质聚合物粘合到矿物基质中的用途。 偶联剂包括用金属阳离子部分中和的酰胺酸官能的硅烷，并且通过使（I）胺官能的硅烷，（II）化学计量过量的二羧酸有机酸和（III）的离子 含有金属阳离子的化合物，其中10％至80％的过量羧酸官能团被金属阳离子中和。 偶联剂极大地改善了在潮湿环境中与基质聚合物的粘结，并且特别适用于配制填充的注塑组合物。

公开(公告)号：US4933327A

公开(公告)日：1990-06-12

申请号：US341890

申请日：1989-04-24

Applicant: Edwin P. Plueddemann ,  Anthony Revis

Inventor： Edwin P. Plueddemann ,  Anthony Revis

IPC: A01N55/00 ,  A01N55/10 ,  C07F7/18

CPC classification number: A01N55/00 ,  C07F7/1836

Abstract: Organosilicon quaternary ammonium antimicrobial compounds are described, particularly, ammonium chloride derivatives of multifunctional diamino quaternary salts, and salts containing a combination of amino, ester, and fluoroalkyl, functionality.

Abstract translation: 有机硅季铵抗微生物化合物特别描述了多官能二氨基季铵盐的氯化铵衍生物和含有氨基，酯和氟烷基的组合的官能团的盐。

公开(公告)号：US4849294A

公开(公告)日：1989-07-18

申请号：US216061

申请日：1988-06-20

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C08K5/092 ,  C08K5/544 ,  C08K9/06

CPC classification number: C08K9/06 ,  C08K5/092 ,  C08K5/544 ,  Y10T428/31667

Abstract: Compositions which are particularly useful as coupling agents and primers for polyolefin composites. The compositions comprise fumaric acid and diaminefunctional silanes in mole ratios from 1.0 to 1.4 in nonreactive solvent, particularly water. These compositions are particularly effective in polyethylene composite materials.

Abstract translation: 作为聚烯烃复合材料的偶联剂和底漆特别有用的组合物。 组合物包含在非反应性溶剂，特别是水中的摩尔比为1.0至1.4的富马酸和二官能硅烷。 这些组合物在聚乙烯复合材料中特别有效。

公开(公告)号：US4818779A

公开(公告)日：1989-04-04

申请号：US125438

申请日：1987-11-25

Applicant: Gerald L. Witucki ,  Edwin P. Plueddemann

Inventor： Gerald L. Witucki ,  Edwin P. Plueddemann

IPC: B27N3/00 ,  C08K5/5419 ,  C08K5/544 ,  C08L31/04 ,  C09J131/04 ,  C08K5/54

CPC classification number: C08K5/544 ,  C09J131/04 ,  Y10T428/31663 ,  Y10T428/3179 ,  Y10T428/31895 ,  Y10T428/31906

Abstract: The present invention relates to water-borne emulsion adhesives based on polymers or copolymers of vinyl acetate and having uniformly dispersed therein an adhesion promoter consisting essentially of an alkoxysilane and up to about 80% by weight of a plasticizer for the poly(vinyl acetate). The alkoxysilane useful herein may be selected from ##STR1## in which R is independently selected from alkyl or alkoxyalkyl radicals having 1-4 carbon atoms. The modified adhesives have improved bond strength to wood, particularly after exposure to moisture.

公开(公告)号：US4800125A

公开(公告)日：1989-01-24

申请号：US88917

申请日：1987-08-24

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C07F7/18 ,  C08K5/5455 ,  B05D3/02 ,  B32B9/04

CPC classification number: C07F7/1836 ,  C08K5/5455 ,  Y10T428/2995 ,  Y10T428/31612 ,  Y10T428/31663

Abstract: A coupling agent composition comprised of the reaction product of (a) about two mole parts of maleic anhydride with (b) about one mole part of a diamine functional silane compound of the general formula ##STR1## where R denotes an alkyl radical, R' denotes an alkyl radical, R" and R'" denote alkylene radicals and x is 0 to 1; and (c) sufficient solvent to solubilize (a) and (b).

Abstract translation: 由（a）约2摩尔份马来酸酐与（b）约1摩尔通式为“IMAGE”的二胺官能化硅烷化合物的反应产物组成的偶联剂组合物，其中R表示烷基，R' 表示烷基，R“和R”“表示亚烷基，x为0至1; 和（c）足够的溶剂以溶解（a）和（b）。

公开(公告)号：US4690959A

公开(公告)日：1987-09-01

申请号：US861384

申请日：1986-05-09

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C08L23/02 ,  C03C25/10 ,  C03C27/12 ,  C08J5/08 ,  C08J5/12 ,  C08J7/04 ,  C08K3/00 ,  C08K5/092 ,  C08K5/544 ,  C08K9/06 ,  C08K13/02 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C09C3/12 ,  C09J5/02 ,  C08K3/40 ,  C08K5/54

CPC classification number: C08K5/092 ,  C08K5/544 ,  C08K9/06 ,  Y10T428/31663

Abstract: Compositions which are particularly useful as coupling agents and primers for polyolefin composites. The compositions comprise fumaric acid and diaminefunctional silanes in mole ratios from 1.0 to 1.4 in nonreactive solvent, particularly water. These compositions are particularly effective in polyethylene composite materials.

Abstract translation: 作为聚烯烃复合材料的偶联剂和底漆特别有用的组合物。 组合物包含在非反应性溶剂，特别是水中的摩尔比为1.0至1.4的富马酸和二官能硅烷。 这些组合物在聚乙烯复合材料中特别有效。

公开(公告)号：US4617057A

公开(公告)日：1986-10-14

申请号：US741642

申请日：1985-06-04

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: C09D5/00 ,  C09D7/12 ,  C09D109/08 ,  C09D123/08 ,  C09D183/04 ,  C09D201/00 ,  C09K3/18 ,  D06M15/263 ,  D06M15/333 ,  D06M15/643 ,  D06M15/693

CPC classification number: C09D109/08 ,  C09D123/08 ,  C09D183/04 ,  C09D7/1233 ,  C09K3/18 ,  D06M15/263 ,  D06M15/333 ,  D06M15/6436 ,  D06M15/693 ,  C08K5/02 ,  C08K5/5442

Abstract: An oil and water repellent coating composition is disclosed. The composition comprises a blend of an aminoorganosilane, a perfluorinated organic compound and a resin selected from the group consisting of colloidal inorganic-based siloxane resin, poly (dialkylsiloxane)-monoorgano substituted silsesquioxane block copolymer, acrylic polymer and copolymer, ethylene-vinyl acetate latex and styrene-butadiene latex. The silane and perfluorinated organic, combined, constitute from 0.1% to 10% by weight of the total resin solids in a solution or suspension of the blend. A method of coating a smooth substrate or treating a fabric to render the respective surface oleophobic and hydrophobic is further disclosed.

Abstract translation: 公开了一种防油和防水涂料组合物。 该组合物包含氨基有机硅烷，全氟化有机化合物和选自胶体无机基硅氧烷树脂，聚（二烷基硅氧烷） - 单有机取代倍半硅氧烷嵌段共聚物，丙烯酸聚合物和共聚物，乙烯 - 醋酸乙烯酯胶乳 和苯乙烯 - 丁二烯胶乳。 硅烷和全氟化有机物的组合占混合物溶液或悬浮液中树脂固体总重量的0.1％至10％。 进一步公开了涂覆光滑底物或处理织物以使各自表面疏油和疏水的方法。