Low-temperature-curable, solid polyurethane powder coating compositions containing uretdione groups
    39.
    发明授权
    Low-temperature-curable, solid polyurethane powder coating compositions containing uretdione groups 失效
    含有脲二酮基团的低温可固化的固体聚氨酯粉末涂料组合物

    公开(公告)号:US06914115B2

    公开(公告)日:2005-07-05

    申请号:US10305137

    申请日:2002-11-27

    Abstract: Polyurethane powder coating compositions containing uretdione groups and curing at low temperatures are provided, along with processes for preparing such compositions, and their use as powder coatings, wherein the compositions generally contain: A) a uretdione-containing powder coating hardener derived from aliphatic, (cyclo)aliphatic, cycloaliphatic or aromatic polyisocyanates and hydroxyl-containing compounds, and having a melting point from 40 to 130° C., a free NCO content of less than 5% by weight, and a uretdione content of 6-18% by weight; B) a hydroxyl-containing polymer having a melting point from 40 to 130° C., and an OH number between 20 and 200 mg KOH/gram, and C) a catalyst of the formula [NR1R2R3R4]+[R5]−, in which R1-R4 simultaneously, or independently of one another, are alkyl, aryl, aralkyl, heteroaryl or alkoxyalkyl radicals, and each R1-R4 is aromatic, linear or branched, unbridged or bridged with other radicals, R1-R4.

    Abstract translation: 提供含有脲二酮基团并在低温下固化的聚氨酯粉末涂料组合物及其制备方法,以及它们作为粉末涂料的用途,其中组合物通常包含:A)衍生自脂肪族的含脲二酮的粉末涂料固化剂,( 环)脂族,脂环族或芳族多异氰酸酯和含羟基化合物,熔点为40至130℃,游离NCO含量小于5重量%,脲二酮含量为6-18重量% ; B)具有40-130℃的熔点和20-200mg KOH /克的OH值的含羟基的聚合物,和C)式[NR 1]的催化剂, R 2 O 3 R 4 S 4 O 3 R 4 R 4 O 3 其中R 1〜R 4同时或彼此独立地是烷基,芳基,芳烷基,杂芳基或烷氧基烷基,并且每个R R 4是具有其它基团的芳族,直链或支链,未桥连或桥连的,其中R 1,R 2,R 4, >。

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