公开(公告)号：US4784727A

公开(公告)日：1988-11-15

申请号：US459314

申请日：1983-01-20

Applicant: Wolf-Dieter Schroer ,  Joachim Probst ,  Ingeborg Kolb ,  Ulrich Beck ,  Peter Mummenhoff ,  Heinz Baumgen

Inventor： Wolf-Dieter Schroer ,  Joachim Probst ,  Ingeborg Kolb ,  Ulrich Beck ,  Peter Mummenhoff ,  Heinz Baumgen

IPC: D21H17/08 ,  D21H17/15 ,  D21H17/17 ,  D21H17/35 ,  D21H17/36 ,  D21H17/37 ,  D21H17/45 ,  D21H3/02

CPC classification number: D21H17/08 ,  D21H17/15 ,  D21H17/17 ,  D21H17/35 ,  D21H17/36 ,  D21H17/37 ,  D21H17/455

Abstract: A sizing agent which contains from 1 to 60 parts, by weight, of a fixing and sizing accelerating agent and from 0 to 80 parts, by weight, of conventional auxiliaries per 10 parts by weight of hydrophobic, cellulose-reactive sizing materials, the fixing and sizing accelerating agent being a polymer composed of linear or branched carbon chains, to which primary, secondary or tertiary amino and/or quaternary ammonium groups are bound directly or by side chains exhibits a thorough and rapid sizing effect, in particular in the better sizing of paper.

Abstract translation: 一种施胶剂，其含有1至60重量份的定影和施胶促进剂和0至80重量份的常规助剂，每10重量份疏水性纤维素反应性施胶材料，固定 和作为由直链或支链碳链构成的聚合物的定型促进剂，其中伯，仲或叔氨基和/或季铵基团直接或由侧链结合，表现出彻底和快速的施胶效果，特别是在更好的施胶 的纸。

公开(公告)号：US4659431A

公开(公告)日：1987-04-21

申请号：US691991

申请日：1985-01-16

Applicant: Joachim Probst ,  Ulrich Beck ,  Heinz Baumgen

Inventor： Joachim Probst ,  Ulrich Beck ,  Heinz Baumgen

IPC: C08F2/00 ,  C08F2/24 ,  C08F2/28 ,  C08F212/00 ,  C08F212/08 ,  C08F220/00 ,  C08F220/10 ,  C08F220/12 ,  C08F257/02 ,  D21H17/35 ,  D21H17/37 ,  D21H17/45 ,  D21H19/20 ,  D21H21/16 ,  D21H3/38

CPC classification number: C08F257/02 ,  C08F2/24 ,  C08F212/08 ,  D21H17/35 ,  D21H17/37 ,  D21H17/455 ,  D21H21/16

Abstract: New, highly effective cationic sizing agents for paper have been provided. They can be obtained by a method in which a water-soluble cationic chemically pure terpolymer compound consisting of(a) 7-40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate,(b) 40-80% by weight of styrene and(c) 4-40% by weight of acrylonitrileis dissolved in an aqueous medium, the sum of the components (a) to (c) always being 100% by weight and at least 10% of the N,N-dimethylamino groups of the terpolymer being quaternized and the remainder being protonated, and, in the presence of 10 to 70% by weight, relative to the monomer mixture below, of this emulsifier,(d) 0 to 90% by weight of acrylonitrile and/or methacrylonitrile,(e) 5 to 95% by weight of styrene and(f) 5 to 95% by weight of acrylates and/or methacrylates having 1 to 12 C atoms in the alcohol radical,the sum of the components (d) to (f) always being 100% by weight, are emulsified, and the emulsion thus obtained is subjected to free radical-initiated emulsion polymerization at temperatures from 20.degree. to 150.degree. C.

Abstract translation: 已经提供了用于纸的新的高效阳离子上胶剂。 它们可以通过以下方法获得：其中由（a）7-40重量％的丙烯酸N，N-二甲基氨基乙酯和/或甲基丙烯酸酯组成的水溶性阳离子化学纯三元共聚物，（b）40-80重量％ 的苯乙烯和（c）4-40重量％的丙烯腈溶解在水性介质中，组分（a）至（c）的总和总是为100重量％，并且至少10重量％的N， 三元共聚物的二甲基氨基被季铵化，其余部分被质子化，并且在该乳化剂相对于单体混合物的10至70重量％的存在下，（d）0至90重量％的丙烯腈和/ 或甲基丙烯腈，（e）5至95重量％的苯乙烯和（f）5至95重量％的醇基中具有1至12个碳原子的丙烯酸酯和/或甲基丙烯酸酯，组分（d）至 （f）总是为100重量％，乳化，得到的乳液在20D的温度下进行自由基引发的乳液聚合 EG至150℃

公开(公告)号：US4481319A

公开(公告)日：1984-11-06

申请号：US410906

申请日：1982-08-24

Applicant: Gunter Sackmann ,  Gunter Kolb ,  Joachim Probst ,  Friedhelm Muller ,  Heinz Baumgen

Inventor： Gunter Sackmann ,  Gunter Kolb ,  Joachim Probst ,  Friedhelm Muller ,  Heinz Baumgen

IPC: C08F8/32 ,  D21H17/35 ,  D21H17/43 ,  D21H17/45 ,  C08K5/21 ,  C08K5/05

CPC classification number: D21H17/45 ,  C08F8/32 ,  D21H17/35 ,  D21H17/43

Abstract: Low-foam surface sizing agents for paper in the form of aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers containing carboxylic acid semi-amide groups obtainable by reacting copolymers of maleic acid anhydride and diisobutylene and/or terpolymers of maleic acid anhydride, diisobutylene and a vinyl monomer copolymerizing with maleic acid anhydride, with from 5 to 50 mole percent, based on maleic acid anhydride groups, of a primary aliphatic or aromatic monoamine. The solutions may optionally contain urea or derivatives of urea.

Abstract translation: 水性或水性醇碱金属形式的纸的低泡表面施胶剂，含有羧酸半酰胺基团的共聚物的胺或铵盐溶液，可通过马来酸酐和二异丁烯的共聚物和/或马来酸三元共聚物 与马来酸酐共聚的酸酐，二异丁烯和乙烯基单体，基于马来酸酐基团的5-50摩尔％的伯脂肪族或芳族单胺。 溶液可以任选地含有脲或尿素衍生物。

公开(公告)号：US07005470B2

公开(公告)日：2006-02-28

申请号：US10393588

申请日：2003-03-21

Applicant: Joachim Probst ,  Martin Melchiors ,  Gerhard Ruttmann ,  Thomas Stingl ,  Hartmut Ottensmann

Inventor： Joachim Probst ,  Martin Melchiors ,  Gerhard Ruttmann ,  Thomas Stingl ,  Hartmut Ottensmann

IPC: C08J3/00 ,  C08K3/20 ,  C08L75/00 ,  B05D3/00 ,  B32B27/00

CPC classification number: C09D175/04 ,  C04B41/4884 ,  C08F257/02 ,  C08F265/04 ,  C08G18/632 ,  C08G18/706 ,  C08G18/7837 ,  C08G18/792 ,  C08L51/003 ,  Y10T428/31551 ,  C08L2666/14

Abstract: The invention relates to aqueous two-component polyurethane systems comprising vinyl polymer polyol dispersions modified with reactive diluents, to a process for preparing them and to use as coating materials.

Abstract translation: 本发明涉及包含用反应性稀释剂改性的乙烯基聚合物多元醇分散体的水性双组分聚氨酯体系，其制备方法和用作涂料。

公开(公告)号：US06590028B1

公开(公告)日：2003-07-08

申请号：US09868207

申请日：2001-06-13

Applicant: Joachim Probst ,  Ulrich Biskup ,  Claus Kobusch ,  Christoph Irle

Inventor： Joachim Probst ,  Ulrich Biskup ,  Claus Kobusch ,  Christoph Irle

IPC: C08J300

CPC classification number: C08G18/6254 ,  C08F265/06 ,  C08G18/283 ,  C08G18/633 ,  C08G18/792 ,  C09D175/04

Abstract: The invention relates to aqueous two-component polyurethane systems, a process for their production, and their use for the production of coatings having increased impact strength, high stability properties and outstanding optical properties.

Abstract translation: 本发明涉及水性双组分聚氨酯体系，其生产方法及其用于生产具有增加的冲击强度，高稳定性和优异的光学性能的涂料。

公开(公告)号：US06583215B2

公开(公告)日：2003-06-24

申请号：US09944447

申请日：2001-08-30

Applicant: Joachim Probst ,  Erhard Lühmann ,  Horst Clemens ,  Wolfgang Kremer ,  Jürgen Meixner ,  Hans-Josef Laas

Inventor： Joachim Probst ,  Erhard Lühmann ,  Horst Clemens ,  Wolfgang Kremer ,  Jürgen Meixner ,  Hans-Josef Laas

IPC: C08J300

CPC classification number: B01D47/00 ,  B08B3/024 ,  B08B3/026 ,  B08B2203/0229 ,  B44D3/16 ,  C08G18/4063 ,  C08G18/6254 ,  C08G18/706 ,  C09D175/04 ,  E04G23/00 ,  Y10T428/31551

Abstract: The invention relates to an aqueous 2-component polyurethane (PU) coating composition comprising a vinyl polymer polyol dispersion, having a hydroxyl number between 10 and 264 mg KOH/g solid resin, an acid value (calculated from the sum of neutralized and non-neutralized acid groups) between 0 and 55 mg KOH/g solid resin, a number-average molecular weight Mn of at least 5000 g/mol and a weight average molecular weight Mw of at least 30,000 g/mol, a glass transition temperature of at least 20° C. and an average particle diameter of no greater than 300 nm, which is prepared in the presence of 0.1 to 10.0 wt. %, relative to the sum of the solids contents of polymer polyol and polyisocyanate, of a non-ionic polyether surfactant and a polyisocyanate having a viscosity at 23° C. of no more than 12,000 mPa*s and either a non-hydrophilic or a non-ionically or anionically hydrophilic character, whereby the equivalent ratio of isocyanate groups of component b) to hydroxyl groups of component a) is 0.2:1 to 5:1; a process for the preparation of such aqueous 2-component coating compositions, and their use as 2-component PU paints for painting any type of substrate.

公开(公告)号：US06479106B2

公开(公告)日：2002-11-12

申请号：US10008427

申请日：2001-11-13

Applicant: Burkhard Köhler ,  Beate Baumbach ,  Christian Füssel ,  Joachim Probst

Inventor： Burkhard Köhler ,  Beate Baumbach ,  Christian Füssel ,  Joachim Probst

IPC: B05D302

CPC classification number: C09D175/04 ,  C08G18/10 ,  C08G18/6212 ,  Y10T428/31551 ,  Y10T428/8305 ,  C08G18/341

Abstract: The present invention relates to coated substrates obtained by stoving mixtures containing A) 1 part by weight of ester group-free polyols having an OH content of 1 to 10%, B) 0.05 to 1 part by weight of oxalic acid and C) 0.2 to 5 parts by weight of organic solvents, at temperatures of 120° C. to 250° C. and a stoving time of 1 to 100 min on substrates. The present invention also relates to a process for preparing the coated substrates.

Abstract translation: 本发明涉及通过将含有A）1重量份的OH含量为1至10％的无酯基的多元醇，B）0.05-1重量份草酸和C）0.2至5重量份的混合物 的有机溶剂，在120℃至250℃的温度下和在基材上1至100分钟的烘烤时间。 本发明还涉及一种制备涂覆的基材的方法。

公开(公告)号：US06386841B1

公开(公告)日：2002-05-14

申请号：US09473487

申请日：1999-12-28

Applicant: Joachim Probst

Inventor： Joachim Probst

IPC: F04B1700

CPC classification number: F04B9/1276 ,  F01L23/00 ,  F04B9/1256 ,  F04B9/133 ,  F04B9/14

Abstract: A pneumatically operated hydraulic pump includes a cylinder housing accommodating a main piston to subdivide the housing interior in two working chambers. The main piston is connected to a hydraulic piston for joint reciprocation so that the hydraulic piston can carry out a suction stroke when the main piston moves to one end position and a pressure stroke when the main piston moves to the other end position. Arranged laterally to the cylinder housing is a control mechanism for regulating a flow of working fluid alternately to the working chambers. The control mechanism includes a plastic valve casing for accommodating a control piston having opposite end faces of different size to define different effective areas and thereby realize reciprocation of the control piston by the working fluid. A slide shoe is guided in the valve casing for conjoint movement with the control piston. A displacement of the main piston into the two end positions actuates respective pilot valves which regulate the reciprocation of the control piston and the slide shoe to thereby move the main piston between the end positions which discharging working fluid via the deflection zone in the slide shoe to the atmosphere.

Abstract translation: 气动液压泵包括容纳主活塞的气缸壳体，以将壳体内部细分成两个工作室。 主活塞连接到液压活塞用于联合往复运动，使得当主活塞移动到一个终端位置时，液压活塞可以执行吸入冲程，并且当主活塞移动到另一端位置时，液压活塞可以执行吸入冲程。 与气缸壳体侧向排列的是用于将工作流体的流动交替地调节到工作室的控制机构。 该控制机构包括：用于容纳具有不同尺寸的相对端面的控制活塞的塑料阀壳体，以限定不同的有效区域，从而实现控制活塞由工作流体往复运动。 滑阀在阀壳体中被引导以与控制活塞一起运动。 主活塞进入两个端部位置的位移致动相应的先导阀，其调节控制活塞和滑靴的往复运动，从而使主活塞在通过滑靴中的偏转区域将工作流体排出到工作流体的端部位置之间移动到 气氛。

公开(公告)号：US06376602B1

公开(公告)日：2002-04-23

申请号：US08432560

申请日：1995-05-01

Applicant: Joachim Probst ,  Werner Kubitza ,  Rolf Roschu ,  Hans Josef Laas

Inventor： Joachim Probst ,  Werner Kubitza ,  Rolf Roschu ,  Hans Josef Laas

IPC: C08J300

CPC classification number: C08G18/6245 ,  C08G18/0819 ,  C08G18/283 ,  C08G18/6229 ,  C08G18/706 ,  C08G18/8064

Abstract: The present invention relates to water-borne coating compositions wherein the binder contains a mixture of a) a polyol component dispersed in water or a water/solvent mixture which contains at least one polymer prepared from olefinically unsaturated monomers and having a molecular weight (Mn) of at least 500, at least two alcoholic hydroxyl groups per molecule, a hydroxyl value of 15 to 250 mg KOH/g, an acid value of 0 to 7 mg KOH/g and a total content of sulfonate and carboxylate groups of 0 to 4.5 milliquivalents per 100 g of solid resin and b) a polyisocyanate component which is emulsified in the dispersion of polyol component a), has a viscosity at 23° C. of 50 to 10,000 mPa.s and an average NCO functionality of 1.8 to 4.2, and contains 12.0 to 21.5% by weight of (cyclo)aliphatically bound isocyanate groups and, optionally, 2 to 20% by weight of ethylene oxide units present within polyether chains, the polyether chains containing a statistical average of 5 to 70 ethylene oxide units, wherein the components are present in quantities corresponding to an equivalent ratio of isocyanate groups of component b) to alcoholic hydroxyl groups of component a) of 0.2:1 to 5:1. The present invention also relates to a process for the production of these coating compositions and to coated water-resistant substrates prepared from these coating compositions.

Abstract translation: 本发明涉及水性涂料组合物，其中粘合剂含有分散在水中的多元醇组分或含有至少一种由烯属不饱和单体制备的聚合物的水/溶剂混合物的混合物，其分子量（Mn）为 每分子至少500个，至少两个醇羟基，羟基值为15-250mg KOH / g，酸值为0-7mg KOH / g，磺酸盐和羧酸酯基团的总含量为0-4.5毫克 每100g固体树脂和b）在多元醇组分a）的分散体中乳化的多异氰酸酯组分，其在23℃下的粘度为50至10,000mPa.s，平均NCO官能度为1.8至4.2，并且包含 12.0至21.5重量％的（环）脂族结合的异氰酸酯基团和任选地2至20重量％存在于聚醚链内的环氧乙烷单元，所述聚醚链含有5-70个环氧乙烷单元的统计平均值 其中组分以对应于组分b）的异氰酸酯基团与组分a）的醇羟基的当量比为0.2:1至5:1存在。 本发明还涉及制备这些涂料组合物的方法和由这些涂料组合物制备的涂覆的耐水基材。

公开(公告)号：US06319981B1

公开(公告)日：2001-11-20

申请号：US08211698

申请日：1994-04-13

Applicant: Rolf Dhein ,  Knud Reuter ,  Lothar Bäcker ,  Joachim Probst ,  Werner Kubitza ,  Rainer Rettig

Inventor： Rolf Dhein ,  Knud Reuter ,  Lothar Bäcker ,  Joachim Probst ,  Werner Kubitza ,  Rainer Rettig

IPC: C08K320

CPC classification number: C08G18/706 ,  C08G18/0823 ,  C08G18/4063 ,  C08G18/4263 ,  C08G18/4288 ,  C08G18/7831

Abstract: The present invention relates to coating compounds of which the binder consists essentially of a combination of a) a polyol component dissolved and/or dispersed in water or a water/solvent mixture, and b) a polyisocyanate component emulsified in the solution and/or dispersion of the polyol component with a viscosity at 23° C. of 50 to 10,000 mPa.s, in quantities corresponding to an equivalent ratio of isocyanate groups of component a) to alcoholic hydroxyl groups of component b) of 0.5:1 to 5:1, characterized in that component consists essentially of a1) a water-dilutable, hydroxyfunctional polycondensate resin free from urethane and sulfonate groups and having a molecular weight Mn above 500 or a2) a mixture of such a polycondensation resin with up to 100% by weight, based on the weight of the polycondensation resin, of at least one water-dilutable, hydroxyfunctional polymerization resin having a molecular weight Mn above 500. The present invention also relates to a process for the preparation of these coating compounds and to their use for the production of coatings.

Abstract translation: 本发明涉及涂料化合物，其粘合剂基本上由以下组合组成：a）溶解和/或分散在水中的多元醇组分或水/溶剂混合物，和b）在溶液和/或分散体中乳化的多异氰酸酯组分 多元醇组分，其在23℃下的粘度为50至10,000mPa.s，其量对应于组分a）的异氰酸酯基团与组分b）的醇羟基的当量比为0.5:1至5:1，其特征在于 该组分基本上由以下组分组成：a）不含氨基甲酸酯基和磺酸酯基团并具有分子量Mn在500以上的水可稀释的羟基官能团的缩聚物树脂2）这种缩聚树脂与至多100重量％的混合物，基于重量 的缩聚树脂，其至少一种分子量Mn高于500的水可稀释的羟基官能聚合树脂。本发明还涉及制备方法 这些涂料化合物及其用于生产涂料的用途。