Cationic sizing agents for paper
    2.
    发明授权
    Cationic sizing agents for paper 失效
    阳离子上胶剂纸

    公开(公告)号:US4418175A

    公开(公告)日:1983-11-29

    申请号:US329721

    申请日:1981-12-11

    摘要: The aqueous solution of a statistical terpolymer containing quaternized amino groups and having a regular chemical structure of(a) from 8 to 20%, by weight, of N,N-dimethylaminoethyl acrylate and/or N,N-dimethylaminoethyl methacrylate;(b) from 45 to 80%, by weight, of styrene; and(c) from 8 to 35%, by weight, of acrylonitrile;the sum of (a) to (c) being 100%, by weight, and at least 10% of the dimethylamino groups of the terpolymer being quaternized and the remainder protonated is suitable as cationic paper sizing agent.

    摘要翻译: 具有季铵化氨基的统计三元共聚物的水溶液,其具有规则的化学结构(a)8至20重量%的丙烯酸N,N-二甲基氨基乙酯和/或甲基丙烯酸N,N-二甲基氨基乙酯; (b)45〜80重量%的苯乙烯; 和(c)8至35重量%的丙烯腈; (a)至(c)的总和为100重量%,并且至少10%的三元共聚物的二甲基氨基被季铵化,其余被质子化适合作为阳离子纸上胶剂。

    Production of copolymer powders from maleic anhydride and 1-olefins
    3.
    发明授权
    Production of copolymer powders from maleic anhydride and 1-olefins 失效
    从马来酸酐和1-烯烃制备共聚物粉末

    公开(公告)号:US4048422A

    公开(公告)日:1977-09-13

    申请号:US647502

    申请日:1976-01-08

    摘要: An improved process for the production of powders of maleic acid anhydride/1-olefin copolymers by suspension polymerization in the presence of special dispersion agents which are obtained by the reaction of a copolymer of maleic acid anhydride and a 1-olefin with an aliphatic monohydric alcohol or an aliphatic monoamine or a mixture thereof, at least 30 mol % of the anhydride groups being esterified to semi-esters or amidated to semi-amides. The copolymer powders obtained have a surprisingly narrowparticle size distribution and can be used without grinding or sifting as reactive fillers for natural and synthetic rubbers. They also can be used for the production of paper coating agents as they dissolve easily and without residue in alkalis, ammonia or amines.

    摘要翻译: 在马来酸酐与1-烯烃的共聚物与脂族一元醇反应得到的特殊分散剂存在下,通过悬浮聚合制备马来酸酐/ 1-烯烃共聚物粉末的改进方法 或脂族单胺或其混合物,至少30mol%的酸酐基团被酯化成半酯或半酰胺化。 获得的共聚物粉末具有令人惊讶的窄粒度分布,并且可以在不用作天然和合成橡胶的反应性填料的研磨或筛分下使用。 它们也可用于生产纸张涂层剂,因为它们容易溶解,在碱,氨或胺中没有残留物。

    Process for the production of a substantially equimolecular copolymer of
maleic acid anhydride and diisobutylene
    4.
    发明授权
    Process for the production of a substantially equimolecular copolymer of maleic acid anhydride and diisobutylene 失效
    用于生产马来酸酐和二异丁烯基本上等摩尔分子共聚物的方法

    公开(公告)号:US4151336A

    公开(公告)日:1979-04-24

    申请号:US869043

    申请日:1978-01-13

    摘要: An improved process for the production of a substantially equimolecular copolymer of maleic acid anhydride and diisobutylene in which from 10 to 100 mole % of the anhydride groups are esterified with linear or branched aliphatic monoalcohols containing from 1 to 20 carbon atoms or with cycloaliphatic monoalcohols containing from 5 to 6 carbon atoms to form the corresponding semiesters, wherein shortly before or after the end of the solution or suspension copolymerization of maleic acid anhydride and diisobutylene a monomer corresponding to the general formula ##STR1## in which R=H, CH.sub.3, C.sub.2 H.sub.5, --OR.sub.2, --O--CO--CH.sub.3, ##STR2## --CH.sub.2 OH, --CH.sub.2 O--C--CH.sub.3, R.sub.1 =H , CH.sub.3 andR.sub.2 =a linear or branched alkyl group containing from 1 to 4 carbon atoms,Or mixtures of these monomers with one another are added to the polymerization mixture in quantities of from 1 to 12 mole %, based on the maleic acid anhydride used. The aqueous or aqueous-alcoholic alkali, amine or ammonium salt solutions of the semiesters of the copolymer are highly effective as anionic sizing agents for paper.

    摘要翻译: 用于生产马来酸酐和二异丁烯的基本上等分子的共聚物的改进方法,其中10至100摩尔%的酸酐基团被含有1至20个碳原子的直链或支链脂族一元醇或含有1至20个碳原子的脂环族一元醇酯化 5至6个碳原子以形成相应的半分子,其中在马来酸酐和二异丁烯的溶液或悬浮液共聚之前或之后不久,对应于通式为“IMAGE”的单体,其中R = H,CH 3,C 2 H 5, -OR 2,-O-CO-CH 3, -CH 2 OH,-CH 2 O-C-CH 3,R 1 = H,CH 3和R 2 =含有1至4个碳原子的直链或支链烷基,或这些单体的混合物 另有一种添加到1至12%MOES%的聚合物混合物中,基于所用的非水性非离子表面活性剂。 共聚物的半酯的水性或水性醇碱性,胺或铵盐溶液作为纸张的阴离子施胶剂是非常有效的。

    Polyamines containing urea groups
    8.
    发明授权
    Polyamines containing urea groups 失效
    含尿素的聚胺

    公开(公告)号:US4348514A

    公开(公告)日:1982-09-07

    申请号:US156832

    申请日:1980-06-05

    CPC分类号: D21H17/56 C08G73/0206

    摘要: Non-crosslinking, water-soluble polyamines which can be obtained by reacting(A) basic polyureas which have been prepared by condensation of ureas with polyamines containing at least three amino groups, of which at least one is a tertiary amino group, or with mixtures of these polyamines with aliphatic, araliphatic, cycloaliphatic or heterocyclic polyamines containing two primary or two secondary amino groups or one primary or one secondary amino group, and optionally with .omega.-aminocarboxylic acids containing at least three carbon atoms, or lactams thereof,(B) polyalkylenepolyamines of the general formula ##STR1## in which R denotes H or CH.sub.3, the indices y are in each case identical or different and denote the number 0 or 1 andx denotes a number from 4 to 2,500,or mixtures of these polyalkylenepolyamines with amines of the same general formula, but in whichx denotes a number from 1 to 3, and(C) compounds which are polyfunctional towards amino groups, are used as agents for increasing the retention of fibres, fillers and pigments, for accelerating the drainage in the production of paper and for working up effluents from paper machines by filtration, sedimentation and flotation.

    摘要翻译: 非交联性水溶性多胺,其可以通过使(A)通过脲与缩醛反应制备的碱性聚脲与至少三个氨基的多胺(其中至少一个是叔氨基)或与混合物 这些多胺与含有两个伯或仲仲氨基或一个伯或仲仲氨基以及任选含有至少三个碳原子的ω-氨基羧酸或其内酰胺的脂族,芳脂族,脂环族或杂环多胺,(B) 通式为“IMAGE”的聚亚烷基多胺,其中R表示H或CH 3,指数y在各自的情况下相同或不同,表示数字0或1,x表示4至2,500的数,或这些聚亚烷基多胺与胺的混合物 具有相同的通式,但其中x表示1至3的数,和(C)对于氨基具有多官能性的化合物,用作增加剂 考虑到纤维,填料和颜料的保留,用于加速纸张生产中的排水和通过过滤,沉淀和浮选处理造纸机的废水。

    Chlorination of polyolefins in the presence of complex formers
    9.
    发明授权
    Chlorination of polyolefins in the presence of complex formers 失效
    在复合成型剂存在下氯化聚烯烃

    公开(公告)号:US4165431A

    公开(公告)日:1979-08-21

    申请号:US881675

    申请日:1978-02-27

    IPC分类号: C08F8/00 C08F8/20 C08F8/22

    CPC分类号: C08F8/22

    摘要: A chlorinated colorless polyolefin, preferably a chlorinated colorless isotactic polypropylene, soluble in carbon tetrachloride and having a chlorine content of from 60% to 70% by weight and an average degree of polymerization of from 2000 to 6000, produced by chlorinating polyolefins having a degree of polymerization of from 2000 to 20,000 in suspension or solution or in suspension and solution at 40 to 60.degree. C. in the presence of a halogen transfer agent, a chlorination catalyst and from 0.2 to 0.5% by weight, based on polyolefin, of at least one compound corresponding to the general Formula (I):h.sub.2 n--r--nh>.sub.n H (I)in which R represents the ethylene, propylene or butylene group and n=1-6.

    摘要翻译: 氯化无色聚烯烃,优选氯化无色全同立构聚丙烯,其可溶于四氯化碳,氯含量为60〜70重量%,平均聚合度为2000〜6000,通过氯化具有一定程度的聚烯烃 在卤素转移剂,氯化催化剂和基于聚烯烃的0.2至0.5重量%的存在下,在悬浮液或溶液中或悬浮液和溶液中在40至60℃下聚合2000至20,000,至少 对应于通式(I)的一种化合物:

    Polyamines containing urea groups prepared from lactam or
aminocarboxylic acid
    10.
    发明授权
    Polyamines containing urea groups prepared from lactam or aminocarboxylic acid 失效
    含有由内酰胺或氨基羧酸制备的尿素基团的多胺

    公开(公告)号:US4384110A

    公开(公告)日:1983-05-17

    申请号:US358406

    申请日:1982-03-15

    CPC分类号: D21H17/56 C08G73/0206

    摘要: Non-crosslinking, water-soluble polyamines which can be obtained by reacting(A) basic polyureas which have been prepared by condensation of ureas with polyamines containing at least three amino groups, of which at least one is a tertiary amino group, or with mixtures of these polyamines with aliphatic, araliphatic, cycloaliphatic or heterocyclic polyamines containing two primary or two secondary amino groups or one primary or one secondary amino group, and optionally with .omega.-aminocarboxylic acids containing at least three carbon atoms, or lactams thereof,(B) polyalkylenepolyamines of the general formula ##STR1## in which R denotes H or CH.sub.3,the indices y are in each case identical or different and denote the number 0 or 1 andx denotes a number from 4 to 2,500, or mixtures of these polyalkylenepolyamines with amines of the same general formula, but in whichx denotes a number from 1 to 3, and(C) compounds which are polyfunctional towards amino groups, are used as agents for increasing the retention of fibres, fillers and pigments, for accelerating the drainage in the production of paper and for working up effluents from paper machines by filtration, sedimentation and flotation.

    摘要翻译: 非交联性水溶性多胺,其可以通过使(A)通过脲与缩醛反应制备的碱性聚脲与至少三个氨基的多胺(其中至少一个是叔氨基)或与混合物 这些多胺与含有两个伯或仲仲氨基或一个伯或仲仲氨基以及任选含有至少三个碳原子的ω-氨基羧酸或其内酰胺的脂族,芳脂族,脂环族或杂环多胺,(B) 通式为“IMAGE”的聚亚烷基多胺,其中R表示H或CH 3,指数y在各自的情况下相同或不同,表示数字0或1,x表示4至2,500的数,或这些聚亚烷基多胺与胺的混合物 具有相同的通式,但其中x表示1至3的数,和(C)对于氨基具有多官能性的化合物,用作增加剂 考虑到纤维,填料和颜料的保留,用于加速纸张生产中的排水和通过过滤,沉淀和浮选处理造纸机的废水。