公开(公告)号：US5350646A

公开(公告)日：1994-09-27

申请号：US945639

申请日：1992-11-06

申请人： Michel Armand ,  Jean-Yves Sanchez ,  Daniel Deroo

发明人： Michel Armand ,  Jean-Yves Sanchez ,  Daniel Deroo

IPC分类号： C08K5/00 ,  C08G75/32 ,  C08G79/02 ,  C08L71/02 ,  H01B1/06 ,  H01B1/12 ,  H01M6/16 ,  H01M6/18 ,  H01M10/40

CPC分类号： H01M6/166 ,  C08G75/32 ,  C08G79/025 ,  H01B1/122 ,  H01M6/181

摘要： The present invention relates to ionically conductive polymeric materials, to their preparation and to their use as a solid electrolyte. The materials comprise a solid solution of one or more salts in a polymer and are characterized in that the transport and the mobility of a metal cation M.sup.n+ which has the valency n, 1.ltoreq.n.ltoreq.5, are provided by at least one complex anion, corresponding to the general formula [MZ.sub.n Y.sub.p ].sup.p- formed between an anionic ligand Z.sup.-, an anionic ligand Y.sup.- and the cation M.sup.n+, with 1.ltoreq.p.ltoreq.3. Application to the formation of electrochemical generators and of electrochemical systems which make it possible to affect the transmission of light.

摘要翻译： PCT No.PCT / FR92 / 00198 Sec。 371日期：1992年11月6日 102（e）日期1992年11月6日PCT 1992年3月4日PCT公布。 出版物WO92 / 日本1992年9月17日。本发明涉及离子导电聚合物材料，其制备方法及其作为固体电解质的用途。 这些材料包括聚合物中一种或多种盐的固溶体，其特征在于具有化合价n 1，n = 5的金属阳离子Mn +的迁移率和迁移率至少由 对应于在阴离子配体Z-，阴离子配体Y-和阳离子Mn +之间形成的通式[MZnYp] p-对应于1≤n≤3的一个复合阴离子。 应用于电化学发生器和电化学系统的形成，这使得可能影响光的透射。

公开(公告)号：US5283310A

公开(公告)日：1994-02-01

申请号：US944094

申请日：1992-09-11

申请人： Michel Armand ,  Christiane Poinsignon ,  Jean-Yves Sanchez ,  Veronica de Zea Bermudez

发明人： Michel Armand ,  Christiane Poinsignon ,  Jean-Yves Sanchez ,  Veronica de Zea Bermudez

IPC分类号： C08G77/26 ,  C08G77/22 ,  C08G77/28 ,  C08L83/04 ,  C08L83/08 ,  G02F1/15 ,  H01B1/12 ,  H01M6/18 ,  H01M10/052 ,  H01M10/0565 ,  C08G77/78

CPC分类号： H01M10/052 ,  C08G77/22 ,  C08G77/28 ,  H01B1/122 ,  H01M10/0565 ,  G02F1/1525

摘要： This invention has as its subject a basic organo-mineral proton conducting polymer, produced by copolymerization of three precursors:a precursor based upon a trialkoxysilane, onto which a methane sulphonamide group is grafted by means of an alkyl or aryl link,a "deprotonizing" precursor based upon a trialkoxysilane, onto which is grafted a group derived from a nitrogenous base, preferably an imidazoline group, by means of an alkyl or aryl link,a "plasticizing" and solvating precursor, having at least one urea group which is the product of a reaction between a primary mono-, di- or triamine D and a trialkoxysilane E onto which an isocyanate group has been grafted by means of an alkyl link.

摘要翻译： 本发明的主题为基本的有机 - 矿物质子导电聚合物，其通过三种前体的共聚产生：基于三烷氧基硅烷的前体，甲烷磺酰胺基团通过烷基或芳基键接枝在其上，“去质子化” 基于三烷氧基硅烷的前体，其上通过烷基或芳基键接受衍生自含氮碱，优选咪唑啉基的基团，具有至少一个作为产物的脲基的“增塑”和溶剂化前体 初级单 - ，二 - 或三胺D和三烷氧基硅烷E之间的反应，其上异氰酸酯基团已经通过烷基链接接枝。

公开(公告)号：US4851307A

公开(公告)日：1989-07-25

申请号：US114721

申请日：1987-10-30

申请人： Michel Armand ,  Michel Gauthier ,  Daniel Muller

发明人： Michel Armand ,  Michel Gauthier ,  Daniel Muller

IPC分类号： C08K5/43 ,  C08L77/00 ,  C08L101/00 ,  H01B1/12 ,  H01M6/16 ,  H01M6/18 ,  H01M10/40

CPC分类号： H01B1/122 ,  H01M6/164 ,  H01M6/181 ,  H01M6/166

摘要： An ionically conductive material useful in electrochemical generators is disclosed. This ionically material comprises a salt in solution in a solvent. The solvent comprises a sulfonated derivative of Formula (I):R.sub.1 R.sub.2 N--SO.sub.2 NR.sub.3 R.sub.4wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently a C.sub.1-10 alkyl group or a C.sub.1-10 oxaalkyl group.

摘要翻译： 公开了一种用于电化学发生器的离子导电材料。 该离子材料包括在溶剂中的溶液中的盐。 溶剂包括式（I）的磺化衍生物：R1R2N-SO2NR3R4，其中R1，R2，R3和R4各自独立地为C1-10烷基或C1-10氧杂烷基。

公开(公告)号：US4758483A

公开(公告)日：1988-07-19

申请号：US774915

申请日：1985-09-11

申请人： Michel Armand ,  Daniel Muller ,  Michel Duval ,  Paul E. Harvey ,  Jean M. Chabagno

发明人： Michel Armand ,  Daniel Muller ,  Michel Duval ,  Paul E. Harvey ,  Jean M. Chabagno

IPC分类号： C08G65/04 ,  C08L71/02 ,  H01B1/12 ,  H01M6/18 ,  H01M10/40

CPC分类号： C08L71/02 ,  C08G65/04 ,  H01B1/122 ,  H01M6/181

摘要： A solid polymeric electrolyte comprises a macromolecular material in which there is dissolved an ionic compound, particularly an ionic compound in solution in a copolymer of ethylene oxide and a second unit selected so that the copolymer chain maintains a polyether characteristic. Also a high performance composite electrode embodying this electrolyte, and a process for obtaining this electrolyte.

摘要翻译： 固体高分子电解质包含大分子材料，其中溶解离子化合物，特别是溶解在环氧乙烷和第二单元的共聚物中的溶液中的离子化合物，使得共聚物链保持聚醚特性。 还有一种体现该电解质的高性能复合电极，以及获得该电解质的方法。

公开(公告)号：US4742127A

公开(公告)日：1988-05-03

申请号：US889198

申请日：1986-07-25

申请人： Michel Armand ,  Mireille Fouletier ,  Pierre Degott

发明人： Michel Armand ,  Mireille Fouletier ,  Pierre Degott

IPC分类号： C08F8/34 ,  H01M4/60 ,  H01M10/052 ,  H01M10/0565 ,  C08F8/26

CPC分类号： H01M10/052 ,  C08F8/34 ,  H01M10/0565 ,  H01M4/60

摘要： Polycarbon sulphide derivatives comprise units (R.sub.x CS.sub.m).sub.n in whichR represents hydrogen, an alkali metal or a transition metal,x is the degree to which R is present in the carbon-sulphur structure,m is the degree of substitution with sulphur andn is the number of units in the polymer chain.As shown by the single FIGURE of the drawing, the insertion of R is reversible.

公开(公告)号：US4620944A

公开(公告)日：1986-11-04

申请号：US739057

申请日：1985-05-29

申请人： Michel Armand ,  Daniel Muller ,  Jean-Michel Chabagno

发明人： Michel Armand ,  Daniel Muller ,  Jean-Michel Chabagno

IPC分类号： C08K5/00 ,  C08G65/32 ,  C08L71/00 ,  C08L71/02 ,  C08L85/00 ,  H01B1/12 ,  H01M4/60 ,  H01M6/18 ,  H01M10/36 ,  H01M10/40 ,  H01B1/06

CPC分类号： H01M6/181 ,  C08L71/02 ,  C08L85/00 ,  H01B1/122

摘要： Macromolecular material of ionic conduction constituted by a salt in solution in a polyether. The polyether is polycondensed and/or cross-linked and presents at least two chains connected to each other by a bridge that comprises a silicon, cadmium, boron or titanium atom connected to one of the chains by an oxygen atom.Application to producing electrodes and electrolytes for electrochemical accumulators.

摘要翻译： 离子导电的高分子材料由聚醚中溶液中的盐构成。 所述聚醚是缩聚的和/或交联的并且具有至少两条链，所述链通过桥连接，所述桥包含通过氧原子连接到所述链之一的硅，镉，硼或钛原子。 用于电化学蓄电池生产电极和电解质的应用。

公开(公告)号：US09722240B2

公开(公告)日：2017-08-01

申请号：US12792607

申请日：2010-06-02

申请人： Michel Armand ,  Christophe Michot ,  Nathalie Ravet

发明人： Michel Armand ,  Christophe Michot ,  Nathalie Ravet

IPC分类号： H01M4/13 ,  H01M4/60 ,  H01M4/137 ,  H01M10/052 ,  H01M10/0525 ,  H01M4/02

CPC分类号： H01M4/137 ,  H01M4/60 ,  H01M4/602 ,  H01M4/604 ,  H01M4/606 ,  H01M4/608 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028

摘要： The present invention is concerned with novel compounds derived from polyquinonic ionic compounds and their use in electrochemical generators.

公开(公告)号：US08785043B2

公开(公告)日：2014-07-22

申请号：US13645341

申请日：2012-10-04

申请人： Michel Armand ,  John B. Goodenough ,  Akshaya K. Padhi ,  Kirakodu S. Nanjundaswamy ,  Christian Masquelier

发明人： Michel Armand ,  John B. Goodenough ,  Akshaya K. Padhi ,  Kirakodu S. Nanjundaswamy ,  Christian Masquelier

IPC分类号： H01M4/58 ,  H01M4/13

CPC分类号： H01M4/136 ,  C01B25/45 ,  G02F1/155 ,  H01M4/049 ,  H01M4/1397 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/583 ,  H01M4/622 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028 ,  H01M2300/0068 ,  Y10T29/49108

摘要： The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine or the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.

摘要翻译： 本发明涉及用作碱离子二次（可再充电）电池，特别是锂离子电池中的电极的材料。 本发明提供具有有序橄榄石或菱方NASICON结构的过渡金属化合物，聚阴离子（PO4）3-作为至少一种用作碱性离子可再充电电池的电极材料的组分。

公开(公告)号：US20130302673A1

公开(公告)日：2013-11-14

申请号：US13945713

申请日：2013-07-18

申请人： Nathalie Ravet ,  Simon Besner ,  Martin Simoneau ,  Alain Vallee ,  Michel Armand ,  Jean-Francois Magnan

发明人： Nathalie Ravet ,  Simon Besner ,  Martin Simoneau ,  Alain Vallee ,  Michel Armand ,  Jean-Francois Magnan

IPC分类号： H01M4/485 ,  H01G9/042

CPC分类号： H01M4/136 ,  H01B1/24 ,  H01G9/042 ,  H01G9/155 ,  H01M4/364 ,  H01M4/48 ,  H01M4/485 ,  H01M4/50 ,  H01M4/52 ,  H01M4/58 ,  H01M4/5825 ,  H01M4/583 ,  H01M4/622 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0082 ,  Y02E60/13

摘要： The present invention concerns electrode materials capable of redox reactions by electron and alkali-ion exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, supercapacitors and light modulating systems of the electrochromic type.

公开(公告)号：US20130298386A1

公开(公告)日：2013-11-14

申请号：US13704418

申请日：2011-06-16

申请人： Jean-Marie Tarascon ,  Michel Armand ,  Shanmukaraj Devaraj ,  Sylvie Grugeon ,  Stephane Laruelle

发明人： Jean-Marie Tarascon ,  Michel Armand ,  Shanmukaraj Devaraj ,  Sylvie Grugeon ,  Stephane Laruelle

IPC分类号： H01M4/139

CPC分类号： H01M4/139 ,  H01M4/13 ,  H01M4/131 ,  H01M4/136 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/054 ,  H01M10/0562 ,  H01M10/0565 ,  H01M10/3909 ,  Y10T29/49108

摘要： The invention relates to a method for producing a battery using A+ (Li+ or Na+) as an electrochemical carrier, as well as to the resulting batteries. The method involves assembling together a negative electrode, a positive electrode, and an electrolyte, and then exposing the assembly to a firm charge at the operating temperature of the battery. The electrolyte is a ceramic or a solution of an A+ salt in a polar liquid, a polymer, or the mixture thereof. The active material of the negative electrode is a material which has a redox couple, the potential of which is 0 V to 1.6 V relative to the A+/A+ couple. The active material of the positive electrode is a material which has a redox couple, the potential of which is higher then that of the couple of the negative electrode. The positive electrode used during assembly consists of a current collector having a comprises material which contains the positive active material and at least one sacrificial salt of a cations E+ is selected from among Li+, Na+, K+ and the onium cations, and a redox action selected from azide anions, ketocarboxylate anions, and hydrazide anions, optionally in the form of a polymers.

摘要翻译： 本发明涉及使用A +（Li +或Na +）作为电化学载体制造电池的方法，以及所得的电池。 该方法包括将负极，正电极和电解质组装在一起，然后在电池的工作温度下将组件暴露于牢固的电荷。 电解质是陶瓷或A +盐在极性液体，聚合物或其混合物中的溶液。 负极的活性材料是具有氧化还原电位的材料，其电位相对于A + / A +电压为0V至1.6V。 正极的活性物质是具有氧化还原电位的材料，其电位高于负电极的电位。 在组装期间使用的正电极由具有包含正极活性材料的材料和至少一种阳离子E +的牺牲盐选自Li +，Na +，K +和鎓阳离子的集电器组成，并且选择氧化还原作用 从叠氮阴离子，酮羧酸根阴离子和酰肼阴离子，任选地以聚合物的形式。