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公开(公告)号：US5080871A
公开(公告)日：1992-01-14
申请号：US620628
申请日：1990-12-03
CPC分类号： C07C37/14 , B01D3/009 , C07C2/66 , C07C2529/00 , C07C2531/08 , Y02P20/127
摘要： Organic aromatic compounds are alkylated in a Reactive Distillation.TM. reactor, wherein the solid particulate catalyst is slurried in the aromatic feed stream and fed to a reaction zone containing inert distillation packing. Olefin is vaporized and fed to the bottom of the reaction zone and agitates the catalyst while reacting the olefin with the aromatic to form an alkylation product. The alkylation product is removed from the lower end of the reaction zone and recovered. Any unreacted aromatic is distilled overhead and recycled or recovered. Recycling the aromatic controls the molar ratio of aromatic to olefin to the extent that substantially all of the olefin is reacted.
摘要翻译： 有机芳族化合物在反应蒸馏TM反应器中烷基化，其中固体颗粒催化剂在芳族进料流中浆化并进料至含有惰性蒸馏填料的反应区。 将烯烃蒸发并进料到反应区的底部并搅拌催化剂，同时使烯烃与芳族化合物反应形成烷基化产物。 将烷基化产物从反应区的下端除去并回收。 将任何未反应的芳香族馏分塔顶馏出并回收或回收。 回收芳族物质控制芳族与烯烃的摩尔比达到基本上所有的烯烃反应的程度。
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公开(公告)号：US4629710A
公开(公告)日：1986-12-16
申请号：US684964
申请日：1984-12-20
CPC分类号： C07C29/04 , B01J31/10 , B01J2231/32 , Y02P20/52
摘要： Heat stabilized catalyst compositions are prepared from nuclear sulfonic acid, for example, macroporous crosslinked polyvinyl aromatic compounds containing sulfonic acid groups are neutralized with a metal of Al, Fe, Zn, Cu, Ni, ions or mixtures and alkali, alkaline earth metals or ammonium ions by contacting the resin containing the sulfonic acid with aqueous solutions of the metals salts and alkali, alkaline earth metal or ammonium salts. The catalysts have at least 50% of the sulfonic acid groups neutralized with metal ions and the balance of the sulfonic acid groups neutralized with alkali, alkaline earth ions or ammonium ions.
摘要翻译： 由核酸磺酸制备热稳定的催化剂组合物，例如含有磺酸基的大孔交联聚乙烯基芳族化合物用Al，Fe，Zn，Cu，Ni，离子或混合物的金属中和，碱金属，碱土金属或铵 离子通过使含有磺酸的树脂与金属盐和碱金属，碱土金属或铵盐的水溶液接触。 催化剂具有至少50％的用金属离子中和的磺酸基团，其余的磺酸基团用碱金属，碱土金属离子或铵离子中和。
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33.发明授权Process for producing high purity isoolefins and dimers thereof by dissociation of ethers 失效通过醚解离生产高纯度异烯烃及其二聚体的方法
公开(公告)号：US4447668A
公开(公告)日：1984-05-08
申请号：US496983
申请日：1983-05-25
CPC分类号： C07C11/02 , C07C1/20 , C07C2/28 , C07C2531/08 , Y02P20/127
摘要： Alkyl tertiary butyl ether or alkyl tertiary amyl ether is dissociated by vapor phase contact with a cation acidic exchange resin at temperatures in the range of 150.degree. to 250.degree. F. at LHSV of 0.1 to 20 to produce a stream consisting of unreacted ether, isobutene or isoamylene and an alcohol corresponding to the alkyl radical. After the alcohol is removed, the ether/isoolefin stream may be fractionated to obtain a high purity isoolefin (99+%) or the ether/isoolefin stream can be contacted in liquid phase with a cation acidic exchange resin to selectively dimerize the isoolefin in a highly exothermic reaction, followed by fractionation of the dimerization product to produce high purity diisoolefin (97+%). In the case where the alkyl is C.sub.3 to C.sub.6 and the corresponding alcohol is produced on dissociation of the ether, combined dissociation-distillation may be carried out such that isoolefin is the overhead product and alcohol the bottom.
摘要翻译： 烷基叔丁基醚或烷基叔戊基醚通过与阳离子酸性交换树脂在150至250°F的温度下以0.1至20的LHSV气相接触而解离，以产生由未反应的醚，异丁烯 或异戊烯和对应于烷基的醇。 在除去醇之后，可以分离乙醚/异烯烃流以获得高纯度异烯烃（99 +％），或者乙醚/异烯烃流可以与阳离子酸性交换树脂液相接触，以选择性地使异烯烃二聚 高度放热反应，然后分馏二聚产物以产生高纯度二异氰酸酯（97 +％）。 在烷基为C 3至C 6的情况下，并且在醚的解离时产生相应的醇，可以进行组合的解离 - 蒸馏，使得异烯烃为塔顶产物，醇为底部。
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公开(公告)号：US08101810B2
公开(公告)日：2012-01-24
申请号：US12195118
申请日：2008-08-20
IPC分类号： C07C2/52
CPC分类号： C07C2/66 , Y02P20/127 , C07C15/085 , C07C15/02
摘要： A process for reformate benzene reduction, the process including: feeding a light reformate fraction, an olefin feed, and an alkylation catalyst to an alkylation reaction zone; contacting the light reformate fraction and the olefin feed in the presence of the alkylation catalyst in the alkylation reaction zone to convert at least a portion of the benzene and the olefin to a monoalkylate; recovering a catalyst fraction from an alkylation reaction zone effluent; and recovering a light reformate product having a reduced benzene content.
摘要翻译： 一种重整苯还原的方法，该方法包括：将轻质重整油馏分，烯烃进料和烷基化催化剂进料至烷基化反应区; 在烷基化反应区中在烷基化催化剂存在下使轻重整油馏分和烯烃进料接触，将至少一部分苯和烯烃转化成单烷基化物; 从烷基化反应区流出物回收催化剂级分; 并回收苯含量降低的轻质重整产物。
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公开(公告)号：US07125484B2
公开(公告)日：2006-10-24
申请号：US10958857
申请日：2004-10-05
CPC分类号： C10G65/04 , C10G45/02 , C10G49/002 , C10G57/00 , C10G65/02 , C10G69/02 , C10G69/04 , C10G2300/4087
摘要： A process for the treatment of light naphtha hydrocarbon streams is disclosed wherein the mercaptans contained therein are reacted with diolefins simultaneous with fractionation into a light stream and a heavy stream. The heavy stream is then simultaneously treated at high temperatures and low pressures and fractionated. The naphtha is then stripped of the hydrogen sulfide in a final stripper.
摘要翻译： 公开了一种处理轻石脑油烃流的方法，其中所含的硫醇与二烯烃反应，同时分馏成轻质流和重质流。 然后在高温和低压下同时处理重质流并分馏。 然后在最后的汽提塔中汽提石脑油。
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36.发明授权公开(公告)号：US06169218A
公开(公告)日：2001-01-02
申请号：US08978123
申请日：1997-11-25
申请人： Dennis Hearn , Robert P. Arganbright , Edward M. Jones, Jr. , Lawrence A. Smith, Jr. , Gary R. Gildert
发明人： Dennis Hearn , Robert P. Arganbright , Edward M. Jones, Jr. , Lawrence A. Smith, Jr. , Gary R. Gildert
IPC分类号： C07C503
CPC分类号： C10G70/02 , C07C7/163 , C07C2523/44 , C10G45/32 , Y02P20/127 , Y10S203/06 , C07C11/02
摘要： A process for the selective hydrogenation of the diolefins and acetylenic compounds in a olefin rich aliphatic hydrocarbon streams is disclosed wherein the selective hydrogenation is carried out at 40 to 300° F. under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig in a distillation column reactor containing a hydrogenation catalyst which serves as a component of a distillation structure, such as supported PdO encased in tubular wire mesh. Essentially no hydrogenation of the olefins occurs.
摘要翻译： 公开了一种在富含烯烃的脂肪族烃流中选择性氢化二烯烃和炔属化合物的方法，其中选择性氢化在40至300°F的低氢分压下进行，其范围为约0.1psi至小于 在含有氢化催化剂的蒸馏塔反应器中，在0至350psig下为70psia，其用作蒸馏结构的组分，例如包裹在管状丝网中的负载型PdO。 基本上没有发生烯烃的氢化。
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公开(公告)号：US5756872A
公开(公告)日：1998-05-26
申请号：US789650
申请日：1997-01-27
CPC分类号： B01D53/72 , C07C15/073 , C10G11/18 , C10G29/205 , C07C2527/173 , C07C2529/70
摘要： A process wherein an FCCU off gas is treated by first subjecting the off gas to an alkylation with a heavy reformat to remove the propylene and contaminants after which the gas is separated from the reformat and alkylated products by distillation to produce an ethylene feed suitable for the reaction with benzene to produce ethyl benzene.
摘要翻译： 一种方法，其中通过首先使废气进行烷基化处理以除去丙烯和污染物，然后通过蒸馏将气体从重整塔和烷基化产物中分离出来，以生产适合于 与苯反应生成乙苯。
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公开(公告)号：US5321181A
公开(公告)日：1994-06-14
申请号：US63130
申请日：1993-05-17
CPC分类号： C07C37/14 , B01D3/009 , C07C2/66 , C07C2529/00 , C07C2531/08 , Y02P20/127 , Y10S203/06
摘要： Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.
摘要翻译： 芳族化合物在催化蒸馏中烷基化，其中催化剂结构还用作蒸馏组分，通过在0.25至50个大气压和80℃的温度下在催化剂床中使芳族化合物与C 2至C 10烯烃接触 使用以酸性或酸性阳离子交换树脂为特征的摩尔筛作为催化剂。 例如，乙苯通过在催化剂床下方进料乙烯来制备，同时通过摩尔过量的回流与乙烯反应所需的方法加入苯，从而使基本上所有的乙烯和回收的苯作为主要塔顶馏出物和乙苯 在底部。
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公开(公告)号：US5262576A
公开(公告)日：1993-11-16
申请号：US837113
申请日：1992-02-19
摘要： A method and apparatus for conducting a catalytic distillation process is provided which allows for maintaining a liquid level in selected portions of the catalyst bed. Three particular processes disclosed are the production of methyl tertiary butyl ether, tertiary butyl alcohol and cumene.
摘要翻译： 提供了一种用于进行催化蒸馏方法的方法和装置，其允许在催化剂床的选定部分保持液位。 公开的三个具体方法是生产甲基叔丁基醚，叔丁醇和异丙基苯。
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公开(公告)号：US5262012A
公开(公告)日：1993-11-16
申请号：US584649
申请日：1990-09-19
CPC分类号： B01J19/30 , B01D3/009 , B01J8/02 , B01J2219/30207 , B01J2219/30223 , B01J2219/30408 , B01J2219/30416 , B01J2219/30433 , B01J2219/30466 , B01J2219/30475 , Y10S203/06 , Y10S261/72
摘要： A catalytic distillation system is provided having a first component which is a particulate catalyst useful for carrying out the desired chemical reaction and a second component which is a hollow geometric shape having openings through the outer surface to allow gas and liquid to pass therethrough. The two components are mixed to provide the desired open space and loaded into a distillation column reactor. The hollow geometric shapes provides the spacing, while the openings permit the gas and liquid to flow through, thus providing the requisite vapor liquid contact space and surfaces.
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