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31.发明授权Ethylene polymers with a norbornene comonomer for LLDPE like resins of improved toughness and processibility for film production 失效具有用于LLDPE类树脂的降冰片烯共聚单体的乙烯聚合物具有改进的韧性和用于膜生产的可加工性
公开(公告)号：US5942587A
公开(公告)日：1999-08-24
申请号：US976163
申请日：1997-11-21
IPC分类号： C08F4/659 , C08F4/6592 , C08F210/02 , C08F210/16 , C08F232/04 , C08L23/08 , C08F232/08
CPC分类号： C08F210/02 , C08L23/0815 , C08F210/16 , C08F4/65912 , C08F4/65925 , C08L23/0823 , C08L2314/06 , Y10S526/943
摘要： An ethylene cyclic olefin polymer, particularly an ethylene/norbornene copolymer and an ethylene/norbornene/alpha olefin terpolymer resin, of improved toughness and processibility for film production. This invention provides ethylene based resins which are processible like an LLDPE but which are significantly improved with respect to their capability to be fabricated into a film layer, particularly by a blown bubble extrusion technique. Films prepared of the resins of this invention are significantly improved with respect to certain of their film properties, such as tear strength, without detracting from the beneficial properties that an LLDPE-like resin otherwise provides to a film. Molding application of the above E/NB copolymers and E/NB/O terpolymers is also disclosed.
摘要翻译： 乙烯环烯烃聚合物，特别是乙烯/降冰片烯共聚物和乙烯/降冰片烯/α-烯烃三元共聚物树脂，具有改进的薄膜生产的韧性和加工性。 本发明提供了乙烯基树脂，它们像LLDPE那样可加工，但是在其制造成膜层的能力方面，特别是通过吹塑气泡挤出技术，其可显着改善。 制备本发明树脂的薄膜相对于它们的某些膜性质如撕裂强度而显着改善，而不会降低LLDPE类树脂另外提供给薄膜的有益性质。 还公开了上述E / NB共聚物和E / NB / O三元共聚物的成型应用。
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公开(公告)号：US5635573A
公开(公告)日：1997-06-03
申请号：US412507
申请日：1995-03-29
IPC分类号： C08F4/643 , C08F4/659 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F210/06 , C08F232/00 , C08F232/04
CPC分类号： C08F232/00 , C08F210/00 , C08F210/02 , C08F210/06 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/912
摘要： Cycloolefin/alpha-olefin copolymers in a molar ratio from 5/95 to 95/5, optionally including long linear alpha-olefin, branched alpha-olefins and/or polyenes as additional comonomers, are prepared using a cyclopentadienyl metallocene catalyst system based on a transition metal compound from Group 4 of the Periodic Table of Elements. The copolymers have a high molecular weight, a narrow molecular weight distribution and a substantially uniform, random comonomer distribution.
摘要翻译： 摩尔比为5/95至95/5的环烯烃/α-烯烃共聚物，任选地包括长链线性α-烯烃，支链α-烯烃和/或多烯作为额外的共聚单体，使用基于以下的环戊二烯基茂金属催化剂体系制备： 元素周期表第4组的过渡金属化合物。 共聚物具有高分子量，窄分子量分布和基本均匀的随机共聚单体分布。
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公开(公告)号：US09399746B2
公开(公告)日：2016-07-26
申请号：US13612450
申请日：2012-09-12
申请人： Craig J. Emett , Mark P. Hagemeister , Bruce A. Harrington , Phillip T. Matsunaga , Pramod J. Nandapurkar , Charles J. Ruff , Kevin B. Stavens
发明人： Craig J. Emett , Mark P. Hagemeister , Bruce A. Harrington , Phillip T. Matsunaga , Pramod J. Nandapurkar , Charles J. Ruff , Kevin B. Stavens
IPC分类号： C10M105/04 , C10M105/02 , C10M105/00 , C10M169/04 , C10M103/00 , C10M105/32 , C10M169/02 , C10M171/02 , C10M107/10 , C10M111/04 , C07C2/06 , C07C2/02
CPC分类号： C10M105/04 , C10M3/00 , C10M105/32 , C10M107/10 , C10M111/04 , C10M169/02 , C10M169/04 , C10M171/02 , C10M2203/1025 , C10M2203/1065 , C10M2205/003 , C10M2205/024 , C10M2205/0285 , C10M2205/22 , C10M2205/223 , C10M2223/045 , C10N2210/02 , C10N2220/028 , C10N2230/02 , C10N2230/04 , C10N2230/10 , C10N2230/12 , C10N2230/45 , C10N2230/52 , C10N2230/54 , C10N2230/68 , C10N2230/74 , C10N2240/10 , C10N2270/00 , C10N2220/022 , C10M2205/026
摘要： Poly alpha olefins (PAOs) are characterized by very low viscosity and excellent Noack volatility. A preferred process for synthesizing said PAOs involves first oligomerizing low molecular weight linear alpha olefins in the presence of a single site catalyst at high temperatures without adding hydrogen and then subsequently oligomerizing at least a portion of the product from the first step in the presence of an oligomerization catalyst.
摘要翻译： 聚α-烯烃（PAO）的特征在于非常低的粘度和优异的Noack挥发性。 合成所述PAO的优选方法包括首先使低分子量直链α-烯烃在单一部位催化剂存在下在高温下低聚而不添加氢，然后随后在第一步存在下使至少一部分产物低聚 低聚催化剂。
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34.发明授权公开(公告)号：US08664461B2
公开(公告)日：2014-03-04
申请号：US13423686
申请日：2012-03-19
申请人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
发明人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
IPC分类号： C07C2/08 , C07C2/34 , C08F4/6592
CPC分类号： C08F110/14 , C08F210/16 , C08F10/00 , C08F4/6592 , C08F2500/02 , C08F2500/03 , C08F2500/17
摘要： This invention is directed to new mono-cyclopentadienyl (“mono-Cp”) metallocene catalyst compounds useful for producing high viscosity PAOs with narrow molecular weight distribution and good shear stability. Specifically, this invention relates to a group of bridged mono-Cp catalysts wherein, in an embodiment of the invention, the aromatic ring structure is substituted with: 1) at least one phenyl group, 2) at least one alkyl group, and 3) at least one other group, such as a hydrocarbyl group, a heteroatom, or a heteroatom-containing group.
摘要翻译： 本发明涉及用于生产具有窄分子量分布和良好剪切稳定性的高粘度PAO的新单环戊二烯（“一Cp”）茂金属催化剂化合物。 具体地，本发明涉及一组桥连的单Cp催化剂，其中在本发明的一个实施方案中，芳环结构被以下物质取代：1）至少一个苯基，2）至少一个烷基，和3） 至少一个其它基团，例如烃基，杂原子或含杂原子的基团。
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公开(公告)号：US20130245344A1
公开(公告)日：2013-09-19
申请号：US13612450
申请日：2012-09-12
申请人： Craig J. Emett , Mark P. Hagemeister , Bruce A. Harrington , Phillip T. Matsunga , Pramod J. Nandapurkar , Charles J. Ruff , Kevin B. Stavens
发明人： Craig J. Emett , Mark P. Hagemeister , Bruce A. Harrington , Phillip T. Matsunga , Pramod J. Nandapurkar , Charles J. Ruff , Kevin B. Stavens
IPC分类号： C10M105/04
CPC分类号： C10M105/04 , C10M3/00 , C10M105/32 , C10M107/10 , C10M111/04 , C10M169/02 , C10M169/04 , C10M171/02 , C10M2203/1025 , C10M2203/1065 , C10M2205/003 , C10M2205/024 , C10M2205/0285 , C10M2205/22 , C10M2205/223 , C10M2223/045 , C10N2210/02 , C10N2220/028 , C10N2230/02 , C10N2230/04 , C10N2230/10 , C10N2230/12 , C10N2230/45 , C10N2230/52 , C10N2230/54 , C10N2230/68 , C10N2230/74 , C10N2240/10 , C10N2270/00 , C10N2220/022 , C10M2205/026
摘要： Poly alpha olefins (PAOs) are characterized by very low viscosity and excellent Noack volatility. A preferred process for synthesizing said PAOs involves first oligomerizing low molecular weight linear alpha olefins in the presence of a single site catalyst at high temperatures without adding hydrogen and then subsequently oligomerizing at least a portion of the product from the first step in the presence of an oligomerization catalyst.
摘要翻译： 聚α-烯烃（PAO）的特征在于非常低的粘度和优异的Noack挥发性。 合成所述PAO的优选方法包括首先使低分子量直链α-烯烃在单一部位催化剂存在下在高温下低聚而不添加氢，然后随后在第一步存在下使至少一部分产物低聚 低聚催化剂。
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36.发明授权公开(公告)号：US08476360B2
公开(公告)日：2013-07-02
申请号：US12722292
申请日：2010-03-11
CPC分类号： C08J5/18 , C08J2323/08 , C08J2323/16 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L23/22 , C08L53/00 , C08L91/005 , C08L2207/02 , C08L2666/06 , C08L2666/02
摘要： This invention relates to a film or sheet and a process to make a film or sheet having a thickness of 0.5 to 35 mils comprising a blend composition comprising: a) 4 to 50 wt % of one or more polypropylene-based TPO(s); and b) 30 to 80 wt % of one or more ethylene plastomer(s); and c) 0.5 to 35 wt % of one or more non-functionalized plasticizer(s) having a kinematic viscosity at 100° C. of 4 to 300 cSt, a pour point of −20° C. or less, and a flash point of 200° C. or more; and d) 0 to 69.5 wt % of one or more filler(s); and wherein the blend composition is calendered into a film or sheet.
摘要翻译： 本发明涉及一种薄膜或片材以及制备厚度为0.5至35密耳的薄膜或片材的方法，该薄膜或片材包含共混组合物，其包含：a）4至50重量％的一种或多种聚丙烯基TPO; 和b）30至80重量％的一种或多种乙烯塑性体; 和c）0.5至35重量％的在100℃下的运动粘度为4至300cSt，倾点为-20℃或更低的一种或多种非官能化增塑剂和闪点 200℃以上; 和d）0至69.5重量％的一种或多种填料; 并且其中所述共混组合物压延成膜或片。
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公开(公告)号：US20110306717A1
公开(公告)日：2011-12-15
申请号：US13132675
申请日：2009-12-10
IPC分类号： C08L23/10
CPC分类号： C08L23/14 , C08J3/005 , C08J2323/14 , C08J2323/16 , C08L23/10 , C08L23/12 , C08L23/16 , D01F6/46 , C08L2666/06
摘要： A method for forming a polymer blend, the method comprising charging to a reactive extruder a first polymer and a second polymer to form an initial blend, where the first polymer is a propylene-based elastomer including up to 35% by weight ethylene-derived units and a heat of fusion, as determined according to DSC procedures according to ASTM E-793, of less than 80 J/g and a melt temperature of less than 110° C., where the second polymer is a propylene-based polymer having a melt temperature in excess of 110° C. and a heat of fusion in excess of 80 J/g.
摘要翻译： 一种用于形成聚合物共混物的方法，所述方法包括将第一聚合物和第二聚合物装入反应性挤出机以形成初始共混物，其中第一聚合物是基于丙烯的弹性体，其包含至多35重量％的来自乙烯的单元 以及根据ASTM E-793的DSC程序测定的小于80J / g和小于110℃的熔体温度的熔化热，其中第二聚合物是丙烯类聚合物，其具有 熔融温度超过110℃，熔融热超过80J / g。
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公开(公告)号：US07863206B2
公开(公告)日：2011-01-04
申请号：US11937882
申请日：2007-11-09
IPC分类号： D04H3/00
CPC分类号： C08L23/14 , C08L23/10 , C08L23/142 , C08L2203/12 , C08L2205/02 , C08L2205/03 , C08L2314/06 , Y10T442/602 , Y10T442/637 , Y10T442/68 , Y10T442/681 , C08L2666/02
摘要： Nonwoven fabrics and methods for making the same are described, wherein the fabrics comprise two or more propylene-based elastomers in combination with one or more propylene-based thermoplastic polymers. Specifically, the first propylene-based elastomer comprises at least 7% by weight ethylene or non-propylene alpha-olefin units, the second propylene-based elastomer comprises less than 7% by weight ethylene or non-propylene alpha-olefin units, the first and second propylene-based elastomers each have a heat of fusion less than 80 J/g, and the propylene-based thermoplastic polymer has a heat of fusion greater than 80 J/g.
摘要翻译： 描述了非织造织物及其制备方法，其中织物包含两种或多种丙烯类弹性体与一种或多种基于丙烯的热塑性聚合物的组合。 具体地，第一丙烯类弹性体包含至少7重量％的乙烯或非丙烯α-烯烃单元，第二丙烯类弹性体包含小于7重量％的乙烯或非丙烯α-烯烃单元，第一 和第二丙烯类弹性体各自具有小于80J / g的熔化热，并且丙烯类热塑性聚合物具有大于80J / g的熔化热。
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公开(公告)号：US20100076121A9
公开(公告)日：2010-03-25
申请号：US12402211
申请日：2009-03-11
CPC分类号： C08K5/01 , C08K3/013 , C08L7/00 , C08L23/20 , C08L23/22 , C08L23/283 , C08L61/00 , C08L2312/04 , C08L2666/08 , C08L2666/06
摘要： Provided are elastomeric compositions, such as a tire innerliner, comprising at least one isobutylene based elastomer and at least one hydrocarbon fluid additive (“HFA”). The compositions have improved cold temperature properties and are particularly useful as tire innerliners for an aircraft tire. The use of a HFA in the elastomeric composition may allow for the use of reduced amounts of secondary elastomers, such as natural rubber, while allowing for an improved balance in the composition's brittleness and permeability properties. Examples of useful HFAs include polyalphaolefins, high purity hydrocarbon fluids, and water white group III mineral oils.
摘要翻译： 提供了弹性体组合物，例如轮胎内衬，其包含至少一种异丁烯基弹性体和至少一种烃流体添加剂（“HFA”）。 组合物具有改善的冷温度性能，并且特别适用于用于飞机轮胎的轮胎内衬。 在弹性体组合物中使用HFA可允许使用减少量的二次弹性体，例如天然橡胶，同时允许组合物的脆性和渗透性能的改善的平衡。 有用的HFAs的实例包括聚α-烯烃，高纯度烃流体和水白III族矿物油。
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公开(公告)号：US20090197995A1
公开(公告)日：2009-08-06
申请号：US12402211
申请日：2009-03-11
CPC分类号： C08K5/01 , C08K3/013 , C08L7/00 , C08L23/20 , C08L23/22 , C08L23/283 , C08L61/00 , C08L2312/04 , C08L2666/08 , C08L2666/06
摘要： Provided are elastomeric compositions, such as a tire innerliner, comprising at least one isobutylene based elastomer and at least one hydrocarbon fluid additive (“HFA”). The compositions have improved cold temperature properties and are particularly useful as tire innerliners for an aircraft tire. The use of a HFA in the elastomeric composition may allow for the use of reduced amounts of secondary elastomers, such as natural rubber, while allowing for an improved balance in the composition's brittleness and permeability properties. Examples of useful HFAs include polyalphaolefins, high purity hydrocarbon fluids, and water white group III mineral oils.
摘要翻译： 提供了弹性体组合物，例如轮胎内衬，其包含至少一种异丁烯基弹性体和至少一种烃流体添加剂（“HFA”）。 组合物具有改善的冷温度性能，并且特别适用于用于飞机轮胎的轮胎内衬。 在弹性体组合物中使用HFA可允许使用减少量的二次弹性体，例如天然橡胶，同时允许组合物的脆性和渗透性能的改善的平衡。 有用的HFAs的实例包括聚α-烯烃，高纯度烃流体和水白III族矿物油。
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