摘要:
Processes and apparatus are provided that provide high yields of xylenes per unit of aromatic-containing feed while enabling a high purity benzene co-product to be obtained without the need for an extraction or distillation to remove C6 naphthenes. The processes of this invention include a transalkylation section and a disproportionation section in the benzene and toluene-containing feed is directly provided to the transalkylation section and in which a benzene recycle loop in the transalkylation section isolates the disproportionation section from C6 naphthenes.
摘要:
The use of a layered catalyst composition to selectively hydrogenate C5-C11 diolefins in a hydrocarbon mixture to one or more respective C5-C11 monoolefins is disclosed. The layered catalyst comprises an inner core having a first inorganic oxide and an outer layer bonded to the inner core. The outer layer has a non-refractory second inorganic oxide with at least one Group 1-2 metal and at least one Group 8-10 metal dispersed thereon.
摘要:
Processes for making xylene employ catalysts containing rhenium and a molecular sieve component comprising an acidic MFI molecular sieve having a Si/Al2 molar ratio of less than about 80 and mordenite to provide a transalkylation product with a low content of benzene co-boilers. The invention encompasses the use of sulfided catalyst embodiments in xylene production processes.
摘要翻译:制备二甲苯的方法使用含有铼的催化剂和包含Si / Al 2摩尔比小于约80的酸性MFI分子筛和丝光沸石的分子筛组分,以提供低含量的烷基转移产物 的苯共锅炉。 本发明包括在二甲苯生产方法中使用硫化催化剂实施方案。
摘要:
A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
摘要:
A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
摘要:
One exemplary embodiment can be a process for increasing a mole ratio of methyl to phenyl of one or more aromatic compounds in a feed. The process can include reacting an effective amount of one or more aromatic compounds and an effective amount of one or more non-aromatic compounds to convert about 90%, by weight, of one or more C6+ non-aromatic compounds.
摘要:
One exemplary embodiment can be a process for increasing a mole ratio of methyl to phenyl of one or more aromatic compounds in a feed. The process can include reacting an effective amount of one or more aromatic compounds and an effective amount of one or more aromatic methylating agents to form a product having a mole ratio of methyl to phenyl of at least about 0.1:1 greater than the feed.
摘要:
One exemplary embodiment can be a layered catalyst for use in a selective hydrogenation of acetylenes and diolefins to olefins. The layered catalyst may include an inner core having an inert material, an outer layer including a metal oxide bonded to the inner core, and a metal deposited on the outer layer. Generally, the metal is an IUPAC Group 8-10 metal and the layered catalyst has an accessibility index of about 3- about 500.
摘要翻译:一个示例性实施方案可以是用于将烯烃和二烯烃选择性氢化成烯烃的层状催化剂。 层状催化剂可以包括具有惰性材料的内芯,包含结合到内芯的金属氧化物的外层和沉积在外层上的金属。 通常,金属是IUPAC Group 8-10金属,层状催化剂具有约3-约500的可达性指数。
摘要:
A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
摘要:
A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.