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    Preparation of electrically conductive polyarylene compounds having electron-attracting side groups
    38.
    发明授权
    Preparation of electrically conductive polyarylene compounds having electron-attracting side groups 失效
    具有吸电子基团的导电聚亚芳基化合物的制备

    公开(公告)号：US4488986A

    公开(公告)日：1984-12-18

    申请号：US519507

    申请日：1983-08-02

    申请人： Herbert Naarmann ,  Petr Simak ,  Gernot Kohler

    发明人： Herbert Naarmann ,  Petr Simak ,  Gernot Kohler

    IPC分类号： C08L65/00 ,  C07C57/42 ,  C08F8/30 ,  C08F8/42 ,  C08F38/00 ,  C08G16/00 ,  C08G61/00 ,  C08L101/00 ,  H01B1/12 ,  H01M4/60 ,  H01B1/06

    CPC分类号： C07C255/00 ,  C07C57/42 ,  C08L101/00 ,  H01B1/128 ,  H01M4/60 ,  C08L2201/04

    摘要： Electrically conductive polymeric systems having electrical conductivities greater than 10.sup.-4 S/cm are prepared by a method wherein a polyarylene compound which contains one or more chain members of the formula ##STR1## where n is greater than 1, preferably from 5 to 50, R is a nitrile, acid amide, carboxyl or ester group, R.sup.1 and R.sup.2 are each hydrogen or a nitrile, acid amide, carboxyl or ester group, with the proviso that in each case one of the radicals R.sup.1 and R.sup.2 is hydrogen and the other is a nitrile, acid amide, carboxyl or ester group, and Y is an aromatic radical, preferably phenylene, is doped, in the absence of moisture and oxygen, with from 0.03 to 0.9 mole percent of an electron-attracting or electron-donating complexing agent. The resulting electrically conductive polymeric systems are useful in the electrical industry for the production of solar cells, for converting and fixing electromagnetic radiation and for the production of electrical and magnetic switches and electrical storage devices, and can be used for the antistatic treatment of plastics.

    摘要翻译： 电导率大于10 -4 S / cm的导电聚合体系通过一种方法制备，其中含有一个或多个下式的链成员的聚亚芳基化合物，其中n大于1，优选为5至50， R是腈，酰胺，羧基或酯基，R 1和R 2各自为氢或腈，酰胺，羧基或酯基，条件是在每种情况下，基团R 1和R 2中的一个为氢，另一个为氢 是腈，酰胺，羧基或酯基，并且Y是芳族基团，优选亚苯基，在没有水分和氧的情况下掺杂有0.03-0.9摩尔％的吸电子或给电子络合物 代理商 所得到的导电聚合物体系可用于电气工业中用于生产太阳能电池，用于转换和固定电磁辐射以及生产电磁开关和电存储装置，并可用于塑料的抗静电处理。

    Preparation of electrically conductive polymers
    39.
    发明授权
    Preparation of electrically conductive polymers 失效
    导电聚合物的制备

    公开(公告)号：US4418187A

    公开(公告)日：1983-11-29

    申请号：US254258

    申请日：1981-04-15

    申请人： Volker Muench ,  Herbert Naarmann ,  Klaus Penzien

    发明人： Volker Muench ,  Herbert Naarmann ,  Klaus Penzien

    IPC分类号： C08F4/06 ,  C08F38/00 ,  H01L51/30 ,  C08F112/32 ,  C08F126/00 ,  C08F126/06 ,  C08F126/12

    CPC分类号： H01L51/004 ,  C08F38/00 ,  H01L51/0042 ,  Y02E10/549

    摘要： A process for the preparation of electrically conductive polymers by polymerizing acenaphthylene, N-vinyl-heterocyclics, eg. N-vinylcarbazole or N-vinylpyridine, or N,N-divinylaniline at from -80.degree. to +100.degree. C. in the presence of a cationtic catalyst, wherein from 1 to 50 percent by weight of an oxidizing Lewis acid, preferably FeCl.sub.3, FeBr.sub.3, SbCl.sub.5, SbF.sub.5, AsF.sub.5 or CF.sub.3 -SO.sub.3 H, or a combination of AlCl.sub.3 or TiCl.sub.4 with the said compounds or with CrO.sub.3 or OsO.sub.4 is used as the catalyst. In a preferred embodiment of the process, thin films of the monomers to be polymerized, applied to glass or to a polymeric base, preferably to a plastic film, are treated with gaseous SbCl.sub.5, SbF.sub.5 or AsF.sub.5. The conductive polymers obtained can be used in the electrical industry for the production of solar cells, for the conversion and fixing of radiation and for the production of electrical and magnetic switches, as well as for the antistatic treatment of plastics.

    摘要翻译： 通过聚合苊烯，N-乙烯基 - 杂环化合物制备导电聚合物的方法， N-乙烯基咔唑或N-乙烯基吡啶或N，N-二乙烯基苯胺，在-80℃至+ 100℃下，在阳离子催化剂存在下，其中1至50重量％的氧化路易斯酸，优选FeCl 3， FeBr 3，SbCl 5，SbF 5，AsF 5或CF 3 SO 3 H，或AlCl 3或TiCl 4与所述化合物或与CrO 3或OsO 4的组合用作催化剂。 在该方法的优选实施方案中，将待聚合的单体的薄膜施加到玻璃上或聚合物基体上，优选用塑料膜，用气态SbCl 5，SbF 5或AsF 5处理。 所得到的导电聚合物可用于电气工业中用于生产太阳能电池，用于辐射的转换和固定以及电气和磁性开关的生产以及用于塑料的抗静电处理。