Abstract:
A METHOD IS PROVIDED FOR CONVERTING ORGANOSILICON HALIDES, FOR EXAMPLE, HALOSILANES AND BIS(HALOSILYL)HYDROCARBONS, TO THE CORRESPONDING HYDRIDES. SILICON HALIDE REDUCTION IS EFFECTED BY UTILIZING CERTAIN ORGANOMETALLIC HYDRIDES.
Abstract:
Alkoxy-substituted mercaptoalkyl silanes are prepared by reacting an olefinically substituted silane with a thioacid and treating the reaction product with an alcohol so as to form or maintain an alkoxy substituent, while forming a mercaptoalkyl substituent of the original olefinic portion. The process is also applicable to the production of polymeric organosilicon materials with mercaptoalkyl substituents.
Abstract:
Bis(aminoorganosilyl)hydrocarbons are employed in combination with organic diacids or organic dianhydrides to provide for the production of bis(organosilyl)hydrocarbon modified polyamides including polyamide acids. The bis(organosilyl)hydrocarbon modified polyamides also can contain chemically combined polydiorganosiloxane. The bis(organosilyl)hydrocarbon modified polyamides can be employed to make molding compounds, and polyamide and polyimide insulating films.
Abstract:
In the above formulas, R is an organic radical, R'' is an organic radical or hydrogen, X is a hydrolyzable group, Z is a OR A -CN radical, a has a value of 0 to 2, b has a value of 0 to 4, and c has a value of one to five. The copolymer containing cyanoalkylesteralkylsilane units is useful as a solvent resistant protective coating material. The copolymer containing aminoalkylesteralkylsilane units is the primary ingredient of a detergent resistant car polish. D R A W I N G Cyanoalkylesteralkylsilanes within the scope of the formula:
Abstract translation:氰基烷基酯烷基硅烷在下列范围内:在上式中,R是有机基团,R'是有机基团或氢,X是可水解基团,Z是OR A -CN基团,a的值为0至 2,b的值为0〜4,c的值为1〜5。 含有氰基烷基酯烷基硅烷单元的共聚物可用作耐溶剂的保护涂层材料。 含有氨基烷基酯烷基硅烷单元的共聚物是耐洗涤剂汽车抛光剂的主要成分。
Abstract:
A PROCESS FOR FORMING ORGANOSILICON COMPOUNDS WITH AN ISTHIOCYANATE GROUP BONDED TO THE SILICON ATOM THROUGH AN ALKYLENE BRIDGE OR ALKYLENE BRIDGE HAVING SURFUR, OXYGEN NITROGEN LINKAGES BY REACTING THE CORRESPONDING AMINOALKYL-SUBSTITUTED ORGANOSILICON COMPOUND WITH CARBON DISULFIDE AND A DIALKYL CARBODIMIDE. A NEW CLASS OF ORGANOSILICON COMPOUNDS HAVING AN ISOTHIOCYANATE GROUP BONDED TO THE SILICON ATOM THROUGH AN ALKYLENE BRIDGE OR ALKYLENE BRIDGE HAVING SULFUR, OXYGEN, OR NITROGEN LINKAGES.
IS MADE BY HYDROGENATING THE CORRESPONDING NITRILE. IN THE ABOVE FORMULAS, A IS SIC BOND OR A HYDROGEN RADICAL, A IS A MONOVALENT ORGANIC RADICAL, R'' IS A MONOVALENT ORGANIC RADICAL OR HYDROGEN, X IS A HYDROLYZABLE GROUP, A HAS A VALUE OF 0 TO 3, AND B HAS A VALUE OF ONE TO 4. COMPOUNDS (1) AND (2) ARE USEFUL IN DETERGENT RESISTANT POLISH COMPOSITIONS.
Abstract:
MONOMERIC ORGANOSILICON COMPOUNDS, HAVING MERCAPTOALKYL SUBSTITUENTS, ARE FORMED THROUGH TREATMENT OF AN ORGANOSILICON COMPOUND, HAVING AN ALKYL SUBSTITUENT WITH A THIOACID SALT GROUP, WITH AMMOIA OR AN AMINE COM POUND. THE REMAINING GROUPS ON THE ORGANOSILICON COMPOUND ARE NOT AFFECTED BY THE TREATMENT AND RETAIN FUNCTIONAL OR NONFUNCTIONAL SUBSTITUENTS, UNCHANGED.
Abstract:
1,202,498. Silyl isocyanurates; polysiloxane adhesive compositions. GENERAL ELECTRIC CO. 19 Aug., 1968 [20 Sept., 1967], No. 39645/68. Headings C3S and C3T. The invention comprises silyl isocyanurates of the formula wherein R is a C 1 _ 8 alkyl radical, R 1 is a monovalent saturated hydrocarbon or halohydrocarbon radical, R 11 is a divalent saturated hydrocarbon or halohydrocarbon radical, G is a radical R 1 or (RO) 3-a R 1 a SiR 11 - or a monovalent unsaturated hydrocarbon or halohydrocarbon radical and a is 0, 1, 2 or 3. They may be prepared by reaction of appropriate amounts of the hydrosilane (RO) 3-a R 1 a SiH with the corresponding unsaturated isocyanurate i.p.o. a Pt catalyst; the trisilyl isocyanurate may be obtained also by reaction of the silylorganohalide with a metal cyanate in an aprotic solvent. In Examples 1-3 trimethoxysilane is reacted with triallyl isocyanurate in molar ratios of 1, 2 and 3: 1 to give the corresponding mono-, di- and tri-silyl isocyanurates. In Example 4 phenyldiethoxysilane is reacted with allyl dipropyl isocyanurate. Two parts by weight of the tris(trimethoxysilylpropyl)isocyanurate of Example 3 are mixed with 100 of a hydroxy-terminated polydimethylsiloxane, 150 of a silica filler and 0À8 of a curing catalyst to give a room temperature vulcanizing (RTV) composition used to bond plywood strips.