公开(公告)号：US07220697B2

公开(公告)日：2007-05-22

申请号：US10992211

申请日：2004-11-19

申请人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

发明人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

IPC分类号： B01J21/18 ,  B01J23/40 ,  C01B31/08 ,  C01B31/02 ,  D01F9/12

CPC分类号： B01J35/1061 ,  B01J21/18 ,  B01J23/42 ,  B01J29/0308 ,  B01J37/06 ,  B01J37/084 ,  C01B32/00 ,  H01M4/9083 ,  H01M4/926

摘要： The present invention is related to a mesoporous carbon molecular sieve, which can be used as a catalyst carrier capable of improving the activity of a supported catalyst and a method of preparing the same. Additionally, the invention is related to a supported catalyst employing the mesoporous carbon molecular sieve as a carrier, and a fuel cell employing the supported catalyst. The mesoporous carbon molecular sieve has an average primary particle size of less than about 500 nm, an average mesopore size in the range of about 3 nm to about 6 nm, and a surface area in the range of about 500 m2/g to about 2000 m2/g.

摘要翻译： 本发明涉及可用作能够提高负载型催化剂的活性的催化剂载体的介孔碳分子筛及其制备方法。 另外，本发明涉及使用中孔碳分子筛作为载体的负载催化剂和使用负载型催化剂的燃料电池。 介孔碳分子筛的平均一次粒径小于约500nm，平均中孔尺寸在约3nm至约6nm的范围内，表面积在约500μm2范围内， /约至约2000m 2 / g。

公开(公告)号：US20060239890A1

公开(公告)日：2006-10-26

申请号：US11262812

申请日：2005-11-01

申请人： Hyuk Chang ,  Chan-ho Pak ,  Jian Wang

发明人： Hyuk Chang ,  Chan-ho Pak ,  Jian Wang

IPC分类号： C01B31/02 ,  H01M4/96

CPC分类号： H01M4/926 ,  B01J21/18 ,  B82Y30/00 ,  C01B32/05 ,  H01M4/92 ,  H01M4/921 ,  H01M2008/1095 ,  Y10S977/734 ,  Y10S977/737 ,  Y10S977/843 ,  Y10S977/847 ,  Y10S977/888

摘要： A carbon nanosphere has at least one opening. The carbon nanosphere is obtained by preparing a carbon nanosphere and treating it with an acid to form the opening. The carbon nanosphere with at least one opening has higher utilization of a surface area and electrical conductivity and lower mass transfer resistance than a conventional carbon nanotube, thus allowing for higher current density and cell voltage with a smaller amount of metal catalyst per unit area of a fuel cell electrode.

公开(公告)号：US20060094928A1

公开(公告)日：2006-05-04

申请号：US11262813

申请日：2005-11-01

申请人： Hyuk Chang ,  Kyoung Choi ,  Christopher Ko

发明人： Hyuk Chang ,  Kyoung Choi ,  Christopher Ko

IPC分类号： H01M8/18 ,  A61B1/00

CPC分类号： A61B1/041 ,  H01M4/8605 ,  H01M4/8882 ,  H01M4/8896 ,  H01M4/921 ,  H01M8/1009 ,  H01M8/1013 ,  Y02E60/522

摘要： A fuel cell for a microcapsule-type robot uses alcohol or an aqueous alcohol solution as a fuel and was hydrogen peroxide or an aqueous hydrogen peroxide solution as an oxidizing agent. A microcapsule-type robot also uses the fuel cell. The fuel cell may be used in a microcapsule-type endoscope and have an operating time that is long enough to diagnose human organs. The fuel cell may comprise hydrogen peroxide as an oxidizing agent instead of air or oxygen such that the fuel cell can operate inside the human body. Thus, an oxygen source, which cannot be obtained in a human body, can be easily supplied to the fuel cell, and the fuel cell has higher performance than a fuel cell in which air is used as an oxidizing agent.

摘要翻译： 用于微胶囊型机器人的燃料电池使用醇或醇水溶液作为燃料，并且是过氧化氢或过氧化氢水溶液作为氧化剂。 微胶囊型机器人也使用燃料电池。 燃料电池可以用于微胶囊型内窥镜，其操作时间足以诊断人体器官。 燃料电池可以包括作为氧化剂的过氧化氢代替空气或氧气，使得燃料电池可以在人体内部操作。 因此，能够容易地向燃料电池供给在人体中不能获得的氧源，并且燃料电池具有比使用空气作为氧化剂的燃料电池更高的性能。

公开(公告)号：US06743541B2

公开(公告)日：2004-06-01

申请号：US09805580

申请日：2001-03-14

申请人： Hyuk Chang ,  Chan Lim

发明人： Hyuk Chang ,  Chan Lim

IPC分类号： H01M810

CPC分类号： H01M8/2418 ,  H01M8/1009 ,  H01M8/241 ,  H01M8/249 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02P70/56

摘要： A proton exchange membrane fuel cell and a direct methanol fuel cell pack using a monopolar electrode are provided. The fuel cell pack includes a plurality of cells each having a membrane in its middle and a cathode and an anode at both sides of the membrane, collector plates contacting the cathode and the anode, respectively, in each cell, and an electrical connection member for electrically connecting adjacent cells. The cells are evenly disposed on an arbitrary plane with a hollow interposed between two adjacent cells. The electrical connection member is positioned in the hollow. The fuel cell pack also includes a porous fuel diffusion member contacting the anode of each cell; a porous air contact member contacting the cathode of each cell; an anode end plate and a cathode end plate disposed at the side of the anodes of the cells and at the side of the cathodes of the cells, respectively, for protecting the cells; a fuel supply and discharge unit for supplying fuel toward the anodes in the hollow and discharging the fuel; a fuel flow stopper disposed at a portion at the part of the cathodes in the hollow, for preventing fuel flowing at a portion at the part of the anodes in the hollow from flowing toward the portion at the part of the cathodes in the hollow; and a sealing member for sealing the anodes of the cells and the portion of the hollow corresponding to the anodes. Accordingly, circulation of fuel for the plurality of cells is performed through a single inlet and a single outlet so that a fuel supply line is very simple compared to a structure of a fuel supply line for each cell in a conventional cell pack having a structural limitation. In addition, the cell pack generates current of a high density without a separate cooling device.

摘要翻译： 提供质子交换膜燃料电池和使用单极电极的直接甲醇燃料电池组。 燃料电池组包括多个电池，每个电池在其中间具有膜，阴极和膜两侧的阳极，在每个电池中分别与阴极和阳极接触的集电板，以及用于 电连接相邻电池。 细胞均匀地设置在任意平面上，中间插入两个相邻的细胞之间。 电连接构件定位在空心中。 燃料电池组还包括接触每个电池单元的阳极的多孔燃料扩散部件; 与每个电池的阴极接触的多孔空气接触构件; 阳极端板和阴极端板分别设置在电池的阳极侧和电池的阴极侧，用于保护电池; 燃料供给和排出单元，用于向中空中的阳极供应燃料并排出燃料; 设置在中空部分阴极部分处的燃料流动塞，用于防止在中空部分的阳极部分处的燃料流向中空部分阴极部分的部分; 以及用于密封电池的阳极和对应于阳极的中空部分的密封构件。 因此，通过单个入口和单个出口进行用于多个电池的燃料的循环，使得与具有结构限制的常规电池组中的每个电池的燃料供应管线的结构相比，燃料供应管线非常简单 。 此外，电池组在没有单独的冷却装置的情况下产生高密度的电流。

公开(公告)号：US08791043B2

公开(公告)日：2014-07-29

申请号：US12650750

申请日：2009-12-31

申请人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim ,  Jeong-kuk Shon

发明人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim ,  Jeong-kuk Shon

IPC分类号： B01J23/16 ,  B01J23/44 ,  B01J23/46 ,  B01J23/75 ,  B01J23/745 ,  B01J23/755 ,  H01M4/36 ,  C01B31/00

CPC分类号： H01M4/90 ,  H01M4/8814 ,  H01M4/8825 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1004 ,  Y02P70/56

摘要： An ordered mesoporous carbon (OMC) composite catalyst includes an OMC; and metal particles and at least one component selected from a group consisting of nitrogen and sulfur included in the OMC. The ordered mesoporous carbon composite catalyst may be formed by impregnating an ordered mesoporous silica with a mixture of at least one selected from the group consisting of a nitrogen-containing carbon precursor, and a sulfur-containing carbon precursor, a metal precursor, and a solvent; drying and heat-treating the impregnated OMS; carbonizing the dried and heat-treated OMS to obtain a carbon-OMS composite; and removing the OMS from the carbon-OMS composite. A fuel cell may contain the OMC composite catalyst.

摘要翻译： 有序介孔碳（OMC）复合催化剂包括OMC; 和金属颗粒和至少一种选自包含在OMC中的氮和硫的组分。 有序介孔碳复合催化剂可以通过用选自含氮碳前体和含硫碳前体，金属前体和溶剂中的至少一种的混合物浸渍有序介孔二氧化硅来形成 ; 干燥和热处理浸渍的OMS; 对干燥和热处理的OMS进行碳化以获得碳-OMS复合材料; 并从碳-OMS复合材料中除去OMS。 燃料电池可以包含OMC复合催化剂。

公开(公告)号：US08603934B2

公开(公告)日：2013-12-10

申请号：US13443599

申请日：2012-04-10

申请人： Hyuk Chang ,  Chan-Ho Pak ,  Jian Nong Wang

发明人： Hyuk Chang ,  Chan-Ho Pak ,  Jian Nong Wang

IPC分类号： B01J21/04 ,  B01J23/00 ,  B01J21/18 ,  C01B31/08 ,  H01M8/10 ,  B01J3/06

CPC分类号： H01M4/926 ,  B01J21/18 ,  B82Y30/00 ,  C01B32/05 ,  H01M4/92 ,  H01M4/921 ,  H01M2008/1095 ,  Y10S977/734 ,  Y10S977/737 ,  Y10S977/843 ,  Y10S977/847 ,  Y10S977/888

摘要： A carbon nanosphere has at least one opening. The carbon nanosphere is obtained by preparing a carbon nanosphere and treating it with an acid to form the opening. The carbon nanosphere with at least one opening has higher utilization of a surface area and electrical conductivity and lower mass transfer resistance than a conventional carbon nanotube, thus allowing for higher current density and cell voltage with a smaller amount of metal catalyst per unit area of a fuel cell electrode.

摘要翻译： 碳纳米球具有至少一个开口。 碳纳米球通过制备碳纳米球并用酸处理以形成开口获得。 具有至少一个开口的碳纳米球具有比常规碳纳米管更高的表面积利用率和导电性和较低的传质阻力，从而允许较高的电流密度和电池电压，每单位面积的金属催化剂量 燃料电池电极。

公开(公告)号：US08083905B2

公开(公告)日：2011-12-27

申请号：US12511468

申请日：2009-07-29

申请人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

发明人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

IPC分类号： C01B31/00 ,  D01F9/12

CPC分类号： H01M4/8605 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  H01M4/9083 ,  H01M4/926 ,  H01M2008/1095 ,  Y10S977/70 ,  Y10S977/701 ,  Y10S977/72 ,  Y10S977/743 ,  Y10S977/843 ,  Y10S977/847

摘要： The internal and external walls of the carbon nanotubes are doped with nano-sized metallic catalyst particles uniformly to a degree of 0.3-5 mg /cm2. The carbon nanotubes are grown over a carbon substrate using chemical vapor deposition or plasma enhanced chemical vapor deposition. Since the carbon nanotubes have a large specific surface area, and metallic catalyst particles are uniformly distributed over the internal and external walls thereof, the reaction efficiency in an electrode becomes maximal when the carbon nanotubes are used for the electrode of a fuel cell. The carbon nanotubes fabricated using the method can be applied to form a large electrode. The carbon nanotubes grown over the carbon substrate can be readily applied to an electrode of a fuel cell, providing economical advantages and simplifying the overall electrode manufacturing process. A fuel cell using as the carbon nanotubes for its electrode provides improved performance.

摘要翻译： 碳纳米管的内壁和外壁均匀掺杂有纳米尺寸的金属催化剂颗粒至0.3-5mg / cm2的程度。 使用化学气相沉积或等离子体增强化学气相沉积在碳衬底上生长碳纳米管。 由于碳纳米管具有大的比表面积，并且金属催化剂颗粒均匀地分布在其内壁和外壁上，所以当将碳纳米管用于燃料电池的电极时，电极中的反应效率最大。 使用该方法制造的碳纳米管可以应用于形成大电极。 生长在碳基板上的碳纳米管可以容易地应用于燃料电池的电极，提供经济的优点并简化整个电极的制造过程。 使用作为其电极的碳纳米管的燃料电池提供改进的性能。

公开(公告)号：US07994088B2

公开(公告)日：2011-08-09

申请号：US11708600

申请日：2007-02-21

申请人： Chan-ho Pak ,  Dae-jong Yoo ,  Sang-hoon Joo ,  Hyuk Chang ,  Seol-ah Lee

发明人： Chan-ho Pak ,  Dae-jong Yoo ,  Sang-hoon Joo ,  Hyuk Chang ,  Seol-ah Lee

IPC分类号： H01M4/88 ,  B01J21/18 ,  B01J23/00 ,  B01J23/40 ,  B01J23/74 ,  H01M4/02 ,  H01M4/36 ,  H01M4/92 ,  H01M4/94 ,  H01M4/90

CPC分类号： H01M4/926 ,  H01M4/8657 ,  H01M4/8814 ,  H01M4/885 ,  H01M4/92 ,  H01M4/921 ,  H01M8/1007 ,  H01M8/1011 ,  Y02E60/523 ,  Y02P70/56

摘要： A method of preparing a supported catalyst, a supported catalyst prepared by the method, and a fuel cell using the supported catalyst. In particular, a method of preparing a supported catalyst by preparing a primary supported catalyst containing catalytic metal particles that are obtained by a primary gas phase reduction reaction of a portion of the final loading amount of a catalytic metal, and reducing the remaining portion of the catalytic metal by a secondary liquid phase reduction reaction using the primary supported catalyst. The supported catalyst contains catalytic metal particles having a very small average particle size, which are uniformly distributed on a carbon support at a high concentration, and thus exhibits maximal catalyst activity. A fuel cell produced using the supported catalyst has improved efficiency.

摘要翻译： 制备载体催化剂的方法，通过该方法制备的负载催化剂和使用负载型催化剂的燃料电池。 特别是制备负载型催化剂的方法，该方法是通过制备含有催化金属颗粒的主载体催化剂，所述催化剂金属颗粒是通过催化金属的最终负载量的一部分的一次气相还原反应获得的，并且还原剩余部分 催化金属通过使用主要负载催化剂的二次液相还原反应。 载体催化剂含有平均粒径非常小的催化金属颗粒，其以高浓度均匀分布在碳载体上，因此表现出最大的催化剂活性。 使用负载型催化剂制造的燃料电池具有提高的效率。

公开(公告)号：US07923159B2

公开(公告)日：2011-04-12

申请号：US11515900

申请日：2006-09-06

申请人： Hye-jung Cho ,  Hyuk Chang ,  Kyoung Hwan Choi ,  Jae-yong Lee

发明人： Hye-jung Cho ,  Hyuk Chang ,  Kyoung Hwan Choi ,  Jae-yong Lee

IPC分类号： H01M8/06

CPC分类号： H01M8/1011 ,  H01M8/04097 ,  H01M8/04119 ,  H01M8/04141 ,  H01M8/04291 ,  Y02E60/523

摘要： A water recovery system of a direct liquid feed fuel cell and a direct liquid feed fuel cell having the water recovery system. The water recovery system in which water produced at a cathode electrode of a membrane electrode assembly (MEA) is recovered to supply to an anode electrode, the water recovery system includes: a first member located on the cathode electrode and a first supporting plate that supports the first member; and a second member located on the anode electrode and a second supporting plate that supports the second member, wherein the first member and the second member are connected to each other through a slit formed in an electrolyte membrane of the MEA. The direct liquid feed fuel cell having the water recovery system can be used, for example, in a direct methanol fuel cell (DMFC).

摘要翻译： 直接液体进料燃料电池的水回收系统和具有水回收系统的直接液体进料燃料电池。 水回收系统，其中回收在膜电极组件（MEA）的阴极处产生的水以供应到阳极电极，所述水回收系统包括：第一构件，位于所述阴极电极上，第一支撑板支撑 第一名成员; 以及位于阳极电极上的第二构件和支撑第二构件的第二支撑板，其中第一构件和第二构件通过形成在MEA的电解质膜中的狭缝相互连接。 具有水回收系统的直接液体进料燃料电池可以用于例如直接甲醇燃料电池（DMFC）中。

公开(公告)号：US07732094B2

公开(公告)日：2010-06-08

申请号：US11443165

申请日：2006-05-31

申请人： Chan-ho Pak ,  Yeong-suk Choi ,  Hyuk Chang ,  Sang Hoon Joo

发明人： Chan-ho Pak ,  Yeong-suk Choi ,  Hyuk Chang ,  Sang Hoon Joo

IPC分类号： H01M4/60 ,  H01M4/62 ,  H01M4/88 ,  B01J31/00

CPC分类号： B01J21/18 ,  B01J23/42 ,  B01J29/0308 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/084 ,  H01M4/90 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/08 ,  H01M8/086 ,  H01M8/10 ,  H01M8/1007 ,  H01M8/1011 ,  Y02E60/523 ,  Y02P70/56

摘要： A mesoporous carbon composite includes mesoporous carbon having mesopores; a conductive polymer coated on only an outer surface of the mesoporous carbon; and an organic electrolyte. The mesoporous carbon composite may be prepared by impregnating an ordered mesoporous silica (OMS) with a mixture comprising a carbon precursor, an acid, and a solvent; heat-treating and carbonizing the impregnated OMS to form an OMS-carbon composite; mixing the OMS-carbon composite with a monomer that forms a conductive polymer and a solvent to provide a surface of the OMS-carbon composite with the monomer; polymerizing the monomer to obtain a conductive polymer-coated OMS-carbon composite; removing the OMS from the composite to obtain a conductive polymer-coated mesoporous carbon; and doping the conductive polymer-coated mesoporous carbon with an organic electrolyte. A supported catalyst and a fuel cell include the mesoporous carbon composite.

摘要翻译： 介孔碳复合材料包括具有中孔的中孔碳; 只涂覆在介孔碳外表面上的导电聚合物; 和有机电解质。 介孔碳复合材料可以通过用含有碳前体，酸和溶剂的混合物浸渍有序介孔二氧化硅（OMS）来制备; 对浸渍的OMS进行热处理和碳化以形成OMS-碳复合材料; 将OMS-碳复合物与形成导电聚合物和溶剂的单体混合以提供OMS-碳复合材料与单体的表面; 聚合单体以获得导电聚合物涂覆的OMS-碳复合材料; 从复合材料中除去OMS以获得导电聚合物涂覆的介孔碳; 并用有机电解质掺杂导电聚合物涂覆的中孔碳。 载体催化剂和燃料电池包括介孔碳复合材料。