公开(公告)号：US4663408A

公开(公告)日：1987-05-05

申请号：US814362

申请日：1985-12-30

申请人： Donald N. Schulz ,  Enock Berluche ,  John J. Maurer ,  Jan Bock

发明人： Donald N. Schulz ,  Enock Berluche ,  John J. Maurer ,  Jan Bock

IPC分类号： C08F8/12 ,  C09K8/12 ,  C09K8/588 ,  C08F20/06

CPC分类号： C09K8/588 ,  C08F8/44 ,  C09K8/12

摘要： The present invention relates to improved viscosification agents for an aqueous or brine solutions. Typically, the viscosification agents are tetrapolymers of N-vinyl pyrrolidone/acrylamide/salt of acrylic acid/N-alkyl acrylamide wherein said tetrapolymers have the formula: ##STR1## wherein w is about 1 to about 80 mole percent, more preferably about 5 to about 75 mole percent, and most preferably about 10 to about 70 mole percent; x is about 10 to about 90 mole percent, more preferably about 20 to about 80 mole percent, and most preferably about 30 to about 70 mole percent; and y is about 0.1 to about 10.0 mole percent, more preferably about 0.15 to about 5.0 mole percent; and most preferably about 0.2 to about 3.0 mole percent; z is about 1.0 to about 30.0 mole percent, more preferably about 2.0 to about 25.0 mole percent, and most preferably about 5.0 to about 20.0 mole percent; R is an alkyl group having about 6 to about 30 carbon atoms, more preferably about 7 to about 20, and most preferably about 8 to about 18; and M is a cation selected from the group consisting of monovalent cations, preferably Na.sup.+, K.sup.+ or R.sub.4 N.sup.+.

摘要翻译： 本发明涉及用于水溶液或盐水溶液的改进的增粘剂。 通常，增粘剂是N-乙烯基吡咯烷酮/丙烯酰胺/丙烯酸/ N-烷基丙烯酰胺盐的四元共聚物，其中所述四元共聚物具有下式：其中w为约1至约80摩尔％，更优选约5至 约75摩尔％，最优选约10至约70摩尔％; x为约10至约90摩尔％，更优选约20至约80摩尔％，最优选约30至约70摩尔％ y为约0.1至约10.0摩尔％，更优选约0.15至约5.0摩尔％; 最优选约0.2至约3.0摩尔％; z为约1.0至约30.0摩尔％，更优选约2.0至约25.0摩尔％，最优选约5.0至约20.0摩尔％ R是具有约6至约30个碳原子，更优选约7至约20，最优选约8至约18的烷基; 并且M是选自一价阳离子，优选Na +，K +或R 4 N +的阳离子。

公开(公告)号：US4650848A

公开(公告)日：1987-03-17

申请号：US814252

申请日：1985-12-30

申请人： Donald N. Schulz ,  Ilan Duvdevani ,  Jan Bock ,  Enock Berluche

发明人： Donald N. Schulz ,  Ilan Duvdevani ,  Jan Bock ,  Enock Berluche

IPC分类号： C08F220/56 ,  C08F20/56

CPC分类号： C08F220/56

摘要： A water soluble terpolymer having the structure: ##STR1## wherein x is selected from the group consisting of ##STR2## wherein x is about 1 to about 95 mole percent; y is about 0.1 to about 5.0 mole percent; R.sub.1 is methyl or hydrogen; z is about 1 to about 30 mole percent; R.sub.2 is an alkyl group of 1-5 carbon atoms; R.sub.3 is an alkyl group of 3 to 4 carbon atoms; R.sub.4 is an alkyl group of 1-5 carbon atoms; and R.sub.5 is an alkyl group of 4-20.

摘要翻译： 具有以下结构的水溶性三元共聚物：其中x选自由下列组成的组：其中x为约1至约95摩尔％; y为约0.1至约5.0摩尔％; R1是甲基或氢; z为约1至约30摩尔％; R2是1-5个碳原子的烷基; R3是3〜4个碳原子的烷基; R4是1-5个碳原子的烷基; R5为4-20的烷基。

公开(公告)号：US20120071605A1

公开(公告)日：2012-03-22

申请号：US12012380

申请日：2008-02-01

申请人： Lisa Saunders Baugh ,  Bryan R. Chapman ,  Enock Berluche

发明人： Lisa Saunders Baugh ,  Bryan R. Chapman ,  Enock Berluche

IPC分类号： C08L45/00 ,  C08L51/06 ,  C08L47/00

CPC分类号： C08L23/0823 ,  C08L23/16 ,  C08L53/00 ,  C08L2314/06 ,  C08L2666/24 ,  C08L2666/06

摘要： This invention relates to a polymer composition comprising a blend comprising: (a) greater than 30 wt (based upon the weight of the composition) of a cyclic olefin polymer having a Tg greater than 60° C. and having a Tm heat of fusion (ΔHf) of 40 J/g or less selected from the group consisting of: i) copolymers comprising at least one acyclic olefin and at least 15 mole % of one or more cyclic olefins; ii) partially or completely hydrogenated copolymers comprising at least one acyclic olefin and at least 15 mole % of one or more cyclic olefins; iii) metathesis copolymers comprising two or more cyclic olefins; iv) partially or completely hydrogenated metathesis copolymers comprising two or more cyclic olefins; v) metathesis homopolymers comprising cyclic olefins; vi) partially or completely hydrogenated metathesis homopolymers comprising cyclic olefins; and vii) mixtures thereof; (b) from 1 to 50 wt % (based upon the weight of the composition) of an acyclic olefin polymer modifier having a glass transition temperature of less than 0° C.; (c) from 0.1 to 50 wt % (based upon the weight of the composition) of a non-functionalized plasticizer having a kinematic viscosity at 100° C. of 3 to 3000 cSt, a viscosity index of 120 or more, a pour point of 0° C. or less and a flash point of 200° C. or more.

摘要翻译： 本发明涉及一种包含共混物的聚合物组合物，其包含：（a）大于30重量％（基于组合物的重量）的Tg大于60℃并具有Tm熔化热的环状烯烃聚合物 40J / g或更低，选自：i）包含至少一种非环烯烃和至少15摩尔％的一种或多种环烯烃的共聚物; ii）部分或完全氢化的共聚物，其包含至少一种非环烯烃和至少15摩尔％的一种或多种环烯烃; iii）包含两个或更多个环烯烃的复分解共聚物; iv）包含两种或多种环烯烃的部分或完全氢化的复分解共聚物; v）包含环烯烃的复分解均聚物; vi）包含环状烯烃的部分或完全氢化的复分解均聚物; 和vii）其混合物; （b）1至50重量％（基于组合物的重量）的玻璃化转变温度低于0℃的无环烯烃聚合物改性剂; （c）0.1至50重量％（基于组合物的重量）的在100℃下的运动粘度为3至3000cSt，粘度指数为120或更大的非官能化增塑剂，倾点 为0℃以下，闪点为200℃以上。

公开(公告)号：US20100159177A1

公开(公告)日：2010-06-24

申请号：US12653744

申请日：2009-12-17

申请人： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Enock Berluche

发明人： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Enock Berluche

IPC分类号： C08L91/00 ,  C07C51/16 ,  C07C57/00 ,  B32B1/08 ,  B32B27/04 ,  A61M1/00

CPC分类号： C08L91/00 ,  C08K5/103 ,  Y10T428/139 ,  Y10T442/20 ,  C08L27/06 ,  C08L67/00 ,  C08L75/04 ,  C08L31/04 ,  C08L33/00

摘要： Provided are compositions, processes for making, and processes for using triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C10 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.

摘要翻译： 提供组合物，制备方法和使用甘油三酯作为增塑剂的方法。 甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 10醛，用氧和/或空气氧化成酸，回收所得酸，并用甘油进行酯化来制备，其中三酯的总碳数 对于大于或等于45重量％的增塑剂，基团为20至25。 这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

公开(公告)号：US07605105B2

公开(公告)日：2009-10-20

申请号：US12025468

申请日：2008-02-04

申请人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

发明人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

IPC分类号： B01J31/18 ,  B01J31/22 ,  C08F4/60 ,  C08F4/80

CPC分类号： C07F15/045 ,  C07F15/04 ,  C08F4/619 ,  C08F10/00 ,  C08F110/02 ,  C08F2500/20 ,  C08F4/7013

摘要： A transition metal ligand complex has the following formula: wherein R1 and R2 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R3 and R4 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R5 represents an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms, provided that R4 and R5 may be joined to form a cyclic structure; R6 represents an alkyl or aryl group having up to 20 carbon atoms; and Mt represents a transition metal selected from Group 7, 8, 9, 10, 11, or 12 of the Periodic Table of the Elements.

摘要翻译： 过渡金属配体络合物具有下式：其中R1和R2（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基; R3和R4（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基; R5表示具有至多20个碳原子的芳基，烷基或环烷基，条件是R 4和R 5可以连接形成环状结构; R6表示具有至多20个碳原子的烷基或芳基; 而Mt表示选自元素周期表第7,8,9,10,11或12族的过渡金属。

公开(公告)号：US07504465B2

公开(公告)日：2009-03-17

申请号：US12214189

申请日：2008-06-17

申请人： Lisa S. Baugh ,  Stephen E. Lehman, Jr. ,  Kenneth B. Wagener ,  Donald N. Schulz ,  Enock Berluche

发明人： Lisa S. Baugh ,  Stephen E. Lehman, Jr. ,  Kenneth B. Wagener ,  Donald N. Schulz ,  Enock Berluche

IPC分类号： C08F216/36

CPC分类号： C08F210/02 ,  C08F210/16 ,  C08F4/80 ,  C08F236/20 ,  C08F2500/02 ,  C08F2500/03 ,  C08F220/10 ,  C08F218/00 ,  C08F218/08 ,  C08F232/00

摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

摘要翻译： 本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1表示极性官能团。 每个B单元，每个D单元和每个B和D单元分开至少四个A单元。 值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数 单位，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < 数学溢出=“滚动”> j = y + h x + y +

公开(公告)号：US07498390B2

公开(公告)日：2009-03-03

申请号：US11904057

申请日：2007-09-25

申请人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

发明人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

IPC分类号： C08F4/69

CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, ps where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.

摘要翻译： 具有式I的组合物，其中R1和R2独立地为氢，C1至C12直链和支链烷基，C3至C12环烷基，芳基，C1至C12烷氧基，F，C1，SO3，C1至C12全氟烷基和N（​​CH3） 2，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基和2,2,2-三氟乙基，A是-C（R 4） - ， - （CH 2） x - ， - （CH 2）x NH（CH 2）x - 或-CY 2 CY 2 - ，其中R 4是烃基，卤代烃基或具有1至12个碳原子的烷氧基，x是1至12的整数， Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，可用于聚合烯烃单体。

公开(公告)号：US07429548B2

公开(公告)日：2008-09-30

申请号：US11204828

申请日：2005-08-16

申请人： Baiyi Zhao ,  Enock Berluche ,  Smita Kacker ,  Jo Ann Marie Canich

发明人： Baiyi Zhao ,  Enock Berluche ,  Smita Kacker ,  Jo Ann Marie Canich

IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J31/00

CPC分类号： C07F15/0066 ,  C07F15/045

摘要： A This invention relates to a composition comprising a catecholate ligand, palladium or nickel, and an ancillary ligand with the following structure: where Pn is a Group-15 element; H is hydrogen; R7 and R8 are independently hydrogen or C1-C30 hydrocarbyl radicals, or both are C1-C30 hydrocarbyl radicals that form a ring structure comprising one or more aromatic or non-aromatic rings; and R13-R18 are, independently, hydrogen or C1-C30 hydrocarbyl radicals. The composition can be used to oligomerize ethylene.

摘要翻译： 本发明涉及包含儿茶酚酸配体，钯或镍的组合物和具有以下结构的辅助配体：其中Pn是15族元素; H是氢; R 7和R 8独立地是氢或C 1 -C 30烃基，或两者都是C 1 -C 6烷基， 形成包含一个或多个芳族或非芳族环的环结构的亚烷基-C 30亚烷基; R 13和R 12独立地是氢或C 1 -C 30烃基。 该组合物可用于使乙烯低聚。

公开(公告)号：US20080221275A1

公开(公告)日：2008-09-11

申请号：US12074213

申请日：2008-02-29

申请人： Lisa S. Baugh ,  Enock Berluche ,  Abhimanyu O. Patil ,  Beverly J. Poole ,  Kevin D. Robinson ,  Kevin R. Squire

发明人： Lisa S. Baugh ,  Enock Berluche ,  Abhimanyu O. Patil ,  Beverly J. Poole ,  Kevin D. Robinson ,  Kevin R. Squire

IPC分类号： C08F4/76 ,  C08F36/00 ,  C08F36/04 ,  C08F4/80

CPC分类号： C08C19/06 ,  C08F8/04 ,  C08F8/08 ,  C08F210/02

摘要： Provided are selected types of terpolymer components comprising terpolymers having monomer units derived from ethylene (E), dicyclopentadiene (DCPD) and norbornene-based (NB) co-monomers. Such terpolymer components have certain specified amounts of each co-monomer as well as certain specified molecular weight and glass transition temperature characteristics. Terpolymer components which are derivatized by hydrogenation and/or by epoxidation and/or hydroxylation are also disclosed, as well as thermoplastic polyolefin compositions which contain the terpolymer components and which have especially desirable structural and thermal properties.Also provided are processes for preparing and derivatizing the terpolymer components herein. Such preparation processes comprise: a) contacting ethylene with a polymerization mixture comprising selected amounts of both DCPD and NB co-monomers, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst under specific polymerization conditions to thereby form the desired ethylene-dicyclopentadiene-norbornene terpolymer components within the polymerization mixture. These terpolymer components can then be subsequently derivatized by hydrogenation or functionalization of the residual double bonds therein.

摘要翻译： 提供了包含来自乙烯（E），二环戊二烯（DCPD）和降冰片烯基（NB））共聚单体的单体单元的三元共聚物的选择类型的三元共聚物组分。 这些三元共聚物组分具有特定量的每种共聚单体以及某些特定的分子量和玻璃化转变温度特性。 还公开了通过氢化和/或通过环氧化和/或羟基化衍生化的三元共聚物组分，以及含有三元共聚物组分并且具有特别期望的结构和热性质的热塑性聚烯烃组合物。 还提供了用于制备和衍生本文中三元共聚物组分的方法。 这样的制备方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在特定的聚合条件下，使乙烯与包含选定量的DCPD和NB共聚单体的聚合混合物接触，从而形成所需的乙烯 - 二环戊二烯 - 降冰片烯三元共聚物组分在聚合混合物内。 然后可以通过氢化或官能化其中的残余双键将这些三元共聚物组分衍生化。

公开(公告)号：US07297805B2

公开(公告)日：2007-11-20

申请号：US11152802

申请日：2005-06-14

申请人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

发明人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

IPC分类号： C07F11/00 ,  C08F4/69

CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.

摘要翻译： 具有式I的组合物，其中R 1和R 2独立地是氢，C 1至C 12直链 和支链烷基，C 3至C 12环烷基，芳基，C 1至C 12烷氧基，F， Cl，SO 3，C 1至C 12全氟烷基和N（​​CH 3 3）2 R 3，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 1〜 C 1 -C 4 - （CH 3） - ，其中C（R 4） - ， x（CH 2）2 - ， - （CH 2 CH 2）x NH 2（CH 2） ）其中R 4是烃基，卤代烃基，卤代烃基， 或1至12个碳原子的烷氧基，x是1至12的整数，Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，可用于聚合烯烃单体。