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    Linear functional copolymers of ethylene with precise and minimum run length distributions and methods of making thereof
    1.
    发明申请
    Linear functional copolymers of ethylene with precise and minimum run length distributions and methods of making thereof 失效
    具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法

    公开(公告)号：US20080312393A1

    公开(公告)日：2008-12-18

    申请号：US12214189

    申请日：2008-06-17

    申请人： Lisa S. Baugh ,  Stephen E. Lehman, JR. ,  Kenneth B. Wagener ,  Donald N. Schulz ,  Enock Berluche

    发明人： Lisa S. Baugh ,  Stephen E. Lehman, JR. ,  Kenneth B. Wagener ,  Donald N. Schulz ,  Enock Berluche

    IPC分类号： C08F4/80

    CPC分类号： C08F210/02 ,  C08F210/16 ,  C08F4/80 ,  C08F236/20 ,  C08F2500/02 ,  C08F2500/03 ,  C08F220/10 ,  C08F218/00 ,  C08F218/08 ,  C08F232/00

    摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

    摘要翻译： 本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1表示极性官能团。 每个B单元，每个D单元和每个B和D单元分开至少四个A单元。 值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数 单位，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < 数学溢出=“滚动”> j = y + h x + y +

    Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof
    2.
    发明授权
    Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof 失效
    具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法

    公开(公告)号：US07402642B2

    公开(公告)日：2008-07-22

    申请号：US10962086

    申请日：2004-10-08

    申请人： Lisa S. Baugh ,  Stephen E. Lehman, Jr. ,  Kenneth B. Wagener ,  Donald N. Schulz ,  Enock Berluche

    发明人： Lisa S. Baugh ,  Stephen E. Lehman, Jr. ,  Kenneth B. Wagener ,  Donald N. Schulz ,  Enock Berluche

    IPC分类号： C08F216/36

    CPC分类号： C08F210/02 ,  C08F210/16 ,  C08F4/80 ,  C08F236/20 ,  C08F2500/02 ,  C08F2500/03 ,  C08F220/10 ,  C08F218/00 ,  C08F218/08 ,  C08F232/00

    摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

    摘要翻译： 本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1 表示极性官能团。 每个B单元，每个D单元和每个B和D单元分开至少四个A单元。 值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数 单位，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < MATH OVERFLOW =“SCROLL”> j = y + h x + y + > <= 0.032

    Linear functional copolymers of ethylene with precise and minimum run length distributions and methods of making thereof
    3.
    发明授权
    Linear functional copolymers of ethylene with precise and minimum run length distributions and methods of making thereof 失效
    具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法

    公开(公告)号：US07504465B2

    公开(公告)日：2009-03-17

    申请号：US12214189

    申请日：2008-06-17

    申请人： Lisa S. Baugh ,  Stephen E. Lehman, Jr. ,  Kenneth B. Wagener ,  Donald N. Schulz ,  Enock Berluche

    发明人： Lisa S. Baugh ,  Stephen E. Lehman, Jr. ,  Kenneth B. Wagener ,  Donald N. Schulz ,  Enock Berluche

    IPC分类号： C08F216/36

    CPC分类号： C08F210/02 ,  C08F210/16 ,  C08F4/80 ,  C08F236/20 ,  C08F2500/02 ,  C08F2500/03 ,  C08F220/10 ,  C08F218/00 ,  C08F218/08 ,  C08F232/00

    摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

    摘要翻译： 本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1表示极性官能团。 每个B单元，每个D单元和每个B和D单元分开至少四个A单元。 值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数 单位，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < 数学溢出=“滚动”> j = y + h x + y +

    Transition Metal Polymerization Catalysts, Their Synthesis And Use In Olefin Polymerization
    5.
    发明申请
    Transition Metal Polymerization Catalysts, Their Synthesis And Use In Olefin Polymerization 失效
    过渡金属聚合催化剂，其在烯烃聚合中的合成和应用

    公开(公告)号：US20080161517A1

    公开(公告)日：2008-07-03

    申请号：US12025468

    申请日：2008-02-04

    申请人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

    发明人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

    IPC分类号： C08F4/80 ,  B01J31/12

    CPC分类号： C07F15/045 ,  C07F15/04 ,  C08F4/619 ,  C08F10/00 ,  C08F110/02 ,  C08F2500/20 ,  C08F4/7013

    摘要： A transition metal ligand complex has the following formula: wherein R1 and R2 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R3 and R4 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R5 represents an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms, provided that R4 and R5 may be joined to form a cyclic structure; R6 represents an alkyl or aryl group having up to 20 carbon atoms; and Mt represents a transition metal selected from Group 7, 8, 9, 10, 11, or 12 of the Periodic Table of the Elements.

    摘要翻译： 过渡金属配体络合物具有下式：其中R 1和R 2（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基 ; R 3和R 4（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基; R 5表示具有至多20个碳原子的芳基，烷基或环烷基，条件是R 4和R 5可以连接到 形成循环结构; R 6表示具有至多20个碳原子的烷基或芳基; 而Mt表示选自元素周期表第7,8,9,10,11或12族的过渡金属。

    Chromium complexes and their use in olefin polymerization
    6.
    发明授权
    Chromium complexes and their use in olefin polymerization 失效
    铬络合物及其在烯烃聚合中的应用

    公开(公告)号：US07498287B2

    公开(公告)日：2009-03-03

    申请号：US11904056

    申请日：2007-09-25

    申请人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    发明人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    IPC分类号： C08F4/69

    CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

    摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful polymerizing olefinic monomers.

    摘要翻译： 具有式I的组合物，其中R1和R2独立地为氢，C1至C12直链和支链烷基，C3至C12环烷基，芳基，C1至C12烷氧基，F，C1，SO3，C1至C12全氟烷基和N（​​CH3） 2，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基和2,2,2-三氟乙基，A是-C（R 4） - ， - （CH 2） x - ， - （CH 2）x NH（CH 2）x - 或-CY 2 CY 2 - ，其中R 4是烃基，卤代烃基或具有1至12个碳原子的烷氧基，x是1至12的整数，Y 是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，有用的是使烯烃单体聚合。

    Transition metal polymerization catalysts, their synthesis and use in olefin polymerization
    8.
    发明授权
    Transition metal polymerization catalysts, their synthesis and use in olefin polymerization 有权
    过渡金属聚合催化剂，它们在烯烃聚合中的合成和应用

    公开(公告)号：US07351845B2

    公开(公告)日：2008-04-01

    申请号：US11333639

    申请日：2006-01-17

    申请人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

    发明人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

    IPC分类号： C07F15/00 ,  C07F9/00 ,  C07F9/02

    CPC分类号： C07F15/045 ,  C07F15/04 ,  C08F4/619 ,  C08F10/00 ,  C08F110/02 ,  C08F2500/20 ,  C08F4/7013

    摘要： A transition metal ligand complex has the following formula: wherein R1 and R2 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R3 and R4 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R5 represents an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms, provided that R4 and R5 may be joined to form a cyclic structure; R6 represents an alkyl or aryl group having up to 20 carbon atoms; and Mt represents a transition metal selected from Group 7, 8, 9, 10, 11, or 12 of the Periodic Table of the Elements.

    摘要翻译： 过渡金属配体络合物具有下式：其中R 1和R 2（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基 ; R 3和R 4（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基; R 5表示具有至多20个碳原子的芳基，烷基或环烷基，条件是R 4和R 5可以连接到 形成循环结构; R 6表示具有至多20个碳原子的烷基或芳基; 而Mt表示选自元素周期表第7,8,9,10,11或12族的过渡金属。

    Transition metal polymerization catalysts, their synthesis and use in olefin polymerization
    9.
    发明授权
    Transition metal polymerization catalysts, their synthesis and use in olefin polymerization 失效
    过渡金属聚合催化剂，它们在烯烃聚合中的合成和应用

    公开(公告)号：US07605105B2

    公开(公告)日：2009-10-20

    申请号：US12025468

    申请日：2008-02-04

    申请人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

    发明人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

    IPC分类号： B01J31/18 ,  B01J31/22 ,  C08F4/60 ,  C08F4/80

    CPC分类号： C07F15/045 ,  C07F15/04 ,  C08F4/619 ,  C08F10/00 ,  C08F110/02 ,  C08F2500/20 ,  C08F4/7013

    摘要： A transition metal ligand complex has the following formula: wherein R1 and R2 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R3 and R4 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R5 represents an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms, provided that R4 and R5 may be joined to form a cyclic structure; R6 represents an alkyl or aryl group having up to 20 carbon atoms; and Mt represents a transition metal selected from Group 7, 8, 9, 10, 11, or 12 of the Periodic Table of the Elements.

    摘要翻译： 过渡金属配体络合物具有下式：其中R1和R2（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基; R3和R4（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基; R5表示具有至多20个碳原子的芳基，烷基或环烷基，条件是R 4和R 5可以连接形成环状结构; R6表示具有至多20个碳原子的烷基或芳基; 而Mt表示选自元素周期表第7,8,9,10,11或12族的过渡金属。

    Chromium complexes and their use in olefin polymerization
    10.
    发明授权
    Chromium complexes and their use in olefin polymerization 失效
    铬络合物及其在烯烃聚合中的应用

    公开(公告)号：US07498390B2

    公开(公告)日：2009-03-03

    申请号：US11904057

    申请日：2007-09-25

    申请人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    发明人： Smita Kacker ,  Enock Berluche ,  Robert T. Stibrany ,  Joseph A. Sissano ,  Lisa S. Baugh

    IPC分类号： C08F4/69

    CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

    摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, ps where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.

    摘要翻译： 具有式I的组合物，其中R1和R2独立地为氢，C1至C12直链和支链烷基，C3至C12环烷基，芳基，C1至C12烷氧基，F，C1，SO3，C1至C12全氟烷基和N（​​CH3） 2，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基和2,2,2-三氟乙基，A是-C（R 4） - ， - （CH 2） x - ， - （CH 2）x NH（CH 2）x - 或-CY 2 CY 2 - ，其中R 4是烃基，卤代烃基或具有1至12个碳原子的烷氧基，x是1至12的整数， Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，可用于聚合烯烃单体。